COLLEGE NAME

JEE MAINS MODEL PRACTICE TEST

GRAND TEST - 4
Exam Date : ............................ Max. Marks: 300
INSTRUCTIONS
1. The question paper consists of three subjects (Physics 1 to 25; Chemistry 26 to 50 and Mathematics 51 to 75).
2. All questions are Multiple Choice questions with single correct answer only and each question has four choices
(1), (2), (3) and (4) out of which ONLY ONE is correct. Each question carries +4 for Correct Option and –1 for
Wrong Option.
3. No Negative Marks for Numerical Value Questions.

PHYSICS
01. The positive terminals of two batteries with emf’s 14 V & 10 V respectively are connected together.
The circuit is completed by connecting the negative terminals. If each battery has internal
resistance of 1 , then the rate at which electrical energy is converted to chemical energy in
battery having smaller emf is
1) 4 W 2) 20 W 3) 14 W 4) 120 W
02. A rod AB of mass ‘m’ and length ‘  ’ is positively charged with linear charge density  c / m . It is
pivoted at end A and is hanging freely. If a horizontal electric field E is switched on in the region,
find the angular acceleration of the rod with which it starts rotating.
E 3E 3E
1) 2) 3) 4) zero
2m 2m m
03. A bar of copper of length 75 cm and a bar of steel of length 125 cm are joined together end to end.
Both are of circular cross-section with diameter 2 cm. The free ends of the copper and steel bars
are maintained at 100°C and 0°C respectively. The surfaces of the bars are thermally insulated.
What is the temperature of the copper-steel junction ? What is the heat transmitted per unit time
across the junction ? Thermal conductivity of copper 9.2  102 k calm 1 C1s1 and that of steel is
1.1  102 k calm 1s1 C1 .
1) 2.58  104 J / s 2) 3.58  104 J / s 3) 1.58  104 J / s 4) 0.58  104 J / s
04. A vertical U-tube of uniform cross-section contains water upto a height of 30 cm. Show that if the
water on one side is depressed and then released, its motion up and down the two sides of the
tube is simple harmonic. Calculate its period.
1) 1.098s 2) 1.198s 3) 2.098s 4) 1.598s
05. On a uniform circular disk of mass m & radius R a ring of mass 2 m & radius slightly greater than
r is attached, in addition to this a point object of mass 2m is fixed at center of disk, and this entire
system is left on a rough inclined plane of inclination  with the horizontal, then minimum value
of coefficient of friction for pure rolling would be
25tan  tan  5tan 
1) 2) 3) 4) None of these
3 3 9
06. A 500 kg satellite is in a circular orbit at an altitude of 500 km above the Earth’s surface. Because
of air friction, the satellite eventually falls to the Earth’s surface, where it hits the ground with a
speed of 2km/s. The work done by air friction is [ME  6  1024 kg R E  6400 km]
1) 1.67  1011 J 2) 6  109 J 3) 6  109 J 4) 1.67  1011 J
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SPACE FOR ROUGH WORK
07. Two soap bubbles combine under isothermal condition to form a single soap bubble. If, in this
process, the change in volume is V and change in area is S, then
1) PV  TS  0 2) 4PV  3TS  0 3) 3PV  4TS  0 4) 3PV  TS  0

1 1 1
08. Electrical potential ‘V’ in space as a function of coordinates is given by V    , then the
x y z
electric field intensity at (1, 1, 1) is given by

1   
1) (i  j  k)
 2) i  j  k 3) zero 4) (i  j  k)
3
09. A block of mass 4 kg is pressed against the wall by a force of 80N as shown in figure. Determine the
value of friction force and acceleration ? (Take g  10m / s2 &  s  0.2 ,  k  0.15 )

80N
4kg

37°

1) 8N, 0 m / s2 2) 32N, 6 m / s2 3) 8N, 6 m / s2 4) 32N, 2 m / s2

10. An uniform chain of mass M, length  is placed on the rough table as shown. Chain is on the verge
of slipping, find the velocity of the chain, when it has completely slipped off from the table.

