For Sales & Service Contact

Operating manual

2650 E. 40th Ave. Denver, CO 80205

Phone 303-320-4764 Fax 303-322-7242
1-800-833-7958
www.geotechenv.com

Multi 340i

79 O

17
2 mg
/l

6 C
M ARng TP

STO
CAL
RCL
O

AR

pH/Dissolved Oxygen/Conductivity
Measuring Instrument

ba52318e02 03/2004
Accuracy when The use of advanced technology and the high quality standard of our
going to press instruments are the result of continuous development. This may result
in differences between this operating manual and your instrument. Al-
so, we cannot guarantee that there are absolutely no errors in this man-
ual. Therefore, we are sure you will understand that we cannot accept
any legal claims resulting from the data, figures or descriptions.

Warranty We guarantee the instrument described for 3 years from the date of
purchase.
The instrument warranty covers manufacturing faults that are discov-
ered within the warranty period. The warranty does not cover compo-
nents that are replaced during maintenance work, e.g. batteries.
The warranty claim extends to restoring the instrument to readiness for
use but not, however, to any further claim for damages. Improper han-
dling or unauthorized opening of the instrument invalidates any warran-
ty claim.
To ascertain the warranty liability, return the instrument and proof of
purchase together with the date of purchase freight paid or prepaid.

Copyright Weilheim 2004, WTW GmbH

Reproduction in whole - or even in part - is prohibited without the ex-
press written permission of WTW GmbH, Weilheim.
Printed in Germany.
Multi 340i List of contents

1 Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
1.1 General features . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
1.2 SETs of equipment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
1.3 Keypad . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
1.4 Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
1.5 Jack field . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
1.6 Operating structure . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

2 Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
2.1 Authorized use . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
2.2 General safety instructions . . . . . . . . . . . . . . . . . . . . . . . 12

3 Commissioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
3.1 Scope of delivery . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
3.2 Initial commissioning . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

4 Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
4.1 Switching on the measuring instrument . . . . . . . . . . . . . 15
4.2 pH value / ORP voltage . . . . . . . . . . . . . . . . . . . . . . . . . 16
4.2.1 General information . . . . . . . . . . . . . . . . . . . . . . 16
4.2.2 Measuring the pH value . . . . . . . . . . . . . . . . . . 18
4.2.3 Measuring the ORP voltage . . . . . . . . . . . . . . . 19
4.2.4 pH calibration . . . . . . . . . . . . . . . . . . . . . . . . . . 20
4.3 Dissolved oxygen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
4.3.1 General information . . . . . . . . . . . . . . . . . . . . . . 26
4.3.2 Measuring the D. O. concentration . . . . . . . . . . 27
4.3.3 Measuring the D. O. saturation . . . . . . . . . . . . . 28
4.3.4 AutoRead AR (Drift control) . . . . . . . . . . . . . . . 29
4.3.5 D. O. calibration . . . . . . . . . . . . . . . . . . . . . . . . 30
4.3.6 Salt content correction . . . . . . . . . . . . . . . . . . . 33
4.4 Conductivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
4.4.1 General information . . . . . . . . . . . . . . . . . . . . . . 34
4.4.2 Measuring the conductivity . . . . . . . . . . . . . . . . 36
4.4.3 Measuring the salinity . . . . . . . . . . . . . . . . . . . . 36
4.4.4 AutoRead AR (Drift control) . . . . . . . . . . . . . . . 37
4.4.5 Determining the cell constant (Calibration in the
control standard) . . . . . . . . . . . . . . . . . . . . . . . . 38
4.5 Calibration intervals (Int 3, Int 4, Int 5) . . . . . . . . . . . . . . 41
4.6 Saving data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42
4.6.1 Saving manually . . . . . . . . . . . . . . . . . . . . . . . . 42
4.6.2 Switching on AutoStore (Int 1) . . . . . . . . . . . . . 44
4.6.3 Outputting the data storage . . . . . . . . . . . . . . . . 46
4.6.4 Clearing the memory . . . . . . . . . . . . . . . . . . . . . 52
4.7 Transmitting data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
4.7.1 Data transmission interval (Int 2) . . . . . . . . . . . 53

3
List of contents Multi 340i

4.7.2 PC/external printer (RS232 interface) . . . . . . . . 55

4.7.3 Remote control . . . . . . . . . . . . . . . . . . . . . . . . . 55
4.8 Configuration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56
4.9 Reset . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60

5 Maintenance, cleaning, disposal . . . . . . . . . . . . . . . . . 63

5.1 Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
5.2 Cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64
5.3 Disposal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64

6 What to do if... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
6.1 pH system messages . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
6.2 Oxi system messages . . . . . . . . . . . . . . . . . . . . . . . . . . . 67
6.3 Conductivity system messages . . . . . . . . . . . . . . . . . . . 68
6.4 General errors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69

7 Technical data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71

8 Lists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77

4
Multi 340i Overview

1 Overview
1.1 General features
The compact precision handheld meter Multi 340i enables you to carry
out pH measurements, dissolved oxygen (D. O.) measurements and
conductivity measurements quickly and reliably.
The Multi 340i handheld meter provides the maximum degree of oper-
ating comfort, reliability and measuring certainty for all applications.

The proven MultiCal and OxiCal calibration procedures and the pro-
cedures to determine/set up the cell constant support you in your work
with the meter. The special AutoRead function enables precise mea-
surements.

79 O

17
2 mg
/l

6 C
2
M ARng TP

STO
CA L
RCL
O

AR 1

1 Keypad
2 Display
3 Jack field

Note
If you need further information or application notes, you can obtain the
following material from WTW:
l Application reports
l Primers
l Safety datasheets.

You will find information on available literature in the WTW catalog or

via the Internet.

5
Overview Multi 340i

1.2 SETs of equipment

The measuring instrument is also available as part of individual SETs
of equipment.
You will find additional information on this and other accessories in the
WTW catalog or via the Internet.

16
15
14 17

18

13

12 19

9 8

10 7

11 6
5 5

4 4

2
3

1
Set (sample configuration):

1 Multi 340i meter, carrying strap with 2 carrying clips, armoring

2 Cond/Oxi beaker with beaker clip
3 pH beaker
4 Stand
5 Plastic beaker
6 Storing solution for pH electrodes

6
Multi 340i Overview

7 50 ml pH buffer solution, STP 4

8 50 ml pH buffer solution, STP 7
9 Calibration and control standard for conductivity measuring
cells, 50 ml
10 50 ml ELY/G electrolyte solution for D.O. probes
11 50 ml RL/G cleaning solution for D.O. probes
12 WP 90/3 exchange membrane heads for D. O. probes
(3 pieces)
13 SF 300 abrasive film for D.O. probes
14 Conductivity measuring cell
TetraCon 325-3 or
TetraCon 325
15 pH electrode
SenTix 41-3 or
SenTix 41
16 Oxygen sensor
CellOx 325-3 or
CellOx 325
17 Operating manual + short operating manual
18 Equipment case
19 Plug-in power supply unit

7
Overview Multi 340i

1.3 Keypad

M STO

CAL RCL AR

RUN/ENTER

Key functions Select the measured variable <M>:

M
pH value / ORP voltage
D. O. concentration / D. O. saturation
Conductivity / salinity
Save a measured value
STO
<STO>

Switch measuring instrument on/off

<ON/OFF>

Calibrate the currently set measured variable

CAL
<CAL>

Display/transmit measured values

RCL
<RCL>

Activate/deactivate the AutoRead function

AR
<AR>

Select the measuring mode, increase values,

scroll
< >
Select the measuring mode, decrease values,
scroll
<>

RUN/ENTER Confirm entries, start AutoRead,

output measured values
<RUN ENTER>

8
Multi 340i Overview

1.4 Display

Status display

TDS UpH O Sal

mV/pH Sensor symbol
S % mg/l

1888
Time Baud
m S/cm
mbarM cm
1/ cmSal
Meas. value display

8 8 .8 F % /K TP
C Function and
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

temperature display
LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

1.5 Jack field

1 2 3

1 D. O. probe or conductivity measuring cell

2 pH electrode
3 pH temperature sensor
4 Plug-in power supply unit
5 RS232 serial interface

9
Overview Multi 340i

1.6 Operating structure

The following overview diagram shows which keys you have to press
to select between the different measuring modes:

Note
When a D. O. probe or a conductivity measuring cell with a temperature
probe is connected, the measuring instrument recognizes the probe or
measuring cell and automatically switches to the oxygen measuring
mode or conductivity measuring mode last selected. As soon as the
probe/measuring cell is disconnected, the instrument switches to the
pH or ORP measuring mode.

10
Multi 340i Safety

2 Safety
This operating manual contains basic instructions that you must follow
during the commissioning, operation and maintenance of the measur-
ing instrument. Consequently, all responsible personnel must read this
operating manual carefully before working with the measuring system.
The operating manual must always be available within the vicinity of the
measuring system.

Target group The measuring instrument was developed for work in the field and in
the laboratory.
Thus, we assume that, as a result of their professional training and ex-
perience, the operators will know the necessary safety precautions to
take when handling chemicals.

Safety instructions The individual chapters of this operating manual use the following safe-
ty instruction to indicate various types of danger:

Warning
indicates instructions that must be followed precisely in order to avoid
the possibility of slight injuries or damage to the instrument or the envi-
ronment.

Further notes

Note
indicates notes that draw your attention to special features.

Note
indicates cross-references to other documents, e.g. operating manu-
als.

2.1 Authorized use

The authorized use of the measuring instrument consists exclusively of
the:
l pH and ORP measurement
l measurement of the oxygen content and
l measurement of the conductivity, salinity and temperature
in the field and laboratory.

The technical specifications as given in chapter 7 TECHNICAL DATA must

be observed. Only the operation and running of the measuring instru-
ment according to the instructions given in this operating manual is au-
thorized. Any other use is considered to be unauthorized.

11
Safety Multi 340i

2.2 General safety instructions

This instrument is built and inspected according to the relevant guide-
lines and norms for electronic measuring instruments (see chapter 7
TECHNICAL DATA).
It left the factory in a safe and secure technical condition.

Function and operating The smooth functioning and operational safety of the measuring instru-
safety ment can only be guaranteed if the generally applicable safety mea-
sures and the specific safety instructions in this operating manual are
followed during operation.

The smooth functioning and operational safety of the measuring instru-

ment can only be guaranteed under the environmental conditions that
are in specified in chapter 7 TECHNICAL DATA.

If the instrument was transported from a cold environment to a warm

environment, the formation of condensate can lead to the faulty func-
tioning of the instrument. In this event, wait until the temperature of the
instrument reaches room temperature before putting the instrument
back into operation.

