SAFETY DATA SHEET

Revision Date: 15/Aug/2013

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING
1.1. Product identifier
Product Description:
POLYLITE® 32166-17
SAP ID(s): 193840 ; 194381; 199505
Chemical Family: Polyester Resin

1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended Use Panel Resin
Marble Resin
Sector of use SU 3 - Industrial uses
SU12 - Manufacture of plastics products, including compounding and conversion
SU 22 - Professional uses
Product category PC32 - Polymer Mixtures and Compounds
Process categories PROC1 - Use in closed process, no likelihood of exposure
PROC3 - Use in closed batch process (synthesis or formulation); Industrial setting
PROC4 - Use in batch and other process (synthesis) where opportunity for exposure arises
PROC5 - Mixing or blending in batch processes for formulation of mixtures and articles
(multistage and/or significant contact)
PROC7 - Industrial spraying
PROC8a - Transfer of substance or mixture (charging/discharging) from/to vessels/large
containers at non dedicated facilities
PROC 8b - Transfer of substance or preparation (charging/discharging) from/to
vessels/large containers at dedicated facilities
PROC9 - Transfer of substance or mixture into small containers (dedicated filling line,
including weighing)
PROC10 - Roller application or brushing
PROC11 - Non industrial spraying
PROC13 - Treatment of articles by dipping and pouring
PROC14 - Production of mixtures or articles by tabletting, compression, extrusion,
pelletization
PROC15 - Use as a laboratory reagent
Uses advised against No information available

1.3. Details of the supplier of the safety data sheet

Manufacturer:
Reichhold UK Ltd.
54 Willow Road
Mitcham, Surrey
United Kingdom
CR4 4NA
+44 208 648 4684

Email: prodsafety@reichhold.com

1.4. Emergency telephone number

(CareChem24) +44(0)1235 239670

2. HAZARDS IDENTIFICATION
2.1. - Classification of the substance or mixture

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Classification according to Regulation (EC) No. 1272/2008

Not Determined

Classification according to EU Directives 67/548/EEC or 1999/45/EC

R10 - Xn;R48/20 - Xn;R20 - Xi;R36/37/38 - R43

2.2. Label Elements

Labelling according to Regulation (EC) 1272/2008 (CLP)

Not Determined

Labeling according to EU Directives 67/548/EEC or 1999/45/EC

Symbol(s) Xn - Harmful

Contains Styrene, methyl methacrylate

R -phrase(s)
R10 - Flammable
R20 - Harmful by inhalation
R43 - May cause sensitization by skin contact
R36/37/38 - Irritating to eyes, respiratory system and skin
R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation

EUH208 - Contains Methyl Methacrylate. May produce an allergic reaction.

S -phrase(s)
S16 - Keep away from sources of ignition - No smoking
S23 - Do not breathe gas/fumes/vapour/spray
S24 - Avoid contact with skin
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label
S7/9 - Keep container tightly closed and in a well-ventilated place
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection

2.3. Other hazards

No information available.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Component EC No. CAS-No Weight % Classification EU - GHS Substance REACH No.

Classification
Styrene 202-851-5 100-42-5 27.5 - 31.5 R10 Skin Irrit. 2 (H315) 01-2119457861-32
Xn;R20-48/20 Flam. Liq. 3 (H226)
Xn;R65 Eye Irrit. 2 (H319)
Xi;R36/37/38 Acute Tox. 4 (H332)
STOT RE 1 (H372)
STOT SE 3 (H335)
Asp. Tox. 1 (H304)

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Methyl 201-297-1 80-62-6 3-5 F; R11 Skin Irrit. 2 (H315) 01-2119452498-28

Xi; R37/38 Flam. Liq. 2 (H225)
methacrylate
R43 STOT SE 3 (H335)
Eye Irrit. 2 (H319)
Skin Sens. 1 (H317)

4. FIRST AID MEASURES

4.1. Description of first aid measures
Eye Contact:
Immediately flush eyes for at least 15 minutes. Get medical attention.

Skin contact:
Wash off with warm water and soap. Remove contaminated clothing and shoes. If skin irritation persists, call a physician. Wash
contaminated clothing before reuse.

