PRACTICE SET-3. (Single Correct Answer Type) 1. Consider the following reaction: A(g) + Big) > 2C(@) ‘The rate of this reaction fat is 3 x 108 at -dBl mol litre-' min“. What is the value of Sata in mol litre! min“!? (a) 3 x 10% (c) 103 (b) 9x 109 (@) 1.5 x 10% 2. For a reaction: 3A+B—C+D aa EKA) 4B then the rate expression for =a) will be (@) K[Ap [B] (>) 3K [A} [B] © FKATB] — @ Kfeap pp] 8. Inareaction:2X - Y, the concentration of X decreases from 0.5 (M) to 0.4 (M) in 10 minutes. ‘The rate of reaction during this interval is (@) 5*10%Mmin* (b) 5x10 M mint @ 1*10¢Mmint = @) 2x10? M min 4. The hypothetical reaction: 2X + 5Y + Z, is carried out in a closed vessel. The molar concentration of Y is increased by ‘5x10 mol Lift 10 seconds. The rate of reaction is: (@) 5x104Msee1 —(b) 1x 10M sect © 5x10%Msect (4) 2x 104 Mec 5. Rate of formation of SO, in the following reaction: 280,(g) + 0,(g) + 280 ,(g) 4s 100 gm/min. The rate of disapperance of O, is (@) 50 g/min ©) 200 g/min (©) 40 g/min @ 20g/min 6. For the reaction: A+2B +0 the formation of C is: () Rate=KIAI[Bf () Rate= KIA) [B] (© Rate=KIAF [B] » the rate law for _ (@) Impossible to state from the data gyen For the reaction: 2X > ¥ +37,, say _ “ae “KP the correct relation between K,, (@ K,=K,=K, Ky and Kis () 2K, =K, = Ky @) 3K, =6K, For the reaction: 2NO + Cl, ~» 2NOCL itis ou, that doubling the concentration of both re increases the rate by a factor of 8, but deuke the Cl, concentration alone, only doubles ié rate, What is the order of the reaction? (a0 1 @2 @ 3 Amechanism for a naturally occurring reaction that destroys ozone is Step 1: 0, (g) + HO(®) + HO, (®) + 0, Step 2: HO, (g) + O() + HOW) + 0,4) What is the molecularity of the overall reaction? (@) Unimolecular () Bimolecular (©) None of these because molecularity is the difference of the exponents in the rate law (@) None of these because molecularity only refers to elementary steps 3 =2k, (©) 4K, =K, |. The reaction of hydrogen and iodine monodhloride is given as: H,(@) + 21Clig) + 2HCl@)+L(@. This reaction is of first order with respect to each Hy (g) and ICI (g), following mechanisms were proposed: Mechanism A: Hy (@) + 21Cl@) + 2HCL® +1@ Mechanism B: Hy (g) + ICl(g) + HCI(g) + HI(g); slow HI@) + ICl@) 4 HClig) + Ip (gs fast Which of the above mechaniam(s) can be consistent with the given information. reaction? (a) Aonly b) Bonly (©) Aand B both @) Neither A nor B Scanned with CamScannerna ante teeiviatilndadpaeiaa aulatssacaue ee following mechanism has been proposed for th . fection of NO with Br to form NOBr. ser! NO() + Bro(g) == NOBr,(g) pe NOBry(€)+ NO) -» 2NOBr) second step is the rate determining ste ih ger ofthe reaction with respect to NOW s oe 4 go @ 3 pe rate constant forthe reaction: 7 4042 4NOz +02 i8 5x 10+ see ifthe rate is 2 x 10° mol L* sec, then the tion of N,O, (in mol L*) is concentrat @i4 ® 12 (9 004 @ 080 15, Thereaction A(®) +2B(@)—> C(@) + Dig)isan slementary process. In an experiment, the initial pressure of A and Bare P, = 0.6 atm and ~0.8 atm. When P, =0.20 atm, the rate of P, reaction, relative to the initial rate is... . 