FD8402 THERMODYNAMICS L T P C

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UNIT I THERMODYNAMIC LAW AND PROPERTIES OF FLUIDS 9

First Law of thermodynamics, a generalized balance equation and conserved quantities, Volumetric
properties of fluids exhibiting non ideal behavior; residual properties; estimation of thermodynamic
properties using equations of state; calculations involving actual property exchanges; Maxwell’s
relations and applications.
UNIT II SOLUTION THERMODYNAMICS 9
Partial molar properties; concepts of chemical potential and fugacity; ideal and non-ideal solutions;
concepts and applications of excess properties of mixtures; activity coefficient; composition models;
Gibbs Duhem equation.
UNIT III PHASE EQUILIBRIA 9
Criteria for phase equilibria; VLE calculations for binary and multi component systems; liquid-liquid
equilibria and solid-solid equilibria.
UNIT IV CHEMICAL REACTION EQUILIBRIA 9
Equilibrium criteria for homogeneous chemical reactions; evaluation of equilibrium constant; effect
of temperature and pressure on equilibrium constant; calculation of equilibrium conversion and
yields for single and multiple reactions.
UNIT V THERMODYNAMIC DESCRIPTION OF MICROBIAL GROWTH AND 9
PRODUCT FORMATION
Thermodynamics of microbial growth stoichiometry thermodynamics of maintenance, Calculation of
the Operational Stoichiometry of a growth process at Different growth rates, Including Heat using
the Herbert –Pirt Relation for Electron Donor, thermodynamics and stoichiometry of Product
Formation
TOTAL: 45 PERIODS

STAFF IN-CHARGE HOD

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 COURSE PLAN
Sub code : FD8402 Branch/Year/Sem :FOOD TECH /II/IV
Subject name : THERMODYNAMICS Batch : 2018-2022

Staff name : PARTHIBAN S R Academic Year : 2019-2020

COURSE OBJECTIVE
1. To introduce fundamental thermodynamic principles and their application.

TEXT BOOKS:
1. Smith J.M., Van Ness H.C., and Abbot M.M. “Introduction to Chemical Engineering
Thermodynamics”, VI Edition. Tata McGraw-Hill, 2003.
2. Narayanan K.V. “A Text Book of Chemical Engineering Thermodynamics”, PHI, 2003.
3. Christiana D. Smolke, “The Metabolic Pathway Engineering Handbook Fundamentals”,
CRC Press Taylor & Francis Group, 2010.

REFERENCES:
1. Sandler S.I. “Chemical and Engineering Thermodynamics”, John Wiley,1989.
WEB SOURCES:
 https://nptel.ac.in/courses/112104030/
 https://nptel.ac.in/courses/112106061/

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 UNIT I
Session BOOKS Page No of Teaching Cumulative
Topics to be covered No Periods Method
No Referred hours
1 First Law Of Thermodynamics T1 35 1 BB 1
A Generalized Balance Equation And Conserved
2 T1 1 BB
Quantities 43 2

3 Volumetric Properties Of Fluids Exhibiting Non T1 2 BB

Ideal Behavior 45 4
4 Residual Properties T1 46 1 BB 5

5 Estimation Of Thermodynamic Properties Using T1 1 BB

Equations Of State 61 6
6 Calculations Involving Actual Property Exchanges T1 78 1 BB 7
7 Maxwell’s Relations And Applications. T1 84 2 BB 9
UNIT II
Session BOOKS Page No of Teaching Cumulative
Topics to be covered
No Referred No Periods Method hours
8 Partial Molar Properties T1 110 1 BB 10
9 Concepts Of Chemical Potential And Fugacity T1 116 2 BB 12
10 Ideal And Non-Ideal Solutions T1 138 1 BB 13
Concepts And Applications Of Excess Properties
11 T1 2 BB 15
Of Mixtures 149
12 Activity Coefficient T1 150 1 BB 16
13 Composition Models T1 151 1 BB 17
14 Gibbs Duhem Equation. T1 156 1 BB 18
IAT-I
UNIT III
Session BOOKS Page No of Teaching Cumulative
Topics to be covered No Periods Method
No Referred hours
15 Criteria For Phase Equilibria T1 316 2 BB 20
16 VLE Calculations For Binary Component Systems T1 331 2 BB 22
17 VLE Calculations For Multi Component Systems T1 332 2 BB 24
18 Liquid-Liquid Equilibria T1 348 2 BB 26
19 Solid-Solid Equilibria. T1 349 1 BB 27
UNIT IV
Session BOOKS Page No of Teaching Cumulative
Topics to be covered No Periods Method
No Referred hours
Equilibrium Criteria For Homogeneous Chemical
20 T1 2 BB 29
Reactions 213
21 Evaluation Of Equilibrium Constant T1 236 2 BB 31

22 Effect Of Temperature And Pressure On T1 2 BB 33

Equilibrium Constant 245

23 Calculation Of Equilibrium Conversion And Yields T1 3 BB 36

For Single And Multiple Reactions. 274

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 IAT-II
UNIT V
Session BOOKS Page No of Teaching Cumulative
Topics to be covered No Periods Method
No Referred hours

24 Thermodynamics Of Microbial Growth T1 2 BB 38

Stoichiometry Thermodynamics Of Maintenance 385

25 Calculation Of The Operational Stoichiometry Of T1 2 BB 40

A Growth Process At Different Growth Rates 407

26 Including Heat Using The Herbert –Pirt Relation T1 2 BB 42

For Electron Donor 408
Thermodynamics And Stoichiometry Of Product
27 T1 3 BB 45
Formation 414
MODEL EXAM

INTERNAL ASSESMENT DETAILS

ASSESSMENT NUMBER I II MODEL

Topic Nos 1-14 15-23 1-27

Date

ASSIGNMENT DETAILS

ASSIGNMENT I II III

TOPIC Nos For Reference 1-9 10-18 19-27

Deadline

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 ASSIGNMENT TOPICS

ASS:NO SECTION BATCH DESCRIPTIVE QUESTIONS/TOPICS

NO

I 1. Maxwell’s Relations And Applications.

I II 1. Volumetric Properties Of Fluids Exhibiting Non Ideal Behavior

III 1. Concepts Of Chemical Potential And Fugacity

I 1. Concepts And Applications Of Excess Properties Of Mixtures

II II 1. VLE Calculations For Binary Component Systems

III 1. VLE Calculations For Multi Component Systems

I 1. Effect Of Temperature And Pressure On Equilibrium Constant

1. Thermodynamics Of Microbial Growth Stoichiometry

III II
Thermodynamics Of Maintenance

III 1. Thermodynamics And Stoichiometry Of Product Formation

BATCH DETAIL
BATCH I
BATCH II
BATCH III

Prepared by Verified by Approved by

(S.R.Parthiban) HOD/MECH Principal

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