8/25/2021 Chemical Kinetics MCQ | Questions – Paper 2

Chemical Kinetics MCQ | Questions – Paper 2

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Topic: Chemical Kinetics, Test No.: 02, Total MCQs: 15

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Question 1 CORRECT

Consider the reaction,

Cl2 (aq) + H2S (aq) → S(s) + 2H+(aq) + 2Cl–(aq)

The rate equation for this reaction is, rate = k [Cl2]

[H2S]

Which of these
mechanisms is/are consistent with this rate equation? [AIEEE 2010]

(a).  Cl2 + H2S → H+ + Cl– + Cl+

+ HS– (slow)

     Cl+ + HS– → H+ + Cl– + S

(fast)

(b).  H2S  H+ + HS–

(fast equilibrium)

     Cl2 + HS– → 2Cl– + H+ + S

(slow)

(a) only

(b) only

Both (a) and (b)

Neither (a) nor (b)

Question 2 CORRECT

The time for

half life period of a certain reaction A →
Products is 1 h. When the initial
concentration of the reactant 'A' is 2.0
mol L–1, how much time does it take for its
concentration to come
from 0.50 to 0.25 mol L–1, if it is a zero order reaction?
[AIEEE
2010] 
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8/25/2021 Chemical Kinetics MCQ | Questions – Paper 2

0.25 h

1h

4h

0.5 h

Question 3 CORRECT

The time taken

for 10% completion of a first order reaction is 20 min. Then, for 19%
completion, the reaction will take [WB JEE 2009]

40 mins

60 mins

30 mins

50 mins

Question 4 CORRECT

For a chemical
reaction A → B, the rate of the
reaction is 2 × 10–3 mol dm–3 s–1 when
the
initial concentration is 0.05 mol dm–3. The rate of the same
reaction is 1.6 × 10–2
mol dm–3 s–1 when the
initial concentration is 0.1 mol dm–3. The order of the reaction
is
[Karnataka CET 2009]

Question 5 CORRECT

For the decomposition

of a compound AB at 600 K, the following data were obtained
[Karnataka CET
2009]

[AB] mol dm–3 Rate of

decomposition of AB in mol dm–3 s–1

0.20 2.75 × 10–8

0.40 11.0 × 10–8

0.60 24.75 × 10–8

The order for

the decomposition of AB is

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8/25/2021 Chemical Kinetics MCQ | Questions – Paper 2

1.5

Question 6 CORRECT

The rate
equation for a reaction: A → B
is r = K [A]°. If the initial
concentration of the
reactant is a mol dm–3, the half life period
of the reaction is [Karnataka CET 2009]

K/a

a/K

2a/K

a/2K

Question 7 CORRECT

For a first
order reaction A → P, the
temperature (T) dependent rate constant (k) was
found to follow the equation

log k =
–(2000)  + 6.0.

The pre–exponential
factor A and the activation energy Ea, respectively, are [IIT
JEE
2009]

1.0
× 106 s−1 and 9.2 kJmol−1

6.0
s−1 and 16.6 kJmol−1

1.0
× 106 s−1 and 16.6 kJmol−1

1.0
× 106 s−1 and 38.3 kJmol−1

Question 8 CORRECT

For the
reaction A + B → products, it is
observed that

(i) On
doubling the concentration of A only, the rate of reaction is also doubled.

(ii) On
doubling the initial concentration of both A and B, there is change by a
factor of
8 in the rate of reaction.

The rate of
reaction is given by [CBSE AIPMT 2009]

rate = k [A] [B]

rate = k [A]2 [B]

rate = k [A] [B]2

rate = k [A]2 [B]2

Question 9 CORRECT
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8/25/2021 Chemical Kinetics MCQ | Questions – Paper 2

For the
reaction, N2 + 3H2 →
2NH3, if  = 2 × 10–4
mol L–1 s–1, the value of –
would be [CBSE
AIPMT 2009]

4 ×
10–4 mol L–1 s–1

6 ×
10–4 mol L–1 s–1

1 ×
10–4 mol L–1 s–1

3 ×
10–4 mol L–1 s–1

Question 10 CORRECT

Half life
period of a first order reaction is 1386 seconds. The specific rate constant
of
the reaction is [CBSE AIPMT 2009]

0.5
× 10–2 s–1

0.5
× 10–3 s–1

5.0
× 10–2 s–1

5.0
× 10–3 s–1

Question 11 CORRECT

In the
reaction

BrO3–
(aq) + 5Br– (aq) + 6H+ →
3Br2 (l) + 3H2O(l)

The rate of
appearance of bromine (Br2) is related to the rate of
disappearance of
bromide ions as [CBSE AIPMT 2009]

Question 12 CORRECT

The half life

period of a first order chemical reaction is 6.93 minutes. The time required
for the completion of 99% of the chemical reaction will be (log 2 = 0.301) [AIEEE
2009]

230.3 minutes

23.03 minutes

46.06 minutes

460.6 minutes 
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8/25/2021 Chemical Kinetics MCQ | Questions – Paper 2
Question 13 CORRECT

Under the same

reaction conditions, initial concentration of 1.386 mol dm–3 of a
substance becomes half in 40 seconds and 20 seconds through first order and
zero
order kinetics respectively. Ratio  of the rate
constants for first order (k1) and zero

order (k0) of
the reaction is [IIT JEE 2008]

0.5
mol–1 dm3

1.0
mol–1 dm–3

1.5
mol dm–3

2.0
mol–1 dm–3

Question 14 CORRECT

The
bromination of acetone that occurs in acid solution is represented by the
equation

CH3COCH3(aq)
+ Br2(aq) → CH3COCH2Br(aq)
+ H+(aq) + Br–(aq)

These kinetic
data were obtained from given reaction concentrations. [CBSE AIPMT
2008]

Initial
concentrations, (M)

[CH3COCH3] [Br2] [H+]

0.30 0.05 0.05

0.30 0.10 0.05

0.30 0.10 0.10

0.40 0.05 0.20

Initial Rate,
disappearance of Br2, Ms–1

5.7 × 10–5

5.7 × 10–5

1.2 × 10–4

3.1 × 10–4

Based on these
data, the rate of reaction is

rate = k [CH3COCH3] [Br2]

rate = k [CH3COCH3] [Br2] [H+]2

rate = k[CH3COCH3][Br2] [H+]

rate = k[CH3COCH3] [H+]

Question 15 CORRECT

The rate
constants k1 and k2 for two different reactions are 1016
× e–2000/T and 1015
× e–
1000/T
, respectively.
The temperature at which k1 = k2 is [CBSE AIPMT
2008] 
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8/25/2021 Chemical Kinetics MCQ | Questions – Paper 2

2000 K

1000 K

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