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Tabla de Datos Experimentales Experimento Tiempo (Min) Vol. HCL (ML) 1 2 3 4 5 6 7 8 9 10

The document contains the results of an experiment measuring the change in concentration of HCl over time. It includes a table with the experimental data and calculations using the differential and integral methods to determine the rate constant k for the reaction. Using the differential method, a plot of ln(CA) vs ln((ΔCA)/Δt) was made and the slope gave a value of k = 1.55317 M-1 min-1. The integral method using n=2 gave an average k value of 1.00063 M-1 min-1.

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28 views4 pages

Tabla de Datos Experimentales Experimento Tiempo (Min) Vol. HCL (ML) 1 2 3 4 5 6 7 8 9 10

The document contains the results of an experiment measuring the change in concentration of HCl over time. It includes a table with the experimental data and calculations using the differential and integral methods to determine the rate constant k for the reaction. Using the differential method, a plot of ln(CA) vs ln((ΔCA)/Δt) was made and the slope gave a value of k = 1.55317 M-1 min-1. The integral method using n=2 gave an average k value of 1.00063 M-1 min-1.

Uploaded by

DenisRoger
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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Tabla de datos experimentales

Experimento Tiempo (min) Vol. HCl (mL)


1 6 0.01248
2 5.6 0.01164
3 5 0.0104
4 4.5 0.00936
5 4 0.00832
6 3.8 0.007904
7 3.5 0.00728
8 3.1 0.006448
9 3 0.00624
10 --------- ----------

Mtodo Diferencial:

1.- Clculo de la concentracin de NaOH M=CA


V HCl M HCl
MNaOH = V NaOH VNaOH = 10 mL MHCl = 0.0208 M

6 (0.0208)
MNaOH = 10 = 0.01248 M

2.- Clculo de -CA


-CA = C2-C1
-CA = abs (0.011648-0.01248) = 0.000832
3.- Clculo de t
t= t2-t1
t= 6-3 = 3
4.- Calculo de la concentracin A
C 1+C 2
A = 2

0.01248+ 0.011648
A = 2 = 0.012064

5.- Clculo del Ln CA


X= Ln (CA)
X = Ln (0.01248) = -4.3836

C A
6.- Calculo de Ln ( )t

Y = Ln ( Ct )
A

Y = Ln ( 0.000832
3 )= -8.19029

Tabla de resultados mtodo diferencial


Tiempo CA -CA t A X= Ln (CA) Y = Ln

( Ct )
A

0 0.01248 0.000832 3 0.012064 -4.38362792 -8.19029041


3 0.011648 0.001248 3 0.011024 -4.45262079 -7.7848253
6 0.0104 0.00104 3 0.00988 -4.56594947 -7.96714685
9 0.00936 0.00104 3 0.00884 -4.67130999 -7.96714685
12 0.00832 0.000416 3 0.008112 -4.78909302 -8.88343759
15 0.007904 0.000624 3 0.007592 -4.84038632 -8.47797248
18 0.00728 0.000832 3 0.006864 -4.92262442 -8.19029041
21 0.006448 0.000208 3 0.006344 -5.04398527 -9.57658477
24 0.00624 0.00624 3 0.00312 -5.0767751 -6.17538739
27 - - - - - -

7.- De la regresin lineal


b
Y = mx + b m = n = 1.8731 k= e b= 0.4403

k= eb k= e 0.4403 k = 1.55317
Grafica X vs Y
0
-5.1 -5 -4.9 -4.8 -4.7 -4.6 -4.5 -4.4 -4.3
-2

-4
Y = Ln(()/)
-6

-8
f(x) = 1.87x + 0.44
-10

-12

X= Ln (CA)

1.8731
-rA = 1.55317 C A min-1

Mtodo Integral:

-rA= k CnA

d C A n
dt
= k CA

d C A
= k dt
CnA
CA t
dCA

CA 0 C nA
= k 0 dt

CA
1 d C A
k=
t C C nA
A0

Tiempo CA n=1 n = 1.5 n=2 n=3


0 0.01248 - - - -
3 0.011648 0.022 0.209 1.907 158.32
6 0.0104 0.018 0.180 1.717 156.25
9 0.00936 0.011 0.117 1.187 120.48
12 0.00832 0.0098 0.104 1.112 126.33
15 0.007904 0.0034 0.037 0.421 52.02
18 0.00728 0.0045 0.052 0.602 79.48
21 0.006448 0.0057 0.069 0.844 123.41
24 0.00624 0.0013 0.017 0.215 33.96
27 - - - - -

Despus de obtener los valores de K y n con el mtodo diferencial, se tomaron los


valores de n=2 y se calcul la K promedio.
Nota: los valores comienzan a variar es decir subir y bajar con n =1.5 por lo que el valor de n se podra tomar
desde 1.5, dado que se haba obtenido anteriormente los valores de k y n se opt por tomar el valor de n=2
para obtener el valor de k

1.907+ 1.717+1.187+1.112+ 0.421+ 0.602+ 0.844+0.215


k= 8

2
k= 1.00063 C A min-1

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