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Dow Corning (R) 732 Multi-Purpose Sealant White: Safety Data Sheet

This document provides a safety data sheet for Dow Corning 732 Multi-Purpose Sealant White. It lists the product name and code, manufacturer details, recommended use as an adhesive, and contains sections about hazards, ingredients, first aid measures, fire-fighting, accidental releases, handling, storage, exposure controls, and personal protective equipment. The key ingredients are silicon dioxide and titanium dioxide.

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Jivendra Kumar
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0% found this document useful (0 votes)
183 views13 pages

Dow Corning (R) 732 Multi-Purpose Sealant White: Safety Data Sheet

This document provides a safety data sheet for Dow Corning 732 Multi-Purpose Sealant White. It lists the product name and code, manufacturer details, recommended use as an adhesive, and contains sections about hazards, ingredients, first aid measures, fire-fighting, accidental releases, handling, storage, exposure controls, and personal protective equipment. The key ingredients are silicon dioxide and titanium dioxide.

Uploaded by

Jivendra Kumar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 13

SAFETY DATA SHEET

DOW CORNING(R) 732 MULTI-PURPOSE


SEALANT WHITE

Version Revision Date: SDS Number: Date of last issue: 04/25/2016


2.1 05/06/2016 3280111-00003 Date of first issue: 12/21/2015

SECTION 1. IDENTIFICATION

Product name : DOW CORNING(R) 732 MULTI-PURPOSE SEALANT


WHITE

Product code : 000000000004023910

Manufacturer or supplier's details


Company name of supplier : Dow Corning Corporation

Address : South Saginaw Road


Midland Michigan 48686

Telephone : (989) 496-6000

Emergency telephone : 24 Hour Emergency Telephone : (989) 496-5900


CHEMTREC : (800) 424-9300

Recommended use of the chemical and restrictions on use


Recommended use : Adhesive, binding agents

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Not a hazardous substance or mixture.
GHS label elements
Not a hazardous substance or mixture.
Precautionary Statements :
Prevention:
P271 Use only outdoors or in a well-ventilated area.

Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Chemical nature : Silicone elastomer

Hazardous ingredients
Chemical name CAS-No. Concentration (% w/w)
Silicon dioxide 7631-86-9 >= 5 - < 10
Titanium dioxide 13463-67-7 >= 0.1 - < 1

SECTION 4. FIRST AID MEASURES

1 / 13
SAFETY DATA SHEET

DOW CORNING(R) 732 MULTI-PURPOSE


SEALANT WHITE

Version Revision Date: SDS Number: Date of last issue: 04/25/2016


2.1 05/06/2016 3280111-00003 Date of first issue: 12/21/2015

If inhaled : If inhaled, remove to fresh air.


Get medical attention if symptoms occur.

In case of skin contact : Wash with water and soap as a precaution.


Get medical attention if symptoms occur.

In case of eye contact : Flush eyes with water as a precaution.


Get medical attention if irritation develops and persists.

If swallowed : If swallowed, DO NOT induce vomiting.


Get medical attention if symptoms occur.
Rinse mouth thoroughly with water.

Most important symptoms : None known.


and effects, both acute and
delayed

Protection of first-aiders : No special precautions are necessary for first aid responders.

Notes to physician : Treat symptomatically and supportively.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Water spray


Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical

Unsuitable extinguishing : None known.


media

Specific hazards during fire : Exposure to combustion products may be a hazard to health.
fighting

Hazardous combustion prod- : Carbon oxides


ucts Silicon oxides
Formaldehyde

Specific extinguishing meth- : Use extinguishing measures that are appropriate to local cir-
ods cumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do
so.
Evacuate area.

Special protective equipment : Wear self-contained breathing apparatus for firefighting if nec-
for fire-fighters essary.
Use personal protective equipment.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Follow safe handling advice and personal protective

2 / 13
SAFETY DATA SHEET

DOW CORNING(R) 732 MULTI-PURPOSE


SEALANT WHITE

Version Revision Date: SDS Number: Date of last issue: 04/25/2016


2.1 05/06/2016 3280111-00003 Date of first issue: 12/21/2015

tive equipment and emer- equipment recommendations.


gency procedures

Environmental precautions : Discharge into the environment must be avoided.


Prevent further leakage or spillage if safe to do so.
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages
cannot be contained.

Methods and materials for : Soak up with inert absorbent material.


containment and cleaning up For large spills, provide diking or other appropriate
containment to keep material from spreading. If diked material
can be pumped, store recovered material in appropriate
container.
Clean up remaining materials from spill with suitable
absorbent.
Local or national regulations may apply to releases and
disposal of this material, as well as those materials and items
employed in the cleanup of releases. You will need to
determine which regulations are applicable.
Sections 13 and 15 of this SDS provide information regarding
certain local or national requirements.

