Part B: Stoichiometry: UNIT 4: Chemical Reactions, The Mole, Stoichiometry and Thermodynamics
Part B: Stoichiometry: UNIT 4: Chemical Reactions, The Mole, Stoichiometry and Thermodynamics
Zn + 2 HCl ZnCl2 + H2
1 mol Zn
2. What mass of aluminum oxide is produced when 2.3 grams of aluminum reacts with iron
II oxide? 2 Al + 3 FeO Al2O3 + 3 Fe
3. Sodium bicarbonate reacts with hydrochloric acid to product sodium chloride, carbon
dioxide, and water. If 4.0 g of sodium bicarbonate reacts, how many liters of carbon
dioxide are produced?
4. If 0.38 L of hydrogen reacts with chlorine gas, what is the volume of hydrogen chloride
gas that is produced?
H2 + Cl2 2 HCl
Cu + AgNO3 CuNO3 + Ag
5.0 g Cu 1 mol Cu 1 mol Ag 107.9 g Ag = 8.5 g Ag
63.5 g Cu 1 mol Cu 1 mol Cu
8.5 x 100 = 55.9 % yield
15.2
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CHAPTER 11: STOICHIOMETRY
When nitrogen and hydrogen gas are heated under the correct conditions, ammonia gas (NH3) is
formed.
b. How many moles of nitrogen react with three moles of hydrogen?___1 mol N2______________
3 mol H2 1 mol N2
3 mol H2
c. How many moles of nitrogen react with six moles of hydrogen? ____2 mol N2______________
6 mol H2 1 mol N2
3 mol H2
d. How many moles of ammonia would be formed if 6 moles of hydrogen react with plenty of
nitrogen?
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2. When potassium chlorate is heated it breaks down to potassium chloride and oxygen. Write a
balanced equation for the reaction below:
a. How many moles of potassium chloride will be produced if 6.2moles of potassium chlorate break
down?
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MOLE TO MASS/VOLUME PROBLEMS
When fluorine gas is bubbled through a solution of aluminum iodide, elemental iodine and
aqueous aluminum fluoride are formed. Write and balance the reaction below:
1. How many moles of fluorine gas are needed to react with 2.50 moles of aluminum iodide?
2. What mass of iodine will form if 4.20 moles of fluorine gas react with excess aluminum iodide?
_1065.96 g I2__________
3. What mass of fluorine gas is needed to react with 2.15moles of aluminum iodide?
__122.55 g F2__________
4. What volume of fluorine gas, at STP, was used if 0.55 moles aluminum fluoride were formed?
__18.48 L F2___________
5. How many moles of aluminum fluoride will be produced if 20.0g of fluorine react with excess
aluminum iodide?
6. How many moles of AlI3 are needed to react with 10.0L of fluorine at STP?
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MASS/MASS, MASS/VOLUME AND MASS/PARTICLE PROBLEMS
1. When iron is heated in pure oxygen, iron(III) oxide is formed. Write a balanced equation
for the reaction below.
_____4 Fe + 3 O2 2 Fe2O3_________________________________
a. How many moles of iron are needed to react with 2.5moles of oxygen?
b. What mass of iron must react with excess oxygen in order to form 4.81moles of iron(III) oxide?
d. What mass of iron(III) oxide can be formed from the reaction of 10.2g of iron with excess
oxygen?
f. What mass of iron(III) oxide will be formed if 10.0L of oxygen at STP react with excess iron?
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2. Barium hydroxide reacts with hydrochloric acid to form barium chloride and water. Write
a balanced equation for the reaction below.
a. What mass of barium chloride will form if 14.0g of barium hydroxide reacts with excess
hydrochloric acid?
__17 g BaCl2____
b. How many grams of hydrochloric acid are needed to react with 15.0g of barium hydroxide?
__6.4 g HCl_____
c. What mass of barium chloride will form if 5.98g of hydrochloric acid react with excess barium
hydroxide?
__17.1 g BaCl2___
d. How many molecules of water are formed by the reaction of 10.8g of barium hydroxide with excess
hydrochloric acid?
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PER CENT YIELD
actual yield x 100
theoretical yield
A student burns 20.0L of propane gas in excess oxygen at STP. Determine the volume of carbon
dioxide that should form in the reaction.
20.0 L C3H8 1 mol C3H8 3 mol CO2 22.4 L CO2 = 60.0 L CO2
22.4 L C3H8 1 mol C3H8 1 mol CO2
The reaction only produces 48.0L of carbon dioxide. What is the percent yield?
48-60 x 100
60 ___20 % error_________
Sodium chlorate decomposes to produce sodium chloride and oxygen. Write and balance the
reaction. The determine the mass of sodium chloride should form if 150g of sodium chlorate
decomposes?
__82.39 g NaCl______
The reaction above is carried out in lab, and 55g of sodium chloride are collected. Determine the
percent yield.
55g x 100
82.39 g __66.7 % yield_________
82.39-55 x 100
82.39 __33.3 % error_________
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NOTES: LIMITING REACTANT
1. Define the terms limiting reactant, excess reactant and percent yield.
Limiting reactant –
Excess reactant –
3. 4.0 moles of aluminum are placed in a container with 4.0 moles of oxygen. How many moles
of aluminum oxide should form?
4. Predict the mass of aluminum oxide that will form if 20.0g of aluminum react with 15.0L of
oxygen gas at STP.
