SDS no.

MI11332
Version 8
Revision date 06/Feb/2015
Supersedes date 26/Mar/2014

Safety Data Sheet

SODIUM CHLORIDE POWDER (SALT PVD or GRANULAR SALT)

1. Identification of the substance/preparation and of the Company/undertaking

1.1 Product identifier

Product name SODIUM CHLORIDE POWDER (SALT PVD or GRANULAR SALT)

Product code MI11332
Synonyms Sodium chloride, NaCl
Molecular weight 58.44 g/mol
REACH registration name Exempt
Denmark Pr. no. 701625

1.2 Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Additive in oilfield applications

Uses advised against Consumer use

1.3 Details of the supplier of the safety data sheet

Supplier
M-I Australia Pty Ltd
Level 5
256 St. George Terrace
Perth
WA 6000
T= 08 9440 2900
MISDS@slb.com

1.4 Emergency Telephone Number

Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44
(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600
Denmark Poison Control Hotline (DK): +45 82 12 12 12
Norway Poison information centre: +47 22 59 13 00

2. Hazards identification
2.1 Classification of the substance or mixture

Classification according to (EC) No. 1272/2008

Health hazards Not classified

Environmental hazards Not classified

Physical Hazards Not classified

2.2 Label elements

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Signal word
Not applicable

Hazard statements
This product is not classified as hazardous therefore no (H) hazard statements assigned.

Precautionary Statements - EU (§28, 1272/2008)

This product is not classified as hazardous therefore has no (P) precautionary statements assigned.

Classification according to EU Directives 67/548/EEC or 1999/45/EC

Indication of danger
Not classified

Contains
Sodium chloride

For the full text of the R-phrases and H-Statements mentioned in this Section, see Section 16.

2.3 Other data

Not classified as PBT/vPvB by current EU criteria

Australian statement of hazardous/dangerous nature

Classified as Non-Hazardous according to the criteria of NOHSC.
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.

3. Composition/information on ingredients
3.1 Substances

Component EC-No. CAS-No Weight % - Classification Classification (Reg. REACH

range (67/548) 1272/2008) registration
number
Sodium chloride 231-598-3 7647-14-5 60-100 - Not classified No data available

3.2 Mixtures

Not Applicable

4. First aid measures

4.1 First-Aid Measures

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.

Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouth
to an unconscious person. Get medical attention if symptoms occur.

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Skin contact Wash off immediately with soap and plenty of water removing all contaminated clothes and
shoes. Get medical attention immediately if symptoms occur.

Eye contact Remove contact lenses. Promptly wash eyes with lots of water while lifting eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

4.2 Most important symptoms and effects, both acute and delayed

General advice The severity of the symptoms described will vary dependant of the concentration and the
length of exposure. If adverse symptoms develop, the casualty should be transferred to
hospital as soon as possible.

Main symptoms

Inhalation Please see Section 11. Toxicological Information for further information.

Ingestion Please see Section 11. Toxicological Information for further information.

Skin contact Please see Section 11. Toxicological Information for further information.

Eye contact Please see Section 11. Toxicological Information for further information.

4.3 Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically.

5. Fire-fighting measures
5.1 Extinguishing media

Suitable extinguishing media

Use extinguishing media appropriate for surrounding material.

Extinguishing media which shall not be used for safety reasons

None known.

5.2 Special hazards arising from the substance or mixture

Unusual fire and explosion hazards

None.

Hazardous combustion products

Fire or high temperatures create:, Chlorine, chlorine oxides, hydrogen chloride.

5.3 Advice for firefighters

Special protective equipment for fire-fighters

As in any fire, wear self-contained breathing apparatus and full protective gear.

Special Fire-Fighting Procedures

Containers close to fire should be removed immediately or cooled with water.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. See also section 8.

6.2 Environmental precautions

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The product should not be allowed to enter drains, water courses or the soil.

Environmental exposure controls

Avoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.

6.3 Methods and materials for containment and cleaning up

Methods for containment

Prevent further leakage or spillage if safe to do so.

Methods for cleaning up

Sweep up and shovel into suitable containers for disposal. After cleaning, flush away traces with water.

