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Ethylene Glycol MSDS

1) The document is a safety data sheet for ethylene glycol industrial grade that provides information on product identification, hazards, composition, first aid measures, firefighting measures, and more. 2) Ethylene glycol is harmful if swallowed and may cause damage to organs like the kidneys through prolonged or repeated exposure. 3) In case of inhalation, skin contact, eye contact, or ingestion, flush areas with water and seek medical attention if irritation or other symptoms persist. Induced vomiting is only recommended if directed by medical personnel.

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0% found this document useful (0 votes)
92 views16 pages

Ethylene Glycol MSDS

1) The document is a safety data sheet for ethylene glycol industrial grade that provides information on product identification, hazards, composition, first aid measures, firefighting measures, and more. 2) Ethylene glycol is harmful if swallowed and may cause damage to organs like the kidneys through prolonged or repeated exposure. 3) In case of inhalation, skin contact, eye contact, or ingestion, flush areas with water and seek medical attention if irritation or other symptoms persist. Induced vomiting is only recommended if directed by medical personnel.

Uploaded by

mitsosmitroglou
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 16

SAFETY DATA SHEET

According to OSHA Hazard Communication Standard, 29 CFR


1910.1200

Version 19.0 Revision Date: 06/27/2016 Print Date: 06/29/2016

SECTION 1. IDENTIFICATION

Product name : Ethylene Glycol Industrial Grade

Product code : U1284


Manufacturer or supplier's details
Company : Shell Chemical LP
PO Box 2463
HOUSTON TX 77252-2463
USA
SDS Request : 1-800-240-6737
Customer Service : 1-855-697-4355

Emergency telephone number


Chemtrec Domestic (24 hr) : 1-800-424-9300
Chemtrec International (24 : 1-703-527-3887
hr)

Recommended use of the chemical and restrictions on use


Recommended use : Chemical intermediate.

Restrictions on use : This product must not be used in applications other than the
above without first seeking the advice of the supplier., Do not
use in the manufacture or preparation of foods or pharmaceu-
ticals., Keep out of reach of children and pets., Do not use in
theatrical fogs or other artificial smoke generator applications.,
Do not use in aircraft deicing applications.

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Acute toxicity (Oral) : Category 4

Specific target organ toxicity : Category 2 (Kidney)


- repeated exposure

GHS label elements


Hazard pictograms :

Signal word : Warning

Hazard statements : PHYSICAL HAZARDS:


Not classified as a physical hazard under GHS criteria.
HEALTH HAZARDS:
H302 Harmful if swallowed.
H373 May cause damage to organs (Kidney) through prolonged
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SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200

Version 19.0 Revision Date: 06/27/2016 Print Date: 06/29/2016

or repeated exposure.
ENVIRONMENTAL HAZARDS:
Not classified as an environmental hazard under GHS criteria.

Precautionary statements : Prevention:


P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
Response:
P301 + P312 IF SWALLOWED: Call a POISON CENTER or
doctor/ physician if you feel unwell.
P330 Rinse mouth.
P314 Get medical advice/ attention if you feel unwell.
Storage:
No precautionary phrases.
Disposal:
P501 Dispose of contents and container to appropriate waste
site or reclaimer in accordance with local and national regula-
tions.

Other hazards which do not result in classification


Inhalation of vapours or mists may cause irritation to the respiratory system.

The classification of this material is based on OSHA HCS 2012 criteria.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms : Dihydroxy ethane 1,2, Ethane diol 1,2, Ethylene Glycol, Gly-
col, MEG

Hazardous components
Chemical name Synonyms CAS-No. Concentration (%)
Ethylene glycol ethane-1,2-diol (In- 107-21-1 99 - 100
gested)
Diethylene glycol 2,2'-oxydiethanol 111-46-6 0 -<1

SECTION 4. FIRST-AID MEASURES

General advice : Not expected to be a health hazard when used under normal
conditions.

If inhaled : Remove to fresh air. If rapid recovery does not occur,


transport to nearest medical facility for additional treatment.