/4

3 / 4

1 1 1 1
1) v  g 2) v  g 3) v  g 4) v  g
2 4 6 3
11. A point object is placed in front of a thick plane mirror as shown in figure.

3

2
10 cm
O

5 cm

Find the location of final image with respect to object.

1) 15/2 cm 2) 15 cm 3) 40/3 cm 4) 80/3 cm

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SPACE FOR ROUGH WORK
12. A beam of certain monochromatic light is incident on a plane surface, which absorbs 80% of the
light, and rest has been reflected. If the incident beam carries 20W of power, find the force exerted
by it on the surface.
1) 4  108 N 2) 2.66  108 N 3) 1.33  108 N 4) 8  108 N
13. An electron is in an excited state in hydrogen-like atom. It has a total energy of –3.4 eV. If the
kinetic energy of the electron is E and its de-Broglie wavelength is  , then
1) E  6.8 eV ,   6.6  1010 m 2) E  3.4 eV   6.6  1010 m
3) E  3.4 eV ,   6.6  1011 m 4) E  6.8 eV ,   6.6  1011 m
14. A radioactive substance is being produced at a constant rate of 200 nuclei/s. The decay constant
of the substance is 1 sec–1. After what time the number of radioactive nuclei will become 100.
Initially there are no nuclei present ?
1) 1s 2) 3s 3) n (2)s 4) 2s
15. The combination of NOR gates shown here are equivalent to

A
Y

1) OR 2) AND 3) NAND 4) XOR

16. Frequencies higher than 10 MHz were found not being reflected by the ionosphere on a particular
day at a place. The maximum electron density of the ionosphere on the day was near to
1) 1.5  1010 m3 2) 1.24  1012 m3 3) 3  1012 m3 4) None of these
17. A square loop of side 5 cm enters in a magnetic field with constant speed 1cms –1 as shown in
figure. The front edge enters the magnetic field at t  0 then which graph best depicts induced
emf versus time.

v = 5 cm/s

55 cm

V V
V V

5 20 t
0 t(s)
1) 2) 20
3) 15 20 4) 0 15
t(s) t(s)
0 5 15 20 0 5 15

18. In LCR series ac circuit, the current is found to be maximum, when the value of the inductance is
0.3 Henry and capacitor is having capacitance 30 f , angular frequency of the input ac supply
would be
1) 50 2) 100  3) 1000/3 4) 100
19. A beam of light of wavelength 590 nm is focussed by a converging lens of diameter 10.0 cm at a
distance of 20 cm from it. Find the diameter of the disc image formed.
1) 5.6  104 cm 2) 4.6  104 cm 3) 4.7  104 cm 4) 5.7  104 cm
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SPACE FOR ROUGH WORK
 20. A particle when projected in vertical plane moves along the fixed smooth surface with initial velocity
20ms–1 at an angle of 60°, so that its normal reaction on the surface remains zero throughout the
motion. Then the slope of the tangent to the surface at height at 5m from the point of projection A
will be

60°
A

1) 30° 2) 45° 3) tan1 2 4) tan 1 2

NUMERICAL VALUE QUESTIONS:
21. An iron bar of length 10 cm and diameter 2 cm is placed in a magnetic field of intensity 1000 Am1
with its length parallel to the direction of the field. Determine the magnetic moment produced in
the bar if permeability of its material is 6.3  104 TmA 1 .

