Scribd
Upload
95 views30 pages

Week 5 Hydrotreating PDF

The document discusses various approaches to deep desulfurization of gasoline, diesel fuel, and jet fuel. It classifies desulfurization processes based on how they transform organosulfur compounds. Various techniques are described to improve the performance of HDS catalysts, including increasing active components, modifying active sites, and using advanced supports. Pathways for the transformation of specific organosulfur compounds over sulfided catalysts are presented. The document also discusses several industrial processes for deep desulfurization including selective naphtha HDS processes, approaches for ultra-deep desulfurization of diesel, and new catalyst technologies.

Uploaded by

Beenxauzai Likegirlcute
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
95 views30 pages

Week 5 Hydrotreating PDF

The document discusses various approaches to deep desulfurization of gasoline, diesel fuel, and jet fuel. It classifies desulfurization processes based on how they transform organosulfur compounds. Various techniques are described to improve the performance of HDS catalysts, including increasing active components, modifying active sites, and using advanced supports. Pathways for the transformation of specific organosulfur compounds over sulfided catalysts are presented. The document also discusses several industrial processes for deep desulfurization including selective naphtha HDS processes, approaches for ultra-deep desulfurization of diesel, and new catalyst technologies.

Uploaded by

Beenxauzai Likegirlcute
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 30

NEW APPROACHES TO DEEP

DESULFURIZATION FOR ULTRA CLEAN


GASOLINE, DIESEL FUEL AND J ET FUEL
CLASSIFICATION OF DESULFURIZATION PROCESSES BASED
ON ORGANOSULFUR COMPOUND TRANSFORMATION
Desulfurization technologies classified by
nature of a key process to remove sulfur
Gasoline production
Formation of sulfur compounds in FCC gasoline
Formation of 2,5-dimethylthiophene through the addition of
H
2
S to hex-1-ene
Typical organosulfur compounds and their hydrotreating pathway
Different approaches to improve HDS
catalyst performance
Increased amount of
active component;
change nature of
active sites (P addition,
nitride, noble metal,
etc.)
application of advanced
support (TiO
2
-Al
2
O
3
, ASA
carbon, zeolite, etc.)
change HDS reaction
route
application of
difference precursons
(carbonyl, chelate
compounds, etc.)
catalysts
preparation using sol
gel techniques;
different
activetion/sulfidation
techniques
Possible pathways for the transformation of 2-
methylthiophene over sulfided CoMo catalysts
Hydrodesulfurization reaction
mechanisms
Hydrodesulfurization reaction
mechanisms
Mechanism of reactive adsorption
desulfurization process
ExxonMobils SCANfining process for selective
naphtha HDS
Relative activities of SCANfining catalyst
for selective cat naphtha HDS
Prime G + process developed IFP
General performance of Prime G +
process developed by IFP
Deep HDS combined with octane recovery
processing
ExxonMobil

OCTGain process of selective naphta HDS


Design approaches to deep desulfurization of
diesel
Approaches to ultra-deep desulfurization include:
1, improving catalytic activity by new catalyst formulation for
HDS of 4,6-DMDBT;
2, tailoring reaction and process condition;
3, designing new reactor configurations;
4, developing new processes.
Design approaches for ultra-deep HDS focus on how to
remove 4,6-DMDBT more effective. One or more
approaches may be employed by a refinery to meet the
challenges of producing ultra-clean fuels at affordable cost
Design approaches to deeep desulfurzation
of diesel
Flow scheme of CDTechs CDHydro +
CDHDS for naphtha desulfurization
ConocoPhillips S-Zorb sulfur removal process based
on solid adsorbent and its continuous regeneration
Relative activity of the new NEBULA and STARS
catalysts compared to conventional CoMo/ Al
2
O
3
developed over the last 50 years

You might also like

pFad - Phonifier reborn

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


Alternative Proxies:

Alternative Proxy

pFad Proxy

pFad v3 Proxy

pFad v4 Proxy