SECTION 7. HANDLING AND STORAGE

Technical measures : See Engineering measures under EXPOSURE


CONTROLS/PERSONAL PROTECTION section.

Local/Total ventilation : Use only with adequate ventilation.

Advice on safe handling : Handle in accordance with good industrial hygiene and safety
practice.
Take care to prevent spills, waste and minimize release to the
environment.

Conditions for safe storage : Keep in properly labeled containers.


Store in accordance with the particular national regulations.

Materials to avoid : Do not store with the following product types:


Strong oxidizing agents

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters


Ingredients CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
Silicon dioxide 7631-86-9 TWA (Dust) 20 Million OSHA Z-3
particles per cubic
foot
(Silica)

3 / 13
SAFETY DATA SHEET

DOW CORNING(R) 732 MULTI-PURPOSE


SEALANT WHITE

Version Revision Date: SDS Number: Date of last issue: 04/25/2016


2.1 05/06/2016 3280111-00003 Date of first issue: 12/21/2015

TWA (Dust) 80 mg/m3 OSHA Z-3


/ %SiO2
(Silica)
TWA 6 mg/m³ NIOSH REL
(Silica)
Titanium dioxide 13463-67-7 TWA (total 15 mg/m³ OSHA Z-1
dust)
TWA 10 mg/m³ ACGIH
(Titanium dioxide)
Engineering measures : Processing may form hazardous compounds (see section
10).
Ensure adequate ventilation, especially in confined areas.
Minimize workplace exposure concentrations.

Personal protective equipment


Respiratory protection : No personal respiratory protective equipment normally
required.

Hand protection

Remarks : Wash hands before breaks and at the end of workday.

Eye protection : Wear the following personal protective equipment:


Safety glasses

Skin and body protection : Skin should be washed after contact.

Hygiene measures : Ensure that eye flushing systems and safety showers are
located close to the working place.
When using do not eat, drink or smoke.
Wash contaminated clothing before re-use.
These precautions are for room temperature handling. Use at
elevated temperature or aerosol/spray applications may
require added precautions.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : paste

Color : white

Odor : Acetic acid

Odor Threshold : No data available

pH : Not applicable

Melting point/freezing point : No data available

Initial boiling point and boiling : Not applicable


range

4 / 13
SAFETY DATA SHEET

DOW CORNING(R) 732 MULTI-PURPOSE


SEALANT WHITE

Version Revision Date: SDS Number: Date of last issue: 04/25/2016


2.1 05/06/2016 3280111-00003 Date of first issue: 12/21/2015

Flash point : Not applicable

Evaporation rate : Not applicable

Flammability (solid, gas) : Not classified as a flammability hazard

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapor pressure : Not applicable

Relative vapor density : No data available

Relative density : 1.04

Solubility(ies)
Water solubility : No data available

Partition coefficient: n- : No data available


octanol/water

Autoignition temperature : No data available

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : Not applicable

Explosive properties : Not explosive

Oxidizing properties : The substance or mixture is not classified as oxidizing.

Molecular weight : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Not classified as a reactivity hazard.

Chemical stability : Stable under normal conditions.

Possibility of hazardous reac- : Use at elevated temperatures may form highly hazardous
tions compounds.
Can react with strong oxidizing agents.
Acetic acid is formed upon contact with water or humid air.
Hazardous decomposition products will be formed at elevated
temperatures.

Conditions to avoid : None known.

Incompatible materials : Oxidizing agents

5 / 13
SAFETY DATA SHEET

DOW CORNING(R) 732 MULTI-PURPOSE


SEALANT WHITE

Version Revision Date: SDS Number: Date of last issue: 04/25/2016


2.1 05/06/2016 3280111-00003 Date of first issue: 12/21/2015

Hazardous decomposition products


Thermal decomposition : Formaldehyde

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure


Skin contact
Ingestion
Eye contact
Acute toxicity
Not classified based on available information.
Ingredients:

Silicon dioxide:
Acute oral toxicity : LD50 (Rat): > 3,300 mg/kg
Assessment: The substance or mixture has no acute oral tox-
icity
Remarks: Information taken from reference works and the
literature.

Acute inhalation toxicity : LC50 (Rat): > 2.08 mg/l


Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute inhala-
tion toxicity
Remarks: Information taken from reference works and the
literature.

Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg


Assessment: The substance or mixture has no acute dermal
toxicity
Remarks: Information taken from reference works and the
literature.

