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Alkyl Halide (Quiz Cum Practice Test)

1. The document contains a 15 question quiz on nucleophilic substitution and elimination reactions of alkyl halides. 2. The questions cover identifying slower reactions, reactivity order of alkyl halides, and determining the mechanism and products of substitution and elimination reactions. 3. The key is to match reaction mechanisms - SN1, SN2, E1, E2, and E1cb - to example reactions.

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Akshit Sharma
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1K views2 pages

Alkyl Halide (Quiz Cum Practice Test)

1. The document contains a 15 question quiz on nucleophilic substitution and elimination reactions of alkyl halides. 2. The questions cover identifying slower reactions, reactivity order of alkyl halides, and determining the mechanism and products of substitution and elimination reactions. 3. The key is to match reaction mechanisms - SN1, SN2, E1, E2, and E1cb - to example reactions.

Uploaded by

Akshit Sharma
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOC, PDF, TXT or read online on Scribd
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Alkyl Halide (Quiz Cum Practice Test)

Nucleophilic Substitution and Elimination

Name of the Student


Batch No.

:_____________________
:_____________________

Maximum marks : 45
Maximum Time : 30 minutes

* Each question carries 3 marks and -1 mark will be awarded for each wrong answer in the
case of objective questions only.
1.

Select the slower reaction.


Br

(A)

SCH3

Na SCH3

CH3OH

Br

2.

OCH3

(C)

NaOCH3

CH3 OH

(B)

both take place at same rate.

(D)

None

(B)

both take place at same rate.

(D)

None

Select the slower reaction.


OC2 H5

Br

(A)

C2H5 O
CH3C CH3
P
O

Br
O
OCCH 3

Br
CH3 C O
P

(C)

CH3 C CH3

Br

P
O

3.

Select the molecule that reacts slowest in an SN 2 reaction.


(A)

Br

(C)

4.

OSO 2CF 3

LiSH

EtOH,

Cl

(D)

CH3 CH2Br

(B)

both take place at same rate.

(D)

None

SH

LiSH
EtOH,

(C)

SH

Which will undergo faster SN1 reaction


(A) (CH3 )3 C F
(C) (CH3 )3 C Br

6.

CH3 OH

Which reaction is faster


(A)

5.

(B)

HO

Br
C

(B) (CH3 )3 C Cl
(D) (CH3 )3 C I

H3C

C
(A)

CH3

OH

What is the final product formed in the above reaction and what is the configuration of the
product, if the compound (A) has RS configuration.
7.

H3 C
C
H

OH

CH2CH3
(R - Configuration)

S
Cl

Cl

........................................................

pyridine
........................................................

What are the configuration of products forming in the above reactions.

8.

D
Br
H
H

OH

E2

CH3
H

H
.
What product is formed in the above reaction.

9.

What is the increasing order of reactivity of alkyl halide towards elimination


(A) 3o > 1o > 2o
(B) 1o > 2o > 3o
(C) 3o > 2o > 1o

10.

(D) 2o > 1o > 3o

1 chloro, 1, 2 diphenyl ethane reacts with nucleophile F and (C2H5 )3 N exactly the same
rate because
..

11.

(A)

CH2CH3

CH2CH3

CH

H3CH2C

Cl

OEt

E2

....................................

CH2CH3

(B)
H 3C

CH3

CH3

CH

OEt
Cl
....................................
E2

CH3

What products are formed in the above reaction and in which case rate of reaction is fast?
Me

12.
Me

CH2Br

OEt

X
at 25o C

Me

OEt
at 50o C
Y

Reactions X and Y are


(A) SN1, E1
(C) SN1, E2

(B) SN 2, E2
(D) SN 2, E1

Match the following


Section A
N

13.

Section - B
(a) SN1

H3C

OH

CH3

14.

(b) SN 2

Et 3 N

DMSO

Cl
H

15.

C
H

CH

CHMe

(c) E1

EtO

OH

Solution 13 14 .....
15

(d) E2
(e) E1 CB

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