Safe operation If safe operation is no longer possible, the instrument must be taken out
of service and secured against inadvertent operation!
Safe operation is no longer possible if the measuring instrument:
l has been damaged in transport
l has been stored under adverse conditions for a lengthy period of
time
l is visibly damaged
l no longer operates as described in this manual.

If you are in any doubt, please contact the supplier of the instrument.

Obligations of the pur- The purchaser of the measuring instrument must ensure that the fol-
chaser lowing laws and guidelines are observed when using dangerous sub-
stances:
l EEC directives for protective labor legislation
l National protective labor legislation
l Safety regulations
l Safety datasheets of the chemical manufacturers.

12
Multi 340i Commissioning

3 Commissioning
3.1 Scope of delivery
l Multi 340i handheld meter
l Plug-in power supply unit
l Operating manual and short operating manual
l 4 batteries, 1.5 V Mignon type AA (in the instrument)

For details of scope of delivery of SETs, see section 1.2 SETS OF

EQUIPMENT and WTW catalog.

3.2 Initial commissioning

Perform the following activities:
l Set the date and time
l Connect the plug-in power supply (optional)

Setting the date and

1 Press the <M> key and hold it down.
time
2 Press the <ON/OFF> key.
The display test appears briefly on the display.
3 Press the <RUN/ENTER> key repeatedly until the date ap-
pears on the display.
4 Set the date of the current day with <> <>.
5 Confirm with <RUN/ENTER>.
The date (month) flashes in the display.
6 Set the current month with <> <>.
7 Confirm with <RUN/ENTER>.
The year appears on the display.
8 Set the current year with <> <>.
9 Confirm with <RUN/ENTER>.
The hours flash on the display.
10 Set the current time with <> <>.
11 Confirm with <RUN/ENTER>.
The minutes flash on the display.
12 Set the current time with <> <>.

13
Commissioning Multi 340i

13 Confirm with <RUN/ENTER>.

The instrument switches to a measuring mode.
14 Switch the instrument off using <ON/OFF>.

Connecting the You can either operate the measuring instrument with batteries or with
plug-in power supply the plug-in power supply. The plug-in power supply supplies the mea-
suring instrument with low voltage (12 VDC). This saves the batteries.

Warning
The line voltage at the operating site must lie within the input voltage
range of the original plug-in power supply (see chapter 7 TECHNICAL DA-
TA).

Warning
Use original plug-in power supplies only (see
chapter 7 TECHNICAL DATA).

1
3

1 Plug the jack (1) into the socket (2) of the measuring instru-
ment.
2 Connect the original WTW plug-in power supply (3) to an easily
accessible mains socket.

14
Multi 340i Operation

4 Operation
4.1 Switching on the measuring instrument

1 Press the <ON/OFF> key.

The display test appears briefly on the display.
After this, the measuring instrument automatically switches to
the measuring mode.

Measuring mode when Connected sensor Measuring mode

switching on
No sensor or pH/ORP electrode pH or ORP measurement (de-
pending on the last selected set-
ting)
D. O. probe or conductivity mea- Last selected measuring mode
suring cell
2 sensors of any type Last selected measuring mode

Note
The measuring instrument has an energy saving feature to avoid un-
necessary battery depletion. The energy saving feature switches the
measuring instrument off if no key has been pressed for an hour.

The energy saving feature is not active

l if the power is supplied by the plug-in power supply,
l if the AutoStore function is active,
l if the communication cable and a PC with a running communication
program are connected,
l if the printer cable is connected (for external printers).

AutoRange measure- There are several measuring ranges available for both oxygen and
ment range selection conductivity measurements. As a rule, the measuring instrument is in
the measuring range with the highest possible resolution. If a measur-
ing range is exceeded, AutoRange causes the measuring instrument to
change automatically to the next higher measuring range.
The AutoRange function is always active with oxygen and conductivity
measurements and cannot be switched off.

Note
The measuring ranges for oxygen and conductivity measurements can
be found in chapter 7 TECHNICAL DATA.

15
Operation Multi 340i

4.2 pH value / ORP voltage

4.2.1 General information

Preparatory activities Perform the following preparatory activities when you want to measure:

1 Connect the pH electrode to the measuring instrument.

If necessary, press the <M> key repeatedly until the status dis-
play pH (pH measurement) or U (measurement of the ORP
voltage) appears.
2 Adjust the temperature of the buffer solutions or test solutions,
or measure the current temperature, if you measure without a
temperature sensor.
3 Calibrate or check the measuring instrument with the elec-
trode.
4 Using < > <>, toggle between the pH or mV measuring
modes.

Note
Incorrect calibration of pH electrodes leads to incorrect measured val-
ues. Calibrate regularly before measuring. You can only connect elec-
trodes of the NTC30 type or without temperature sensor.

Warning
When connecting an earthed PC/printer, measurements cannot be per-
formed in earthed media as incorrect values would result. The RS232
interface is not galvanically isolated.

16
Multi 340i Operation

Temperature measure- You can perform pH measurements with or without a temperature sen-
ment in pH measure- sor as well as with the temperature sensor of an oxygen sensor or a
ments conductivity measuring cell. The measuring instrument recognizes
which sensors are connected and switches automatically to the correct
mode for the temperature measurement.

The following cases are distinguishable.

Temperature sensor Display Mode

pH Cond or
Oxi
yes - TP Automatic with
pH temperature sensor
yes yes TP
- - Manual
- yes TP The temperature value of the
flashes second probe (Cond or Oxi) in
the same sample is taken
over for the pH measurement*
* If you do not wish that, you can:
either disconnect the 2nd sensor and use the manual temperature
input or
use an electrode with a temperature sensor.
If a temperature sensor is connected, it is indicated on the display by
TP.

Note
When calibrating without a temperature sensor (no TP display indicator
displayed), enter the current temperature of the respective buffer solu-
tion manually using the <> <> keys while keeping the <RUN/EN-
TER> key depressed.

17
Operation Multi 340i

4.2.2 Measuring the pH value

1 Perform the preparatory activities according to section 4.2.1.

2 Immerse the pH electrode in the test sample.
3 Press the <> <> keys until pH appears in the status display.
The pH value appears on the display.

TDS U pHO Sal

mV/pH
S % mg/l

1699
Time Baud
m S/cm
mbarM cm
1/ cmSal
8248 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

4 When measuring without a connected temperature sensor:

Options:
l Determine the current temperature using a thermometer
and, while keeping the <RUN/ENTER> key depressed, en-
ter this temperature value with <> <>.
l TP display indicator not displayed, socket for the second
probe is free:
Connect the second probe (Oxi or Cond) and immerse it in
the same sample. TP flashes, the temperature is automati-
cally measured using the second probe.

AutoRead AR The AutoRead function (drift control) checks the stability of the mea-
(Drift control) surement signal. The stability has a considerable impact on the repro-
ducibility of the measured values.

For identical measurement conditions, the following criteria apply:

Reproducibility Response time

Better than 0.02 > 30 seconds

1 Call up the pH measuring mode with <> <>.

2 Activate the AutoRead function with <AR>.
The current measured value is frozen (hold function).

18
Multi 340i Operation

3 Start AutoRead with <RUN/ENTER>.

AR flashes until a stable measured value is reached.
This measured value is transmitted to the interface.
4 If necessary, start the next AutoRead measurement with
<RUN/ENTER>.
5 To terminate the AutoRead function: Press the <AR> key.

Note
The current AutoRead measurement can be terminated at any time
(accepting the current value) by pressing <RUN/ENTER>.

4.2.3 Measuring the ORP voltage

In conjunction with an ORP electrode, e.g. SenTix ORP, the measuring

instrument can measure the ORP voltage (U) of a solution.

1 Perform the preparatory activities according to section 4.2.1.

2 Submerse the Redox electrode in the sample.
3 Press the <> <> keys until the U status display appears.
The ORP voltage (mV) of the sample appears on the display.
4 Wait for a stable measured value.

TDS U pHO Sal

mV/pH
S % mg/l

1823
Time Baud
m S/cm
mbarM cm
1/ cmSal
8248 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

Note
ORP electrodes are not calibrated. However, you can check ORP elec-
trodes using a test solution.

19
Operation Multi 340i

4.2.4 pH calibration

Why calibrate? pH electrodes age. This changes the asymmetry (zero point) and slope
of the pH electrode. As a result, an inexact measured value is dis-
played. Calibration determines the current values of the asymmetry
and slope of the electrode and stores them in the measuring instru-
ment. Thus, you should calibrate at regular intervals.

When to calibrate? l After connecting another electrode

l When the sensor symbol flashes:
after the calibration interval has expired
after a voltage interruption, e. g. after changing the batteries

AutoCal TEC is specially matched to the WTW technical buffer solutions as a fully au-
tomatic two-point calibration. The buffer solutions are automatically
recognized by the measuring instrument. Depending on the instrument
setting (see section 4.8 CONFIGURATION), the instrument displays the
relevant buffer nominal value or the current electrode voltage in mV.
The calibration can be terminated after the first buffer solution. This cor-
responds to a single-point calibration. To do this, the instrument uses
the Nernst slope (-59.2 mV/pH at 25 C) and determines the asymme-
try of the electrode.

AutoRead The calibration procedure automatically activates the AutoRead func-

tion.
The current AutoRead measurement can be terminated at any time
(accepting the current value) by pressing <RUN/ENTER>.

Displaying the calibra- You can view the data of the last calibration on the display. The pro-
tion data ceeding is described on page 48.

Printing the The calibration record contains the calibration data of the current cali-
calibration protocol bration. You can transmit the calibration protocol to a printer via the se-
rial interface (see OUTPUTTING THE CALIBRATION PROTOCOL ON THE
INTERFACE, page 51).

Note
You can automatically print a calibration record after the calibration. To
do so, connect a printer to the interface according to section 4.7.2 be-
fore calibrating. After a valid calibration, the record is printed.

20
Multi 340i Operation

Sample printout:

CALIBRATION PROTOCOL
02.03.01 14:19
Device No.: 12345678
Calibration pH
Cal time: 01.03.01 / 15:20
Cal interval: 7d
AutoCal TEC Tauto
Buffer 1 2.00
Buffer 2 4.01
Buffer 3 7.00 *
Buffer 4 10.00
C1 184.1 mV 25.0C
C2 3.0 mV 25.0C
S1 -59.4 mV/pH
ASY1 - 4 mV
Probe: +++

Calibration evaluation After calibrating, the measuring instrument automatically evaluates the
calibration. The asymmetry and slope are evaluated separately. The
worst evaluation appears on the display.