Titanium dioxide:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg

Acute inhalation toxicity : LC50 (Rat): > 6.82 mg/l


Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute inhala-
tion toxicity

Skin corrosion/irritation
Not classified based on available information.
Product:
Result: No skin irritation
Remarks: Based on data from similar materials

6 / 13
SAFETY DATA SHEET

DOW CORNING(R) 732 MULTI-PURPOSE


SEALANT WHITE

Version Revision Date: SDS Number: Date of last issue: 04/25/2016


2.1 05/06/2016 3280111-00003 Date of first issue: 12/21/2015

Ingredients:

Silicon dioxide:
Result: No skin irritation
Remarks: Information taken from reference works and the literature.

Titanium dioxide:
Species: Rabbit
Result: No skin irritation

Serious eye damage/eye irritation


Not classified based on available information.
Product:
Result: No eye irritation
Remarks: Based on data from similar materials

Ingredients:

Silicon dioxide:
Result: No eye irritation
Remarks: Information taken from reference works and the literature.

Titanium dioxide:
Species: Rabbit
Result: No eye irritation

Respiratory or skin sensitization

Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Ingredients:

Silicon dioxide:
Assessment: Does not cause skin sensitization.

Test Type: Skin: test type not specified


Species: Guinea pig
Remarks: Information taken from reference works and the literature.

Titanium dioxide:
Test Type: Local lymph node assay (LLNA)
Routes of exposure: Skin contact
Species: Mouse
Result: negative

7 / 13
SAFETY DATA SHEET

DOW CORNING(R) 732 MULTI-PURPOSE


SEALANT WHITE

Version Revision Date: SDS Number: Date of last issue: 04/25/2016


2.1 05/06/2016 3280111-00003 Date of first issue: 12/21/2015

Germ cell mutagenicity


Not classified based on available information.
Ingredients:

Silicon dioxide:
Genotoxicity in vitro : Result: negative
Remarks: Information taken from reference works and the
literature.

Genotoxicity in vivo : Application Route: Ingestion


Result: negative
Remarks: Information taken from reference works and the
literature.

Germ cell mutagenicity - : Animal testing did not show any mutagenic effects.
Assessment

Titanium dioxide:
Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES)
Result: negative

Genotoxicity in vivo : Test Type: In vivo micronucleus test


Species: Mouse
Result: negative

Carcinogenicity
Not classified based on available information.
Ingredients:

Titanium dioxide:
Species: Rat
Application Route: inhalation (dust/mist/fume)
Exposure time: 24 Months
Method: OECD Test Guideline 453
Result: positive
Remarks: The mechanism or mode of action may not be relevant in humans.
The substance is inextricably bound in the product and therefore does not contribute to a dust
inhalation hazard.

Carcinogenicity - Assess- : Limited evidence of carcinogenicity in inhalation studies with


ment animals.

IARC Group 2B: Possibly carcinogenic to humans

Titanium dioxide 13463-67-7

OSHA No ingredient of this product present at levels greater than or


equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.

8 / 13
SAFETY DATA SHEET

DOW CORNING(R) 732 MULTI-PURPOSE


SEALANT WHITE

Version Revision Date: SDS Number: Date of last issue: 04/25/2016


2.1 05/06/2016 3280111-00003 Date of first issue: 12/21/2015

NTP No ingredient of this product present at levels greater than or


equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.
Repeated dose toxicity

Ingredients:

Titanium dioxide:
Species: Rat
NOAEL: 24,000 mg/kg
Application Route: Ingestion
Exposure time: 28 Days

Species: Rat
NOAEL: 10 mg/m³
Application Route: inhalation (dust/mist/fume)
Exposure time: 2 y
Remarks: The substance is inextricably bound in the product and therefore does not contribute
to a dust inhalation hazard.

Aspiration toxicity
Not classified based on available information.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Ingredients:

Titanium dioxide:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h

Toxicity to algae : EC50 (Skeletonema costatum (marine diatom)): > 10,000 mg/l
Exposure time: 72 h

Toxicity to bacteria : EC50: > 1,000 mg/l


Exposure time: 3 h

9 / 13
SAFETY DATA SHEET

DOW CORNING(R) 732 MULTI-PURPOSE


SEALANT WHITE

Version Revision Date: SDS Number: Date of last issue: 04/25/2016


2.1 05/06/2016 3280111-00003 Date of first issue: 12/21/2015

Method: OECD Test Guideline 209

Persistence and degradability


No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Resource Conservation and : This product has been evaluated for RCRA characteristics
Recovery Act (RCRA) and does not meet the criteria of hazardous waste if discarded
in its purchased form.

Waste from residues : Dispose of in accordance with local regulations.

Contaminated packaging : Empty containers should be taken to an approved waste


handling site for recycling or disposal.
If not otherwise specified: Dispose of as unused product.

