University of San Agustin

General Luna St., Iloilo City 5000, Philippines

www.usa.edu.ph
COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

Module 1
Review of General Chemistry

Virtual Consultation Time: ____________

Overview:
In this module, we will cover general chemistry principles in preparation for higher
chemistry throughout the duration of this course, CHEM7. The topics of this module
includes a recap of the basic chemistry from Senior High School, formation of
chemical bonds using lewis structures, solving stoichiometric problems using
dimensional analysis, and acids, bases, pH and pKa.

Topics to be covered:
1.1. Classification of Matter 1.4. Stoichiometry
1.2. Atoms 1.5. Acids, Bases & pH
1.3. Chemical Bonding

Learning Outcomes:
1. Draw the Lewis structure and the chemical bonds usually encountered with C, H,
O, N, S, P
2. Compute stoichiometric and concentration problems
3. Classify whether the compound is an acid, or a base
4. Compute the pH of a solution

Learning Plan:
1.1. Classification of Matter : asynchronous, forum discussion via Google classroom,
seatwork
1.2. Atoms: asynchronous, forum discussion via Google classroom, seatwork
1.3. Chemical Bonding: synchronous, Google Meet (20mins), seatwork and homework
1.4. Stoichiometry: synchronous, Google Meet (30mins), seatwork
1.5. Acids, Bases & pH: synchronous, Google Meet (30mins), seatwork

Recap of Chemistry, Classification of Matter, Atomic Structure and Valence

Electrons from SHS : Section 1.1 and 1.2

Chemistry is the study of matter and the changes it undergoes

1.1 Classification of Matter (refer to Chapter 2 of text book)

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 University of San Agustin
General Luna St., Iloilo City 5000, Philippines
www.usa.edu.ph
COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

Matter is divided in to 2 classes: Pure substances and Mixtures.

Figure 1. Classification of Matter2

Examples of Pure substances: Oxygen gas, Water, Diamond, Gold

Examples of Mixtures: orange juice concentrate, sand, five spice, oil with water,
seawater, macaroni salad

Exercise (1) Identify which of the example of pure substance is an

element/compound.

Element: oxygen gas, gold Compound: diamond, water

Compounds can be decomposed further by chemical means, while elements cannot

be decomposed by physical nor chemical means.1

Exercise (2) Identify which of the example of pure substance is

homogeneous/heterogeneous.

Homogeneous: orange juice concentrate, sand, five spice, seawater

Heterogeneous: oil & water, macaroni salad

Homogeneous mixture is a mixture where there is uniform composition and you

can’t tell apart one substance from the other. In heterogeneous mixture, the
components are distinguishable.1
Seatwork (1-1): refer to the textbook

CHEM 7 Module 1: Review of General Chemistry 2/17

 University of San Agustin
General Luna St., Iloilo City 5000, Philippines
www.usa.edu.ph
COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

Problems from Chapter 2: 2.10, (a) to (e)

1.2 Atoms (refer to Chapter 2 of text book)

What is matter made of? – Dalton’s Atomic Theory1
Postulates:
• All matter is composed of very tiny particles, which Dalton called atoms.
• All atoms of the same element have the same chemical properties. Atoms of
different elements have different chemical properties.
• Compounds are formed by the chemical combination of two or more of the
same or different kinds of atoms.
• Molecules are a tightly bound combination of two or more atoms that acts as
a single unit.

Law of Conservation of Mass: “Matter is neither created nor destroyed”

Explanation: If matter is made up of indestructible atoms, then any chemical
reaction just changes the attachments among atoms, but does not destroy the atoms
themselves.1

Figure 2. A carbon monoxide molecule reacts with a lead oxide molecule to give a carbon
dioxide molecule and a lead atom. All of the original atoms are still present at the end; they
have merely changed partners.1

The total mass after this chemical change is the same as the mass that existed before
the reaction took place.
Carbon monoxide + Lead oxide → Carbon dioxide + Lead
(mass = 28) (mass = 223) → (mass = 44) (mass = 207)
Total mass = 251 → Total mass = 251

What are atoms made of? Protons, Electrons and Neutrons 1

Proton – positively charged; found in a nucleus.