96 ) 14 ous @ a” 14, Consider the reaction, 2A + B > Products When concentration of B alone was doubled, the halflife did not change. When the concentration of A alone was doubled, the rate increased by two times. The unit of rate constant for this reaction is (@) L mol-1 s+ (©) Mol L-! s+ 15, Theinitial rate of zero order reation A> 2B is 0.01 mol L-! min-1, If the initial concentration of A is 0.1 mol L-?, what would be the (b) No unit @ st concentration of B after 60 seconds? (@) 0.090) (b) 0.01(M) (0) 0.02(M) @ 0.04(M) 18 For the zero order reaction: X-> Y, initial concentration of X is 0.1 mol L-t. If [XI = 0.08 (Mf) after 10 gainutes then its half life and completion time are respectively (a) 15 min, 30 min o 30 min, 60 min ou 17. The half life period of a 18. certain reaction A Products is one hour when initial concentration of the reactant (A) is 2 moV/dm". How much time does it take for its oncentratio® to come from 0.50 to 0.25 moV/dm if tis 8 267° order reaction ? (a) Lhour (©) 0.5 hour For the reaction, -(28) =i). Find the value of Xin data table provided. (b) 4hours @ 0.25 hour A> B+ C; the rate law is Time (In min) 0 10 30 19. 21. Concentration of A x 3M) [15D (b) 0.375(M) (a) 0.1875 (M) (@ none of these (c) 0.75(M) For a reaction: X (g) > ¥ (@) + 2(@) ‘The half life period is 6.93 min, which is independent of concentration of X. The time required for the completion of 99% of the chemical reaction will be: : (a) 230.3 min (b) 23.03 min (©) 46.06 min (@ 460.6 min . Fora particular first order reaction, it takes 12 minutes for the concentration of the reactant to decrease to 25% of its initial value. What is the Value for the rate constant (in sec!) for the reaction? (a) 5.775 x 10-2 sec? (b) 1.925 x 10° sec (© 9.625 x 10-4 sec (@) 2.88 x 10°$ sec (A) follows first order reaction (A) — Products. Concentration of A changes from 0.3(M) to 0.075(M) in 40 minutes. Find the rate of reaction when concentration of A is 0.01 (M). (@) 3.47x104M min? (b) 3.47x10% M min © 1.73x104M min? @) 1.78x10 M min . For a first order reaction X + P, the rate of reaction at reactant concentration of 0.01 (M) is found to be 2 x 10 mol L7? sec’, The half life period of the reaction is: (@) 220 sec (b) 30sec (© 300 sec (@ 347 sec © 25 min, 50 min @)_20 min, 40 mi Scanned with CamScanneree weeny 28. Thereaction A—K Products is zero order while the reaction B—S—> Products is 1" order. For what initial concentration of A the half lives of the two reactions are equal? Assume rate constant is same for both reactions. (a) 2 (mol L-4) ) In 2(mol L*) (©) 2log2 (mol L) — @ 21n.2 (mol L) 24. For a reaction: 24 +B -> Products, Rate law is: -4) = K{A]-Ata time =(1/K), concentration it of the reactant is (C, = Initial concentration) ior () c, 1. o() wd 25. Consider the following first order completing reaction (i) X— P, (ty, =Smin) Gi) ¥ > Q (t,).-= 15min) Initially [X] = 4[Y]. The time after which the concentration of both the substance will be equal. is (@) 5 min © 20min (d) Concentrations can never be equal 26. In a first order reaction A — P, the ratio of @/ (a —x) was found to be 8 after 60 minutes. If the concentration of (A) is 0.1 M, then the rate of reaction is (a) 2.226x10-3 M min-} ©) Ce (b) 15 min —_ 28, The half life of hypothetical reaction y independent of initial concentration op, Y it (0). The concentration of X decreases facta (QM) to 0.6 (M) in 30 minutes. The time 08 the concentration to change from 9.9 ry for 0.676 (M) is: to (@) 30 minutes ©) 60 minutes (© 15 minutes (@ 45 minutes 29, The gas phase decomposition of azome isa first order process with a rate connie’ 45 x 10 sl at 100°C. The decomprant! reaction