In case of skin contact : Remove contaminated clothing. Flush exposed area with wa-
ter and follow by washing with soap if available.
If persistent irritation occurs, obtain medical attention.

In case of eye contact : Flush eye with copious quantities of water.


If persistent irritation occurs, obtain medical attention.

If swallowed : If swallowed, do not induce vomiting: transport to nearest


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SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200

Version 19.0 Revision Date: 06/27/2016 Print Date: 06/29/2016

medical facility for additional treatment. If vomiting occurs


spontaneously, keep head below hips to prevent aspiration.
Rinse mouth.

Most important symptoms : Kidney toxicity may be recognized by blood in the urine or
and effects, both acute and increased or decreased urine flow. Other signs and symptoms
delayed can include nausea, vomiting, abdominal cramps, diarrhoea,
lumbar pain shortly after ingestion, and possibly narcosis and
death.
Eye irritation signs and symptoms may include a burning sen-
sation, redness, swelling, and/or blurred vision.
Skin irritation signs and symptoms may include a burning sen-
sation, redness, swelling, and/or blisters.
Respiratory irritation signs and symptoms may include a tem-
porary burning sensation of the nose and throat, coughing,
and/or difficulty breathing.

Protection of first-aiders : When administering first aid, ensure that you are wearing the
appropriate personal protective equipment according to the
incident, injury and surroundings.

Immediate medical attention, : The preferred treatment is immediate transportation to a med-


special treatment ical facility and use of appropriate treatment including possible
administration of activated charcoal, gastric lavage and or
gastric aspiration. If none of the above are immediately avail-
able and a delay of more than one hour is anticipated before
such medical attention can be obtained, induction of vomiting
may be appropriate using IPECAC syrup (Contraindicated if
there are any signs of CNS depression). This should be con-
sidered on a case by case basis following specialist advice.
Specific other treatments may include ethanol therapy, fomep-
izole, treatment of acidosis and haemodialysis. Seek specialist
advice without delay.
May cause significant renal, respiratory, and CNS toxicity.
May cause significant acidosis.
Call a doctor or poison control center for guidance.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Alcohol-resistant foam, water spray or fog. Dry chemical pow-
der, carbon dioxide, sand or earth may be used for small fires
only.

Unsuitable extinguishing : Do not use water in a jet.


media

Specific hazards during fire- : Material will not burn unless preheated.
fighting Carbon monoxide may be evolved if incomplete combustion
occurs.
Containers exposed to intense heat from fires should be
cooled with large quantities of water.

Specific extinguishing meth- : Standard procedure for chemical fires.


ods

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SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200

Version 19.0 Revision Date: 06/27/2016 Print Date: 06/29/2016

Further information : Clear fire area of all non-emergency personnel.


Evacuate the area of all non-essential personnel.
Keep adjacent containers cool by spraying with water.

Special protective equipment : Proper protective equipment including chemical resistant


for firefighters gloves are to be worn; chemical resistant suit is indicated if
large contact with spilled product is expected. Self-Contained
Breathing Apparatus must be worn when approaching a fire in
a confined space. Select fire fighter's clothing approved to
relevant Standards (e.g. Europe: EN469).

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Observe all relevant local and international regulations.
tive equipment and emer- Notify authorities if any exposure to the general public or the
gency procedures environment occurs or is likely to occur.
Local authorities should be advised if significant spillages
cannot be contained.

: Avoid contact with skin, eyes and clothing.

Environmental precautions : Prevent from spreading or entering into drains, ditches or riv-
ers by using sand, earth, or other appropriate barriers.
Use appropriate containment to avoid environmental contami-
nation.
Ventilate contaminated area thoroughly.

Methods and materials for : Contain run-off from residue flush and dispose of properly.
containment and cleaning up Soak up residue with an absorbent such as clay, sand or other
suitable material.

For small liquid spills (< 1 drum), transfer by mechanical


means to a labeled, sealable container for product recovery or
safe disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely Remove
contaminated soil and dispose of safely.
For large liquid spills (> 1 drum), transfer by mechanical
means such as vacuum truck to a salvage tank for recovery or
safe disposal. Do not flush away residues with water. Retain
as contaminated waste. Allow residues to evaporate or soak
up with an appropriate absorbent material and dispose of
safely. Remove contaminated soil and dispose of safely

Additional advice : For guidance on selection of personal protective equipment


see Chapter 8 of this Safety Data Sheet.
For guidance on disposal of spilled material see Chapter 13 of
this Safety Data Sheet.