SECTION 14. TRANSPORT INFORMATION

International Regulations

UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation

49 CFR
Not regulated as a dangerous good

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity

10 / 13
SAFETY DATA SHEET

DOW CORNING(R) 732 MULTI-PURPOSE


SEALANT WHITE

Version Revision Date: SDS Number: Date of last issue: 04/25/2016


2.1 05/06/2016 3280111-00003 Date of first issue: 12/21/2015

Ingredients CAS-No. Component RQ Calculated product RQ


(lbs) (lbs)
Acetic acid 64-19-7 5000 *
Acetic anhydride 108-24-7 5000 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards : No SARA Hazards

SARA 302 : No chemicals in this material are subject to the reporting re-
quirements of SARA Title III, Section 302.

SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

US State Regulations

Pennsylvania Right To Know


Dimethyl siloxane, hydroxy-terminated 70131-67-8
Silicon dioxide 7631-86-9
Distillates (petroleum), hydrotreated middle 64742-46-7
Acetic acid 64-19-7
Acetic anhydride 108-24-7
California Prop. 65 This product does not contain any chemicals known to the
State of California to cause cancer, birth, or any other repro-
ductive defects.
California List of Hazardous Substances
Silicon dioxide 7631-86-9
California Permissible Exposure Limits for Chemical Contaminants
Silicon dioxide 7631-86-9
The ingredients of this product are reported in the following inventories:
NZIoC All ingredients listed or exempt.

TSCA All chemical substances in this material are included on or


exempted from listing on the TSCA Inventory of Chemical
Substances.

AICS All ingredients listed or exempt.

IECSC All ingredients listed or exempt.

ENCS/ISHL All components are listed on ENCS/ISHL or exempted from


inventory listing.

KECI All ingredients listed, exempt or notified.

PICCS All ingredients listed or exempt.

DSL All chemical substances in this product comply with the CEPA

11 / 13
SAFETY DATA SHEET

DOW CORNING(R) 732 MULTI-PURPOSE


SEALANT WHITE

Version Revision Date: SDS Number: Date of last issue: 04/25/2016


2.1 05/06/2016 3280111-00003 Date of first issue: 12/21/2015

1999 and NSNR and are on or exempt from listing on the


Canadian Domestic Substances List (DSL).

REACH For purchases from Dow Corning EU legal entities, all


ingredients are currently pre/registered or exempt under
REACH. For purchases from non-EU Dow Corning legal
entities with the intention to export into EEA please contact
your DC representative/local office.

TCSI All ingredients listed or exempt.

SECTION 16. OTHER INFORMATION

Further information

NFPA: HMIS III:


Flammability

HEALTH 0
1
Instability
Health

0 0 FLAMMABILITY 1
PHYSICAL HAZARD 0
0 = not significant, 1 =Slight,
Special hazard.
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Full text of other abbreviations


ACGIH : USA. ACGIH Threshold Limit Values (TLV)
NIOSH REL : USA. NIOSH Recommended Exposure Limits
OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-
its for Air Contaminants
OSHA Z-3 : USA. Occupational Exposure Limits (OSHA) - Table Z-3 Min-
eral Dusts
ACGIH / TWA : 8-hour, time-weighted average
NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek
OSHA Z-1 / TWA : 8-hour time weighted average
OSHA Z-3 / TWA : 8-hour time weighted average

AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-
stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Haz-
ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Sched-
ule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated
with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized

12 / 13
SAFETY DATA SHEET

DOW CORNING(R) 732 MULTI-PURPOSE


SEALANT WHITE

Version Revision Date: SDS Number: Date of last issue: 04/25/2016


2.1 05/06/2016 3280111-00003 Date of first issue: 12/21/2015

System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System;
IARC - International Agency for Research on Cancer; IATA - International Air Transport Associa-
tion; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous
Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Avia-
tion Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - Interna-
tional Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial
Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Ko-
rea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50
- Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Conven-
tion for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Administration;
n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Ob-
served (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR -
No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand
Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development;
OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative
and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances;
(Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and Re-
covery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ -
Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund
Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Sub-
stance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations;
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB -
Very Persistent and Very Bioaccumulative

Sources of key data used to : Internal technical data, data from raw material SDSs, OECD
compile the Material Safety eChem Portal search results and European Chemicals Agen-
Data Sheet cy, http://echa.europa.eu/

Revision Date : 05/06/2016

Items where changes have been made to the previous version are highlighted in the body of
this document by two vertical lines.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, in-
formation and belief at the date of its publication. The information is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and
shall not be considered a warranty or quality specification of any type. The information provid-
ed relates only to the specific material identified at the top of this SDS and may not be valid
when the SDS material is used in combination with any other materials or in any process, un-
less specified in the text. Material users should review the information and recommendations
in the specific context of their intended manner of handling, use, processing and storage, in-
cluding an assessment of the appropriateness of the SDS material in the user’s end product, if
applicable.

US / Z8

13 / 13

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