Display Asymmetry Slope

[mV] [mV/pH]
-15 ... +15 -60.5 ... -58

-20 ... +20 -58 ... -57

-25 ... +25 -61 ... -60.5

or
-57 ... -56

-30 ... +30 -62 ... -61

or
-56 ... -50

Clean the electrode according

to the electrode operating
manual
< -30 or ... -62 or
E3
> 30 ... -50
Eliminate the error according to
chapter 6 WHAT TO DO IF...

21
Operation Multi 340i

Preparatory activities
1 Connect the pH electrode to the measuring instrument.
If necessary, press the <M> key repeatedly until the status dis-
play pH (pH measurement) or U (measurement of the ORP
voltage) appears.
2 Keep the buffer solutions ready.
3 Adjust the temperature of the solution and measure the current
temperature if the measurement is made without the use of a
temperature sensor (the TP display indicator is missing from
the display).

AutoCal TEC For this procedure, use any two WTW technical buffer solutions (pH
values at 25 C: 2.00 / 4.01 / 7.00 / 10.01).

Note
The calibration for pH 10.01 is optimized for the WTW technical buffer
solution TEP 10 Trace or TPL 10 Trace. Other buffer solutions can lead
to an erroneous calibration. The correct buffer solutions are given in the
WTW catalog or in the Internet.

Note
The buffer solutions are automatically recognized by the measuring in-
strument. Depending on the instrument setting (see section
4.8 CONFIGURATION), the instrument displays the relevant buffer nomi-
nal value or the current electrode voltage in mV.

Note
Skip the steps 2 and 7 if you use a pH electrode with temperature sen-
sor or the temperature sensor of a conductivity measuring cell or a D.
O. probe.

Starting the calibration

1 Press the <CAL> key. The Ct1 display and the function display
AutoCal TEC appears. The sensor symbol displays the evalu-
ation of the last calibration (or no sensor symbol in the delivery
state or after the measurement parameter has been reset).

22
Multi 340i Operation

TDS U pHO Sal

mV/pH
S % mg/l

1C t 1
Time Baud
m S/cm
mbarM cm
1/ cmSal
8248 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

2 If required, enter the temperature of the first buffer solution,

while keeping the <RUN/ENTER> key depressed, using <>
<>.
3 Immerse the pH electrode in the first buffer solution.
4 Press the <RUN/ENTER> key.
The AR display indicator flashes.
The electrode voltage (mV) or the buffer nominal value ap-
pears on the display. Example:

pH O
TDS UpH Sal pH O
TDS UpH Sal
mV
mV/pH mV/pH
S % mg/l S % mg/l

1733
Time Baud
m S/cm
mbarM cm
1/ cmSal
1700
Time Baud
m S/cm
mbarM cm
1/ cmSal
0248 F % /K TP
C 0248 F % /K TP
C
Day.Month No. Day.Month No.
Year Ident Year Ident

Tref25 Tref20 AutoCal DIN Auto Store Tref25 Tref20 AutoCal DIN Auto Store
LoBat nLF Lin Cal AutoCal TEC ARng AR RCL LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

5 When the measured value is stable, Ct2 appears.

TDS U pHO Sal

mV/pH
S % mg/l

1C t 2
Time Baud
m S/cm
mbarM cm
1/ cmSal
8248 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

Note
At this point, the AutoCal TEC calibration can be terminated with <M>.
This corresponds to a single-point calibration. To do this, the instru-
ment uses the Nernst slope (-59.2 mV/pH at 25 C) and determines the
asymmetry of the electrode.

23
Operation Multi 340i

6 Thoroughly rinse the electrode with distilled water.

7 If required, enter the temperature of the first buffer solution,
while keeping the <RUN/ENTER> key depressed, using <>
<>.
8 Immerse the pH electrode in the second buffer solution.
9 Press the <RUN/ENTER> key.
The AR display indicator flashes.
The electrode voltage (mV) or the buffer nominal value ap-
pears on the display. Example:

pH O
TDS UpH Sal pH O
TDS UpH Sal
mV
mV/pH mV/pH
S % mg/l S % mg/l

1184
Time Baud
m S/cm
mbarM cm
1/ cmSal
1401
Time Baud
m S/cm
mbarM cm
1/ cmSal
0248 F % /K TP
C 0248 F % /K TP
C
Day.Month No. Day.Month No.
Year Ident Year Ident

Tref25 Tref20 AutoCal DIN Auto Store Tref25 Tref20 AutoCal DIN Auto Store
LoBat nLF Lin Cal AutoCal TEC ARng AR RCL LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

10 When the measured value is stable, AR disappears. The value

of the slope (mV/pH) appears on the display. The probe symbol
shows the evaluation of the current calibration.

TDS U pHO Sal

mV/pH
S % mg/l

1594
Time Baud
m S/cm
mbarM cm
1/ cmSal
Day.Month No.
Year Ident
SLO F % /K TP
C
Tref25 Tref20 AutoCal DIN Auto Store
LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

11 Press the <RUN/ENTER> key. The value of the asymmetry

(mV) appears on the display.

24
Multi 340i Operation

TDS U pHO Sal

mV
S % mg/l

1602
Time Baud
m S/cm
mbarM cm
1/ cmSal
8ASY F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

12 Switch to the measuring mode with <M>.

25
Operation Multi 340i

4.3 Dissolved oxygen

4.3.1 General information

Note
D. O. measurements with the Multi 340i can only be carried out using
a CellOx 325 or StirrOx G D. O. probe. The stirrer of the StirrOx G
D. O. probe has to be supplied with voltage separately using the
NT/pH Mix 540 power supply.

You can measure the following variables:

l D. O. concentration
l D. O. saturation

The measuring instrument is supplied with the following functions:

l AutoRange (automatic switchover of the measurement range),
l The AutoRead function (drift control) for checking the stability of the
measurement signal. This ensures the reproducibility of the measur-
ing signal. For details of how to switch the AutoRead function on/off,
see page 29.

Warning
When connecting an earthed PC/printer, measurements cannot be per-
formed in earthed media as incorrect values would result.
The RS232 interface is not galvanically isolated.

Preparatory activities Perform the following preparatory activities when you want to measure:

1 Connect the D. O. probe to the measuring instrument. The in-

strument automatically switches over to D. O. measurement
(O2 status display).
If the D. O. probe is already connected, press the <M> repeat-
edly until the O2 status display appears.
2 Calibrate or check the measuring instrument with the sensor.
How to calibrate is described in section 4.3.5 from page 20.
3 Use <> <> to toggle between the measuring modes, D. O.
concentration (mg/L) and D. O. saturation (%).

Note
Incorrect calibration of D. O. probes will result in incorrect
measured values. Calibrate at regular intervals.

Temperature sensor The D. O. probe has an integrated temperature sensor that always
measures the current temperature of the test sample.

26
Multi 340i Operation

4.3.2 Measuring the D. O. concentration

When measuring the concentration of test samples with a salt content

of more than 1 g/l, a salinity correction is required.

Note
How to enter the current salt content is described in section 4.3.6 SALT
CONTENT CORRECTION on page 33.
Switching the salt content correction on or off, see below.

To measure the D. O. concentration with and without salt content cor-

rection, proceed as follows:

1 Perform the preparatory activities according to section 4.3.1.

2 Immerse the D. O. probe in the test sample.
3 Press the <> <> key repeatedly until the D. O. concentra-
tion in mg/l appears on the display.

TDS U pHO Sal

mV/pH
S % mg/l

1792
Time Baud
m S/cm
mbarM cm
1/ cmSal
8176 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

Switching on/off the salt Proceed as follows to switch on the salt content correction:
content correction
1 Perform the preparatory activities according to section 4.3.1.
2 Immerse the D. O. probe in the test sample.
3 While pressing the <RUN/ENTER> key, switch on the salt con-
tent correction with <> . The SAL display indicator appears
on the display. The specified salt content is taken into consid-
eration during the measurement.

27
Operation Multi 340i

TDS UpH O Sal

mV/pH
S % mg/l

1542
Time Baud
m S/cm
mbarM cm
1/ cmSal
8176 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

4 While pressing the <RUN/ENTER> key, switch off the salt con-
tent correction with <>. The SAL display indicator is no longer
displayed.

4.3.3 Measuring the D. O. saturation

You can measure the D. O. saturation as follows:

1 Perform the preparatory activities according to section 4.3.1.

2 Immerse the D. O. probe in the test sample.
3 Press the <> <> key repeatedly until the D. O. saturation in
% appears on the display.

TDS UpH O Sal

mV/pH
S % mg/l

1892
Time Baud
m S/cm
mbarM cm
1/ cmSal
8176 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

28
Multi 340i Operation

4.3.4 AutoRead AR (Drift control)

The AutoRead function (drift control) checks the stability of the mea-
surement signal. The stability has a considerable impact on the repro-
ducibility of the measured values.

1 Call up the measuring mode with <M> and/or <> <> .

2 Activate the AutoRead function with <AR>. The current mea-
sured value is frozen (hold function).
3 Start AutoRead with <RUN/ENTER>.
AR flashes until a stable measured value is reached. This mea-
sured value is transmitted to the interface.

TDS UpH O Sal

mV/pH
S % mg/l

1708
Time Baud
m S/cm
mbarM cm
1/ cmSal
8176 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

4 If necessary, start the next AutoRead measurement with

<RUN/ENTER>.
5 To terminate the AutoRead function: Press the <AR> key.

Criteria With identical measurement conditions, the following applies:

Measuring mode Reproducibility Response time

D. O. concentra- Better than 0.05 mg/l > 10 seconds
tion
D. O. saturation in- Better than 0.6 % > 10 seconds
dex

29
Operation Multi 340i

4.3.5 D. O. calibration

Why calibrate? D. O. probes age. This changes the slope of the D. O. probe. Calibra-
tion determines the current slope of the probe and stores this value in
the instrument.

When to calibrate? l After connecting another D. O. probe

l When the probe symbol flashes (after the calibration interval has ex-
pired).

Calibration procedure The calibration is performed in water vapor-saturated air. Use the
OxiCal-SL air calibration vessel (accessories) for the calibration.

AutoRead The calibration procedure automatically activates the AutoRead func-

tion. The AR display indicator flashes. The calibration process is fin-
ished when AR stops flashing.

Displaying the calibra- You can view the data of the last calibration on the display. The pro-
tion data ceeding is described on page 48.

