4. a ‘The rate of a reaction is expressed in different ways as follows AMC]. _1elD) 1 AtA) at) er rer The reactions (A)4A+ B— 2C4+3D (B)B+3D—34A+2C (Q)A+B—>C+D (D)B+D—> A+C For the reaction 2A + 3B > 4C the rate of reaction may be represented as ~~ Ina reaction N,() + 3H,(2}—92NH, (2) the rate of appearance of NH, is 2.510 “moll: Rate of reaction & rate of disappearance of H, will be(In molL'sec"!) (A) 3.75 % 10-4, 1.25 x 104 (B) 1.25 x 104, 25 x 10+ foe ee (D) 5.0 = 104, 3.75 x 104 For the reaction 4A + B — 2C + 2D The incorrect statement is ~ (A) The rate of disappearance of B is one fourth the rate of disappearance of A (B) The rate of appearance of C is half the rate of disappearance of B (©) The rate of formation of D is half the rate of consumption of A (D) The rates of formation of C and D are equal Which of the following rate law has an overall order of 0.5 for reaction involving substances xy and 2? (A) Rate = k [C,] [C] (C)] (B) Rate = k [PIC IIE (© Rate = k (CP (EVIE? (D) Rate = k (CJC! / (CF For a reaction A + B— products, the rate of the reaction was doubled when the concentration of A was doubled, the rate was again doubled when the cone. of A & B were doubled the order of the reaction with respect to A & B are:~ Wh (2,0 O10 (D) 0,1 Ifthe rate of the reaction is equal to the rate constant, the order of the reaction is:= (yo 1 2 (D)3 If the first order reaction involves gaseous reactants and gaseous products the units of its rate are ~ (A) atm, (B) atm - see. (©) atm ~ see! (D) atm? sec10. ML. R 14 15. Following mechanisim has been proposed for a reaction: 2A +B» D+E Mechanisen| A+B C+D (low) A+ CE (last) ‘The rate law expression for the reaction is — (Ayr = k{AP [B]— (B) r= K{A] [B] (© r= KAP (D) r= K{A]IC] If concentration of reactants is inereased by 'x’ then the k becomes — k k ww we w * (Ok+x wk ‘The rate constant of n® order reaction has units. (A) litre’ mol" see (B) mol titre! ® see" (©) mol litre see! (D) None AA reaction is found to have the rate constant x sec by what factor the rate is inereased if initial ‘conc, of A is tripled aya 9 (Ox (D) Remains same ‘The rate constant ofa zero order reaction is 0.2 mol dns". Ifthe concentration of the reactant after 30 minutes is 0.05 mol dm?, Then its inital concentration would be = (A) 0.15 mol dm (B) 1.05 mol dx? (©) 0.25 mol dmv (D) 4.00 mol dn’ ‘Consider the reaction A —> B, graph between halflife (t,.) and inital concentration (a) of the reactant is sal Hence graph between {AT and time will be a] @ 441 = | maa / 7 Which graph represents zero order reaction [A(g) -> B(g)] as) C C (ay 13 Be «" (D) 1b i16. W. 19, 20. a. 2. 2. m4. 28, 26. K for a zero order reaction is 2 * 10 moll sec". If the concentration of the reactant after 25 sec is 0.5 M, then concentration after 50 sec. must have been. (4) 05M (B) 025M (©) 0.125 M (D) 0.0 M The rate constant of a first order reaction is 4 10° see“, At a reactant concentration of 0.02 M, the rate of reaction would be ~ (A) 8 © 10° M see" (B) 4 = 10" M soe (©) 2 10" M see (D) 4 x 10" M sec" Ina first order reaction the concentration of the reactant is decreased from 1.0 M to 0.25 M in 20 min. ‘The rate constant of the reaction would be ~ (A) 10 mie (B) 6931 mix (C) 0.6931 n (D) 0.06931. mi A first order reaction has a half life period of 69.3 sec. At 0.10 mol lit" reactant concentration rate will be — (A) 104M sec! (B) 10M see! (©) 10 M see (D) 6.93 * 10'Msee What fraction ofa reactant left showing frst order reaction after 40 minute if, is 20 minute a 4 (8) 12 (ous (D) 46 Which of the following curves represents a I" order reaction gt - (A) le -9) NN @) © to] (D) 1&3 both res —S After how many seconds will the cone, of the reaetant in af rate constant is 1.155 = 10° see! = (A) 600 (B) 100 (©) 60 () 10 Correct statement about first order reaction is:~ st order reaction be halved, ifthe (A) tortion = si Bho e p (©) Unit of k is mole Tit"! see (D) ty * k= const. at const. temp. For a given reaction of first order it takes 20 minute for the concentration to drop from 1 M. {o 046 M. The time required forthe eoneentration to drop from 0.6 M to 0.36 M willbe (A) More than 20 min (B) Less than 20 min (C) Equal to 20 min (D) Infinity “The accompanying figure depicts the change in concentration of species X and Y forthe reaction X-—> ¥ as a function of time the point of intersection of the two curves repercsents. At, 5 B) ty ay Oy xa (D) Data insufficient to predict ime ‘A reaction is of first order, Ater 100 minutes 75 g ofthe reactant A are decomposed when 100g are taken inal, calculate the time required when 150g ofthe reactant Aare decomposed, the inital weight taken is 200g (A) 100 minutes (B) 200 minutes (C) 150 minutes: (D) 175 minutesoe enn 2. 28, Azo isopropane decomposes according to the equation : (CH) ,CHN-NCH(CH)(2) + Ns@)'CH, (e) It is found to be a first order reaction. If initial pressure is P, and pressure of the mixture at time t is (P,) then rate constant K would be = 2303, Fe MORSE PRR, 2.303 k= 7 epg Consider the reaction : A—> BHC Initial concentration of A is 1 M. 20 minutes time is required for completion of 80 % reaction, a8] IgG, MAJ, then half ie (,.)is (Use :1n5 = 1.6) (A) 55.44 min, (B) 50 min (C) 8.66 min (D) None of these 13, 17. 21 25. ‘Ans. (B) 2. Ans. (D) 3. Ans. (C) 4. Ans. (BY Ans. (C) 6. Ans. (C) 7. Ans. (A) 8. Ans. (C) Ans.(B) 10. Ans. (D) 11. Ans. (C) 12. Ans. (A) ‘Ans. (A) 14. Ans. (C) 15. Ans. (D) 16. Ans. (D) Ans. (A) 18. Ans. (D) 19. Ans. (B) 20. Ans (A) Ans. (D) 22. Ans(A) 23. Ans (D) 24, Ans. (C) Ans. (A) 26. Ans. (A) 27. Ans. (A) 28. Ans. (C)