1) 17.70 A  m2 2) 16.70 A  m2 3) 14.70 A  m2 4) 11.70 A  m2

22. Calculate the work done when one mole of an ideal monoatomic gas is compressed adiabatically.
The initial pressure and volume of the gas are 105 N/m2 and 6 litre respectively. The final volume
of the gas is 2 litres. Molar specific heat of the gas at constant volume is 3R/2.
1) 759 J 2) 957 J 3) 579 J 4) 357 J
23. A zener diode has a breakdown voltage of 9.1 volts with a maximum power dissipation of 364
milliwatts. What is the maximum current the diode can handle ?
1) 40 mA 2) 50 mA 3) 60 mA 4) 30 mA
24. The pitch of a screw gauge is 0.5 mm and there are 100 divisions on its circular scale. The instrument
reads 2 divisions when nothing is put in between its jaws. In measuring the diameter of a wire,
there are 8 divisions on the main scale and 83rd division coincides with the reference line. Then
the diameter of the wire is
1) 4.05 mm 2) 4.405 mm 3) 3.05 cm 4) 1.25 mm
25. Two balls with masses m1  3kg and m2  5kg have identical velocity V  5ms1 in the direction
shown in figure. They collide at origin. Find the distance of position of C.M from the origin 2sec
after the collision.

m1
37°
V1

V2
m2

1) 5 2) 2 3) 4 4) 0

CHEMISTRY
25 X 4 = 100M
26. When the imidazole ring of Histidine is protonated, tendency of nitrogen to be protonated (proton
migrates from – COOH) is in the order
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 COOH
CH2 CH
NH2

NH
N 


1)      2)      3)      4)     
27. Four metals and their methods of refinement are given
(i) Ni, Cu, Zr, Ga
(ii) Electrolysis, van Arkel process, zone refining, Mond’s process
Choose the right method for each
1) Ni : Electrolysis, Cu : van Arkel process, Zr : Zone refining, ga : Mond’s process
2) Ni : Mond’s process, Cu : Electrolysis, Zr : van Arkel process, Ga : Zone refining
3) Ni : Mond’s process, Cu : van Arkel process, Zr : Zone refining, Ga : Electrolysis
4) Ni : Electrolysis, Cu : Zone refining, Zr : van Arkel process, Ga : Mond’s process
28. On the basis of ellingham diagram which of the following is not correct ?
1) Entropy change for all metal oxides is roughly same
2) Below the boiling point, 'TS' factor is same irrespective of metal
3) Above G  0 line, oxide decomposes into metal & oxygen
4) If randomness increases the slope increases
29. The pair in which both species have the same magnetic moment (spin only) value is
1) [Cr(NH3 )6 ]3 , [Co(H2O)6 ]3 2) [Cr(NH3 )6 ]3 , [Fe(H2O)6 ]2

3) [Co(NH3 )6 ]2 , [Cr(NH3 )6 ]3 4) [Mn(H2O)6 ]2 , [Fe(H2O)6 ]2

30. Which of the following is not correctly matched ?
O

1) Neoprene: CH2  C  CH  CH2 2) Nylon-6,6: NH  (CH2 )6  NH  CO  (CH2 )4  C  O 
C
n
n

O O
3) Terylene: OCH2  CH2  C  C 
n

4) Teflon : CF2  CF2

n

31. Which of the following is the major solute species in a solution of lysine at pH  10.5 ?

CO2H CO2 CO2

CO2H

H2N H
1) H3 N H 2) H2 N H 3) 4) H2N H

(CH2 )4 (CH2 )4 (CH2 )4 (CH2 )4

NH 3 NH3 NH3 NH2

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SPACE FOR ROUGH WORK
32. Consider the following oxides:
i) OF2 ii) C 2O iii) Br2O
The correct sequence of X  O  X bond angle is
1) 1  2  3 2) 3  2  1 3) 2  1  3 4) 1  3  2
o o o
33. EMn3 /Mn2 is highly positive than that of ECr3 /Cr2 or EFe3 /Fe2 because

1) Mn2 (d5 ) can be easily oxidised to Mn3 (d4 ) due to low ionisation enthalpy

2) third ionisation enthalpy of Mn is much larger due to stable half filled d5 electronic configuration
of Mn2
3) Mn3 is more stable than Mn2 due to higher oxidation state
4) second ionisation enthalpy of Mn is higher than third ionisation enthalpy
34. Observe the given graphs carefully.

n [R 0 ]

log [R0]/[R]
K= - slope
n [R] Slope = k/2.303

0 t 0 t
(i) (ii)

Which of the given orders are shown by the graphs respectively ?

