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Chem Extra Grade11

1. The document contains chemistry questions and problems regarding stoichiometry calculations involving reactions of carbon, hydrogen, oxygen, calcium carbonate, hydrochloric acid, ethane, and other substances. 2. A question is asked about the amount of CO2 produced from the combustion of carbon and the limiting reagent in the reaction of carbon with oxygen. 3. Another question involves the mass of calcium chloride formed from the reaction of calcium carbonate with hydrochloric acid, identifying the limiting reagent.

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Lakshmi Desikan
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138 views4 pages

Chem Extra Grade11

1. The document contains chemistry questions and problems regarding stoichiometry calculations involving reactions of carbon, hydrogen, oxygen, calcium carbonate, hydrochloric acid, ethane, and other substances. 2. A question is asked about the amount of CO2 produced from the combustion of carbon and the limiting reagent in the reaction of carbon with oxygen. 3. Another question involves the mass of calcium chloride formed from the reaction of calcium carbonate with hydrochloric acid, identifying the limiting reagent.

Uploaded by

Lakshmi Desikan
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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Gedee Public School

Chemistry
Date:
Class : XI
Answer the following questions
1. A. Calculate the amount of CO2 that could be produced when: (3)
i. 1 mole of carbon is burnt in air
ii. 1 mole of carbon is burnt in 16g of dioxygen.
iii. 2 moles of carbon are burnt in 16 g of O2.
B. Calculate the mass of 112cm3 of hydrogen gas at S.T.P (2)
2. Calcium carbonate reacts with aqueous HCl to give CaCl2 and CO2 according to the
reaction given below: (5)
CaCO3 (s) + 2HCl (aq) → CaCl2(aq) + CO2 (g) + H2O (l)
What mass of CaCl2 will be formed when 250 ml of 0.76 M HCl reacts with 1000g of
CaCO3?Name the limiting reagent. Calculate the number of moles of CaCl2 formed in the
reaction.
3. Commercially available concentrated hydrochloric acid contains 38% HCl by mass. (5)
-1
a. What is the molarity of this solution? The density is 1.19gmL .
b. What volume of concentrated HCl is required to make 1.00L of 0.10m HCl?

4. a.In three moles of ethane (C2H6), calculate the following : (3)

i.Number of moles of carbon atoms.

ii. Number of molees of Hydrogen atoms.


iii. Number of moles of ethane.
b. A solution is prepared by adding of 2 g of a substance A in 18 g of water. Calculate the
mass percentage of the solute. (2)
5.Calculate molecular mass for the following substances. 2
i. H2O, ii.CO2 iii. CH4 iv. H2SO4
6. State Avagadro’s Law. 2
7. Differentiate between molarity and molality. 2
8. 50.0 kg of N2(g) and 10.0 kg of H2 (g) are mixed to produce NH3 (g). Calculate the NH3(g)
formed. Identify the limiting reagent in the production of NH 3 in this situation 2
9. How many electrons are present in 16g of CH4?
10. Calculate the number of atoms present in 1.4g of N2 molecule. 2
11. Calculate the number of atoms present in each of the following. 4
i. 52 moles of He ii. 52 gms of He
12. What is the difference between 5.0g and 5.00 g? 2
13. . A compound is found to contain 64.80 % carbon, 13.62 % hydrogen, and
21.58 % oxygen by weight. What is the empirical formula for this compound?
The molecular weight for this compound is 74.14 g/mol. What is its molecular
formula?
Answers .
1. A i. C(s) + O2 (g) → CO2 (g). 1
1mole air 1 mole
12 g 44 g
Amount of CO2 produced = 44 g
ii. Amount of O2 produced from 44 g of CO2is 32 g 1
32 g of O2 is produced from 44 g of CO2is 32 g
16 g = 44x 16 =22 g of CO2
32
iii. Amount of CO2 produced when 2 moles or 24 g of C are burnt in 16g (limited 1
amount) of O2 = 22g
B. B 22400cm3 of hydrogen at STP weight=2g 1
. Therefore 112cm3 of hydrogen at STP weight= 2 x 112 = 0.01 g 1
22400
2. CaCO3 (s) + 2HCl (aq) → CaCl2(aq) + CO2 (g) + H2O (l)
Number of moles of HCl= volume in litres X Molarity.
= 250 x 0.76 = 0.19 mol 2
1000
Mass of CaCO3 = 1000g
Number of moles of CaCO3 = mass
Molar mass
=1000g = 10 moles
100gmol-1

