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MCQ Coordination Compound

This document contains a quiz on coordination compounds with 30 multiple choice questions. The questions cover topics like naming coordination complexes, identifying the central metal ion, describing complex ion structures, and explaining isomerism. An answer key is provided at the end with the correct response for each question lettered A-D.

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0% found this document useful (0 votes)
555 views3 pages

MCQ Coordination Compound

This document contains a quiz on coordination compounds with 30 multiple choice questions. The questions cover topics like naming coordination complexes, identifying the central metal ion, describing complex ion structures, and explaining isomerism. An answer key is provided at the end with the correct response for each question lettered A-D.

Uploaded by

harshdadhich2006
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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THE GURU Institute,9785414777

Name.………………………………………………… Class…………… Date…………….. Marks……………………

Chapter: Coordination Compound

Q.1 A coordination complex’s core atom/ion is also known as ________

(a) Bronsted-Lowry acid (b) Lewis base (c) Lewis acid (d) Bronsted-Lowry base

Q.2 Determine the proper name for K2[PdCl4].

(a) Potassium tetrachlorinepalladium(II) (b) Potassium tetrachloridopalladate(II)Potassium


(c) Potassium tetrachloridopalladium(II) (d) tetrachlorinepalladate(II)

Q.3 The core atom of which of the following biologically significant coordination molecules is magnesium?

(a) Vitamin B12 (b) Haemoglobin (c) Chlorophyll (d) Carboxypeptidase-A

Q.4 IUPAC name of [Pt(NH3)3 Br (NO2) Cl] Cl is


(a) triamminechlorodibromidoplatinum (IV) chloride (b) triamminechloridobromidonitrochloride- platinum (IV) chloride
(c) triamminebromidochloridonitroplatinum (IV) chloride (d) triamminenitrochlorobromoplatinum (IV) chloride

Q.5 Primary and secondary valency of Pt in [Pt(en)2Cl2] are


(a) 4, 4 (b) 4, 6 (c) 6, 4 (d) 2, 6

Q.6 The complex ions [Co(NH3)5(NO2)]2+ and [Co(NH3)5 (ONO)]2+ are called
(a) Ionization isomers (b) Linkage isomers (c) Co-ordination isomers (d) Geometrical isomers

Q.7 Which of the following has square planar structure?


(a) [NiCl4]2- (b) [Ni(CO)4] (c) [Ni(CN)4]2- (d) None of these

Q.8 Mohr’s salt is


(a) Fe2(SO4)3.(NH4)2SO4 . 6H2O (b) FeSO4.(NH4)2SO4.6H2O (c) MgSO4 . 7H2O (d) FeSO4 . 7H2O

Q.9 EDTA is used for the estimation of


(b) Cl– and Br– ions

THE GURU Creating Talents,9950188020


(a) Na+ and K+ ions (c) Cu2+ and Cs+ ions (d) Ca2+ and Mg2+ ions

Q.10 The solution of the complex [Cu(NH3)4] SO4 in water will


(a) give the tests of Cu2+ ion (b) give the tests of NH3
2-
(c) give the tests of SO4 ions (d) not give the tests of any of the above

Q.11 How many donor atoms can EDTA4- ligand bind through?
(a) 2 (b) 4 (c) 6 (d) 8

Q.12 The SCN– ion is a unidentate ligand.


(a) True (b) False

Q.13 What is the coordination number of chromium in K3[Cr(C2O4)3]?


(a) 1 (b) 2 (c) 3 (d) 6

Q.14 Which of the following will not give test for Cl– with AgNO3(aq) at 25°C?
(a) COCl3.5NH3 (b) COCl3.6NH3 (c) COCl3.3NH3 (d) COCl3.4NH3
THE GURU Institute,9785414777

Q.15 Which of these statements about [Co(CN)6]3- is true?