(i) (ii)
1) Zero order First order
2) First order Zero order
3) First order First order
4) Second order Zero order
35. Which of the following statements is incorrect ?
1) Aspirin is both analgesic and antipyretic 2) Ampicillin is a natural antibiotic
3) Salavarsan is toxic to human beings
4) Some disinfectants are used as antiseptics in lower concentrations
36. A mixture in which the mole ratio of H2 and O 2 is 2 : 1 is used to prepare water by the reaction,
2H2( g )  O2( g )  2H2O( g ) . The total pressure in the container is 0.8 atm at 20°C before the reaction.
The final pressure at 120°C after reaction is (assuming 80% yield of water)
1) 1.787 atm 2) 0.878 atm 3) 0.787 atm 4) 1.878 atm
37. 5.0 cm3 of H2O 2 liberates 0.508 g of iodine from an acidified KI solution. The strength of H2O 2
solution in terms of volume strength at STP is
1) 6.48 volumes 2) 4.48 volumes 3) 7.68 volumes 4) none of these
38. How many of the given statements are correct:
I : Molar entropy of a substance follows the order (Sm )Solid  (Sm )liquid  (Sm )gas .

II : Entropy change of system for the reaction H2 (g) 

 2H(g) is  ve .
III : Molar entropy of a non-crystalline solid will be zero at absolute zero.

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SPACE FOR ROUGH WORK
 IV : If the path of an irreversible process is reversed, then both system and surroundings shall be
restored to their original states.
V : Refractive index and molarity are intensive properties.
1) 2 2) 3 3) 4 4) 5
39. The end product (Z) in the given sequence of reaction is
NaBH4 HC ( i) KCN
CH 3CH  CHCHO  X 
ZnC 2
 Y 
( ii) H
Z

1) CH3CH  CHCH2COOH 2) CH3CH2CH2COOH

3) CH3CH  CHCOOH 4) CH3CH(C )CH2COOH
40. Complete the following reactions:
ZnCu Electrolysis
(i) C2H5I  H2 
C2H5OH
X (ii) CH3COONa  H2O  Y
Cr2O3 /A 2O3
(iii) CH3CH2CH2CH2CH2CH3 
773 K
Z

1) X  C2H6 , Y  C2H6 , Z  C6H6 2) X  CH 4 , Y  CH3COOH , Z  CH3CH3

3) X  C2H6 , Y  CH4 , Z  C4H10 4) X  C2H6 , Y  CH4 , Z  C5H10

Fe(3aq)

[Fe(SCN)](2aq
 SCN(aq )  
);
41. The following reaction is at equilibrium,
Yellow Colourless Deep red

[Fe(SCN)]2
Kc 
[Fe3 ][SCN  ]
In the above reaction, colour intensity of red colour can be increased by
1) addition of KSCN
2) addition of oxalic acid which reacts with Fe 3 ions

3) addition of Hg2 ions which react with SCN  ions

4) red colour intensity cannot be changed
42. The products (A) and (B) are respectively

CH3
C2H5ONa HBr
(i) CH3  CH  CH  CH3  (A) (ii) CH 2  C  CH 2CH 3  
Peroxide
 (B )

Br CH3
CH3
1) CH CH  CH  CH , CH3 (CH2 )2 CH3 2) CH3CH2  C(CH3 )2 , CH2  CH  CH2  CH3
3 2 3

OC2H5 Br CH 3
CH3
3) CH3CH2  CH  CH2CH3 , BrCH  C  CH CH 4) CH3CH2  CH2CH2CH3 , CH3  CH  CH2CH3
2 2 3

ONa Br
Br

43. The bond dissociation energy of B  F in BF3 is 646 kJ mol–1 whereas that of C  F in CF4 is 515 kJ
mol–1. The correct reason for higher B  F bond dissociation energy as compared to that of C  F
bond is
1) stronger  bond between B and F in BF3 as compared to that between C and F in CF4