SECTION 7. HANDLING AND STORAGE

Technical measures : Avoid breathing of or direct contact with material. Only use in
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SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200

Version 19.0 Revision Date: 06/27/2016 Print Date: 06/29/2016

well ventilated areas. Wash thoroughly after handling. For


guidance on selection of personal protective equipment see
Chapter 8 of this Safety Data Sheet.
Use the information in this data sheet as input to a risk as-
sessment of local circumstances to help determine appropri-
ate controls for safe handling, storage and disposal of this
material.
Ensure that all local regulations regarding handling and stor-
age facilities are followed.

Precautions for safe handling : Use local exhaust extraction over processing area.
Handle and open container with care in a well-ventilated area.
Do not empty into drains.
When handling product in drums, safety footwear should be
worn and proper handling equipment should be used.
Handling Temperature:
Ambient.

Avoidance of contact : Strong oxidising agents.


Strong acids.
Strong bases.

Product Transfer : Keep containers closed when not in use. Do not pressurize
drum containers to empty.

Storage
Conditions for safe storage, : Refer to section 15 for any additional specific legislation cov-
including any incompatibili- ering the packaging and storage of this product.
ties
Other data : Tanks must be clean, dry and rust-free.
Keep container tightly closed.
Must be stored in a diked (bunded) well- ventilated area, away
from sunlight, ignition sources and other sources of heat.
Cleaning, inspection and maintenance of storage tanks is a
specialist operation, which requires the implementation of
strict procedures and precautions.
Drums should be stacked to a maximum of 3 high.
Storage Temperature:
Ambient.

Packaging material : Suitable material: Stainless steel., Mild steel., Carbon steel
Unsuitable material: Data not available

Container Advice : Containers, even those that have been emptied, can contain
explosive vapours. Do not cut, drill, grind, weld or perform
similar operations on or near containers.

Specific use(s) : Not applicable

Ensure that all local regulations regarding handling and stor-


age facilities are followed.

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SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200

Version 19.0 Revision Date: 06/27/2016 Print Date: 06/29/2016

SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Components with workplace control parameters


Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
Ethylene glycol 107-21-1 C (Aerosol 100 mg/m3 ACGIH
only)
Biological occupational exposure limits
No biological limit allocated.
Monitoring Methods
Monitoring of the concentration of substances in the breathing zone of workers or in the general
workplace may be required to confirm compliance with an OEL and adequacy of exposure con-
trols. For some substances biological monitoring may also be appropriate.
Validated exposure measurement methods should be applied by a competent person and sam-
ples analysed by an accredited laboratory.
Examples of sources of recommended exposure measurement methods are given below or con-
tact the supplier. Further national methods may be available.
National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods
http://www.cdc.gov/niosh/
Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods
http://www.osha.gov/
Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances
http://www.hse.gov.uk/
Institut für Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany
http://www.dguv.de/inhalt/index.jsp
L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil
Engineering measures : The level of protection and types of controls necessary will
vary depending upon potential exposure conditions. Select
controls based on a risk assessment of local circumstances.
Appropriate measures include:
Adequate ventilation to control airborne concentrations.
Where material is heated, sprayed or mist formed, there is
greater potential for airborne concentrations to be generated.
Eye washes and showers for emergency use.

General Information:
Always observe good personal hygiene measures, such as
washing hands after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants. Discard con-
taminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
Define procedures for safe handling and maintenance of
controls.
Educate and train workers in the hazards and control
measures relevant to normal activities associated with this
product.
Ensure appropriate selection, testing and maintenance of
equipment used to control exposure, e.g. personal protective
equipment, local exhaust ventilation.
Drain down system prior to equipment break-in or mainte-
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According to OSHA Hazard Communication Standard, 29 CFR
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Version 19.0 Revision Date: 06/27/2016 Print Date: 06/29/2016

nance.
Retain drain downs in sealed storage pending disposal or
subsequent recycle.