is: (CH,)5No{e) > CHG Ny Given the following data: 10 moe, azomethane is placed in a first vessel ait 5 moles of azomethane in the second veeet The vessels are at the same temperatey (100°C). How much time is required for halt the azomethane to decompose in each vessel? (a) Vessel (1) requires twice as much time as vessel (2) () Vessel (2) requires twice as much tine vessel (1) : (©) Vessel (1) requires four times as much time as vessel (2) (@ Vessel (1) requires the same interval of time as vessel (2) 30. For the reaction: XY, itis found that aplotot In KX] versus time is linear with negative slope and that in 90 sec [X] decreases from 0.60 (M)ta 0.075 (M). What is the half life of reaction? (@) 30 see (©) 40sec (© 60 see @ 20 see 31. For a second order reaction, (A -». Products), the ratio of (t/q) to (typ) is ... (b) 3.465%10-8 M min? (a) 4:1 (b) 3:2 (©) 4.455x10-3 M min (c) 8:1 (@) 2:1 @ 6.582x10-M mint 82. Consider the decomposition of azomethane: 1 ee? (CHg),Nj (g) > No(g) D 21.-A plot of Fpag7] V8 time is a linear for the aN o> Nie Perel reaction: 8 BrO(aq) > BrO,-(aq) + 2 Br- (aq) The concentration ‘What is the order of the reaction with respect of azomethane oso) to the hydrobromite ion (BrO-) ? as a function of i @o 1 time is shown in eee y ica @s given figure . Scanned with CamScanner| | | | tis the reaction rate after $30 min? 46.775 * 10°S mol L7? min? 14726 x 104 mol L~ mint ig 878 « 10% mol Lt mint (3476 x 1074 mol L"? min? : consider the following reaction: In +2H* > Zn? +H, Jif is independent of concentration of zine. ht constant zine concentration, half life jominutes at pH =2 while 100 minutes ot pH= 1 rfence, the rate law is ‘ ()Rate=K [Zn]{H*] (b) Rate = K (Zn) [H+]? (oRate=K (ZnlH"1° (4) Rate=K taal rd su. Consider the following first order resctions, x—SoProducts -~ (1) y— 5Products © (2) E, and kp are the rate constants of the Faactions (1) and (2) respectively. The ratio of Hime taken (¢,) when 10% of (X) has reacted to the time taken (fq) when 80% of (Y) remained unreacted is k,(1-3log2) (9) (1—2i0g3) kp(1-2l0g3) (b) (0 3log2) ky(1-210g3) kp(1—3l0g2) © yqq3log2) © -k,(-2l0g3) the following 4%. Inthereaction: X + ¥ — Products, when the experimental graphs are obtained, other species (X or Y) are in excess, ‘the overadt order of reaction is: a, va M1 = excess Inf} [xX] excess Time Time @0 ® 2 @ 3 %8, y, Lew NoOs (g) + 2.NOp (8) + 702 @ decomposes, its tg does not change when Ng05 with its 38. changin . ne pressure during the reaction. Which ne isthe correct representation for “Pressi*t jus Time” during the reaction when initial Pressure of NO; is equal to P,. I, i i 'N205 4 1 Nop (a) Fon b) F205, time> ‘ime> time > involving single reactant, ime for half change and centration (C,) remains f experiments (with different C, value). If the concentration of reactant is doubled, then the rate of reaction is changed by the factor (a) 4 (b) 2/2 8 @ 2 ‘The esterification of acetic anhydride by ethyl alcohol is as per equation: (CH,CO),0 + C,H,OH > CH,COOC,H, + CH,COOH in solvent Inacertain reaction the product of the ti square of the initial con constant in a series of When the reaction takes place i ethanol. The rate law is: * (a) Rate= K[(CH,CO), of (b) Rate =K[(CH,CO), © ][C2H50H] (c) Rate =K[(CH3CO), 0] (@) Rate = K[C2Hs0H] ‘The rate constant, the activation energy and ‘Arrhenius parameter of a chemical reaction at ‘g6°C are 3 x 10~ sec"! 