Printing the The calibration record contains the calibration data of the current cali-
calibration protocol bration. You can transmit the calibration protocol to a printer via the se-
rial interface (see page 51).

Note
You can automatically print a calibration record after the calibration. To
do so, connect a printer to the interface according to section 4.7.2 be-
fore calibrating. After a valid calibration, the record is printed.

Sample printout:

CALIBRATION PROTOCOL
02.03.01 14:19
Device No.: 12345678
CALIBRATION 02
Cal time: 02.03.01 / 14:19
Cal interval: 14d
OxiCal Tauto AR
Relative Slope: 0,88
Probe: +++

30
Multi 340i Operation

Probe evaluation After the calibration, the measuring instrument evaluates the current
status of the probe against the relative slope. The evaluation appears
on the display. The relative slope has no effect on the measuring accu-
racy. Low values indicate that the electrolyte will soon be depleted and
the probe will have to be regenerated.

Display Relative slope

S = 0.8 ... 1.25

S = 0.7 ... 0.8

S = 0.6 ... 0.7

S < 0.6 or S > 1.25

E3
Eliminate the error according to
chapter 6 WHAT TO DO IF...

Starting the calibration Proceed as follows to calibrate the instrument:

1 Perform the preparatory activities according to section 4.3.1.

2 Keep the OxiCal-SL air calibration vessel ready.

Note
The sponge in the air calibration vessel must be moist (not wet). Follow
the instructions in the OxiCal-SL operating manual.

3 Put the D. O. probe into the air calibration vessel.

4 Press the <CAL> key repeatedly until the calibration mode ap-
pears. The sensor symbol displays the evaluation of the last
calibration (or no sensor symbol in the delivery state or after the
measurement parameter has been reset).

31
Operation Multi 340i

TDS UpH O Sal

mV/pH
S % mg/l

1C AL
Time Baud
m S/cm
mbarM cm
1/ cmSal
8176 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

5 Press the <RUN/ENTER> key. AutoRead is active, AR flashes.

TDS UpH O Sal

mV/pH
S % mg/l

1088
Time Baud
m S/cm
mbarM cm
1/ cmSal
8176
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN

LoBat nLF Lin Cal AutoCal TEC AR

6 As soon as a stable value is reached, the AR display indicator

stops flashing. The calibration is finished now. The value of the
relative slope appears on the display. The probe symbol shows
the probe evaluation (see page 31).

TDS UpH O Sal

mV/pH
S % mg/l

1088
Time Baud
m S/cm
mbarM cm
1/ cmSal
8176 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

7 Switch to the measuring mode with <M>.

Note
In chapter 6 WHAT TO DO IF... page 65, you will find the measures to
take for error elimination.

32
Multi 340i Operation

4.3.6 Salt content correction

A salt content correction is required in the oxygen concentration mea-

surement of samples with a salt content of more than 1 g/l. To do this,
you have to enter the salinity equivalent of the test sample (range 0.0 -
70.0) and to switch on the salinity correction.

Note
With the Multi 340i handheld meter, you can measure the salinity. How
to proceed is described in section 4.4.3 MEASURING THE SALINITY on
page 36.

Entering the salt con-

1 Determine the salinity of the test sample (any method, see also
tent
section 4.4.3 MEASURING THE SALINITY on page 36).
2 Press the <CAL> key repeatedly until Sal appears on the dis-
play.

TDS UpH O Sal

mV/pH
S % mg/l

155 0
Time Baud
m S/cm
mbarM cm
1/ cmSal
86 96 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

3 Enter the salt content with <> <>.

4 Switch to the measuring mode with <M>.

Note
How to switch on the salt content correction is described on page 27.

33
Operation Multi 340i

4.4 Conductivity

4.4.1 General information

Note
Conductivity measurements with the Multi 340i can only be carried out
using the TetraCon 325 measuring cell.

Warning
When connecting an earthed PC/printer, measurements cannot be per-
formed in earthed media as incorrect values would result.
The RS232 interface is not galvanically isolated.

Preparatory activities Perform the following preparatory activities when you want to measure:

1 Connect a conductivity measuring cell to the measuring instru-

ment. The instrument automatically switches over to conductiv-
ity measurement (status display ).
If the conductivity measuring cell is already connected, press
the <M> key repeatedly until the status display or Sal ap-
pears.
2 Check the selected cell constant or calibrate the measuring in-
strument with the measuring cell (see below).
3 Check the selected cell constant (see below) or calibrate the
measuring instrument with the measuring cell (see section
4.4.5 on page 38).
4 Using < > <>, toggle between the measuring modes, con-
ductivity ( in S/cm) or salinity (SAL).

Temperature probe The TetraCon 325 conductivity measuring cell has a temperature sen-
sor integrated in it. The temperature sensor is shown on the display by
TP.

Temperature The nonlinear temperature compensation is set fixed and is shown on

compensation the display by nLF.

Reference temperature, The reference temperature (Tref) can be switched between 20 C and
Tref 25 C. It appears on the display as Tref20 or Tref25. To switch over the
reference temperature, see SWITCHING OVER THE REFERENCE TEMPERA-
TURE, page 58.

34
Multi 340i Operation

Checking the
1 Press the <RCL> key repeatedly until CAL disp appears on the
cell constant
display.

TDS UpH O Sal

mV/pH
S % mg/l

1C AL
Time Baud
m S/cm
mbarM cm
1/ cmSal
dISP F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

2 Press the <RUN/ENTER> repeatedly until the last calibrated

cell constant is displayed, e. g. 0.472 1/cm.

TDS UpH O Sal

mV/pH
S % mg/l

1C C L
Time Baud
m S/cm
mbarM cm
1/ cmSal
0472 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

3 To return to the measuring mode: Press the <M> key when the
correct cell constant is displayed.
4 If you want to recalibrate the cell constant, proceed according
to section 4.4.5 DETERMINING THE CELL CONSTANT (CALIBRATION
IN THE CONTROL STANDARD) .

35
Operation Multi 340i

4.4.2 Measuring the conductivity

You can carry out the conductivity measurements as follows:

1 Perform the preparatory activities according to section 4.4.1

page 34.
2 Immerse the conductivity measuring cell in the test sample.
3 Press the < > <> keys until in the status display, and the
unit S/cm appears. The conductivity value appears on the dis-
play.

TDS UpH O Sal

mV/pH
S % mg/l

1530
Time Baud
m S/cm
mbarM cm
1/ cmSal
8240 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

4.4.3 Measuring the salinity

You can carry out the salinity measurements as follows:

1 Perform the preparatory activities according to section 4.4.1

page 34.
2 Immerse the conductivity measuring cell in the test sample.
3 Press the <> <> keys until the Sal status display appears.
The salinity value appears on the display.

TDS UpH O Sal

mV/pH
S % mg/l

1323
Time Baud
m S/cm
mbarM cm
1/ cmSal
8212 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

36
Multi 340i Operation

4.4.4 AutoRead AR (Drift control)

The AutoRead function (drift control) checks the stability of the mea-
surement signal. The stability has a considerable effect on the repro-
ducibility of the measured value.

1 Call up the or SAL measuring mode with <M> and/or < >
<>.
2 Immerse the conductivity measuring cell in the test sample.
3 Activate the AutoRead function with <AR>. The current mea-
sured value is frozen (hold function).
4 Start AutoRead with <RUN/ENTER>.
AR flashes until a stable measured value is reached.
This measured value is transmitted to the interface.

TDS UpH O Sal

mV/pH
S % mg/l

1530
Time Baud
m S/cm
mbarM cm
1/ cmSal
8250 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

5 If necessary, start the next AutoRead measurement with

<RUN/ENTER>.
6 To terminate AutoRead: Press the <AR> key.

Note
The current AutoRead measurement can be terminated at any time
(accepting the current value) by pressing <RUN/ENTER>. You can
only change to another measuring mode after completion of AutoRead.

37
Operation Multi 340i

4.4.5 Determining the cell constant (Calibration in the control

standard)

Why determine the cell Aging slightly changes the cell constant, e. g. by coatings. As a result,
constant? an inexact measured value is displayed. The original characteristics of
the cell can often be restored by cleaning the cell. Calibration deter-
mines the current value of the cell constant and stores this value in the
instrument.
Thus, you should calibrate at regular intervals.

In the delivery condition, the cell constant of the measuring instruments

is set to 0.475 cm-1 (conductivity measuring cell TetraCon 325).

AutoRead The calibration procedure automatically activates the AutoRead func-

tion. The AR display indicator flashes. The calibration process is fin-
ished when AR stops flashing.

Displaying the calibra- You can view the data of the last calibration on the display. The pro-
tion data ceeding is described on page 48.

Printing the The calibration record contains the calibration data of the current cali-
calibration protocol bration. You can transmit the calibration protocol to a printer via the se-
rial interface (see page 51).

Note
You can automatically print a calibration record after the calibration. To
do so, connect a printer to the interface according to section 4.7.2 be-
fore calibrating. After a valid calibration, the record is printed.

Sample printout:

CALIBRATION PROTOCOL
14.04.01 11:37
Device No.: 99990000
Calibration Conductivity
Cal time: 14.04.01 / 11:37
Cal interval: 180d
Cal Std.: 0.01 mol/l KCL
40.0 C
Conduct./Tref25: 1413S/cm
Cell Const : 0.478 1/cm
Probe : +++

38
Multi 340i Operation

Calibration evaluation After the calibration, the measuring instrument automatically evaluates
the current status of the calibration. The evaluation appears on the dis-
play.

Display Cell constant [cm-1]

0.450 ... 0.500 cm-1

Outside the range

E3
0.450 ... 0.500 cm-1
Eliminate the error according to
chapter 6 WHAT TO DO IF...

Determining the You can determine the cell constant (conductivity measuring cell Tetra-
cell constant Con 325) as follows:

1 Press the <CAL> key repeatedly until the status display

CAL CELL appears.
2 Press the <RUN/ENTER> key. The CAL display appears, as
well as
the current, calibrated cell constant (with sensor symbol on
the display) or
the fixed cell constant 0.475 1/cm (without sensor symbol
on the display). In this case, the measurement parameters
are initialized (see section 4.9 RESET).

TDS UpH O Sal TDS UpH O Sal

mV/pH mV/pH
S % mg/l S % mg/l

1C AL
Time Baud
m S/cm
mbarM cm
1/ cmSal
1C AL
Time Baud
m S/cm
mbarM cm
1/ cmSal
0472 F % /K TP
C 0475 F % /K TP
C
Day.Month No. Day.Month No.
Year Ident Year Ident

Tref25 Tref20 AutoCal DIN Auto Store Tref25 Tref20 AutoCal DIN Auto Store
LoBat nLF Lin Cal AutoCal TEC ARng AR RCL LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

3 Immerse the conductivity measuring cell in the control standard

solution, 0.01 mol/l KCI.
4 Press the <RUN/ENTER> key.
The AutoRead measurement to determine the cell constant
starts. The AR display indicator flashes until a stable signal is
reached. The cell constant determined is displayed. The mea-
suring instrument automatically stores the cell constants.