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SPACE FOR ROUGH WORK
 2) significant p  p interaction between B and F in BF3 whereas there is no possibility of such
interaction between C and F in CF4
3) lower degree of p  p interaction between B and F in BF3 than that between C and F in CF4
4) smaller size of B-atom as compared to that of C-atom
44. The correct stability order for the following species is

+ + +

O O +
(I) (II) (III) (IV)

1) (II)  (IV)  (I)  (III) 2) (I)  (II)  (III)  (IV) 3) (II)  (I)  (IV)  (III) 4) (I)  (III)  (II)  (IV)
45. Two metals X and Y belong to the second group of periodic table. X forms insoluble oxide but
soluble sulphate. Y forms a soluble oxide but insoluble sulphate. Hydroxide of metal X is soluble
in NaOH while that of metal Y is insoluble in NaOH. What are metals X and Y ?
1) X  Be , Y  Ba 2) X  Mg , Y  Ca 3) X  Ca , Y  Sr 4) X  Ba , Y  Mg
NUMERICAL VALUE QUESTIONS:
46. Copper crystallizes in fcc with a unit cell length of 361 pm. What is the radius of copper atom ?
1) 157 pm 2) 181 pm 3) 127 pm 4) 108 pm
47. Mixture of volatile components A and B has total vapour pressure (in Torr) p  265  130 x A , where
e
xA is mole fraction of A in mixture. Hence p0A  p0B  (in Torr)
1) 265 2) 135 3) 400 4) 150
48. From the mixture of 4 moles Ca 3 (PO 4 )2 and 5 moles of P4O10 and 6 moles of H3 PO3 all the
phosphorus atoms are removed then moles of P4 molecule formed from all these atoms is
1) 8.5 2) 17 3) 34 4) 10
49. The wavelength (  ) of monochromatic light coming from some light sources is listed below. How
many these sources will be above to exhibit photoelectric effect if incident upon surface of Li
metal (work function,   2.4eV )

Light Source A B C D E F G H I
(nm) 100 200 300 400 500 600 700 800 900

1) 6 2) 7 3) 8 4) 5
50. An electric current is passed through silver nitrate solution using silver electrodes. 15.28 g of
silver was found to be deposited on cathode. What will be the weight of copper deposited on
cathode if same amount of electricity is passed through copper sulphate solution using copper
electrodes ?
1) 4.49 g 2) 6.4 g 3) 12.8 g 4) 3.2 g

MATHEMATICS
25 X 4 = 100M
2
1  n

51. If a K  for K  1, 2, 3,......n , then   a K  
K(K  1)  K 1 

n n2 n4 n6
1) 2) 3) 4)
n 1 (n  1)2 (n  1)4 (n  1)6

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52. In the first word war 70% of the soldiers lost one eye, 80% an ear, 75% an arm, 85% a leg, k% lost all
the four limbs, then the minimum value of ‘k’ is
1) 5 2) 10 3) 15 4) 20
53. The mean and standard deviation of 1, 2, 3, 4, 5, 6 ... is

5 7 35 7 35
1) 3, 2) , 3) 3, 3 4) ,
2 2 12 2 12
54. The contra positive of the statement if it is raining, then I will not come”, is
1) if I will come, then it is not raining 2) If I will come, then it is raining
3) If I will not come, then it is raining 4) If I will not come, then it is not raining
1
55. The principal value of sin (sin10) is
1) 10 2) 10  3  3) 3   10 4) none of these
56. A triangle ABC has side c  2 2 and A  30 . If the radius of its circumcircle is 2, then