Ingestion:
DO NOT INDUCE VOMITING. ASPIRATION HAZARD. This material may enter the lungs during vomiting. Never give anything by
mouth to an unconscious person. Get immediate medical attention.

Inhalation:
Remove person to fresh air. Keep patient warm and at rest. If breathing is labored, administer oxygen. If not breathing, give
artificial respiration. Get medical attention immediately.

4.2. Most important symptoms and effects, both acute and delayed
Irritating to eyes, respiratory system and skin. Harmful by inhalation, in contact with skin and if swallowed. May cause allergic skin
reaction.

4.3. Indication of immediate medical attention and special treatment needed

Notes to Physician
Treat symptomatically.

5. FIRE-FIGHTING MEASURES
5.1. Extinguishing media
Suitable Extinguishing Media:
Carbon dioxide (CO2), Foam, Dry chemical, Water spray

Extinguishing media which must not be used for safety reasons:

Do not use a solid water stream as it may scatter and spread fire.

5.2. Special hazards arising from the substance or mixture

Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases
Flammable. Vapors may form explosive mixture with air. Vapors may travel to areas away from work site before igniting/flashing
back to vapor source. Combustion may produce carbon monoxide, carbon dioxide, irritating or toxic vapors and gases. Fight fire
from maximum distance or use unmanned hose holders or monitor nozzles. Move containers from fire area if you can do it without
risk. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from
venting safety devices or discoloration of tank. Fire residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations.

5.3. Advice for firefighters

Special protective equipment for fire-fighters
Wear self-contained breathing apparatus and protective suit.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures
Remove all sources of ignition. Evacuate personnel to safe areas. Avoid contact with the skin and the eyes. Use personal
protective equipment. Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Beware of vapors
accumulating to form explosive concentrations. Vapors can accumulate in low areas.
All equipment used when handling the product must be grounded.

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6.2. Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product
from entering drains.

6.3. Methods and material for containment and cleaning up

A vapor suppressing foam may be used to reduce vapors. Absorb spill with inert material (e.g. dry sand or earth), then place in a
chemical waste container. Use clean non-sparking tools to collect absorbed material.

6.4. Reference to other sections

See Section 12 for additional information.

7. HANDLING AND STORAGE

7.1. Precautions for Safe Handling
Handling:
Do not breathe vapours or spray mist. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before
re-use. Ensure adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and
explosion-proof equipment. Consult your supplier of promoters and catalysts for additional instructions on proper mixing and usage.
Empty containers may retain product residue (liquid and/or vapor). Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose these containers to heat, flame, sparks, static electricity, or other sources of ignition as the container may explode and may
cause injury or death. Empty drums should be completely drained and properly bunged. Empty drums should be promptly returned
to a drum reconditioner or properly disposed. Do not use compressed air for filling, discharging or handling.

Hygiene Measures
Wash hands before eating, drinking, or smoking.

7.2. Conditions for safe storage, including any incompatibilities

Keep away from heat and sources of ignition. No smoking. Keep away from direct sunlight. Store away from incompatible
materials. Keep containers tightly closed in a cool, well-ventilated place. To ensure maximum stability and maintain optimum resin
properties, resins should be stored in closed containers at temperatures below 25°C.

7.3. Specific End Use(s)

Exposure Scenario No information available.
Other Guidelines No information available.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters
Exposure limits
Components with workplace control parameters.

Styrene
Austria 80 ppm STEL
340 mg/m3 STEL
20 ppm TWA
85 mg/m3 TWA
Belgium 50 ppm TWA
216 mg/m3 TWA
(skin)
100 ppm STEL
432 mg/m3 STEL
Bulgaria 85.0 mg/m3 TWA
215.0 mg/m3 STEL
Czech Republic 400 mg/m3 Ceiling
100 mg/m3 TWA
(skin)
Denmark 25 ppm Ceiling
105 mg/m3 Ceiling
(skin)