Electron – negatively charged; found in the space surrounding a nucleus
Neutron – neutral or zero charge; found in the nucleus

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 University of San Agustin
General Luna St., Iloilo City 5000, Philippines
www.usa.edu.ph
COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

Figure 3. Anatomy of an Atom. (A), A “cloud” of rapidly moving, negatively charged

electrons occupies virtually all the atomic volume and surrounds the tiny, central nucleus.
(B), The nucleus contains virtually all the mass of the atom and consists of positively
charged and uncharged particles.3

Figure 4. Depicting atoms.3

Note. p+ for protons, e- for electrons and n0 for neutrons.

The element’s atomic number is equal to the number of protons and electrons. Since
majority of the atom’s weight comes from the nucleus, the mass number will reflect
that of the sum of the subatomic particles found in the nucleus, protons and neutrons.

CHEM 7 Module 1: Review of General Chemistry 4/17

 University of San Agustin
General Luna St., Iloilo City 5000, Philippines
www.usa.edu.ph
COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

Elements in the periodic table are arranged in groups because they share the same
properties. The group number of the elements also corresponds to the number of
valence electrons. The electrons are arranged in different energy levels (shells) to
avoid losing energy continuously and eventually collapse.

Valence electrons - are electrons found in the outermost shell or energy level and
are the ones usually participating in chemical bonding (bonding electrons). Not all
valence electrons participate in a chemical bond (nonbonding electrons). The
valence electrons can be represented as dots (Lewis dot structures).

Figure 5. Lewis Dot Structures of elements in the same group.1 Group 1 elements have a 1
valence electron, therefore, 1 dot. Group 2 elements have 2 electrons in their valence shell,
and so the lewis dot structure of group 2 elements can represented with two dots, and so on.

Seatwork (1-2): refer to the textbook

Problems from Chapter 2: 2.24, (a) and (b); 2.26 (a) to (c); 2.54 (a) to (e)

1.3 Chemical Bonding (refer to Chapter 3 of text book)

When the valence electrons from two or more elements come together by lowering
their total energy, they form a chemical bond.3

Two major types of chemical bonds: ionic and covalent

Ionic - a chemical bond usually formed between a metal and nonmetal; resulting from
the attraction between positive and negative ions due to the differences of the
electronegativities of a metal and nonmetal.1 Electronegativity is a measure of an
atom’s attraction for the electrons it shares in a chemical bond with another atom.3

CHEM 7 Module 1: Review of General Chemistry 5/17

 University of San Agustin
General Luna St., Iloilo City 5000, Philippines
www.usa.edu.ph
COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

A B

Figure 7. (A) General properties of elements in the periodic table.1 (B) Formation of ionic
bonds. 2

Covalent - formed when electron pairs are shared between two atoms whose
difference in electronegativity is less than 1.9; usually formed between two
nonmetals. 1

Figure 8. Single covalent bond between 2 Hydrogen atoms. 1

There are two types of covalent bond: polar and nonpolar.

Table 1 shows the classification of the major types of chemical bonds.1

In polar covalent bond, the difference of electronegativities is large enough to polarize

the bond creating a dipole moment. Thus, there is unequal sharing of electrons, but
because the difference of electronegativities in nonpolar covalent is not large enough
to create a dipole moment, there is equal sharing of electrons between the two atoms.

CHEM 7 Module 1: Review of General Chemistry 6/17

 University of San Agustin
General Luna St., Iloilo City 5000, Philippines
www.usa.edu.ph
COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

Exercise (3), Classify the following bonds whether they are polar covalent, nonpolar
covalent, or ionic using the difference in their electronegativity.
(a) O―H (b) N―H (c) Na―F (d) C―Mg (e) C―S

Homework (submit in a short size / letter size document on our google classroom):
(1) Using the octet rule, why do group 1 elements lose 1 electron? Group 2
elements lose 2 electrons? Group 5 elements gain 3 electrons? Groups 6
electrons gain 2 electrons? Group 7 electrons gain 1 electrons? Group 8 /
Noble gases do not gain nor lose electrons?

(2) What element follows the duet rule?

(3) Which elements are strict followers of octet rule?

(4) Which elements possess an expanded octet in covalent compounds?

Drawing Lewis Structures of Covalent compounds 1

1. Determine the number of valence electrons in the molecule.
2. For a cation, subtract one electron for each positive charge on it. For an anion, add
one electron for each negative charge on it.
3. Determine the connectivity of atoms.
4. Connect the atoms by single bonds.
5. Show bonding electrons as a single line; show nonbonding electrons as a pair of
Lewis dots.
6. In a single bond, atoms share one pair of electrons; in a double bond, they share
two pairs, and in a triple bond they share three pairs.