Personal protective equipment


Respiratory protection : If engineering controls do not maintain airborne concentra-
tions to a level which is adequate to protect worker health,
select respiratory protection equipment suitable for the spe-
cific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers.
Where air-filtering respirators are unsuitable (e.g. airborne
concentrations are high, risk of oxygen deficiency, confined
space) use appropriate positive pressure breathing appa-
ratus.
Where air-filtering respirators are suitable, select an appro-
priate combination of mask and filter.
If air-filtering respirators are suitable for conditions of use:
Select a filter suitable for the combination of organic gases
and vapours [Type A/Type P boiling point >65°C (149°F)].

Respirator selection, use and maintenance should be in ac-


cordance with the requirements of the OSHA Respiratory
Protection Standard, 29 CFR 1910.134.

Hand protection
Remarks : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection. When prolonged or frequent
repeated contact occurs. Nitrile rubber gloves. Incidental
contact/Splash protection: PVC or neoprene rubber gloves.
For continuous contact we recommend gloves with break-
through time of more than 240 minutes with preference for >
480 minutes where suitable gloves can be identified. For
short-term/splash protection we recommend the same, but
recognize that suitable gloves offering this level of protection
may not be available and in this case a lower breakthrough
time maybe acceptable so long as appropriate maintenance
and replacement regimes are followed. Glove thickness is not
a good predictor of glove resistance to a chemical as it is
dependent on the exact composition of the glove material.
Glove thickness should be typically greater than 0.35 mm
depending on the glove make and model. Suitability and du-
rability of a glove is dependent on usage, e.g. frequency and
duration of contact, chemical resistance of glove material,
dexterity. Always seek advice from glove suppliers. Contami-
nated gloves should be replaced. Personal hygiene is a key
element of effective hand care. Gloves must only be worn on
clean hands. After using gloves, hands should be washed
and dried thoroughly. Application of a non-perfumed moistur-
izer is recommended.

Eye protection : If material is handled such that it could be splashed into eyes,
protective eyewear is recommended.

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According to OSHA Hazard Communication Standard, 29 CFR
1910.1200

Version 19.0 Revision Date: 06/27/2016 Print Date: 06/29/2016

Skin and body protection : Skin protection is not ordinarily required beyond standard
work clothes.
It is good practice to wear chemical resistant gloves.

Protective measures : Personal protective equipment (PPE) should meet recom-


mended national standards. Check with PPE suppliers.

Hygiene measures : Wash hands before eating, drinking, smoking and using the
toilet.
Launder contaminated clothing before re-use.

Environmental exposure controls


General advice : Local guidelines on emission limits for volatile substances
must be observed for the discharge of exhaust air containing
vapour.
Minimise release to the environment. An environmental as-
sessment must be made to ensure compliance with local envi-
ronmental legislation.
Information on accidental release measures are to be found in
section 6.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Slightly viscous liquid.

Colour : colourless

Odour : mild

Odour Threshold : 25 ppm

pH : Data not available

Melting / freezing point : -13 °C / 9 °F

Boiling point/boiling range : 196 - 200 °C / 385 - 392 °F

Flash point : 116 °C / 241 °F

Evaporation rate : 0.01


Method: ASTM D 3539, nBuAc=1

Flammability (solid, gas) : Not applicable

Upper explosion limit : 28 %(V)

Lower explosion limit : 3.2 %(V)

Vapour pressure : < 10 Pa (20 °C / 68 °F)

Relative vapour density : 2.2

Relative density : 1.1155 (20 °C / 68 °F)

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According to OSHA Hazard Communication Standard, 29 CFR
1910.1200

Version 19.0 Revision Date: 06/27/2016 Print Date: 06/29/2016

Density : Typical 1,113 kg/m3 (20 °C / 68 °F)