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Estonia 20 ppm TWA

90 mg/m3 TWA
50 ppm STEL
200 mg/m3 STEL
(skin)
Finland 20 ppm TWA
86 mg/m3 TWA
100 ppm STEL
430 mg/m3 STEL
France 50 ppm TWA
215 mg/m3 TWA
Germany 20 ppm TWA
86 mg/m3 TWA
Greece 100 ppm TWA
425 mg/m3 TWA
250 ppm STEL
1050 mg/m3 STEL
Hungary 50 mg/m3 TWA AK
50 mg/m3 STEL CK
Ireland 20 ppm TWA
85 mg/m3 TWA
40 ppm STEL
170 mg/m3 STEL
Latvia 10 mg/m3 TWA
30 mg/m3 STEL
Lithuania 20 ppm TWA (IPRD)
90 mg/m3 TWA (IPRD)
10 ppm TWA (IPRD)
50 ppm STEL (TPRD)
200 mg/m3 STEL (TPRD)
(skin)
Norway 25 ppm TWA
105 mg/m3 TWA
M
37.5 ppm STEL
131.25 mg/m3 STEL
Poland 200 mg/m3 STEL
50 mg/m3 TWA
(skin)
Portugal OELs Data 20 ppm
40 ppm STEL
Romania 12 ppm TWA
50 mg/m3 TWA
35 ppm STEL
150 mg/m3 STEL
Russia 10 mg/m3 TWA (vapor)
30 mg/m3 STEL (vapor)
Slovakia 20 ppm TWA
86 mg/m3 TWA
200 mg/m3 Ceiling
Slovenia 20 ppm TWA
86 mg/m3 TWA
80 ppm STEL
344 mg/m3 STEL
Spain 20 ppm TWA
86 mg/m3 TWA
40 ppm STEL
172 mg/m3 STEL

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Sweden 20 ppm LLV

90 mg/m3 LLV
50 ppm STV
200 mg/m3 STV
(skin)
Switzerland 40 ppm STEL
170 mg/m3 STEL
20 ppm TWA
85 mg/m3 TWA
United Kingdom 100 ppm TWA
430 mg/m3 TWA
250 ppm STEL
1080 mg/m3 STEL
ACGIH - TLV 20 ppm TWA
40 ppm STEL
Methyl methacrylate
European Union 100 ppm Indicative
50 ppm Indicative
Austria 100 ppm STEL
420 mg/m3 STEL
50 ppm TWA
210 mg/m3 TWA
Belgium 50 ppm TWA
208 mg/m3 TWA
100 ppm STEL
416 mg/m3 STEL
Bulgaria 50.0 mg/m3 TWA
Czech Republic 150 mg/m3 Ceiling
50 mg/m3 TWA
(skin)
Denmark 25 ppm
102 mg/m3
(skin)
Estonia 50 ppm TWA
100 ppm STEL
Finland 10 ppm TWA
42 mg/m3 TWA
50 ppm STEL
210 mg/m3 STEL
France 50 ppm TWA
410 mg/m3 TWA
200 ppm
820 mg/m3
Germany 50 ppm TWA
210 mg/m3 TWA
Greece 100 ppm TWA
410 mg/m3 TWA
200 ppm STEL
820 mg/m3 STEL
Hungary 210 mg/m3 TWA AK
210 mg/m3 STEL CK
(skin)
Ireland 50 ppm TWA
100 ppm STEL
Latvia 10 mg/m3 TWA
Lithuania 50 ppm TWA (IPRD)
200 mg/m3 TWA (IPRD)
100 ppm STEL (TPRD)
400 mg/m3 STEL (TPRD)
Luxembourg 50 ppm TWA
100 ppm STEL

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The Netherlands 410 mg/m3 STEL