39
Operation Multi 340i

TDS UpH O Sal

mV/pH
S % mg/l

1C AL
Time Baud
m S/cm
mbarM cm
1/ cmSal
0473 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

5 To return to the measuring mode: Press the <M> key. The de-
termined cell constant is taken over for the measurement.

Note
If the error message E3 appears, refer to chapter 6 WHAT TO DO IF...

40
Multi 340i Operation

4.5 Calibration intervals (Int 3, Int 4, Int 5)

For each measured variable, a time interval is stored. When it has ex-
pired, you will be reminded to calibrate. After a calibration interval has
expired, the probe symbol of the relevant measured variable flashes. It
is still possible to measure. By calibrating the relevant probe, the func-
tion is reset and the interval starts anew.

The following calibration intervals are set in the factory:

Measured parameter Designation Default setting

pH/ORP Int 3 7 days
Dissolved oxygen Int 4 14 days
Conductivity Int 5 180 days

Setting the calibration You can change each of these intervals (1 ... 999 days):
interval
1 Switch off the measuring instrument.
2 Press the <M> key and hold it down.
3 Press the <ON/OFF> key.
The display test appears briefly on the display. After this, the
measuring instrument automatically switches over to configu-
ration.
4 Press the <RUN/ENTER> key repeatedly, until Int 3 ... 5 to-
gether with the required measured variable (pH, O2 or ) ap-
pears on the display. Example:

TDS UpH O Sal

mV/pH
S % mg/l

1nt 4
Time Baud
m S/cm
mbarM cm
1/ cmSal
d114 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

5 Set the required interval until the next calibration with <>
<>.
6 Confirm with <RUN/ENTER>.
7 Switch to the measuring mode with <M>.

41
Operation Multi 340i

4.6 Saving data

The Multi 340i portable measuring instrument has an internal data
memory. It can store up to 500 datasets.
A complete data record consists of:
l Number of the storage location
l Date/time
l Measured values of the probes connected
l Temperature values of the probes connected
l Temperature measuring procedure
l ID number

You can transmit measured values (data records) to the data storage
in two ways:
l Save manually
l Switch on AutoStore (Int 1), see page 44)

4.6.1 Saving manually

You can transmit a measured value to the data storage as follows:

1 Press the <STO> key.

The current number (location number No.) of the next free stor-
age location appears under the current measured value on the
display.

TDS U pHO Sal

mV/pH
S % mg/l

1699
Time Baud
m S/cm
mbarM cm
1/ cmSal
8244 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

2 Confirm with <RUN/ENTER>.

The display switches to entering the ID number.

42
Multi 340i Operation

TDS U pHO Sal

mV/pH
S % mg/l

1699
Time Baud
m S/cm
mbarM cm
1/ cmSal
8242 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

3 Using <> <>, enter the required ID number

(1 ... 999).
4 Confirm with <RUN/ENTER>.
The measured values are stored. The instrument changes to
the measuring mode.

Message StoFull This message appears when all of the 500 storage locations are occu-
pied.

You have the following options:

Saving the current measured value. Press

The oldest measured value (storage location 1) <RUN/ENTER>
will be overwritten by this
Returning to the measuring mode without saving press any key
Outputting the data storage see
section 4.6.3
Clearing the memory see
section 4.6.4

43
Operation Multi 340i

4.6.2 Switching on AutoStore (Int 1)

The save interval (Int 1) determines the chronological interval between

automatic save processes. After the fixed interval has expired, the cur-
rent data record is transmitted to the internal storage and to the inter-
face.

Switching on AutoStore
1 Press the <RUN/ENTER> key and hold it down.
2 Press the <STO> key. Int 1 appears on the display.

TDS UpH O Sal

mV/pH
S % mg/l

1nt 1
Time Baud
m S/cm
mbarM cm
1/ cmSal
8OFF F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

3 Set the required interval between the saving procedures with

<> <> (Selection: 5 s, 10 s, 30 s, 1 min, 5 min, 10 min,
15 min, 30 min, 60 min).
4 Confirm with <RUN/ENTER>.
The number of free memory locations appears on the display.

TDS UpH O Sal

mV/pH
S % mg/l

1499
Time Baud
m S/cm
mbarM cm
1/ cmSal
Fr ee F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

5 Confirm with <RUN/ENTER>.

The prompt for the ID number appears on the display.

44
Multi 340i Operation

TDS UpH O Sal

mV/pH
S % mg/l

1999
Time Baud
m S/cm
mbarM cm
1/ cmSal
Fr e1 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

6 Set the required ID number with <> <>.

7 Confirm with <RUN/ENTER>.
The measuring instrument switches to the last active measur-
ing mode and start the measuring and saving procedure. Au-
toStore flashes on the display.

As soon as all of the 500 storage locations are occupied, AutoStore is

terminated (Int 1 = OFF). If there are not enough storage locations
available for your measurements:
l Output and backup the data storage (see page 46) and
l clear the memory (see page 52).

Note
The AutoStore function is interrupted if you start other functions, e.g.
output the data storage. After the other function is finished, the Au-
toStore function is continued. By this, however, temporal gaps in the re-
cording of the measured values will occur.

Switching off AutoStore Switch AutoStore off by:

l setting the save interval (Int 1) to OFF, or
l switching the measuring instrument off and then on again.

45
Operation Multi 340i

4.6.3 Outputting the data storage

You can output the contents of the data storage:

l Stored data on the display
l Calibration data on the display
l Stored data on the serial interface
l Calibration protocol to the interface

Outputting stored data

1 Press the <RCL> key repeatedly until StO dISP appears on the
on the display
display.

TDS UpH O Sal

mV/pH
S % mg/l

1ST O
Time Baud
m S/cm
mbarM cm
1/ cmSal
dIsp F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

2 Press the <RUN/ENTER> key.

A measured value appears on the display.
The storage location of the data record is displayed for approx.
2 s, then the respective temperature appears.

TDS UpH O Sal

mV/pH
S % mg/l

1603
Time Baud
m S/cm
mbarM cm
1/ cmSal
8250 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

You can perform the following activities:

Display further data of the data record Press <RUN/ENTER>

(ID number, date, time, storage location)
To toggle between two saved measured vari- Press <RUN/ENTER>
ables + <M>
Advance one data record (storage location) Press <>
Go back one data record (storage location) Press <>

46
Multi 340i Operation

Note
If you want to search for a certain element of the data record (e.g. date),
proceed as follows:

1 Using <RUN/ENTER>, select the element (e.g. date).

2 Press <> or <> repeatedly until the required element ap-
pears on the display.
After approx. 2 s the temperature of the displayed measured
value appears.

Outputting stored data

1 Press the <RCL> key repeatedly until Sto SEr appears on the
to the interface
display.

TDS UpH O Sal

mV/pH
S % mg/l

1St o
Time Baud
m S/cm
mbarM cm
1/ cmSal
Day.Month No.
Year Ident
SER F % /K TP
C
Tref25 Tref20 AutoCal DIN Auto Store
LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

2 Press the <RUN/ENTER> key.

The complete contents of the storage are transmitted to the in-
terface. During the data transmission the instrument incre-
ments the storage numbers. After the data transmission, the
instrument automatically switches to the last active measure-
ment mode.

Note
You can cancel the transmission with <M> or <RUN/ENTER>.

The transmitted data contains the entire contents of the storage in in-
crementing order of the location numbers.

47
Operation Multi 340i

Sample printout:

No. 1:
09.03.01 17:10
pH 10.01 25 C
Tauto AR
Ident : 47

No. 2:
09.03.01 17:12
305 mV
Tauto
Ident : 6

No. 3:
09.03.01 17:24
7.88 mg/l 17.6 C
Tauto
Ident : 81

No. 4:
09.03.01 17:46
7.11 mg/l 17.8 C
Tauto
SAL = 17.9
Ident : 4

No. 5:
10.03.01 19:09
2.40 mS/cm 25.3 C
Tauto
nLF
Tref25 C = 0.475 1/cm
Ident : 10

No. 6:
10.03.01 20:48
2.46 mS/cm 25.6 C
Tauto
nLF
Tref25 C = 0.475 1/cm
Ident : 1
...

Outputting the calibra-

1 Press the <RCL> key repeatedly until CAL disp appears on
tion data
the display.
on the display

TDS UpH O Sal

mV/pH
S % mg/l

1C AL
Time Baud
m S/cm
mbarM cm
1/ cmSal
dISP F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

48
Multi 340i Operation

2 Press the <RUN/ENTER> key.

The data of the last calibration of all measured variables ap-
pears in the following sequence:
l pH: Slope SLO and asymmetry ASY
l Dissolved oxygen: Relative slope SLO
l Cond: Cell constant C
Information concerning the calibration procedure is output as
well.

TDS U pHO Sal

mV/pH
S % mg/l

1594
Time Baud
m S/cm
mbarM cm
1/ cmSal
Day.Month No.
Year Ident
SLO F % /K TP
C
Tref25 Tref20 AutoCal DIN Auto Store
LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

3 Press <RUN/ENTER> to display the value of the asymmetry

(mV).

TDS U pHO Sal

mV
S % mg/l

1601
Time Baud
m S/cm
mbarM cm
1/ cmSal
8ASY F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

4 Press <RUN/ENTER> to display the relative slope of the D. O.

probe.

TDS UpH O Sal

mV/pH
S % mg/l

1088
Time Baud
m S/cm
mbarM cm
1/ cmSal
2SL O F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

49
Operation Multi 340i

5 Press <RUN/ENTER> to display the cell constant. The dis-

played value is:
l the current, calibrated cell constant (with sensor symbol on
the display) or
l the fixed cell constant 0.475 1/cm (without probe symbol on
the display). In this case, the measured parameters are ini-
tialized (see section 4.9 RESET).

TDS UpH O Sal

mV/pH
S % mg/l

14C 8
Time Baud
m S/cm
mbarM cm
1/ cmSal
0478 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

6 With <M> you can switch back to the last active measuring
mode.

50
Multi 340i Operation

Outputting the calibra-

1 Press the <RCL> key repeatedly until CAL SEr appears on the
tion protocol on the
display.
interface

TDS UpH O Sal

mV/pH
S % mg/l

1C AL
Time Baud
m S/cm
mbarM cm
1/ cmSal
dSER F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

2 Press the <RUN/ENTER> key.

The calibration protocol for all measured variables is transmit-
ted to the interface. After the data transmission, the instrument
automatically switches to the last active measurement mode.