1 mole of CaCO3 reacts with 2 moles of HCl


10 moles of CaCO3 will react with = 2 x 10 = 20 moles of HCl.
We have only 0.19 mol of HCl, so Hcl is limiting agent 2
2 moles of Hcl gives 1 mole of CaCl2
0.19 moles → ½ x 0.19 = 0.095 moles of CaCl2 1
3. a. Molarity = number of moles of solute (HCl) ½
Volume of the solution

Number of moles of HCl = Mass of the solute (HCl) = 38 ½


Molecular mass of (HCl) 36.5
Volume of solution :
38 g of HCl is present in 100 g of the solution
Volume of 100g of the acid = Mass 1
Density
= 100g = 84.05 cm3 1
1.19 g cm-3

Molarity = 38/36.5 = 12.38M 1


84.05/1000

b. M1V1 = M2V2
12.38 M X V1 = 10M X 1000 mL ½
V1 = 10/1000 = 807.7mL
12.38 ½
4. a. i. 1 mole of C2H6 contains 2 moles of carbon atoms 1
3 moles of C2H6 contains 6 moles of carbon
ii. 1 mole of C2H6 → 6 hydrogen atoms
3moles → 18 moles of Hydrogen 1
iii. 1 mole of C2H6 → 6.023 x 10 23 molecules of ethane 1
b. mass percentage of A = Mass of A X 100 1
mass of solution

= 2g X 100 = 10 % 1
2g of A + 18 g of water

5. Calculate molecular mass for the following substances. 2


ii. H2O= 18 ii.CO2=44 iii. CH4 = 16 iv. H2SO4 =98
6. Equal volumes of all gases at same temperature and pressure should contain equal
number of molecules. 2
7.
molarity molality
No. of moles of solute/ volume of solution in No. of moles of solute/mass of
litres solvent in kg
Unit = molL-1 molKg-1
dependent of temperature Independent of temperature
Dependent on volume Independent on volume
2
8. N2 + 3H2 → 2NH3
28kg + 6 kg
28 kg of N2 reacts with 6 kg of H2

50 .0 kg of N2 reacts = 50.0kg x 6.0 kg/28 .0kg = 10.71 kg


Since H2 is present in small amount it is limiting agent. 2

8. 1 molecule of CH4 = C +4 H
6 e- + 4 x 1 e-
In 16 gms of CH4 = 10 x 6.022 x 10 23
=6.022 x 10 24 electrons

9. 28 g of N2 molecule contains 2 x 6.022 x 10 23atoms


1.4 gm of N2 molecule contains = 2 x 6.022 x 10 23 x 1.4/28 = 6.022 x 10 22
11 . Calculate the number of atoms present in each of the following. 4
i. 52 moles of He

1 mole of He = 6.022 x 10 23 atoms


52 moles of He = 6.022 x 10 23 x 52 = 3.13 x 10 -25 atoms

ii. 52 gms of He
4 gm of He = 6.022 x 10 23 atoms

52 mof He = 6.022 x 10 23 x 52/4 = 7.8286 x 10 24 atoms

12. .What is the difference between 5.0g and 5.00 g?


Both values are equivalent
But significant figure of 5.0 = 2
That of 5.00 = 3

13. 1) Assume 100 g of the compound is present. This changes the percents to grams:

C ⇒ 64.80 g
H ⇒ 13.62 g
O ⇒ 21.58 g

2) Convert the masses to moles:

C ⇒ 64.80 g / 12 = 5.4
H ⇒ 13.62 g / 1 = 13.62
O ⇒ 21.58 g / 16 = 1.349

3) Divide by the lowest, seeking the smallest whole-number ratio:

C ⇒ 5.4 / 1.349 = 4
H ⇒ 13.62 / 1.349 = 10
O ⇒ 1.349 / 1.349 = 1

4) Write the empirical formula:

C4H10O

5) Determine the molecular formula:

"EFW" ⇒ 48+10+16 = 74

74.14 / 74 = 1

molecular formula = C4H10O

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