CHEM 7 Module 1: Review of General Chemistry 7/17

 University of San Agustin
General Luna St., Iloilo City 5000, Philippines
www.usa.edu.ph
COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

Figure 9. Lewis structures of several small molecules1

Watch these 2 supplemental videos made by Ketzbook via Youtube:

https://youtu.be/cIuXl7o6mAw
https://youtu.be/qwqXAlvNxsU

Seatwork (1-3): refer to the textbook

Problems from Chapter 3: 3.34, (a) and (c); 3.35 (a) and (c); 3.59 (a) (c) (e) and (f)

1.4 Stoichiometry (refer to Chapter 4 of text book)

A chemical reaction is brought about by a chemical change in the environment. A

chemical equation is an expression showing which reactants are converted to which
products. A balanced chemical equation shows how many moles of each starting
material are converted to how many moles of each product according to the law of
conservation of mass.1 Substances found on the tail of the arrow are the reactants
while substances on the arrow head are the products of the chemical equation.

CHEM 7 Module 1: Review of General Chemistry 8/17

 University of San Agustin
General Luna St., Iloilo City 5000, Philippines
www.usa.edu.ph
COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

How do you balance chemical equations?

Example: combustion of propane1

1. Begin with atoms that appear only in one compound on the left and one on the
right; in this case, begin with carbon (C) which occurs in C 3H8 and CO2.

2. Now balance hydrogen atoms, which occur in C3H8 and H2O:

3. If an atom occurs as a free element, as for example O 2, balance it last:

Watch this supplemental video made by Khan Academy:

https://youtu.be/RnGu3xO2h74

Seatwork (1-4): refer to the textbook

Problems from Chapter 4: 4.17 and 4.18 (c) to (e)

Why do we need to balance a chemical equation?

Balancing a chemical equation accurately is necessary to be able to compute the mass
relationships such as the amount of reactant consumed and product yield in a given
chemical reaction.

How do we compute these mass relationships?

Stoichiometry is the study of mass relationships in a given chemical reaction. 1 A mole
is the SI unit for the amount of substance and is used in stoichiometric calculations
with the aid of stoichiometry ratio or molar ratio.

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 University of San Agustin
General Luna St., Iloilo City 5000, Philippines
www.usa.edu.ph
COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

Figure 10. Concept map in stoichiometric calculations.1 A is the given substance while B is
the amount of substance desired in the problem. Substance A and B can be any of the
substance in the chemical equation regardless if it is found on the reactant or product side.

How do we convert grams to moles? Using the molar mass / formula mass (may also
be referred to as molecular weight / formula weight) The molar mass is the sum of all
the atomic masses/weights in a given compound.

Example:
In water H2O , there are 2 Hydrogens and 1 Oxygen. (atomic weights: H=1 and O=16)
Molecular/formula weight of water is = (2 x 1 = 2) for Hydrogen + (1 x 16 = 16) for
Oxygen = 18. The molar mass of water is 18g per mole. It means that the weight of
one mole of water is 18g.
So how many moles of water are there in 36g?

1.00 mol H2 O
36.0 g H2O x = 2.00 mol H2O
18.0 g H2O

Watch this supplemental video made by Ketzbook: https://youtu.be/b2raanVWU6c

Seatwork (1-5): refer to the textbook

Problems from Chapter 4: 4.45 (c) and (d) and 4.46 (c) to (e)

Using stoichiometry in chemical equations, refer to Figure 10. Dimensional analysis

is an effective way in computing stoichiometry accurately. MASS → MASS
1. Step 1: Balance the equation
2. Step 2: In order to convert grams to moles, molar mass will be used.
3. Step 3: To convert moles A to moles B, the stoichiometric ratio or molar ratio will
be used. This is the conversion factor.
4. Step 4: Moles B will produced. This needs to be converted to grams if the desired
unit of amount of substance is in grams.