Sample printout:

CALIBRATION PROTOCOL
02.03.01 14:19
Device No.: 12345678

Calibration pH
Cal time: 01.03.01 / 15:20
Cal interval: 7d
AutoCal TEC Tauto
Buffer 1 2.00
Buffer 2 4.01
Buffer 3 7.00 *
Buffer 4 10.00
C1 174.1 mV 25.0C
C2 -133.3 mV 25.0C
S1 -59.4 mV/pH
ASY1 - 4 mV
Probe: +++

CALIBRATION 02
Cal time: 02.03.01 / 14:19
Cal interval: 14d
OxiCal Tauto AR
Relative Slope: 0,88
Probe: +++

Calibration Conductivity
Cal time: 14.12.00 / 11:37
Cal interval: 180d
Cal Std.: 0.01 mol/l KCL
40.0 C
Conduct./Tref25: 1413S/cm
Cell Const : 0.478 1/cm
Probe : +++

51
Operation Multi 340i

4.6.4 Clearing the memory

With this function, you can delete the stored data records. 500 storage
locations will then be available again.

Note
The Clear memory function only appears when there are data records
stored in the memory. Otherwise, the measuring instrument automati-
cally switches to the last active measuring mode.

Proceed as follows to clear all data records:

1 Switch off the measuring instrument.

2 Press the <STO> key and hold it down.
3 Press the <ON/OFF> key.
The display test appears briefly on the display.

4 Confirm the clearing process with <RUN/ENTER>.

Pressing any other key prevents the clearing, the data records
will remain stored.

Note
The calibration data remain stored and can be called up.

52
Multi 340i Operation

4.7 Transmitting data

You have the following possibilities of transmitting data:
l One of the following options:
With the AutoStore function (page 44), measured values are
periodically saved internally (save interval Int 1) and output on the
interface.
With the Data transmission interval function (Int 2), measured
values are periodically output on the interface (see below).
AutoStore (Int 1) covers the Data transmission interval
(Int 2).
l Press the <RUN/ENTER> key
This manually triggers a data transmission of the current measured
value to the serial interface at any time - independently of the select-
ed intervals.
l With the Output data storage function (page 46), calibration data or
saved measured values are output on the interface.

4.7.1 Data transmission interval (Int 2)

The interval to the data transmission (Int 2) determines the chronolog-
ical interval between automatic data transmissions. After the selected
interval expires, the current data record is transmitted to the interface.

Setting the The default setting for the interval is OFF.

Data transmission To start the data transmission, set an interval (5 s, 10 s, 30 s, 1 min,
interval 5 min, 10 min, 15 min, 30 min, 60 min):

1 Press the <RUN/ENTER> key and hold it down.

2 Press the <RCL> key. Int 2 appears on the display.

TDS UpH O Sal

mV/pH
S % mg/l

1nt 2
Time Baud
m S/cm
mbarM cm
1/ cmSal
8OFF F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

3 Set the required interval between the saving procedures with

<> <>.

53
Operation Multi 340i

4 Confirm with <RUN/ENTER>.

The measuring instrument switches to the last active measur-
ing mode.

Note
When the AutoStore function is active at the same time, the data trans-
mission is performed according to the setting of the save interval (Int 1).
Set the save interval (Int 1) to OFF to activate the Data transmission in-
terval (Int 2).

54
Multi 340i Operation

4.7.2 PC/external printer (RS232 interface)

Via the RS 232 interface, you can transmit the data to a PC or an ex-
ternal printer.
Use the AK340/B (PC) or AK325/S (ext. printer) cable.

Warning
The RS232 interface is not galvanically isolated.
When connecting an earthed PC/printer, measurements cannot be per-
formed in earthed media as incorrect values would result.

Set up the following transmission data on the PC/printer:

Baud rate can be selected from: 1200, 2400, 4800, 9600

Handshake RTS/CTS + Xon/Xoff
PC only:
Parity none
Data bits 8
Stop bits 2

Socket assignment 1 CTS

2 RxD
1 2
3 Ground
4 3 4 TxD
RS 232
REC

4.7.3 Remote control

The handheld meter can be remotely controlled from a PC. This re-
quires the KOM pilot communication kit. It is available as an accessory.
The instrument is then controlled via commands that simulate key-
strokes and request the current display contents.

Note
A more detailed description is provided within the scope of delivery of
the communication kit.

55
Operation Multi 340i

4.8 Configuration
You can adapt the handheld meter to your individual requirements. To
do this, the following parameters can be changed (the status on deliv-
ery is marked in bold):

Baud rate 1200, 2400, 4800, 9600

Air pressure display Current value in mbar
(no input possible)
Calibration pH 1 ... 7 ... 999 dInt 3
intervals O2 1 ... 14 ... 999 dInt 4
: 1 ... 180 ... 999 dInt 5
Date/time Any

Note
You can leave the configuration menu at any time with <M> . The pa-
rameters that have already been changed are stored.

1 Switch off the measuring instrument.

2 Press the <M> key and hold it down.
3 Press the <ON/OFF> key.
The display test appears briefly on the display. The measuring
instrument then switches automatically to the setting of the
baud rate.

Baudrate
TDS UpH O Sal
mV/pH
S % mg/l

1nt 2
Time Baud
m S/cm
mbarM cm
1/ cmSal
4800 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

4 Select the required Baud rate with <> <>.

5 Confirm with <RUN/ENTER>. CAL dISP appears on the dis-
play.

56
Multi 340i Operation

TDS pH O Sal
mV/pH/pH
S % mg/l

1C AL
Time Baud
m S/cm
mbarM cm
1/ cmSal
disp F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

6 Select the required display during the pH calibration with

<> <>.
mV: Display of the current electrode voltage
/pH: Display of the buffer nominal value.
7 Confirm with <RUN/ENTER>. P mbar appears on the display.

Displaying the The air pressure is only displayed if an oxygen sensor is connected.
air pressure Otherwise, "---" appears.

TDS UpH O Sal

mV/pH
S % mg/l

1nt P
Time Baud
m S/cm
mbarM cm
1/ cmSal
4949 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

8 Confirm with <RUN/ENTER>. Int 3 and the measured variable

pH appear on the display.

pH calibration interval TDS pH O Sal

mV/pH
S % mg/l

1nt 3
Time Baud
m S/cm
mbarM cm
1/ cmSal
d187 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

9 Set the required interval in days (d) with <> <>.

57
Operation Multi 340i

10 Confirm with <RUN/ENTER>. Int 4 and the measured variable

O2 appear on the display.

Dissolved oxygen TDS UpH O Sal

calibration interval mV/pH
S % mg/l

1nt 4
Time Baud
m S/cm
mbarM cm
1/ cmSal
d114 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

11 Set the required interval in days (d) with <> <>.

12 Confirm with <RUN/ENTER>. Int 5 and the measured variable
appear on the display.

Conductivity TDS UpH O Sal

calibration interval mV/pH
S % mg/l

1nt 5
Time Baud
m S/cm
mbarM cm
1/ cmSal
d180 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

13 Set the required interval in days (d) with <> <>.

14 Confirm with <RUN/ENTER>. The reference temperature set
for conductivity measurements appears on the display.

Switching over the TDS U pHO Sal

reference temperature mV/pH
S % mg/l

1t 25
Time Baud
m S/cm
mbarM cm
1/ cmSal
8248 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

58
Multi 340i Operation

15 Using <> <>, toggle between t20 and t25.

16 Confirm with <RUN/ENTER>.
The date flashes on the display.

Date and time TDS UpH O Sal

mV/pH
S % mg/l

1Dis
Time Baud
m S/cm
mbarM cm
1/ cmSal
0904 F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR

17 Set the date of the current day with <> <>.

18 Confirm with <RUN/ENTER>.
The date (month) flashes in the display.
19 Set the current month with <> <>.
20 Confirm with <RUN/ENTER>.
The year appears on the display.
21 Set the current year with <> <>.
22 Confirm with <RUN/ENTER>.
The hours flash on the display.
23 Set the current time with <> <>.
24 Confirm with <RUN/ENTER>.
The minutes flash on the display.
25 Set the current time with <> <>.
26 Confirm with <RUN/ENTER>.
The measuring instrument switches to the last active measur-
ing mode.

59
Operation Multi 340i

4.9 Reset
You can reset (initialize) the measurement parameters and the config-
uration parameters separately from one another.

Measurement The following measuring parameters (pH/O2/Cond InI) can be reset to

parameters the default condition:

pH Measuring mode pH
Asymmetry 0 mV
Slope -59.16 mV

O2 Measuring mode D. O. concentration

Relative slope 1.00
Salinity (value) 0.0
Salinity (function) Off

Cond Measuring mode

Cell constant 0.475 cm-1 (fixed)

Note
The calibration data gets lost when the measuring parameters are re-
set. Recalibrate after performing a reset.

Configuration The following configuration parameters (InI) are reset to the delivery
parameters status:

Baud rate 4800

Display during the Buffer nominal value
pH calibration
Interval 1
(automatically saved) OFF
Interval 2
(for data transmission) OFF

60
Multi 340i Operation

Resetting the
1 Press the <RUN/ENTER> key and hold it down.
measuring parameters
2 Press the <CAL> key. The setting to reset the pH measuring
parameters appears on the display.

TDS pHO Sal

mV/pH
S % mg/l

1In I
Time Baud
m S/cm
mbarM cm
1/ cmSal
4Yno F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

3 Using <> <>, switch between no and YES.

YES: Resetting the pH measuring parameters
no: Retaining settings.
4 Confirm with <RUN/ENTER>.
The measuring instrument switches to the setting to reset the
O2 measuring parameters.

TDS UpH O Sal

mV/pH
S % mg/l

1In I
Time Baud
m S/cm
mbarM cm
1/ cmSal
4Yno F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

5 Using <> <>, switch between no and YES.

YES: Resetting the O2 measuring parameters.
no: Retaining settings.
6 Confirm with <RUN/ENTER>. The measuring instrument
switches to the setting to reset the Cond measuring parame-
ters.

