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This SDS summarizes information about Dettol Antibacterial Hand Sanitizer Gel, including its ingredients, hazards, safe use, and emergency response procedures. The main ingredients are ethanol (60-75%) and other non-hazardous components. It is classified as flammable and can cause eye irritation. In case of accidental release, isolate the area and contain the spill while wearing proper protective equipment. Dispose of cleaned materials according to local regulations.

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0% found this document useful (0 votes)
133 views10 pages

Soap0047 PDF

This SDS summarizes information about Dettol Antibacterial Hand Sanitizer Gel, including its ingredients, hazards, safe use, and emergency response procedures. The main ingredients are ethanol (60-75%) and other non-hazardous components. It is classified as flammable and can cause eye irritation. In case of accidental release, isolate the area and contain the spill while wearing proper protective equipment. Dispose of cleaned materials according to local regulations.

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vina aviani
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© © All Rights Reserved
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You are on page 1/ 10

This SDS is prepared in accord with the SWA document “Preparation of Safety Data Sheets for Hazardous

Chemicals - Code of Practice” (Feb 2016).

SAFETY DATA SHEET


Dettol Antibacterial Hand Sanitizer Gel, All Scents

1. Identification of the material and supplier


Names
Product name : Dettol Antibacterial Hand Sanitizer Gel, All Scents
SDS no. : D0056641 v13.2
Formulation # : 1231-002 (0087620v1.0 / 0257528v2.0) Original
AA-0266-058A (0138163v2.0 / 0259496v1.0) Refresh
AA-0266-058C (0170697v1.0 / 0337802v1.0) Blush/Soothe
Supplier : AUSTRALIA
Reckitt Benckiser (Australia) Pty Limited
ABN: 17 003 274 655
44 Wharf Road, West Ryde. NSW 2114
Tel: +61 (0)2 9857 2000

NEW ZEALAND
Reckitt Benckiser (New Zealand) Limited
2 Fred Thomas Drive, Takapuna,
Auckland, New Zealand 0622
Tel: +64 9 484 1400
Emergency telephone number : (7am - 10pm business days EST Australia): +61 (02) 9857 2444
(9am - 12am business days New Zealand): +64 9 484 1400
Poison Information contact: : Australia - 13 11 26
New Zealand - 0800 764 766 or 0800 POISON

Material uses : Hand Sanitiser.


Product use : Consumer

Section 2. Hazard(s) identification


Classification of the : FLAMMABLE LIQUIDS - Category 3
substance or mixture SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2A
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 1%

GHS label elements


Hazard pictograms :

Signal word : WARNING


Hazard statements : Flammable liquid and vapour.
Causes serious eye irritation.
Precautionary statements
General : Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
Prevention : Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use
explosion-proof electrical, ventilating, lighting and all material-handling equipment.
Use only non-sparking tools. Take precautionary measures against static discharge.
Keep container tightly closed. Wash hands thoroughly after handling.
Response : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water or shower. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical attention.
Storage : Store in a well-ventilated place. Keep cool.

Date of issue : 27/11/2016 Page: 1/10


D0056641 v13.0

Section 2. Hazard(s) identification


Disposal : Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Supplemental label : Not applicable.
elements

Other hazards which do not : None known.


result in classification

Section 3. Composition and ingredient information


Substance/mixture : Mixture

Ingredient name % (w/w) CAS number


ethanol ≥60 - ≤75 64-17-5
Other Non-hazardous ingredients to 100%
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation. Get medical attention if
adverse health effects persist or are severe. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air
and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness

Date of issue : 27/11/2016 Page: 2/10


D0056641 v13.0

Section 4. First aid measures


Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Firefighting measures


Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Flammable liquid and vapour. In a fire or if heated, a pressure increase will occur
from the chemical and the container may burst, with the risk of a subsequent explosion. Runoff to
sewer may create fire or explosion hazard.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Hazchem code : •2Y

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and material for containment and cleaning up

Date of issue : 27/11/2016 Page: 3/10


D0056641 v13.0

Section 6. Accidental release measures


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach the release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilt product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

See Section 1 for emergency contact information.


See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest.
Avoid contact with eyes, skin and clothing. Avoid breathing vapour or mist. Use
only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved
including any area. Store in original container protected from direct sunlight in a dry, cool and well-
incompatibilities ventilated area, away from incompatible materials (see Section 10) and food and
drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not
store in unlabelled containers. Use appropriate containment to avoid environmental
contamination.

Section 8. Exposure controls and personal protection


Control parameters
Australia
Occupational exposure limits
Ingredient name Exposure limits
ethanol Safe Work Australia (Australia, 1/2014).
TWA: 1880 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
New Zealand

Date of issue : 27/11/2016 Page: 4/10


D0056641 v13.0

Section 8. Exposure controls and personal protection


Ingredient name Exposure limits
ethanol NZ OSH (New Zealand, 2/2013).
WES-TWA: 1000 ppm 8 hours.
WES-TWA: 1880 mg/m³ 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapour or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated.
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties


Appearance
Physical state : Liquid. [Gelatinous precipitate.]
Colour : Clear.
Green.
Pink
Light Blue.
Odour : Characteristic.
Odour threshold : Not available.