(a) It has 4 unpaired electron, high spin (b) No unpaired electron, high spin
(c) No unpaired electron, low spin (d) 4 unpaired electron, low spin

Q.16 Facial and meridional isomerism will be shown by


(a) [Co(NH3)3Cl3] (b) [Co(NH3)4Cl2]Cl (c) [Co(en)3]Cl3 (d) [Co(NH3)5Cl]Cl2

Q.17 Which one has highest molar conductivity?


(a) [Pt(NH3)2 Cl2] (b) [CO(NH3)4 Cl2] Cl (c) K4[Fe(CN)6] (d) [Cr(H2O)6] Cl3

Q.18 Which one will show optical isomerism?


(a) [Co(NH3)3Cl3] (b) cis-[Co(en)2 Cl2] Cl (c) trans-[Co(en)2 Cl2] Cl (d) [Co(NH3)4 Cl2] Cl

Q.19 The pair having the same magnetic moment is (At No. Cr = 24, Mn = 25, Fe = 26, Co = 27)
(а) [Cr(H2O)6]2+ and [CoCl4]2- (b) [Cr(H2O)6]2+ and [Fe (H2O)6]2+
2+ 2+
(c) [Mn(H2O)6] and[Cr(H2O)6] (d) [COCl4]2- and [Fe(H2O)6]2+

Q. 20 Among the ligands NH3, en, CN and CO, the correct order of field strength is
(a) NH3 < en < CN– < CO (b) CN– < NH3 < CO < en
(c) en < CN–< NH3 < CO (d) CO < NH3 < en < CN–

Q.21 Which of the following is the most stable complex species? [NCERT Exemplar]
(a) [Fe(CO)5] (b) [Fe(CN)6]3- (c) [Fe(C2O4)3]3- (d) [Fe(H2O)6]3+

Q.22 Indicate the complex ion which shows geometrical isomerism.


(a) [Cr(H2O)4Cl2]+ (b) [Pt(NH3)3 Cl] (c) [Co(NH3)6]3+ (d) [Co(CN)5(NC)]3-

Q.23 The compounds [Co(SO4)(NH3)5]Br and [CO(SO4)(NH3)5]Cl represent


(a) linkage isomerism (b) ionisation isomerism (c) coordination isomerism (d) no isomerism

Q.24 Which of the following shall form an octahedral complex?


(a) d4 (low spin) (b) d8 (high spin) (c) d6 (low spin) (d) All of these

THE GURU Creating Talents,9950188020


Q.25 The name of complex [Fe(CN)6]3- is
(a) Tricyanido ferrate (III) ion (b) Hexacyanido ferrate (III) ion
(c) Hexacyanido iron (III) (d) Hexacyanido ferrate (II) ion

Q.26 Atomic number of Mn, Fe and Co are 25, 26 and 27 respectively. Which of the following inner orbital
octahedral complex ions are diamagnetic?
(a) [CO(NH3)6]3+ (b) [Mn(CN)]3- (c) [Fe(CN)6]4- (d) [Fe(CN)6]3-

Q.27 If ∆o > P for d4, electronic configuration in terms of CFT is _________ .

Q.28 Write IUPAC name of K3[Fe(C2O4)3].............................................................................................................


Q.29The formula of potassium dicyanobis (oxalato) nickelate (II) is
(a) K4[Ni(CN)(Ox)2] (b) K3[Ni2 (CN)2 (Ox)2] (c) K4[Ni(CN)2(Ox)2] (d) K2[Ni(CN)2(Ox)2]

Q.30 K3[Al(C2O4)3] is called


(a) Potassium alumino oxalate (b) Potassium aluminium (III) trioxalate
(c) Potassium trioxalato aluminate (III) (d) Potassium tris (oxalato) aluminium.
THE GURU Institute,9785414777

Answer Key:

1. C 2. B 3. C 4. C 5. D 6. B 7.C 8.B 9.D 10.C 11.C 12. A 13. D 14.C 15. C


16.A 17. C 18.B 19. B 20. A 21. C 22.A 23. B 24. B 25.B 26.A 27. T2g4 eg0

28…………… 29.C 30.C

THE GURU Creating Talents,9950188020

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