Method: ASTM D4052

Solubility(ies)
Water solubility : completely soluble

Partition coefficient: n- : log Pow: -1.93 (20 °C / 68 °F)Data not available


octanol/water

Auto-ignition temperature : 398 °C / 748 °F

Decomposition temperature : Data not available

Viscosity
Viscosity, dynamic : 16.1 mPa.s (25 °C / 77 °F)

Viscosity, kinematic : 24.8 mm2/s (20 °C / 68 °F)

Explosive properties : Not applicable

Oxidizing properties : Not applicable

Surface tension : Data not available

Conductivity : Data not available

Molecular weight : 62 g/mol

SECTION 10. STABILITY AND REACTIVITY

Reactivity : The product does not pose any further reactivity hazards in
addition to those listed in the following sub-paragraph.

Chemical stability : No hazardous reaction is expected when handled and stored


according to provisions
Oxidises on contact with air.

Possibility of hazardous reac- : None known.


tions

Conditions to avoid : Extremes of temperature and direct sunlight.


Product cannot ignite due to static electricity.

Incompatible materials : Strong oxidising agents.


Strong acids.
Strong bases.

Hazardous decomposition : Thermal decomposition is highly dependent on conditions. A


products complex mixture of airborne solids, liquids and gases includ-
ing carbon monoxide, carbon dioxide, sulphur oxides and
unidentified organic compounds will be evolved when this
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SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200

Version 19.0 Revision Date: 06/27/2016 Print Date: 06/29/2016

material undergoes combustion or thermal or oxidative degra-


dation.

SECTION 11. TOXICOLOGICAL INFORMATION

Basis for assessment : Information given is based on product testing, and/or similar
products, and/or components.

Information on likely routes of exposure


Skin and eye contact are the primary routes of exposure although exposure may occur through
inhalation or following accidental ingestion.
Acute toxicity

Product:
Acute oral toxicity : LD50 (Rat): >300 - <=2000 milligram per kilogram
Remarks: Harmful if swallowed.
There is a marked difference in acute oral toxicity between
rodents and man, man being more susceptible than rodents.
The estimated fatal dose for man is 100 milliliters (1/2 cup).
This material has also been shown to be toxic and potentially
lethal by ingestion to cats and dogs.

Acute inhalation toxicity : Remarks: Low toxicity by inhalation.

Acute dermal toxicity : LD50 : > 5,000 mg/kg


Remarks: Expected to be of low toxicity:

Skin corrosion/irritation

Product:
Remarks: Slightly irritating to skin.

Serious eye damage/eye irritation

Product:
Remarks: Slightly irritating to the eye.

Respiratory or skin sensitisation

Product:
Remarks: Not expected to be a sensitiser.

Germ cell mutagenicity

Product:
: Remarks: No evidence of mutagenic activity.

Carcinogenicity

Product:

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According to OSHA Hazard Communication Standard, 29 CFR
1910.1200

Version 19.0 Revision Date: 06/27/2016 Print Date: 06/29/2016

Remarks: Not carcinogenic in animal studies.

IARC No component of this product present at levels greater than or


equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

ACGIH No component of this product present at levels greater than or


equal to 0.1% is identified as a carcinogen or potential carcino-
gen by ACGIH.

OSHA No component of this product present at levels greater than or


equal to 0.1% is identified as a carcinogen or potential carcino-
gen by OSHA.

NTP No component of this product present at levels greater than or


equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Reproductive toxicity

Product:
:
Remarks: Does not impair fertility., Not a developmental toxi-
cant., Causes foetotoxicity in animals; considered to be sec-
ondary to maternal toxicity.

STOT - single exposure

Product:
Remarks: Inhalation of vapours or mists may cause irritation to the respiratory system., Ingestion
may cause drowsiness and dizziness.

STOT - repeated exposure

Product:
Target Organs: Kidney
Remarks: May cause damage to organs or organ systems through prolonged or repeated expo-
sure.

Aspiration toxicity

Product:
Not considered an aspiration hazard.

Further information

Product:
Remarks: Classifications by other authorities under varying regulatory frameworks may exist.

SECTION 12. ECOLOGICAL INFORMATION

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According to OSHA Hazard Communication Standard, 29 CFR
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Version 19.0 Revision Date: 06/27/2016 Print Date: 06/29/2016

Basis for assessment : Information given is based on product testing.