104.4 kJ mol and 6 x 10" sec respectively. The value of the rate constant as T > co is (@) 2x 10" sec? (© 6x 10" sec? (b) Infinite @ 3x 10-~sec* Scanned with CamScanner40. Temperature coefficient of a reaction is 2. When the temperature is increased from 30 K to 100 K, the rate of reaction increases by @) 500 times (b) 128 times (© 100 times (@ 256 times 41, The rate constant of reaction (X — Y) at 400 K and 450 K are 0.01 L mol~! secy! and ——_ 9 I CH, C-NH+HO->HS+CH-C_ gp is Rate = K[H’*] [TA] where TA = Ifthe temperature of the solution increased fn; 25°C to 75°C, 2.43 L mol"! sec-1, The temperature coefficient | ©) The reaction rate decreases but K remaing of the reaction is: ee : @s3 ® 2 (b) The reaction rate increases but K remaing © 25 we constant, Cn 42, The energies of activation for forward and | (©) Both the reaction ra lecreases, reverse reactions for Ay + By + 2AB are | — (@ Both the reaction rate and K increases, 180 kJ mol-! and 200 kJ mol, respectively. The presence ofa catalyst lowers the activation energy of both (forward and reverse) reactions by 100 kJ mol-. The enthalpy change of the reaction(Ay + By ~> 2AB) in the presence of catalyst will be (@) 300 kJ mol? (b) 120 kJ molt (© 280 kJ mol-! (@) 20 kd mot 43, A reaction take place in three steps. The rate constants are Ky, K, and Ks. The overall rate 47, The rate of hydrolysis of thioacetamide (CH,CSNH,) s il i CH,- C- NH,+H,6> HS + CH,- CNH, is rate = K [H*] [TA] Wafere TA = Thioacetamide, If some sodium acetate is added to a solution that‘is 0.01 (M) in both TA and H*(aq) at 25°C, (@) The reaction rate inereases but K remains the same. constant K = S1*K3. tp energy of activation | (0) The reaction rate remains same but K Kk increases. are 20, 16 and 10 kJ mol", the overall energy | (©) The reaction rate decreases but K remains of activation is [Assume same frequency factor] the same, (@) 25 kJ mol? (b) 15 kJ mol! (@) Both the reaction rate and K decreases. (©) 20 kJ mol? @ 13.34 kJ molt 48. Consider a reaction A(g)— 3B(g)+2C(g) with rate 44. The rate constant k, and ky for two different reactions are 1016 e-2000/T and 1015 ¢1000/7, respectively. The temperature at which k, =k, constant = 1.386 x 10-? min=!. Starting with 2 moles of A in 12.5 litre vessel, if reaction is allowed to takes place at constant pressure and, at 298 K, find the concentration of B after 100 - min. (a) 2000 K 22K (a) 0.04M. () 0.36M 27808. (©) 0.09M @ 0.080) (©) 1000K (a) 2008 x 49. A certain reaction proceeds in a sequence of 2.303 45. For a reaction involving no activation energy, if K, and K, are the rate constants at temperature ‘T and Ty, then the relation between Ky and Ky is: (@) Ky-K, ) Ky>K, © Ky 2B(g) + 2C(g) follows 1 order kinetic. Initially only (A) is present in the reaction vessel. Pressure developed after 20 minutes and infinite time are 3.5 and 4 atm respectively. Which of the following is/are true? (@) t5oq = 20min —() trpq, = 40 min 400 ©) tygg = min (2) ter 5g, = 60 min 7. Consider a first order decomposition reaction Age) > 4A@) Which of the following statements regarding the reaction is/are correct ? (Given: log 2 = 0.30, log 5 = 0.70) 30 minutes: Time—> (a) At 80 minutes, only 20% reaction is completed. (b) typ of reaction increases with decreasing the concentration of Ay. (© Rate of reaction decreases linearly with time, (@ The time for intersection of two curves is independent of initial concentration of Ay gas. Scanned with CamScanner—————— ST 8 A certain reaction A -> B follows the given x 1 0. p concentration (Molarity)—Time graph. Which of the following statement is (are) true? 0.5) toa fal 0.2| © 20 40 60 80 100 ‘Time(sec)—> (a) The half life of reaction is independent of concentration of reactant A. (b) The rate of reaction at 40 seconds will be approximately 3.465x10-* mol L* sect. (© The concentration of B will be 0.35 (M) at t = 60 sec. (@ 93.75 % reaction is completed at t = 80 sec. ‘The rate constant (K) of a reaction X > Yis given by K (see!) = 5 x 1010 ¢-2104RT ‘The correct statement(s) is/are: (@) The fraction of activated reactant molecules js e-210°RT. () The activation energy of this reaction is 20 kJ molt, (©) The intercept of the plot of logK vs (1/T) will be log 5 x 102° on log K axis. @ The half life of reaction depends on’ both concentration and temperature. For the first order reaction: 2N,05 (g) > 4NO,(g) + 0. (g) (a) The concentration of the reactant es exponentially with time. (b) The half-life of the reaction decreases with inéreasing temperature. (© The half-life of the reaction depends on the initial concentration of the reactant. (@) The reaction proceeds to 99.6% completion in eight half-life duration. Which of the following statement(s) is/are correct? (a) A plot of log K, versus 1/T'is linear (b) A plot of log [X] versus time isilinear for a first order reaction, X > P —_ (©) A plot of P versus 1/T is linear at constay, volume : @ A plot of P versus 1/V is linear at constang temperature 12, The rate law for the reaction: RCI + NaOH (aq) > ROH + NaCl is given by Rate = Ky [RCI]. The rate of reaction will be (a) Double on doubling the concentration of NaOH (b) Halved on reducing the concentration of RCI to one half (c) Increased on increasing the temperature of the reaction (@) Unaffected by incrasing the temperature of the reaction jopske oj, PRACTICE SETS cio» G@EEVEE ATA GLANCE) , 1. ‘The rate constant for the reaction, 2N,0, > 4NO, + Op, is 3.0 x 10° sec. Ifthe rate is 2.40 x 10~ mol litre~! sec, then the concentration of N,O, (in mol litre) is @ 14 @) 12 © 0.04 @ 08 (IT-JEE-2000) 2.' If‘ I’ is the intensity of absorbed light and Cis the concentration of AB for the photochemical process, AB + hv + AB, the rate of formation of AB is directly proportional to @c (b) I OF @ a (UT-JEE-200) 8. Consider the chemical reaction, N,(@) + 3H, (g) > 2NH,(@) The rate of this reaction can be expressed in terms of time derivative of concentration of Np H, and NH,, Identify the correct relationship amongest the rate expressions: Scanned with CamScanneraINg] __ alg) ames ge = gee = + SABI OOT-JEE.2002] a first order reaction the concentration of + reactant decreases from 800 50 mol L71 in 2 x 10* sec. The rat fhe reaction in sec"! is: @2* 10¢ (@) 1886 x 10 mol L-1 to (b) 3.45 x 19-5 @ 2x 104, OOT-JEE-2003] 5. The'reaction, A — product, follows first order jnetics. In 40 minutes the concentration of A changes from 0.1 to 0.025 M. The rate of reaction, when concentration of A is 0.01 M is () 1.73 x 104M min (0) 3.47 x 10° M min (© 3.47x 104M min* @ 1.78 x 105M min? UIT-JEE-2004] & Consider a reaction: aG + bH + Products. When concentration of both the reactants Gand His doubled, the rate increases by eight times, however when concentration