Chapter 1 Introduction To Organic Chemistry: Organic Chemisty / Rizalyn B. Cudera - Compiler
Chapter 1 Introduction To Organic Chemistry: Organic Chemisty / Rizalyn B. Cudera - Compiler
CUDERA - COMPILER
Overview
Most of the foodstuffs that we consume every day such as sugar, fats,
starch, vinegar, etc are basically organic compounds. Even though the organic
compounds have been known to man since prehistoric times, their study
practically began from the eighteenth century! The term “organic compound”
was coined by Berzelius in 1807.
Organic Chemistry has enormous economic significance as outlined by
Lopez et al. (2011) “its topics are interwoven into physical, life, and applied
science courses. Thus a poor foundation can have long-term detrimental
effects on future STEM performance, and potentially pose a barrier to the
formation of strong STEM workforce” (p.133). As a subject, Organic Chemistry
can cause confusion and difficulty for novice learners.
Objective
Pre discussion
Have you wondered why organic chemistry is part of your curriculum? Do
you have any feelings of fears that the course is a bit difficult. Johnstone (2010)
listed organic chemistry as one of nine areas of chemistry that were
established as difficult forty years earlier in 1971. Much literature over the
years (Childs & Sheehan, 2009; Johnstone, 2006) has consistently identified
organic as an area of difficulty. Almost all of the main topics in introductory
organic chemistry have been identified as difficult by learners in previous
research; just some of these are listed here:
ORGANIC CHEMISTY / RIZALYN B. CUDERA - COMPILER
What to expect?
At the end of the lesson, the students will be able to:
1. Differentiate Inorganic and organic compounds.
2. Cite the history and development of Organic Chemistry.
3. Understand the properties of organic compounds
Lesson Outline
1985 In the intergalactic space there are stars which are in the
last phase of their development and which produce a lot of
elemental carbon by eruptions. Harold Kroto and his
collaborators Richard Smalley and Robert Curl have
investigated in detail the nature of such intergalactic
carbon. The result of their research has been the
discovery of a new allotropic modification of carbon in
which atoms form structures resembling a ball. By
measuring the relative molecular masses of such
ball-molecules and simulating the interstellar conditions in
the laboratory, Kroto, Smalley and Curl have found that
these molecules mostly consist of 60 carbon atom clusters
distributed as pentagonal and hexagonal structures.
There are 12 pentagons surrounded by hexagons. Since
the proposed structure resembles some works of art,
especially the architecture constructed by the architect
Richard Buckminster Fuller, this C 60 molecule has
been named fullerene . In subsequent research a series
of similar ball-like structures was discovered, some of
which contain tubular structures of carbon atoms. These
ORGANIC CHEMISTY / RIZALYN B. CUDERA - COMPILER
Each carbon atom can form four bonds, either to other carbon atoms, or to
different atoms (such as H, O, N, S, P, etc.)
ORGANIC CHEMISTY / RIZALYN B. CUDERA - COMPILER
Carbon atoms form four bonds to other things, but sometimes those
bonds are multiple bonds (double or triple bonds):
Isomers
Isomers are compounds with the same molecular formulae but different
structural formulae (or arrangement of atoms). They have the same number
of each type of atom but may have different physical and chemical properties.
ORGANIC CHEMISTY / RIZALYN B. CUDERA - COMPILER
Summary
There is distinct difference between the inorganic and organic chemistry,
the former deals with compounds without carbon and the latter studies
compounds with carbon. Organic compound was introduced more than 200
years that further leads to its development such as the discovery of more
organic compounds. Organic compounds have their unique properties which is
associated with the characteristics of carbon. Carbon is capable of forming
covalent bonds with other substances creating a single, double or triple bonds.
Isomerism also exists in organic compounds. Undeniably, organic compounds
are greatly important which is associated with its vast application.
Assessment
1. Identify the organic and inorganic molecules. Encircle the organic
molecules and put a box to the chemical formula of inorganic molecules.
2. What element serves as the foundation for the organic compounds? Why?
3. Answer the question below. Expound your answer
ORGANIC CHEMISTY / RIZALYN B. CUDERA - COMPILER
4. Can you figure out living in this world without carbon compounds? Justify
your answer.
Enrichment
1. Carbon exists in several allotrope, in which one or more forms of an
element that exist in the same physical state. The difference is in the way that
atoms are arranged or held together and each allotrope may have different
physical or chemical properties to another allotrope. Read the figure below
showing the different characteristics of the carbon allotrope. Make a Hugot
line of the four allotropes of carbon based on given descriptions in the table.