205 mg/m3 TWA
Norway 25 ppm TWA
100 mg/m3 TWA
A
100 ppm STEL
400 mg/m3 STEL
(skin)
Poland 300 mg/m3 STEL
100 mg/m3 TWA
Portugal OELs Data 50 ppm
100 ppm STEL
Romania 150 mg/m3 TWA
250 mg/m3 STEL
Russia 10 mg/m3 TWA (vapor)
20 mg/m3 STEL (vapor)
Slovakia 50 ppm TWA
210 mg/m3 TWA
420 mg/m3 Ceiling
Slovenia 50 ppm TWA
210 mg/m3 TWA
100 ppm STEL
420 mg/m3 STEL
Spain 50 ppm TWA
100 ppm STEL
Sweden 50 ppm LLV
200 mg/m3 LLV
150 ppm STV
600 mg/m3 STV
(skin)
Switzerland 100 ppm STEL
420 mg/m3 STEL
50 ppm TWA
210 mg/m3 TWA
United Kingdom 50 ppm TWA
208 mg/m3 TWA
100 ppm STEL
416 mg/m3 STEL
ACGIH - TLV 50 ppm TWA
100 ppm STEL

Legend:
ACGIH - American Conference of Industrial Hygienists
TLV - Threshold Limit Value
TWA - Time weighted average
STEL: Short Term Exposure Limit
MAK - Maximum Occupational Exposure Limits
SKIN: Skin Absorption

Biological occupational exposure limits

Component Styrene
Bulgaria
BEI: 600 mg/g Creatinine, DETERMINANT: Mandelic acid and Phenylglyoxylic acid - together in urine, SAMPLING TIME: at
the end of exposure or end of shift, in remote exposure - after several shifts
Finland
BEI: 1.2 mmol/L, DETERMINANT: MAPGA in urine, SAMPLING TIME: prior to shift, NOTE: MAPGA equals sum of urinary
Mandelic and Phenylglyoxylic acids

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France
BEI: 0.55 mg/L, DETERMINANT: Styrene in venous blood, SAMPLING TIME: end of shift, NOTE: Semi-quantitative
(ambiguous interpretation)
BEI: 0.02 mg/L, DETERMINANT: Styrene in venous blood, SAMPLING TIME: prior to shift, NOTE: Semi-quantitative
(ambiguous interpretation)
BEI: 800 mg/g creatinine, DETERMINANT: Mandelic acid in urine, SAMPLING TIME: end of shift, NOTE: Non-specific
(observed after the exposure to other substances)
BEI: 300 mg/g creatinine, DETERMINANT: Mandelic acid in urine, SAMPLING TIME: prior to shift, NOTE: Non-specific
(observed after the exposure to other substances)
BEI: 240 mg/g creatinine, DETERMINANT: Phenylglyoxylic acid in urine, SAMPLING TIME: end of shift, NOTE: Non-specific
(observed after the exposure to other substances)
BEI: 100 mg/g creatinine, DETERMINANT: Phenylglyoxylic acid in urine, SAMPLING TIME: prior to shift, NOTE:
Germany
BEI: 600 mg/g, DETERMINANT: Mandelic acid plus Phenylglyoxylic acid in urine, SAMPLING TIME: end of shift, NOTE:
measured as mg/g Creatinine
BEI: 600 mg/g, DETERMINANT: Mandelic acid plus Phenylglyoxylic acid in urine, SAMPLING TIME: end of several shifts,
NOTE: measured as mg/g Creatinine; for long-term exposures
Latvia
BEI: 0.8 g/g Creatinine, DETERMINANT: Mandelic acid in urine, SAMPLING TIME: end of shift
BEI: 0.55 mg/g, DETERMINANT: Styrene in blood, SAMPLING TIME: end of shift
Romania
BEI: 800 mg/g creatinine, DETERMINANT: Mandelic acid in urine, SAMPLING TIME: end of shift
BEI: 300 mg/g creatinine, DETERMINANT: Mandelic acid in urine, SAMPLING TIME: beginning of second shift
BEI: 100 mg/g creatinine, DETERMINANT: Phenylglyoxylic acid in urine, SAMPLING TIME: end of shift
BEI: 100 mg/g creatinine, DETERMINANT: Phenylglyoxylic acid in urine, SAMPLING TIME: beginning of second shift
BEI: 0.55 mg/L, DETERMINANT: Styrene in blood, SAMPLING TIME: end of shift
BEI: 0.02 mg/L, DETERMINANT: Styrene in blood, SAMPLING TIME: beginning of second shift
Slovakia
BEI: 600 mg/g creatinine, DETERMINANT: Mandelic acid and phenylglycolic acid in urine, SAMPLING TIME: after all work
shifts, NOTE: for long-term exposure
BEI: 600 mg/g creatinine, DETERMINANT: Mandelic acid and phenylglycolic acid in urine, SAMPLING TIME: end of exposure
or work shift, NOTE:

Component Derived No Effect Level (DNEL) Predicted No Effect Concentration

(PNEC)

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Styrene End Use: Workers Fresh water

Exposure Route: Inhalation Value: 0.028 mg/l
Exposure Type: Acute, systemic effects Assessment factor: 10
Value: 289 mg/m3 (68 ppm)
Sea water
End Use: Workers Value: 0.0028 mg/l
Exposure Route: Inhalation Assessment factor: 100
Exposure Type: Acute, local effects
Value: 306 mg/m3 (72 ppm) Water
Value: 0.04 mg/l Intermittent Releases
End Use: Workers Assessment factor: 100
Exposure Route: Inhalation
Exposure Type: Long term, systemic Fresh water sediment
effects Value: 0.614 mg/kg dw
Value: 85 mg/m3 (20 ppm)
Sea sediment
End Use: Workers Value: 0.0614 mg/kg dw
Exposure Route: Dermal
Exposure Type: Long term, systemic Sewage Treatment Plant
effects Value: 5 mg/l
Value: 406 mg/kg bw/day Assessment factor: 100

End Use: General Population Soil

Exposure Route: Inhalation Value: 0.2 mg/kg dw
Exposure Type: Acute, systemic effects
Value: 174.25 mg/m3 (41 ppm)

End Use: General Population

Exposure Route: Inhalation
Exposure Type: Acute, local effects
Value: 182.75 mg/m3 (43 ppm)

End Use: General Population

Exposure Route: Inhalation
Exposure Type: Long term, systemic
effects
Value: 10.2 mg/m3 (2.4 ppm)

End Use: General Population

Exposure Route: Dermal
Exposure Type: Long term, systemic
effects
Value: 343 mg/kg bw/day

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Methyl methacrylate End Use: Workers Fresh water

Exposure Route: Dermal Value: 0.94 mg/l
Exposure Type: Acute, local effects
Value: 1.5 mg/cm2 Marine water
Value: 0.094 mg/l
End Use: Workers
Exposure Route: Dermal Intermittent releases
Exposure Type: Long term, systemic Value: 0.94 mg/l
effects
Value: 13.67 mg/kg bw/day Sewage Treatment Plant
Value: 10 mg/l
End Use: Workers
Exposure Route: Inhalation Fresh water sediment
Exposure Type: Long term, systemic Value: 5.74 mg/kg dw
effects
Value: 210 mg/m3 (51.3 ppm) Soil
Value: 1.47 mg/kg dw
End Use: Workers
Exposure Route: Dermal
Exposure Type: Long term, local effects
Value: 1.5 mg/cm2

End Use: Workers

Exposure Route: Inhalation
Exposure Type: Long term, local effects
Value: 210 mg/m3 (51.3 ppm)

End Use: General Population

Exposure Route: Dermal
Exposure Type: Acute, local effects
Value: 1.5 mg/cm2

End Use: General Population

Exposure Route: Dermal
Exposure Type: Long term, systemic
effects
Value: 8.2 mg/kg bw/day

End Use: General Population

Exposure Route: Inhalation
Exposure Type: Long term, systemic
effects
Value: 74.3 mg/m3 (18.2 ppm)

End Use: General Population

Exposure Route: Dermal
Exposure Type: Long term, local effects
Value: 1.5 mg/cm2

End Use: General Population

Exposure Route: Inhalation
Exposure Type: Long term, local effects
Value: 105 mg/m3 (25.7 ppm)

8.2. Exposure controls

Engineering Controls: Use general ventilation to maintain airborne concentrations to levels that are below
regulatory and recommended occupational exposure limits. Local ventilation may be
required during certain operations.

Personal protective equipment

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Eye Protection Safety glasses with side-shields conforming to EN166. If splashes are likely to occur, wear:.
Tightly fitting safety goggles (EN166). Ensure that eyewash stations and safety showers are
close to the workstation location.