Ecotoxicity

Product:
Toxicity to fish (Acute toxici- : LC50: > 100 mg/l
ty) Remarks: Practically non toxic:

Toxicity to daphnia and other : EC50: > 100 mg/l


aquatic invertebrates (Acute Remarks: Practically non toxic:
toxicity)
Toxicity to algae (Acute tox- : ErC50: > 100 mg/l
icity) Remarks: Practically non toxic:

Toxicity to fish (Chronic tox- : Remarks: NOEC/NOEL > 100 mg/l


icity)

Toxicity to daphnia and other : Remarks: NOEC/NOEL > 100 mg/l


aquatic invertebrates (Chron-
ic toxicity)

Toxicity to bacteria (Acute : IC50: > 100 mg/l


toxicity) Remarks: Practically non toxic:

Persistence and degradability

Product:
Biodegradability : Remarks: Readily biodegradable.

Bioaccumulative potential

Product:
Bioaccumulation : Remarks: Does not have the potential to bioaccumulate signif-
icantly.

Mobility in soil

Product:
Mobility : Remarks: If the product enters soil, one or more constituents
will or may be mobile and may contaminate groundwater.
Dissolves in water.

Other adverse effects


no data available
Product:
Additional ecological infor- : Data not available
mation

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

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According to OSHA Hazard Communication Standard, 29 CFR
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Waste from residues : Recover or recycle if possible.


Waste arising from a spillage or tank cleaning should be dis-
posed of in accordance with prevailing regulations, preferably
to a recognised collector or contractor. The competence of the
collector or contractor should be established beforehand.
Remove all packaging for recovery or waste disposal.

Do not dispose into the environment, in drains or in water


courses
Waste product should not be allowed to contaminate soil or
water.

Disposal should be in accordance with applicable regional,


national, and local laws and regulations.
Local regulations may be more stringent than regional or na-
tional requirements and must be complied with.

Contaminated packaging : Dispose in accordance with prevailing regulations, preferably


to a recognized collector or contractor. The competence of
the collector or contractor should be established beforehand.

SECTION 14. TRANSPORT INFORMATION

National Regulations
US Department of Transportation Classification (49 CFR Parts 171-180)
UN/ID/NA number : UN 3082
Proper shipping name : Environmentally hazardous substances, liquid, n.o.s.
(Ethylene glycol)
Class : 9
Packing group : III
Labels : 9
Reportable quantity Ethylene glycol
(5,000 lb)
ERG Code : 171
Marine pollutant : yes
International Regulation

IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Pollution category : Y
Ship type : 3
Product name : Ethylene glycol
Special precautions : Refer to Chapter 7, Handling & Storage, for special precau-
tions which a user needs to be aware of or needs to comply
with in connection with transport.

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According to OSHA Hazard Communication Standard, 29 CFR
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Special precautions for user


Remarks : Special Precautions: Refer to Chapter 7, Handling & Storage,
for special precautions which a user needs to be aware of or
needs to comply with in connection with transport.

Additional Information : This product may be transported under nitrogen blanketing.


Nitrogen is an odourless and invisible gas. Exposure to nitro-
gen enriched atmospheres displaces available oxygen which
may cause asphyxiation or death. Personnel must observe
strict safety precautions when involved with a confined space
entry.

SECTION 15. REGULATORY INFORMATION

OSHA Hazards : This material is considered hazardous by the OSHA Hazard


Communication Standard (29 CFR 1910.1200).
EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity


Components CAS-No. Component RQ Calculated product RQ
(lbs) (lbs)
Ethylene glycol 107-21-1 5000 5000
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Immediate (Acute) Health Hazard


Delayed (Chronic) Health Hazard

SARA 302 : No chemicals in this material are subject to the reporting


requirements of SARA Title III, Section 302.