61
Operation Multi 340i

TDS UpH O Sal

mV/pH
S % mg/l

1In I
Time Baud
m S/cm
mbarM cm
1/ cmSal
4Yno F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

7 Using <> <>, switch between no and YES.

YES: Resetting the Cond measuring parameters.
no: Retaining settings.
8 Confirm with <RUN/ENTER>.
The measuring instrument switches to the configuration pa-
rameters.

TDS UpH O Sal

mV/pH
S % mg/l

1In I
Time Baud
m S/cm
mbarM cm
1/ cmSal
4Yno F % /K TP
C
Day.Month No.
Year Ident

Tref25 Tref20 AutoCal DIN Auto Store

LoBat nLF Lin Cal AutoCal TEC ARng AR RCL

Resetting the
9 Using <> <>, switch between no and YES.
configuration parame-
YES: Resetting the configuration parameters
ters
no: Retaining settings.
10 Confirm with <RUN/ENTER>.
The measuring instrument switches to the last active measur-
ing mode.

62
Multi 340i Maintenance, cleaning, disposal

5 Maintenance, cleaning, disposal

5.1 Maintenance
The measuring instrument is almost maintenance-free.
The only maintenance task is replacing the batteries. LoBat indicates
that the batteries should be changed. The batteries are then largely de-
pleted.

Replacing the batteries

1 Open the housing after the instrument has been switched off:
Undo the four screws on the underside of the instrument
Pull down the lower cover (1).
2 If necessary, take the four depleted batteries (2) out of the bat-
tery compartment.
3 Place four new batteries (type Mignon AA) in the battery com-
partment.
4 Close the lower cover (1).

Warning
Make sure that the poles of the batteries are the right way round.
The signs on the batteries must correspond to the signs in the bat-
tery compartment. Only use leakproof alkaline manganese batteries.

63
Maintenance, cleaning, disposal Multi 340i

Note
For maintenance of electrodes, probes and measuring cells refer to the
relevant operating manuals.

5.2 Cleaning
Occasionally wipe the outside of the measuring instrument with a
damp, lint-free cloth. Disinfect the housing with isopropanol as re-
quired.

Warning
The housing is made of a synthetic material (ABS). Thus, avoid contact
with acetone and similar detergents that contain solvents. Remove any
splashes immediately.

5.3 Disposal
Packing This measuring instrument is sent out in a protective transport packing.
We recommend: Keep the packing material. The original packing pro-
tects the instrument against damage during transport.

Batteries This note refers to the battery regulation that applies in the Federal Re-
public of Germany. We would ask end-consumers in other countries to
follow their local statutory provisions.

Note
This instrument contains batteries. Batteries that have been removed
must only be disposed of at the recycling facility set up for this purpose
or via the retail outlet.
It is illegal to dispose of them in household refuse.

Measuring instrument, Dispose of the measuring instrument as electronic waste at an appro-

priate collection point. It is illegal to dispose of the instrument in house-
hold refuse.

64
Multi 340i What to do if...

6 What to do if...
6.1 pH system messages

Error message 0FL Cause Remedy

pH electrode:
Not connected Connect electrode
Air bubble in front of the Remove air bubble
diaphragm
Air in the diaphragm Extract air or
moisten diaphragm
Cable broken Replace electrode
Gel electrolyte dried out Replace electrode

Error message E3 Cause Remedy

Electrode
Diaphragm contaminated Clean diaphragm
Membrane contaminated Clean membrane
Moisture in the plug Dry plug
Electrolyte out of date Replenish electrolyte or
replace electrode
Electrode worn out Replace electrode
Electrode broken Replace electrode

Measuring instrument:
Incorrect calibration procedure Select correct procedure
Incorrect solution temperature Set up correct temperature
(without temperature sensor)
Socket damp Dry socket

65
What to do if... Multi 340i

Buffer solutions
Incorrect buffer solutions Change calibration procedure
Buffer solutions too old Use only once.
Note the shelf life
Buffer solutions depleted Change solutions

No stable measured Cause Remedy

value
pH electrode:
Diaphragm contaminated Clean diaphragm
Membrane contaminated Clean membrane

Test sample:
pH value not stable Measure with air excluded if
necessary
Temperature not stable Adjust temperature if
necessary

Electrode + test sample:

Conductivity too low Use suitable electrode
Temperature too high Use suitable electrode
Organic liquids Use suitable electrode

Obviously incorrect Cause Remedy

measured values
pH electrode:
pH electrode unsuitable Use suitable electrode
Temperature difference Adjust temperature of buffers
between buffer and test or sample
sample too high
Measurement procedure not Follow special procedure
suitable

66
Multi 340i What to do if...

6.2 Oxi system messages

Error message 0FL Cause Remedy

Display range exceeded
Oxygen sensor
Not connected Connect the probe
Cable broken Replace probe
Depleted Replace probe
Short-circuit between gold and Clean probe and replace it if
lead electrode necessary

Error message E3 Cause Remedy

Invalid calibration
Oxygen sensor
Electrolyte solution depleted Regenerate probe
Membrane contaminated Clean membrane
Electrode system poisoned Regenerate probe
Worn out Replace probe
broken Replace probe

Error message E7 Cause Remedy

Membrane damaged

Membrane damaged Regenerate probe

Membrane head not screwed Screw membrane head tight
on tight enough

AR flashes Cause Remedy

continuously
No stable measured value
Membrane contaminated Clean membrane

67
What to do if... Multi 340i

Measured value too low Cause Remedy

Insufficient flow Provide flow to the probe

Measured value too Cause Remedy

high
High amount of dissolved Correct solubility function
substances using the salinity equivalent
Air bubbles bump on the Avoid direct flow to the
membrane with high velocity membrane
The carbon dioxide pressure is Measuring not possible
too high (> 1 bar)

6.3 Conductivity system messages

Error message OFL Cause Remedy

The measured value lies outside
the measuring range
Measuring cell not connected Connect measuring cell
Cable broken Replace measuring cell

Error message E3
Cause Remedy
Measuring cell contaminated Clean cell and replace it if
necessary
Unsuitable calibration Check calibration solutions
solution

68
Multi 340i What to do if...

6.4 General errors

Display LoBat Cause Remedy

Batteries almost empty Exchange the batteries (see
section 5.1 MAINTENANCE)

Instrument does not Cause Remedy

react
to keystroke Operating condition undefined Processor reset:
or EMC load unallowed Hold the <CAL> key
depressed and switch the
instrument on

Display to Cause Remedy

Time-out of the interface Check that the instrument is
connected

Probe symbol flashes Cause Remedy

Calibration interval expired Recalibrate the measuring
system

Message StoFull Cause Remedy

All memory locations are full Output data storage and clear
data storage

69
What to do if... Multi 340i

70
Multi 340i Technical data

7 Technical data

Dimensions and weight Length [mm] 172

Width [mm] 80
Height [mm] 37
Weight [kg] Approx. 0.3

Mechanical structure Type of protection IP 66

Electrical safety Protective class III

Ambient
conditions Storage - 25 C ... + 65 C
Operation -10 C ... + 55 C
Climatic class 2

pH/ORP measuring Measuring range Resolution

ranges
pH - 2.00 ... + 19.99 0.01
U [mV] - 1999 ... + 1999 1
T [C] - 5.0 ... + 105.0 0.1

Precision of pH/ORP pH ( 2 pH units around 0.03

( 1 digit) the calibration point)
U [mV] 1
T [C] 0.1

Temperature input

Manually [C] - 20 ... + 130

71
Technical data Multi 340i

Oxi measuring ranges mg/l %

Measuring range I 0 ... 19.99 0 ... 199.9
Resolution 0.01 0.1
Measuring range II 0 ... 90.0l 0 ... 600
Resolution 0.1 1

Measuring range/resolu- C
tion temperature
Measuring range (Resolution) 0 ... 50.0 (0.1)

Precision of Concentration 0.5 % of measured value

Oxi ( 1 digit) at ambient temperature of 5 C ... 30 C
Saturation 0.5 % of measured value
when measuring in the range of
10 K around the calibration temperature
Temperature < 2 % at 0 ... 40 C
compensation
T [C] 0.1

Correction functions of Salinity correction 0 ... 70.0 SAL

Oxi
Air pressure correction automatic through built-in
pressure sensor in the range 500 ... 1100
mbar

Cond measuring ranges Measuring range Resolution

[S/cm] 0 ... 1999 1
[mS/cm] 0.00 ... 19.99 0.01
0.0 ... 199.9 0.1
0 ... 500 1
SAL 0.0 ... 70.0 accord- 0.1
ing to the IOT table
T [C] 5.0 ... + 105.0 0.1

72
Multi 340i Technical data

Precision of Nonlinear compensation

Cond ( 1 digit) Accuracy Sample temperature
0.5 % 0 C ... 35 C
according to EN 27 888;
0.5 % 35 C ... 50 C
extended nLF function
acc. to
WTW measurements
SAL Range 0.0 ... 42.0
Accuracy Sample temperature
0.1 5 C ... 25 C
0.2 25 C ... 30 C
T [C] 0.1

Cell constant, C [cm-1] 0.450 ... 0.500

calibrating

Cond reference Tref Can be set to 20 C or 25 C

temperature

Serial interface Connection of the cable AK 340/B, AK 325/S

Type RS232, data output

Baud rate Can be set to
1200, 2400, 4800, 9600 Baud
Data bits 8
Stop bits 2
Parity None
Handshake RTS/CTS + Xon/Xoff
Cable length Max. 15m

73
Technical data Multi 340i

Power supply Batteries 4 x 1.5 V alkali-manganese batteries, Type

AA
Operational life Approx. 3000 operating hours
Mains The following applies to all plug-in power
supplies:Connection max.
Overvoltage category II

Plug-in power supply unit

(Euro, US , UK, Australian plug)
FRIWO FW7555M/09, 15.1432
Friwo Part. No. 1822089
Input: 100 ... 240 V ~ / 50 ... 60 Hz / 400 mA
Output: 9 V = / 1,5 A

Plug-in power supply with Euro plug:

FRIWO FW1199, 11.7864
Friwo Part. No. 1762613
Input: 230 V ~ / 50 Hz / 5.6 VA
Output: 12 V = / 130 mA / 1.56 VA

Plug-in power supply with US plug:

FRIWO FW1199, 11.7880
Friwo Part. No. 1794043
Input: 120 V ~ / 60 Hz / 6 VA
Output: 12 V = / 150 mA

Plug-in power supply with UK plug:

FRIWO FW1199, 11.7872
Friwo Part No. 1816491
Input: 230V ~ / 50 Hz / 5.6 VA
Output: 12 V = / 130 mA / 1.56 VA

Guidelines EMC E.C. guideline 89/336/EEC

and norms used EN 61326-1:1997
EN 61000-3-2 A14:2000
EN 61000-3-3:1995
FCC Class A
Instrument safety E.C. guideline 73/23/EEC
EN 61010-1 A2:1995
Climatic class VDI/VDE 3540
IP protection class EN 60529:1991

74
Multi 340i Technical data

FCC Class A Equipment Statement

Note: This equipment has been tested and found to comply with
the limits for a Class A digital device, pursuant to Part 15 of the
FCC Rules. These limits are designed to provide reasonable
protection against harmful interference when the equipment is
operated in a commercial environment. This equipment
generates, uses, and can radiate radio frequency energy and, if
not installed and used in accordance with the instruction manual,
may cause harmful interference to radio communications.
Operation of this equipment in a residential area is likely to cause
harmful interference in which case the user will be required to
correct the interference at his own expense.