of G is doubled keeping the concentration of H fixed, the rate is doubled. The overall order of réaction is @O (b)1 @2, @3 (IT-JEE-2007] 1. Under the same reaction conditions, initial concentration of 1.386 mol dm~ of a substance becomes half in 40 seconds and 20 seconds through first order and zero order kinetics, Tespectively, Ratio (K,/K,) of the rate constants for first order (k,) and zero order (k,) of reaction is (@) 0.5 mol-! dm3 (b) 1 mol dm? 15 mol dm (@)2 mol dm® [1IT-JEE-2008] “Yor a first order reaction:A+P. The perature (TT) dependent rate constant (K) was to follow the equation 2000 | : te constant of Ghemicat nine 7 ‘The pre-exponential factor (A) and the activation energy E,, respectively are (@) 1x 108 sec! and 9.2 kJ mol! + ©) 6 sec“! and 16.6 kJ mol-! (© 1x 108 sec-! and 16.6 kJ mol- @ 1x 108 sec] and 38.3 kJ mol! (1T-JEE-2009] 9. Plots showing the variation of the rate constant (&) with temperature (T) are given below. The Plot that follows Arrhenius equation is: t t a)* w * jo .— t t ok @* To tT. ~ (IT-JEE-2010] 10. In the reaction P+Q——>R+S the time taken for 75% reaction of (P) is twice the time taken for 50% reaction of P. The concentration of Q varies with reaction time as shown in the figure. The overall order of the reaction is [Qh fa) Time (@2 b) 3 @o @ 1 [MT-JEE-2013] 11, The rate of a reaction doubles when its temperature changes from 300 K to 310 K. Activation energy of such a reaction will be (R =8.314 JK“ mol! and log 2 = 0.301): (a) 53.6 kJ mol-! @) 48.6 kJ mol-1 (c) 58.5 kJ mol? @ 60.5 kJ mol-? [JEE (Main) 2013) Scanned with CamScanner12. For the non-stoichiometrie reaction, 14 . For the elementary reaction, M — N, the rate 2A+ B-+C-+D, the following kinetic data were obtained in three separate experiments, all at 298K. tal [1B __—‘[ac, mol 17 | mol L | mol 17sec" O1 0.1 12x10~ O.1 0.2 12x107 0.2 01 24x10 ‘The rate of law for the formation of C is ac @ = AAlB] oy SC =a[af [B] dC 2 dC © FaAlABY @ GA) [JEE (Main) 2014] of disappearance of M increases by a factor of 8 upon doubling the concentrationof M. The order of the reaction with respect to M is @4 ©. 3 @2 @ 1 [JEE (Adv) 2014] Higher order (> 3) reactions are rare due to (a) Low probability of simultaneously collision of all the reacting species () Increase in entropy and activation energy as more molecules are involved ~~ (©) Shifting of equilibrium towards © ue to elastic collision Feactanty (d) Loss of active species on collision EE Main) 215 Decomposition of HO fllows a frst oj, reaction, In fifty minutes the concentratgn HO, decreases from 0.5 0 0.125 M in one ayy decomposition. When the concentration of reaches 0.05 M, the rate of formation of, ff be: 16. (EE Main) 2016) (a) 1.84 x 10-? mol min (b) 6.93 x 10-? mol min! (©) 6.93 x 10 mol min-! @ 266L min“ at STP Ans (c) 16. According to the Arrhenius equation, (@) a high activation energy usually implies a fast reaction rate constant increases with increase in temperature. This is due to a greater number of collisions whose energy exceeds the activation energy higher the magnitude of activation energy, stronger is the temeprature dependence of the rate constant the pre-exponential factor is a measure of the rate at which collisions occur, irrespective of their energy [EE (Adv,) 20161 ©) © Scanned with CamScannerPRACTICESET-3 8. (a,b,c,d) 18.) 14. @) 16. (b, d) Scanned with CamScanner