_________________________________________________________________
b. 1.26g of fluorine are bubbled through a solution containing 20.15g of potassium iodide. What mass
of potassium fluoride should form?
___________________
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REVIEW HOMEWORK: MOLE PRACTICE PROBLEMS
Make the following mole conversions. Show ALL work for credit!
146.87 g NI3
5. 2.24 x 1023 molecules of nitrogen triiodide to grams
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HOMEWORK: MOLE-MOLE PROBLEMS
1. N2 + 3H2 2NH3
How many moles of hydrogen are needed to completely react with two moles of
nitrogen?
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HOMEWORK: MOLE/MASS & VOLUME PROBLEMS
When aluminum carbonate decomposes, aluminum oxide and carbon dioxide gas form.
The reaction is given below:
a. determine the molar mass of each product and reactant for later use:
c. What mass of aluminum oxide will form if 2.2moles of carbon dioxide form?
d. What mass of aluminum carbonate must decompose in order to form 2.2 moles of aluminum oxide?
e. What volume of carbon dioxide will form if 5.0 moles of aluminum carbonate decompose at STP?
336 L CO2____
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HOMEWORK – STOICHIOMETRY: MASS-MASS PROBLEMS
2. N2 + 3H2 2NH3
How many grams of hydrogen are necessary to react with 60.0g of nitrogen?
3. N2 + 3H2 2NH3
How many grams of ammonia are produced if 60.0g of nitrogen react with excess
hydrogen?
5.0 g AgNO3 1 mol AgNO3 2 mol AgCl 143.4 g AgCl = 4.2 g AgCl
169.9 g AgNO3 2 mol AgNO3 1 mol AgCl
5.0 g AgNO3 1 mol AgNO3 1 mol BaCl2 208.3 g BaCl2 = 3.1 g BaCl2
169.9 g AgNO3 2 mol AgNO3 1 mol BaCl2
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HOMEWORK - STOICHIOMETRY: MIXED PROBLEMS
1. N2 + 3H2 2NH3
What volume of NH3 at STP is produced if 25.0g of N2 is reacted with an excess of H2?
5.0 g KClO3 1 mol KClO3 2 mol KCl 74.6 g KCl = 3.0 g KCl
122.6 g KClO3 2 mol KClO3 1 mol KCl
4. Zn + 2 HCl ZnCl2 + H2
What volume of hydrogen at STP is produced when 2.5g of zinc react with an excess of
hydrochloric acid?
2.0 g Na2SO4 1 mol Na2SO4 2 mol H2O 6.02 x 1023 mlc = 1.7 x 1022 mlc H2O
142.1 g Na2SO4 1 mol Na2SO4 1 mol H2O
6. 2 AlCl3 2 Al + 3 Cl2
If 10.0g of aluminum chloride are decomposed, how many molecules of Cl 2 are produced?
10.0 g AlCl3 1 mol AlCl3 3 mol Cl2 6.02 x 1023 mlc Cl2 = 6.8 x 1022 mlc Cl2
133.5 g AlCl3 2 mol AlCl3 1 mol Cl2
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LIMITING REACTANT/ % YIELD HOMEWORK
1. Solid calcium is added to a solution of iron (III) chloride. The reaction is given below:
_______________
e. A student performs the reaction above and produces 4.6g of calcium chloride. What is his per cent
yield?
_______________
2. Write the reaction for the combustion of methane (CH4) in pure oxygen to form carbon
dioxide and water.
_______________________________________________________
a. What mass of carbon dioxide will be produced by the reaction of 120.0g of methane with 180.0g of
of oxygen?
______________
d. A student performs the reaction above, and produces 132g of carbon dioxide. What is his percent
yield?
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CP1 Chemistry Name ________________________
Chapter 11 Review Sheet Date _________________________
1. Calcium carbonate reacts with 14.8g of hydrochloric acid. How many moles of calcium chloride
are produced?
2. How many grams of aluminum are needed to react with nitric acid in order to produce 1.432 L of
hydrogen gas at STP?
3. In the reaction of 8.24 g of silver nitrate with copper II chloride, 6.90 g of silver chloride are
produced. What is the percent yield of this reaction?
8.24 g AgNO3 1 mol AgNO3 2 mol AgCl 143.4 g AgCl = 6.95 g AgCl
169.9 g AgNO3 2 mol AgNO3 1 mol AgCl
4. Determine the number of moles of potassium bromide that need to react with chlorine in order to
produce 6.4 moles of bromine.
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5. In the combustion of 16.2 L of ethane (C2H6) at STP, how many liters of carbon dioxide are
produced?
16.2 L C2H6 1 mol C2H6 4 mol CO2 22.4 L CO2 = 32.4 L CO2
22.4 L C2H6 2 mol C2H6 1 mol CO2
6. How many atoms of iron are produced when 8.4 g of calcium react with iron III bromide?
7. In a synthesis reaction, 7.8 g of sodium oxide reacts with 10.2g of water. How many grams of
sodium hydroxide are produced? What is the limiting reactant?
RXN:
**8. The decomposition of mercury II oxide has a 96.4% yield. If you start with 25.3 g of mercury II
oxide, how many grams of oxygen are produced?
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DATA TABLE:
mass of empty evaporating dish and watch glass
2. Write a balanced equation for the reaction of baking soda (NaHCO3) and hydrochloric acid.
% error = ____________________
CONCLUSIONS: List three sources of error and the effect each would have on the mass of NaCl formed (too high or too low).
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