6.4 Reference to other sections

See section 13 for more information.

7. Handling and storage

7.1 Precautions for safe handling

Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.

Hygiene measures
Handle in accordance with good industrial hygiene and safety practice. When using do not smoke, eat or drink. Wash hands and
face before breaks and immediately after handling the product.

7.2 Conditions for safe storage, including any incompatibilities

Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid contact with:
Strong acids. Oxidizing agents Metals

Storage class Chemical storage.

Packaging material Use specially constructed containers only

Packaging materials to be avoided Metal

7.3 Specific end uses

See Section 1.2.

8. Exposure controls/personal protection

8.1 Control parameters

Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.
No biological limit allocated

Component EU OEL Austria Australia Denmark

Sodium chloride Not determined Not determined Not determined Not determined

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Component Finland France Germany Hungary

Sodium chloride Not determined Not determined Not determined Not determined

Component New Zealand Italy Netherlands Norway

Sodium chloride Not Determined Not determined Not determined Not determined

Component Poland Portugal Romania Russia

Sodium chloride Not determined Not determined Not determined 5 mg/m3 MAC

Component Spain Switzerland Turkey UK

Sodium chloride Not determined Not determined Not determined Not determined

8.2 Exposure controls

All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard
present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical
hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may
be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will
vary from workplace to workplace and should be assessed by the user in each situation.

Engineering measures to reduce exposure

Ensure adequate ventilation. Local exhaust ventilation.

Personal protective equipment

Eye protection It is good practice to wear goggles when handling any chemical. Tightly fitting safety
goggles.
Hand protection Use protective gloves made of:, Rubber or plastic gloves, Be aware that liquid may
penetrate the gloves. Frequent change is advisable.
Respiratory protection No personal respiratory protective equipment normally required, In case of insufficient
ventilation wear suitable respiratory equipment, Half mask with a particle filter P2
(European Norm EN 143 = former DIN 3181).
Skin and body protection Wear suitable protective clothing, Eye wash and emergency shower must be available at
the work place.

Hygiene measures Wash hands before eating, drinking or smoking, Remove and wash contaminated clothing
before re-use.

9. Physical and chemical properties

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9.1 Information on basic physical and chemical properties

Physical state Solid powder
Appearance Crystalline
Odor Odorless
Color White
Odor threshold Not applicable

Property Values Remarks

pH No information available
pH @ dilution 7 @1%
Melting/freezing point 801 °C
Boiling point/range 1461 °C
Flash point No information available
Evaporation rate (BuAc =1)
Flammability (solid, gas) Not Applicable
Flammability Limits in Air Not applicable
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure 1 mmHg @ 865 °C
Vapor density No information available
Specific gravity No information available
Bulk density 800 - 1600 kg/m³
Relative density No information available
Water solubility Soluble in water
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity
Dynamic viscosity No information available
Log Pow Not determined

Explosive properties Not Applicable

Oxidizing properties None known.

9.2 Other information

Pour point No information available
Molecular weight 58.44 g/mol
VOC content(%) None
Density 2.1615 g/cm²

10. Stability and reactivity

10.1 Reactivity

No specific reactivity hazards associated with this product.

10.2 Chemical stability

Stable under normal temperature conditions and recommended use.

10.3 Possibility of Hazardous Reactions

Hazardous polymerization
Hazardous polymerization does not occur.

10.4 Conditions to avoid

Avoid dust formation.

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10.5 Incompatible materials

Strong acids. Oxidizing agents. Metals.

10.6 Hazardous decomposition products

See also section 5.2.

11. Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Inhalation Inhalation of dust in high concentration may cause irritation of respiratory system.

Eye contact May cause slight irritation.

Skin contact Prolonged contact may cause redness and irritation.

Ingestion Ingestion may cause stomach discomfort.

Component LD50 Oral LD50 Dermal LC50 Inhalation

Sodium chloride = 3 g/kg ( Rat ) > 10 g/kg ( Rabbit ) > 42 g/m3 ( Rat ) 1 h

Sensitization This product does not contain any components suspected to be sensitizing.

Mutagenic effects This product does not contain any known or suspected mutagens.