Skin Protection: Impervious clothing.

Hand Protection Protective gloves complying with EN 374. Wear chemical-resistant gloves such as polyvinyl
alcohol or Viton. Gloves made of nitrile rubber or polyvinyl chloride (PVC) may be used for
splash protection and brief or intermittent contact with styrenated polyester resin. Please
observe the instructions regarding permeability and breakthrough time which are provided
by the supplier of the gloves. Also take into consideration the specific local conditions under
which the product is used, such as the danger of cuts, abrasion.

Respiratory Protection: None required if hazards have been assessed and airborne concentrations are maintained
below the exposure limits listed in Section 8. Wear an approved air-purifying respirator with
organic vapor cartridges and particulate filters where airborne concentrations may exceed
exposure limits in Section 8 and/or there is exposure to dust or mists due to sanding,
grinding, cutting, or spraying. Use an approved positive-pressure air-supplied respirator
with emergency escape provisions if there is any potential for an uncontrolled release,
airborne concentrations are not known, or any other circumstances where air-purifying
respirators may not provide adequate protection.

Recommended Filter type: Type A (EN141) and Type P2 (EN143)

Environmental exposure controls Local authorities should be advised if significant spillages cannot be contained.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties
Appearance: Pink Clear Physical State: Liquid
Odor: Pungent Odor Threshold: 0.2 ppm (Styrene)
0.05 - 0.21 ppm (Methyl Methacrylate)

Remarks/ Method
pH: Not applicable None known
Melting Point / Freezing Point Not applicable None known
Boiling point/boiling range 100°C - 146°C None known
Flash Point: 26 °C (ISO 3679)
Evaporation Rate: 0.49 - 3.1 (BuAc = 1) None known
Flammability Limits in Air None known
Upper: 12.5%
Lower: 1.1%
Vapor pressure 6.7 - 27 hPa @ 20°C None known
Vapor Density: 3.6 - 3.94 (Air = 1) None known
Specific Gravity 1.07 - 1.12 @ 23°C None known
Solubility: Insoluble in water None known
Partition coefficient: n-octanol/waterNo data available None known
Autoignition temperature 430°C - 490°C (DIN 51794)
Decomposition temperature No data available None known
Viscosity 900 - 1200 mPas @ 25°C Brookfield Test Method
Explosive Properties No information available
Oxidizing Properties No information available

9.2. Other information

No information available

10. STABILITY AND REACTIVITY

10.1. Reactivity

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Unstable upon depletion of inhibitor.

10.2. Chemical Stability

Stable under normal conditions. Stable under recommended storage conditions.

10.3. Possibility of Hazardous Reactions

Polymerization can occur. Hazardous polymerization will occur if contaminated with peroxides, metal salts and polymerization
catalysts. Hazardous polymerization may occur upon depletion of inhibitor - may cause heat and pressure build-up in closed
containers. Product will undergo hazardous polymerization at temperatures above 150 F (65 C).

10.4. Conditions to Avoid

Heat, flames and sparks. Contamination by those materials referred to under Incompatible materials. Unstable upon depletion of
inhibitor. Elevated temperatures.

10.5. Incompatible materials

Strong acids. Strong oxidizing agents. Metal salts. Polymerization initiators. Copper. Copper alloys. Brass.

10.6. Hazardous Decomposition Products

Hydrocarbons. Carbon monoxide. Carbon dioxide (CO2). Thermal decomposition can lead to release of irritating gases and
vapours.

11. TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects
Acute Toxicity
Inhalation Harmful by inhalation. May cause irritation of respiratory tract. Inhalation of high vapor
concentrations can cause CNS depression and narcosis.
Eye Contact Irritating to eyes.
Skin Contact Causes skin irritation. May cause sensitization by skin contact. Prolonged skin contact may
defat the skin and produce dermatitis.
Ingestion Harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhea. Aspiration hazard if swallowed - can enter lungs and cause damage.

Styrene
LD50 Oral: = 5000 mg/kg (Rat)
LD50 Dermal: > 2000 - (Rat) mg/kg
LC50 Inhalation: = 11.8 mg/l (4 H) Rat
Methyl methacrylate
LD50 Oral: = 7872 mg/kg (Rat)

Irritation Irritating to eyes and skin.