Date of issue : 27/11/2016 Page: 5/10


D0056641 v13.0

Section 9. Physical and chemical properties


pH : 6.5 to 8 [25°C]
Melting point : Not available.
Boiling point : 76°C (168.8°F)
Flash point : Closed cup: 24°C (75.2°F)
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapour pressure : 5.7 kPa (42.754 mm Hg) [room temperature]
Vapour density : Not available.
Relative density : 0.87 to 0.9
Solubility : Easily soluble in the following materials: cold water and hot water.
Solubility in water : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Dynamic (room temperature): 4000 to 8000 mPa·s (4000 to 8000 cP)
Flow time (ISO 2431) : Not available.

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible materials : Reactive or incompatible with the following materials:


oxidizing materials

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
ethanol LC50 Inhalation Vapour Rat 124700 mg/m³ 4 hours
LD50 Oral Rat 7 g/kg -
Conclusion/Summary : Not classified * Information is based on toxicity test result of a similar product.
Irritation/Corrosion

Date of issue : 27/11/2016 Page: 6/10


D0056641 v13.0

Section 11. Toxicological information


Product/ingredient name Result Species Score Exposure Observation
ethanol Eyes - Moderate irritant Rabbit - 0.066666667 -
minutes 100
milligrams
Eyes - Mild irritant Rabbit - 24 hours 500 -
milligrams
Eyes - Moderate irritant Rabbit - 100 -
microliters
Eyes - Severe irritant Rabbit - 500 -
milligrams
Skin - Mild irritant Rabbit - 400 -
milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Dettol Antibacterial Hand Eyes - Cornea opacity Rabbit 2 - -
Sanitizer Gel, All
Scents_Oasis Leo -
Zadie_D0056641_ANZ
Skin - Erythema/Eschar Rabbit 0 - -
Conclusion/Summary
Skin : Non-irritant to skin. * Information is based on toxicity test result of a similar product.
Eyes : Causes serious eye irritation. * Information is based on toxicity test result of a similar
product.
Sensitisation
Product/ingredient name Route of Species Result
exposure
Dettol Antibacterial Hand skin Human Not sensitizing
Sanitizer Gel, All
Scents_Oasis Leo -
Zadie_D0056641_ANZ
Conclusion/Summary
Skin : Non-sensitiser to skin. * Information is based on toxicity test result of a similar
product.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.

Information on likely routes : Not available.


of exposure
Potential acute health effects

Date of issue : 27/11/2016 Page: 7/10


D0056641 v13.0

Section 11. Toxicological information


Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Delayed and immediate effects as well as chronic effects from short and long-term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates
Not available.

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
ethanol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute EC50 2000 μg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 25500 μg/l Marine water Crustaceans - Artemia 48 hours
franciscana - Larvae
Acute LC50 42000 μg/l Fresh water Fish - Oncorhynchus mykiss 4 days
Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - 12 weeks
Larvae

Date of issue : 27/11/2016 Page: 8/10


D0056641 v13.0

Section 12. Ecological information


Persistence and degradability
Not available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
ethanol -0.35 - low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Vapour from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned
thoroughly internally. Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers.

14. Transport information


Regulation UN number Proper shipping name Classes PG* Label Additional information
ADG UN1170 ETHANOL SOLUTION 3 III Hazchem code
•2Y

Special provisions
144, 223

IMDG UN1170 ETHANOL SOLUTION. 3 III Limited quantity


1L

Emergency schedules
(EmS)
F-E, S-D

IATA UN1170 Ethanol solution 3 III See DG list.

PG* : Packing group

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Date of issue : 27/11/2016 Page: 9/10


D0056641 v13.0

Section 15. Regulatory information


Standard Uniform Schedule of Medicine and Poisons
Not scheduled
Model Work Health and Safety Regulations - Scheduled Substances
No listed substance
Australia inventory (AICS) : All components are listed or exempted.
New Zealand Inventory of : All components are listed or exempted.
Chemicals (NZIoC)
HSNO Group Standard : Cosmetic Products
HSNO Approval Number : HSR002552
Approved Handler : No.
Requirement
Tracking Requirement : No.

Section 16. Any other relevant information


Key to abbreviations : ADG = Australian Dangerous Goods
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
NOHSC = National Occupational Health and Safety Commission
SUSMP = Standard Uniform Schedule of Medicine and Poisons
UN = United Nations
Date of issue / Date of : 27/11/2016
revision
Revision comments : Update as per AUS GHS.
Version : 13.2
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2A Calculation method
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-
named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.

Please read all labels carefully before using product.

Date of issue : 27/11/2016 Page: 10/10

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