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General Organic Chemistry: Correct Explanation For STATEMENT-1

The document contains 18 statements about organic chemistry concepts with two statements paired together in each item. The key indicates that for most items, the first statement is true and the second statement is either a correct or incorrect explanation for the first statement. Some examples assessed are the relative stability of carbocations, the acidity of substituted benzoic acids, and the number of stereoisomers in a molecule. The document also provides short explanations for the answers to each item pairing.

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70 views5 pages

General Organic Chemistry: Correct Explanation For STATEMENT-1

The document contains 18 statements about organic chemistry concepts with two statements paired together in each item. The key indicates that for most items, the first statement is true and the second statement is either a correct or incorrect explanation for the first statement. Some examples assessed are the relative stability of carbocations, the acidity of substituted benzoic acids, and the number of stereoisomers in a molecule. The document also provides short explanations for the answers to each item pairing.

Uploaded by

sree anugraphics
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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GENERAL ORGANIC CHEMISTRY

Statement answers type questions:


(A) STATEMENT–1 is True, STATEMENT–2 is True; STATEMENT–2 is a Correct
explanation for STATEMENT–1
(B) STATEMENT–1 is True, STATEMENT–2 is True; STATEMENT–2 is NOT a
Correct explanation for STATEMENT–1
(C) STATEMENT–1 is True, STATEMENT–2 is False
(D) STATEMENT–1 is False, STATEMENT–2 is True
o
||
1 Statement I : Stability: CH 3 − CH ⊕ − C − H > CH 3 − CH ⊕ − CH 3
Statement II : Carbocation stabilized by + I groups
2. Statement -1 :n-Hexanol does not dissolve in water whereas ethanol
dissolves.
Statement -2: + I group present on oxygen decreases strength of
intermolecular hydrogen bonding.
3. Statement - 1: Chloroacetic acid is more acidic than bromoacetic acid.
Statement - 2: group present in acid decreases acidity of the compound
4. Statement I : ⊕ CF3 is more stable than ⊕ CH 3
Statement II : F is an electron withdrawing group
5. Statement-1: 2, 3 dichloropentane has four stereoisomers.
And
Statement-2: It contains two chiral carbon atoms
6. Statement 1 – C6 H 5COOH is more acidic than CH 3COOH
Statement 2 – C6 H 5COO − is more stabilized by resonance than CH 3COO − .
7. Statement 1 : Phenol and cyclohexa - 2,4 - di – ene – 1 – one are resonance
structures
Statement 2 : Relative positions of atoms change.
8. Statement 1 : p-CH3OC6 H 4CH 2 • is more stable than p-O 2 NC6 H 4CH 2 •
Statement 2 : + I effect of OCH3 group destabilizes free radicals while- I effect
of NO 2 stabilizes radicals.

9. STATEMENT1: The carbocation is more stable than


STATEMENT 2: The Cation is stabilised by the +M effect of the –OCH3
substitute.
10. STATEMENT 1: 4- Nitro phenol is a much stronger acid than pheno1
STATEMENT 2: NO2 ( -I,-M effecting group ) stabilizes the phenoxide ion.

11. STATEMENT 1: The cation is resonance stabilized, the cation


CH2 = CH Me3 is not.

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STATEMENT 2: ,
Pentavalency is not possible for Nitrogen.
12. Statement I : Picric acid is more acidic than p- nitrophenol
Statement II : Greater the number of electron with drawing groups, greater is
the acidic character
of phenols.
13. Statement – 1: Sulphanilic acid (p-Aminobenzene sulphonic acid) is stronger
acid than sulphonic acid.
Statement – 2: Sulphanilic acid exists as zwitter ion and H ⊕ ion is lost from
− NH 3 group.
14. Statement – 1: The resonating structure of acylium ion R − C ≡ O + is more stable
than R − C + = O&& : .
Statement – 2: The octet of all atoms is complete in R − C ≡ O + : .
15.
NO2 NO2
CH3 CH3

CH3 CH3
NH2 NH2
(I) (II)
STATEMENT-1: Compound I is more basic than compound II.
STATEMENT-2: In compound II, NH2 group becomes out of the plane due to
steric crowd.
16. Statement 1 : p – Fluorophenol is less acidic than p-chlorophenol
Statement 2 : The conjugate base of p-chlorophenol is more resonance
stablised due to the involvement of d-orbitals of chlorine in
resonance
17. Statement – I :- Ortho hydroxybenzoic acid is more acidic than benzoic acid

Statement – II :- No ortho effect in ortho hydroxybenzoic acid.

18.
NO2 NO2
CH3 CH3

CH3 CH3
NH2 NH2
(I) (II)
STATEMENT-1: Compound I is more basic than compound II.
STATEMENT-2: In compound II, NH2 group becomes out of the plane due to
steric crowd.

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GENERAL ORGANIC CHEMISTRY – KEY SHEET
Statement Answers
1 D 2 A 3 C 4 B 5 A 6 A
7 D 8 C 9 A 10 A 11 A 12 A
13 D 14 A 15 C 16 A 17 C 18 C

GENERAL ORGANIC CHEMISTRY - SOLUTIONS


Statement solutions
1. Conceptual
2. Solubility decreases w.r.t hydrophobic group.
3. groups increases acidic character.
4. Lone pair on flourine back donates to p orbital on carbocation. Stabilizing
Carbocation
5. No of isomers =
6. Conceptual
7. Phenol and cyclohexan (2,4) di – ene – 1 – one are tautomers
8. Conceptual
9. Conceptual
10. Conceptual
11. Conceptual
12. Conceptual
13. Conceptual
14. Conceptual
15. (c)
Compound I is more basic than compound II because NO2 group in
compound I becomes out of the plane due to steric crowd.
16.
O-

Cl

is more stable due to d-orbital resonance of chlorine


17. Conceptual
18. (c)
Compound I is more basic than compound II because NO2 group in
compound I becomes out of the plane due to steric crowd.

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