Corrosivity Not corrosive.

Sensitization: May cause sensitization of susceptible persons by skin contact.

Carcinogenic Effects There is no convincing evidence that styrene possesses significant carcinogenic potential in
humans.

Repeated Dose Toxicity: In humans, styrene may cause a transient decrease in color discrimination and effects on
hearing. Repeated or prolonged exposure may cause skin irritation and dermatitis, due to
defatting properties of the product. May cause damage to the liver, eyes, brain, respiratory
system, central nervous system through prolonged or repeated exposure if inhaled.

Mutagenic Effects: Styrene has given mixed positive and negative results in a number of mutagenicity tests.
Styrene was not mutagenic without metabolic activation but gave negative and positive
mutagenic results with metabolic activation.

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Target Organ(s): Liver, Central nervous system (CNS), Respiratory system, Skin.

12. ECOLOGICAL INFORMATION

12.1. Toxicity
Ecotoxicity effects: .

Styrene
Freshwater Algae EC50 = 1.4 mg/L (Pseudokirchneriella subcapitata) (72h)
EC50 0.46 - 4.3 mg/L (Pseudokirchneriella subcapitata) (72h)
Freshwater Fish LC50 3.24 - 4.99 mg/L (Pimephales promelas) (96 h) flow-through
LC50 19.03 - 33.53 mg/L (Lepomis macrochirus) (96 h) static
LC50 6.75 - 14.5 mg/L (Pimephales promelas) (96 h) static
LC50 58.75 - 95.32 mg/L (Poecilia reticulata) (96 h) static
Aquatic Invertebrates EC50 3.3 - 7.4 mg/L (Daphnia magna) (48h)
Methyl methacrylate
Freshwater Fish LC50 243 - 275 mg/L (Pimephales promelas) (96 h) flow-through
LC50 125.5 - 190.7 mg/L (Pimephales promelas) (96 h) static
LC50 170 - 206 mg/L (Lepomis macrochirus) (96 h) flow-through
LC50 153.9 - 341.8 mg/L (Lepomis macrochirus) (96 h) static
LC50 > 79 mg/L (Oncorhynchus mykiss) (96 h) flow-through
LC50 > 79 mg/L (Oncorhynchus mykiss) (96 h) static
LC50 326.4 - 426.9 mg/L (Poecilia reticulata) (96 h) static
Aquatic Invertebrates EC50 = 69 mg/L (Daphnia magna) (48h)

12.2. Persistence and degradability

No information available.

12.3. Bioaccumulative potential.

Bioaccumulation is unlikely.
Styrene
Log Kow 2.95
Bioconcentration factor (BCF) 13.5 fish
Methyl methacrylate
Log Kow 0.7

12.4. Mobility in soil

No information available.

12.5. Results of PBT and vPvB assessment

This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This mixture contains no
substance considered to be very persistent nor very bioaccumulating (vPvB).

12.6. Other adverse effects

No information available.

13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods
Waste from Residues / Unused This material and its container must be disposed of as hazardous waste. Dispose of in
Products accordance with local regulations. Can be incinerated, when in compliance with local
regulations.

Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.

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EWC Waste Disposal No 07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES

07 02 00 Wastes from MFSU of plastics, synthetic rubber and man-made fibres
07 02 99 Wastes not otherwise specified

14. TRANSPORT INFORMATION

ADR/RID

UN-No UN1866
Proper Shipping Name RESIN SOLUTION
Hazard Class 3
Packing Group III
Environmental hazard None
Classification Code F1
Hazard Identification No: 30
Tunnel Restriction Code D/E
ADR Exception This material meets the viscosity criteria specified in ADR 2.2.3.1.5 and may be classed as
"not dangerous" when packaged in containers of less than 450 liters.

IMDG/IMO

UN-No UN1866
Proper Shipping Name RESIN SOLUTION
Hazard Class CLASS 3
Packing Group PG III
Environmental hazard None
EmS No. F-E, S-E
IMDG Exception This material meets the viscosity criteria specified in IMDG Code 2.3.2.5 and may be
exempt from the marking, labelling and package testing requirements if transported in
containers of 30 liters or less.