Test certificates cETLus, CE

75
Technical data Multi 340i

76
Multi 340i Lists

8 Lists
This chapter provides additional information and orientation aids.

Abbreviations The list of abbreviations explains the indicators and the abbreviations
that appear on the display and in the manual.

Specialist terms The glossary briefly explains the meaning of the specialist terms. How-
ever, terms that should already be familiar to the target group are not
described here.

Index The index will help you to find the topics that you are looking for.

77
Lists Multi 340i

Abbreviations

Conductivity value (international )

AR AutoRead (drift control)
ARng Automatic range switching
Measuring instrument measures with highest reso-
lution
ASY Asymmetry
AutoCal DIN Automatic pH calibration with buffer solutions pre-
pared according to DIN 19 266
AutoCal TEC Automatic pH calibration with WTW technical buff-
er solutions according to DIN 19267
C Cell constant [cm-1] (internat. k)
C Temperature unit, degrees Celsius
Cal Calibration
Cd... Display indicator during calibration for pH mea-
surements. Indicates the selection of the buffer
data record for buffer solutions prepared according
to DIN 19 266
Cm... Display indicator during calibration for pH mea-
surements. Indicates the selection of buffer data
records for buffer solutions of the Merck company
ConCal Conventional single-point or two-point calibration
for pH measurements
Ct... Display indicator during calibration for pH mea-
surements. Indicates the selection of the buffer
data records for WTW technical buffer solutions
E3 Error message
see chapter 6 WHAT TO DO IF...
InI Initialization
Resets individual basic functions to the status they
had on delivery
LoBat Batteries almost empty(Low Battery)
mV Voltage unit
mV/pH Unit of the electrode slope (internat. mV)

78
Multi 340i Lists

nLF Nonlinear temperature compensation

OFL Display range exceeded (Overflow)
OxiCal Automatic calibration for D. O. measurements
pH pH value
S Slope (internat. k)
SAL Salinity
SELV Safety Extra Low Voltage

SLO Slope setting on calibration

TC Temperature coefficient (internat. )

TP Temperature measurement active (temperature
sensor)
TRef 25/T25 Reference temperature of 25 C
UASY Asymmetry

79
Lists Multi 340i

Glossary

Adjusting To manipulate a measuring system so that the relevant value (e. g. the
displayed value) differs as little as possible from the correct value or
a value that is regarded as correct, or that the difference remains with-
in the tolerance.
Asymmetry Designation for the offset potential of a pH electrode. It is the measur-
able potential of a symmetrical electrode, the membrane of which is
immersed in a solution with the pH of the nominal electrode zero point
(WTW electrodes: pH = 7).
AutoRange Name of the automatic selection of the measuring range.
AutoRead WTW name for a function to check the stability of the measured value.
Calibration Comparing the value from a measuring system (e. g. the displayed
value) to the correct value or a value that is regarded as correct. Of-
ten, this expression is also used when the measuring system is adjust-
ed at the same time (see adjusting).
Cell constant, k Characteristic quantity of a conductivity measuring cell, depending on
the geometry.
Conductivity Short form of the expression, specific electrical conductivity. It is a
measured value of the ability of a substance to conduct an electric cur-
rent. In water analysis, the electrical conductivity is a dimension for the
ionized substances in a solution.
D. O. partial pressure Pressure caused by the oxygen in a gas mixture or liquid.
Diaphragm The junction is a porous body in the housing wall of reference elec-
trodes or electrolyte bridges. It forms the electrical contact between
two solutions and makes electrolyte exchange more difficult. The ex-
pression, junction, is also used for ground or junction-less transitions.
Electrode zero point The zero point of a pH electrode is the pH value at which the electro-
motive force of the pH electrode at a specified temperature is zero.
Normally, this is at 25 C.
Electromotive force of The electromotive force U of the electrode is the measurable electro-
an electrode motive force of an electrode in a solution. It equals the sum of all the
galvanic voltages of the electrode. Its dependency on the pH results
in the electrode function which is characterized by the parameters,
slope and zero point.
Measured parameter The measured parameter is the physical dimension determined by
measuring, e. g. pH, conductivity or D. O. concentration.
Measured value The measured value is the special value of a measured parameter to
be determined. It is given as a combination of the numerical value and
unit (e. g. 3 m; 0.5 s; 5.2 A; 373.15 K).

80
Multi 340i Lists

Measuring system The measuring system comprises all the devices used for measuring,
e. g. measuring instrument and probe. In addition, there is the cable
and possibly an amplifier, terminal strip and armature.
Molality Molality is the quantity (in Mol) of a dissolved substance in 1000 g sol-
vent.
MultiCal WTW name stating that a measuring instrument provides several cal-
ibration procedures.
Offset potential The measurable potential of a symmetrical electrode, the membrane
of which is immersed in a solution with the pH of the nominal electrode
zero point. The asymmetry is part of the offset potential.
ORP voltage The ORP is caused by oxidizing or reducing substances dissolved in
water if these substances become effective on an electrode surface
(e. g. a gold or platinum surface).
OxiCal WTW name for a procedure to calibrate D. O. measuring systems in
water vapor saturated air.
Oxygen saturation Short name for the relative D. O. saturation.
Note: The D. O. saturation value of air-saturated water and the D. O.
saturation value of oxygen-saturated water are different.
pH value The pH is a measure of the acidic or basic effect of an aqueous solu-
tion. It corresponds to the negative decadic logarithm of the molal hy-
drogen ions activity divided by the unit of the molality. The practical pH
value is the value of a pH measurement.
Potentiometry Name of a measuring technique. The signal (depending on the mea-
sured parameter) of the electrode is the electrical potential. The elec-
trical current remains constant.
Reference Fixed temperature value to compare temperature-dependent mea-
temperature sured values. For conductivity measurements, the measured value is
converted to a conductivity value at a reference temperature of 20 C
or 25 C.
Reset Restoring the original condition of all settings of a measuring system.
Resistance Short name for the specific electrolytic resistance. It corresponds to
the reciprocal value of the electrical conductivity.
Resolution Smallest difference between two measured values that can be dis-
played by a measuring instrument.
Salinity The absolute salinity SA of seawater corresponds to the relationship
of the mass of dissolved salts to the mass of the solution (in g/Kg). In
practice, this dimension cannot be measured directly. Therefore, the
practical salinity is used for oceanographic monitoring. It is deter-
mined by measuring the electrical conductivity.

81
Lists Multi 340i

Salt content General designation for the quantity of salt dissolved in water.
Sample Designation of the sample ready to be measured. Normally, a test
sample is made by processing the original sample. The test sample
and original sample are identical if the test sample was not processed.
Setting the Name of a function that considers the temperature influence on the
temperature measurement and converts it accordingly. Depending on the mea-
compensation sured parameter to be determined, the temperature compensation
functions in different ways. For conductimetric measurements, the
measured value is converted to a defined reference temperature. For
potentiometric measurements, the slope value is adjusted to the tem-
perature of the test sample but the measured value is not converted.
Slope The slope of a linear calibration function.
Slope (relative) Designation used by WTW in the D. O. measuring technique. It ex-
presses the relationship of the slope value to the value of a theoretical
reference probe of the same type of construction.
Standard solution The standard solution is a solution where the measured value is
known by definition. It is used to calibrate a measuring system.
TDS Total dissolved solids
Temperature Value of the slope of a linear temperature function.
coefficient
Temperature function Name of a mathematical function expressing the temperature behav-
ior of a test sample, a probe or part of a probe.

82
Multi 340i Index

Index

A E P
Air pressure display 57 Energy saving feature 15 pH calibration evaluation 21
Asymmetry 20 Error messages 67, 68 pH value 18
Authorized use 11 Plug-in power supply 14
AutoCal TEC 20, 22 I Precautions 11
AutoRange (oxygen) 15
Initial commissioning 13
AutoRead R
Initialization 60
Conductivity 37
Interval Reference temperature
D. O. 29
Calibration (Int 3) 41 (conductivity) 34
pH 18
save 44 Remote control 55
Replacing the batteries 63
C J Reset 60
Calibration Resetting the measuring
Jack field 9
Conductivity 38 parameters 61
D. O. 30 RS232 interface 55
pH 20 K RS232 socket assignment
Calibration evaluation Keys 8 55
D. O. 31
Dissolved oxygen 31 M S
Calibration interval 41 Measuring 34 Safety 11
conductivity 58 conductivity 36 Salt content correction
Dissolved oxygen 58 D. O. concentration 27 entering the salinity 33
pH 57 D. O. saturation 28 switching on 27
Calibration protocol 20 ORP voltage 19 Save interval 44
conductivity 38 pH value 18 Saving data 42
D. O. 30 Salinity 36 Scope of delivery 13
Cell constant 35, 38 Measuring mode when Setting the baud rate 56
Conductivity calibration switching on 15 Setting the date 13, 59
evaluation 39 Measuring ranges Setting the reference
Configuration parameters 60 Conductivity 72 temperature 58
Connecting a printer 55 oxygen 72 Setting the time 13, 59
pH/ORP 71 Single-point calibration (pH)
D Measuring ranges with 20, 23
D. O. DurOx 72 Slope 20, 30
Measuring the concentra- Measuring the conductivity
tion 27 36 T
Measuring the saturation Measuring the salinity 36
Temperature compensation
28
(conductivity) 34
Data record 42 O Temperature probe
Default condition 60 Operating 10 Conductivity 34
Display 9 Operating safety 12 Temperature sensor
Drift control ORP electrode 19 D. O. 26
Conductivity 37 ORP voltage 19 pH 17
D. O Oxygen Transmitting data 53
29 Measurement range sel- Transmitting measured
pH 18 ection 15

83
Index Multi 340i

values 53
Two-point calibration (pH)
20, 23

84