Allotropes of Carbon
Allotrope Type of Bonding/ Physical Explanation of each Uses of the
particulars of structure Properties physical property allotrope
Diamond Giant covalent bonding 1. Hard 1. Due to strong Drill bits: the
where each carbon 2. Doesn’t conduct covalent bonds hardest natural
makes 4 bonds in a electricity 2. No delocalized substance that
tetrahedral 3. High melting electrons or exists
arrangement and boiling points charged particles
3. Strong covalent
bonds needs lots of
energy to breaks
Graphite Giant covalent bonding 1. Soft and 1. Layers are free to 1. Lubricating
but each carbon only slippery move over each
makes 3 bonds, 2. Conducts other
creating sheets and electricity/heat 2. Delocalised
carbon atoms are 3. High melting electron is able to
arranged in hexagons point carry charge
3. Strong covalent
bonds need lots of
energy to breaks
Graphene As graphite, but only 1 1. Light 1. Only 1 layer 1 and 2: used in
atom thick, so it is a 2D 2. Strong 2. Strong covalent composite
compound 3. Conducts bonds materials, e.g.
electricity 3. Delocalised tennis rackets
4. Transparent eletron can carry 5. Used in
charge electronics
4. Made of a 2D
sheet of atoms
Fullerenes Molecules of carbon 1. Large surface 1. Carbon atoms are 1. Catalyst can be
shaped like tubes or area joined together but attached
spheres. Carbon atoms 2. Nanotubes: spaced out 2. a. Tennis racket
are arranged in a) High tensile 2. a. Strong covalent frames
hexagons, pentagons strength and not bonds b. used in
or heptagons much weight b. Only 3 bonds on electronics
Nanotubes: ratio b) Conduct each carbon so a 3. Can be used as
between length and electricity delocalized electron cages to deliver
diameter is very high can carry charge medicines to only
the target area
https://www.tes.com/teaching-resource/new-gcse-allotropes-of-carbon-differentiated-table-11949710
ORGANIC CHEMISTY / RIZALYN B. CUDERA - COMPILER
Pre discussion
What to expect?
At the end of the lesson, the students will be able to:
1. Discuss the classification of organic compounds.
2. Differentiate the structural formula in writing organic compounds.
3. Describe the various functional groups and classes of organic
compounds.
4. Compare and contrast the different groups and classes of organic
compounds.
Lesson Outline
ORGANIC CHEMISTY / RIZALYN B. CUDERA - COMPILER
Alicyclic Compounds
Their name is attributed to their resemblance to aliphatic compounds in
their properties. Three or more atoms of the element carbon are linked together
in a ring. The bonds between pairs of adjacent atoms are single bond or some
may be double or triple bonds. The examples of this category include
cyclopropane, cyclobutane, cyclopentane, cyclohexane, etc.
ORGANIC CHEMISTY / RIZALYN B. CUDERA - COMPILER
Aromatic Compounds
These are cyclic unsaturated compounds. They derive their name from
the Greek word Aroma which means “fragrant smell” since most of these
compounds bear a pleasant smell. These are further classified into two types:
Benzenoid Aromatic Compounds: They are characterized by the
presence of one or more fused or isolated benzene rings as well as
their derivatives in their structure. Depending upon the number of
benzene rings that are fused together in their structure, they can be
further classified as Monocyclic, Bicyclic, Tricyclic.
Non-Benzenoid aromatic Compounds: They are characterized by
the presence of a single benzene ring to which other groups are
attached.
Heterocyclic Compounds
When one or more heteroatoms such as oxygen, nitrogen, sulphur,
boron, silicon etc, are present in the ring such compounds are known as
heterocyclic compounds.
3. Line
Draw
ings -
in
ORGANIC CHEMISTY / RIZALYN B. CUDERA - COMPILER
Hydrocarbons
The first family listed in Figure 4 is the hydrocarbons. These include
alkanes, with the general molecular formula CnH2n+2 where n is an integer;
alkenes, represented by CnH2n; alkynes, represented by CnH2n−2; and
arenes.
alcohols, phenols (derivatives of benzene), and ethers, and those that contain
a carbonyl group (C=O), which include aldehydes, ketones, and carboxylic
acids.
Summary
Organic compounds are classified depending on their of carbon atoms
in their structure, namely: Acyclic or Open Chain compounds and Cyclic or
Closed Chain compounds. In drawing the organic structure, you can consider
ORGANIC CHEMISTY / RIZALYN B. CUDERA - COMPILER
Assessment
1. Can two substances have the same systematic name and be different
compounds? Justify your answer.
4. Draw an acceptable expanded structure and line drawing for the molecule
structural formula. Identify the functional groups present and give the
functions of these macromolecules.
Enrichment
1. Look for videos online that discuss the strategies on how to familiarize the
structures of the functional group. Post it in the group chat and let two of your
classmates comment on the video. Make a screenshot of the video and your
classmate’s comment. Insert the snapshot in the word document and write
your insights about techniques in familiarizing the functional groups.
Reference
Cudera, R.B., Razon, B.C., Millondaga, K.J.I. (2020). Cultural and ecological
significance of Odonata (Insecta) to the T'boli of Lake Sebu, Mindanao,
Philippines. Biodiversitas 21: 2536-2554.
Childs, P. E., & Sheehan, M. (2009). What's difficult about chemistry? An Irish
perspective. Chemistry Education Research and Practice, 10, 204-218.
Johnstone, A. H. (2010). You can't get there from here. Journal of Chemical
Education, 87(7), 22-29.
Rushton, G. T., Hardy, R. C., Gwaltney, K. P., & Lewis, S. E. (2008). Alternative
conceptions of Organic Chemistry topics among fourth year chemistry
students. Chemistry Education Research and Practice, 9, 122-130.
Vančik, H. (2014). Basic Organic Chemistry for the Life Sciences. Springer
International Publishing Switzerland