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information available.

IATA

UN-No UN1866
Proper Shipping Name RESIN SOLUTION
Hazard Class 3
Packing Group III
Environmental hazard None
Packing Instructions 355; 366

15. REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Denmark

List of substances and processes that are considered to be carcinogenic

Component Status
Styrene (CAS #: 100-42-5) Present
Additional information
Must not be used by youngsters under the age of 18, ref. the notification from the Ministry of Labour regarding work by youngsters.
The user must have undergone special training approved by the Labour Inspection Authority (AT) in order to work with products
containing carcinogenic substances.

Germany

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WGK Classification
Hazardous to water/Class 2

Netherlands

No information available

Water Hazard Class

10-May cause long-term adverse effects in the aquatic environment.

International Inventories
TSCA Inventory Status: All components of this material are listed on or are exempt from the US Toxic Substances
Control Act (TSCA) inventory.

Canadian Inventory Status: All components of this material are listed on the Canadian Domestic Substances List (DSL).

Australian Inventory Status: This product contains only chemicals which are currently listed on the Australian Inventory
of Chemical Substances.

Korean Inventory Status: This product contains only chemicals which are currently listed on the Korean Chemical
Substances List.

Philippine Inventory: This product contains one or more chemicals currently not on the Philippine Inventory of
Chemicals and Chemical Substances.

Japan ENCS: This product contains only chemicals that are currently listed on the Japanese Inventory of
Existing and New Chemical Substances.

Chinese IECS: This product contains only chemicals that are currently listed on the Chinese Inventory of
Existing Chemical Substances.

New Zealand Inventory: This product contains only chemicals which are currently listed on the New Zealand
Inventory of Chemicals.

Product Registrations
Norway Not applicable
Denmark Not applicable
Sweden Not applicable

16. OTHER INFORMATION

Text of R phrases mentioned in Section 3
R10 - Flammable
R11 - Highly flammable
R20 - Harmful by inhalation
R43 - May cause sensitization by skin contact
R65 - Harmful: may cause lung damage if swallowed
R36/37/38 - Irritating to eyes, respiratory system and skin
R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation
R37/38 - Irritating to respiratory system and skin

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Full text of H-Statements referred to under sections 2 and 3

H225 - Highly flammable liquid and vapor
H226 - Flammable liquid and vapor
H302 - Harmful if swallowed
H304 - May be fatal if swallowed and enters airways
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H332 - Harmful if inhaled
H335 - May cause respiratory irritation
H372 - Causes damage to organs through prolonged or repeated exposure if inhaled
H400 - Very toxic to aquatic life
H410 - Very toxic to aquatic life with long lasting effects

AT Bekendgørelse nr. 908 af 27 september 2005 med senere ændringer

Prepared By Reichhold Product Regulatory Department

Phone Number: +1-919-990-7500

Revision Date: 15/Aug/2013

Revision Summary: Initial Release

Former date New

This information is provided in good faith and is correct to the best of Reichhold's knowledge as of the date hereof and is designed
to assist our customers; however, Reichhold makes no representation as to its completeness or accuracy. Our products are
intended for sale to industrial and commercial customers. We require customers to inspect and test our products before use and to
satisfy themselves as to suitability for their specific applications. Any use which Reichhold customers or third parties make of this
information, or any reliance on, or decisions made based upon it, are the responsibility of such customer or third party. Reichhold
disclaims responsibility for damages, or liability, of any kind resulting from the use of this information. THERE ARE NO
WARRANTIES OR REPRESENTATIONS, EXPRESS OR IMPLIED, INCLUDING THOSE OF MERCHANTABILITY OR FITNESS
FOR A PARTICULAR PURPOSE WITH RESPECT TO THIS INFORMATION OR TO THE PRODUCT IT DESCRIBES. IN NO
EVENT SHALL REICHHOLD BE LIABLE FOR SPECIAL, INCIDENTAL, OR CONSEQUENTIAL DAMAGES.

End of Safety Data Sheet

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