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8.lectures Blend Dyeing 3-05-04-11

This document discusses various dyeing methods for different fiber blends: 1. It describes 3 different exhaust dyeing processes for wool-polyester blends using acid and disperse dyes, including a 1-bath 1-stage process at 120C. 2. For nylon-polyester blends, it discusses acid/disperse, disperse-only, and acid/disperse processes involving 1 or 2 baths. Dyes must have low affinity for nylon to limit staining. 3. For polyamide-cotton blends, it recommends dyeing cotton first with reactive dyes or acid/premetallised dyes followed by polyamide. Acid or vat dyes

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Shoaib Wahab
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0% found this document useful (0 votes)
136 views2 pages

8.lectures Blend Dyeing 3-05-04-11

This document discusses various dyeing methods for different fiber blends: 1. It describes 3 different exhaust dyeing processes for wool-polyester blends using acid and disperse dyes, including a 1-bath 1-stage process at 120C. 2. For nylon-polyester blends, it discusses acid/disperse, disperse-only, and acid/disperse processes involving 1 or 2 baths. Dyes must have low affinity for nylon to limit staining. 3. For polyamide-cotton blends, it recommends dyeing cotton first with reactive dyes or acid/premetallised dyes followed by polyamide. Acid or vat dyes

Uploaded by

Shoaib Wahab
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Exhaust Dyeing of Wool-polyester

Blends - Acid/Disperse (1)

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Blends (DA blend)Acid/Disperse (2)

2-bath-2-stage process

1-bath-1-stage process

1. Dye polyester (130C)

Dye at boil

Shortest possible dyeing time to avoid


wool damage
2. Dye wool in weakly acidic conditions

- Use carrier for polyester


-pH 4-5

Remove disperse dye on wool by scouring


with non-ionic detergent
Disperse dye staining on wool
wash fastness

Exhaust Dyeing of Wool-polyester


Blends - Acid/Disperse (3)
1-bath-1-stage process
Dye at 120C
Good transfer of disperse dye held on
wool to polyester -+ little cross staining
Require use of wool protection agent

Exhaust Dyeing of nylon-polyester


Blends - AcidlDisperse only (1)
Also pre-metallised/disperse
1-bath-2-stage
Both disperse and acid/pre-metallised in one
dyebath
Generally
1. Nylon dyed at boil pH 4 (acid dyes) or neutral
(pre-metallised)
-+ polyester reserved
2. Polyester dyed by raising temperature to 130C
Must chose dyes with relatively low affinity for
nylon to limit staining

-+

poor

Exhaust Dyeing. of nylon-polyester


Blends - Disperse only
Disperse dyes exhibit substantivity for both
polyester and nylon: can dye both
1-bath-1-stage process
Quick and economical
Disperse dyes have higher affinity for polyester
than nylon
Disperse dyes diffuse more rapidly in nylon than
in polyester
-+Difficulty in producing solid shade
Disperse dye limited to rapidly diffusing range
:. moderate fastness

Exhaust Dyeing of nylon-polyester


Blends - Acid/Disperse only (2)
2-bath-2-stage
Also pre-metallised/disperse
1. Polyester dyed conventionally
2. Reduction clear to remove staining on nylon
3. Nylon dyed in separate dyebath
Lengthy process
Some desorption of dye from polyester in
nylon dyeing stage
-+ lower fastness + contrast effects limited

Dyeing Polyamide-cotton
(AC blend)

Blends

Dyeing Polyamide-cotton Blends


(AC blend) - Acid (pre-met. )/Direct

Polyamide - reactive I acid I premetallised I disperse (nylon only)

Lower fastness levels than using reactive


Ipre-metallised.

Cellulose - direct I reactive I VAT I sulphur


I azoics (last 3 with nylon blends only)

All-in technique can be employed provided


direct dyes are chosen with good nylon
reserve
Acid dyes tend to have low substantivity
for cotton - good reserve

Dyeing Polyamide-cotton Blends


(AC blend) - Acid (or premetallised)/Reactive (1)
Always dyes cotton first (why?)
If use large reactive dyes
Dye cotton first
~reactive dye do not diffuse into nylon; nylon
reserve
Dye nylon with acid or pre-metallised
If use small reactive dye
Dye cotton first
Lower pH to 4 and dye nylon with hydrolysed
reactive dye (acts as acid dye)

Dyeing Polyamide-cotton Blends


(AC blend) - Acid (pre-met.)N AT

Only for nylon (wool and silk hydrolysis)

E.g. continuous dyeing:

pad - fix - pad - fix - wash - oxidise


1. Pad both acid and VAT
2. Steam to fix acid
3. Pad hydros & caustic
4. Steam to fix VAT dye

Dyeing Acrylic-cotton Blends (BC


blend) - Basic/Reactive (1)

Dyeing Acrylic-cotton Blends (BC


blend) - Basic/Reactive (2)

2-bath-2-stage

1-bath-2-stage

Dye acrylic first

Only if:

Dye cotton with warm dyeing reactives


N.B. high temperature dyeing reactives
applied at temp. above Acrylic Tg :. strip
basic dye
Mild soaping of hydolysed reactive

Exhaustion basic dye very high

Complexing agent added to bath before addition of


anionic dye

Dye acrylic first with basic dyes of low


substantivity for cotton

Dye cotton second (if cotton dyed first then


contain anionic sites: would attract basic dyes)

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