Carcinogenicity This product does not contain any known or suspected carcinogens.

Reproductive toxicity None known.

Routes of exposure Inhalation. Eye contact.

Routes of entry No route of entry noted.

Specific target organ toxicity Not classified

(single exposure)
Specific target organ toxicity Not classified.
(repeated exposure)

Aspiration hazard No hazard from product as supplied.

12. Ecological information

12.1 Toxicity

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The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility that
large or frequent spills can have a harmful or damaging effect on the environment. Listed on PLONOR list of OSPAR

Toxicity to algae
This product is not considered toxic to algae.

Toxicity to fish
This product is not considered toxic to fish.

Toxicity to daphnia and other aquatic invertebrates

This product is not considered toxic to invertebrates.

Component Toxicity to fish Toxicity to algae Toxicity to daphnia and other

aquatic invertebrates
Sodium chloride 5560 - 6080 mg/L LC50 (Lepomis No information available 340.7 - 469.2 mg/L EC50 (Daphnia
macrochirus) = 96 h magna) = 48 h
12946 mg/L LC50 (Lepomis 1000 mg/L EC50 (Daphnia magna)
macrochirus) = 96 h = 48 h
4747 - 7824 mg/L LC50
(Oncorhynchus mykiss) = 96 h
7050 mg/L LC50 (Pimephales
promelas) = 96 h
6420 - 6700 mg/L LC50
(Pimephales promelas) = 96 h
6020 - 7070 mg/L LC50
(Pimephales promelas) = 96 h

12.2 Persistence and degradability

Not Applicable - Inorganic chemical.

12.3 Bioaccumulative potential

Does not bioaccumulate.

12.4 Mobility in soil

Mobility
The product is water soluble, and may spread in water systems.

12.5 Results of PBT and vPvB assessment

Not classified as PBT/vPvB by current EU criteria.

12.6 Other adverse effects.

None known.

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13. Disposal considerations

13.1 Waste treatment methods

Waste from residues / unused Dispose of in accordance with local regulations.

products

Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.

EWC Waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, but
application specific. Waste codes should be assigned by the user based on the application
for which the product was used. The following Waste Codes are only suggestions: EWC
waste disposal No: 06 03 14

14. Transport information

The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,ADR/RID/ADG).

14.1 UN Number
Not regulated

14.2 Proper shipping name

Not regulated

14.3 Hazard class(es)

ADR/RID/ADN Hazard class Not regulated
IMDG Hazard class Not regulated
ICAO Hazard class/division Not regulated

14.4 Packing group

ADR/RID/ADN Packing Group Not regulated
IMDG Packing group Not regulated
ICAO Packing group Not regulated

14.5 Environmental hazard

No

14.6 Special precautions

Not Applicable

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Please contact MISDS@slb.com for info regarding transport in Bulk.

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Germany, Water Endangering Hazardous to water/Class 1

Classes (VwVwS)

Australian Standard for the Uniform Scheduling of Drugs and Poisons

No Poisons Schedule number allocated

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Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European
Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the
Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals
Agency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC)
No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and
2000/21/EC, including amendments.

This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008.

National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].

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Safe Work Australia.

Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).

Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport by
road or rail.

Dutch Mining Regulations: In accordance with Mining Regulations 9.2 and Chapter 4 of the Working Conditions Decree.

International inventories

USA (TSCA) Complies

European Union (EINECS and ELINCS) Complies
Canada (DSL) Complies
Philippines (PICCS) Complies
Japan (ENCS) Complies
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Complies
New Zealand (NZIoC) Complies

Contact REACH@miswaco.slb.com for REACH information.

15.2 Chemical Safety Report

No information available

16. Other information

Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Sarah Malone

Supersedes date 26/Mar/2014

Revision date 06/Feb/2015

Version 8

The following sections have been This SDS have been made in a new database and therefore a new layout. No changes with
revised regard to classification have been made, Updated according to GHS/CLP.

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Text of R phrases mentioned in Section 2 and 3

Not classified

Full text of H-Statements referred to under sections 2 and 3

This product is not classified as hazardous therefore no (H) hazard statements assigned.
Not classified

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

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