SARA 313 : The following components are subject to reporting levels es-
tablished by SARA Title III, Section 313:

Ethylene glycol 107-21-1 100 %

Clean Water Act


This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
Pennsylvania Right To Know
Ethylene glycol 107-21-1
New Jersey Right To Know
Ethylene glycol 107-21-1

California Prop 65 WARNING: This product contains a chemical known to the


State of California to cause birth defects or other reproductive
harm.
The components of this product are reported in the following inventories:
AICS : Listed

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According to OSHA Hazard Communication Standard, 29 CFR
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Version 19.0 Revision Date: 06/27/2016 Print Date: 06/29/2016

DSL : Listed

IECSC : Listed

ENCS : Listed

KECI : Listed

NZIoC : Listed

PICCS : Listed

CH INV : Listed

TSCA : Listed

Other regulations : The regulatory information is not intended to be


comprehensive. Other regulations may apply to this material.

SECTION 16. OTHER INFORMATION

Further information
NFPA Rating (Health, Fire, Reac- 1, 1, 0
tivity)

A vertical bar (|) in the left margin indicates an amendment from the previous version.
Abbreviations and Acronyms : The standard abbreviations and acronyms used in this docu-
ment can be looked up in reference literature (e.g. scientific
dictionaries) and/or websites.

ACGIH = American Conference of Governmental Industrial


Hygienists
ADR = European Agreement concerning the International
Carriage of Dangerous Goods by Road
AICS = Australian Inventory of Chemical Substances
ASTM = American Society for Testing and Materials
BEL = Biological exposure limits
BTEX = Benzene, Toluene, Ethylbenzene, Xylenes
CAS = Chemical Abstracts Service
CEFIC = European Chemical Industry Council
CLP = Classification Packaging and Labelling
COC = Cleveland Open-Cup
DIN = Deutsches Institut fur Normung
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
DSL = Canada Domestic Substance List
EC = European Commission
EC50 = Effective Concentration fifty
ECETOC = European Center on Ecotoxicology and Toxicolo-
gy Of Chemicals
ECHA = European Chemicals Agency
15 / 16 800001001028
US
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200

Version 19.0 Revision Date: 06/27/2016 Print Date: 06/29/2016

EINECS = The European Inventory of Existing Commercial


Chemical Substances
EL50 = Effective Loading fifty
ENCS = Japanese Existing and New Chemical Substances
Inventory
EWC = European Waste Code
GHS = Globally Harmonised System of Classification and
Labelling of Chemicals
IARC = International Agency for Research on Cancer
IATA = International Air Transport Association
IC50 = Inhibitory Concentration fifty
IL50 = Inhibitory Level fifty
IMDG = International Maritime Dangerous Goods
INV = Chinese Chemicals Inventory
IP346 = Institute of Petroleum test method N° 346 for the
determination of polycyclic aromatics DMSO-extractables
KECI = Korea Existing Chemicals Inventory
LC50 = Lethal Concentration fifty
LD50 = Lethal Dose fifty per cent.
LL/EL/IL = Lethal Loading/Effective Loading/Inhibitory loading
LL50 = Lethal Loading fifty
MARPOL = International Convention for the Prevention of
Pollution From Ships
NOEC/NOEL = No Observed Effect Concentration / No Ob-
served Effect Level
OE_HPV = Occupational Exposure - High Production Volume
PBT = Persistent, Bioaccumulative and Toxic
PICCS = Philippine Inventory of Chemicals and Chemical
Substances
PNEC = Predicted No Effect Concentration
REACH = Registration Evaluation And Authorisation Of
Chemicals
RID = Regulations Relating to International Carriage of Dan-
gerous Goods by Rail
SKIN_DES = Skin Designation
STEL = Short term exposure limit
TRA = Targeted Risk Assessment
TSCA = US Toxic Substances Control Act
TWA = Time-Weighted Average
vPvB = very Persistent and very Bioaccumulative

Sources of key data used to : The quoted data are from, but not limited to, one or more
compile the Safety Data sources of information (e.g. toxicological data from Shell
Sheet Health Services, material suppliers’ data, CONCAWE, EU
IUCLID date base, EC 1272 regulation, etc).

Revision Date : 06/27/2016

This information is based on our current knowledge and is intended to describe the product for
the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product.

16 / 16 800001001028
US

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