1) a  2 2) a  2 2 3) C  45 4) C  60
57. The centroid of the triangle whose three sides are given by the combined equation
(x 2  7xy  2y 2 )(y  1)  0 is

2  7 2  7 2
1)  , 0  2)  ,  3)   ,  4) none of these
3  3 3  3 3

1 1
58. The differential coefficient of cosec 1 2
with respect to 1  x 2 at x  is
2x  1 2
1) –4 2) 4 3) –1 4) none of these
59. The equation of the tangent to the curve y  e  x at the point where the curve cuts the line x  1 is

1) x  y  e 2) e(x  y)  1 3) y  ex  1 4) none of these

60. The set of all possible values of x such that 5x  (2 3 )2x  169 is always positive in

1) [3,   ) 2) [2,   ) 3) (2,   ) 4) none of these

6 5 4 3
61. The polynomial x  4x  3x  2x  x  1 is divisible by
2 2
1) x   2) x   3) (x  )(x   ) 4) (x  )(x  2 )

62. If  ,  are the roots of the equation x 2  x     0 , then the values of  and  are

1)   1 and   1 2)   1 and   2 3)   2 and   1 4)   2 and   2

a1  a 2n a 2  a 2n1 a 3  a 2n 2
63. If a r  0 , r  N and a 1 , a 2 , a 3 ,....,a 2n are in A.P., then   
a1  a 2 a2  a 3 a3  a 4
a n  a n 1
....  is equal to
a n  a n 1

n(a1  a 2n ) n 1
1) n  1 2) a1  a n 1
3) a1  a n 1
4) none of these

64. The number of ways in which the letters of word ARGUMENT can be arranged so that only
consonants occur at both ends is
1) 3!  5! 2) 14400 3) 41000 4) none of these
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65. Three different dice are rolled simultaneously, three times. The probability that all of them show different
numbers only two times, is equal to
1 2 100 143
1) 2) 3) 4)
3 3 243 243
        
 
66. Let a , b , c be three unit vectors such that a  5b  3c  0 . Then a  (b  c) is equal to:
       
1) a  b 2) a  (b  2c) 3) b  (a  c) 4) none of these

sinx  log(1  x )
67. lim is
x 0 x2
1 1
1) 0 2)  3) 4) not defined
2 2
3
68. x d(tan 1 x) is equal to

x2 1 x2 1
1)  ln (1  x 2 )  C 2)   ln (1  x 2 )  C
2 2 2 2
x2 1 x2 1
3)   ln (1  x 2 )  C 4)  ln (1  x 2 )  C
2 2 2 2
69. Solution of the differential equation ydx  x dy  xy 2dx  0 , is equal to

x x2 2y 2x 2 2y
1)  c 2)  x2  c 3) y  x  c 4)  x2  c
y 2 x c
70. The equation of the common tangent to the equal parabolas y 2  4ax and x 2  4ay is
1) x  y  a  0 2) x  y  a 3) x  y  a 4) none of these
NUMERICAL VALUE QUESTIONS:
71. The number of rational terms in ( 2  3 3  6 5 )10 is
1) 2 2) 3 3) 4 4) 5
72. The area bounded by the curve f(x )  x  sinx and its inverse between the ordinates x  0 to
x  2 is
1) 2 2) 4 3) 6 4) 8

1 cos  cos 
cos  p cos  
73. If p, q  R and p2  q2  pq  p  q  1  0 ,       0 , then the value of
cos  cos  q
1) 0 2) 2 3) 4 4) 6
74. If   [0, 5 ] and r  R such that 2sin   r4  2r2  3 , then the maximum number of values of the
pair (r,  ) is
1) 2 2) 4 3) 6 4) 8
2 2 2
75. There are two circles whose equations are x 2  y 2  9 and x  y  8x  6y  n  0 , n  Z . If the
two circles have exactly two common tangents, then the number of possible values of n is
1) 3 2) 6 3) 7 4) 9

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