CHEM 7 Module 1: Review of General Chemistry 10/17

 University of San Agustin
General Luna St., Iloilo City 5000, Philippines
www.usa.edu.ph
COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

Exercise: How many grams of nitrogen, N2, are required to produce 7.50 g of
ammonia, NH3? N2 + H2 → NH3

Step 1: N2 + 3H2 → 2NH3

Step 2: How many moles are there in 7.50 grams of NH 3. The given is 7.50 grams of
ammonia and there 17.0g in 1 mole of NH3.
1 mol NH3
7.50 g NH3 x = mol NH3
17.0 g NH3
Step 3: How many moles NH3 was produced? There 2 moles of NH3 produced in 1
mole of N2

1 mol NH3 x 1 mol N2

7.50 g NH3 x = mol N2
17.0 g NH3 2 mol NH3
In converting using dimensional analysis, desired unit of the conversion factor should
always be in the numerator while the given unit should be at the denominator to
cancel the given unit of the preceding factor.

Step 4: How many grams of N2 was consumed?

1 mol NH3 1 mol N2 28.0 g N2

7.50 g NH3 x x x = 6.18 g N2
17.0 g NH3 2 mol NH3 1 mol N2

Watch these supplemental videos made by Ketzbook:

https://youtu.be/BZuS3Agn4pI
https://youtu.be/-1xfnq8yGk8

Using stoichiometric calculations in solutions similar to computing mass

relationships. The difference of the two is that concentration units are the given and
desired units this time instead of mass. Mass and concentration units maybe used
simultaneously in any stoichiometric problem.

Concentration units: refer to Chapter 6 of text book

Percent composition1
1. Weight of solute per volume of solution (w/v)
Example: 10g of table sugar dissolved in enough water to make 100mL of solution
has a concentration of 10% w/v.

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General Luna St., Iloilo City 5000, Philippines
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COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

weight of solute
volume of solution

10g table sugar

x 100 = 10% (w/v)
100mL solution
2. Weight of solute per weight of solution (w/w)
Essentially the same as w/v except that the weight of the solution is used instead
of its volume.

3. Volume of solute per volume of solution (v/v)

Example: 40mL of ethanol dissolved in enough water to make in 100mL of

solution is 40% v/v.
volume of solute
volume of solution

40mL ethanol
x 100 = 40% (v/v)
100mL solution

Molarity 1
Molarity (M) = moles of solute (n)
liter of solution (L)

Exercise: Describe how to prepare 2.0 L of 0.15 M NaOH

1. First find the number of moles of NaOH required: 0.15 M is 0.15 mol/L
0.15 mol NaOH x 2.0 L = 0.30 mol NaOH
1L
2. Next convert 0.30 mol NaOH to g NaOH:
0.30 mol NaOH x 40.0 g NaOH = 12.0 g NaOH
1 mol NaOH
3. To prepare this solution, dissolve 12.0 g NaOH in enough water of make 2.0 L of
solution.

Watch this supplemental video by Ketzbook: https://youtu.be/KLjWa9cE2uk

Dilution problem of solutions

If we dilute a solution, the number of moles of solute remains the same after dilution.
This relation results in the following relationship.

M1V1 = M2V2

CHEM 7 Module 1: Review of General Chemistry 12/17

 University of San Agustin
General Luna St., Iloilo City 5000, Philippines
www.usa.edu.ph
COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

Exercise: How would you prepare 200. mL of 3.5 M aqueous solution of acetic acid if
you have a stock solution of 6.0 M acetic acid.

1. Substitute the values to the formula:

(6.0M) (x) = (3.5 M) (200 mL)

The initial concentration is 6.0 M from the stock solution. The final concentration of
the diluted solution is 3.5 M with a volume of 200 mL. How much of 6.0 M is needed
to make 3.5 M with a volume of 200 mL?

(3.5 M)(200mL)
x= =120 mL
(6.0M)

2. To prepare the desired solution, place 120. mL of 6.0 M acetic in a 200. mL

volumetric flask and fill to the mark.

Applying concentration units and stoichiometry in chemical equations:

CONCENTRATION → MASS

Exercise: given the balanced equation, how much calcium hydroxide in g is needed to
neutralize 100. mL of 0.125M of acetic acid?

? 0.125 M, 100. mL
Ca(OH)2 + 2CH3COOH → Ca(CH3COO)2 + 2H2O
Calcium Acetic acid Sodium Water
hydroxide acetate

mol CH3 COOH 1L 1 mol Ca(OH)2 74.0927g Ca(OH)2

0.125 x x 100. mL CH3 COOHx x
L CH3 COOH 1000 mL 2 mol CH3COOH 1 mol Ca(OH)2

= 0.463g Ca(OH)2
0.463g of Ca(OH)2 is needed to neutralize 100. mL of 0.125 M acetic acid,

Watch this supplemental video made by Khan Academy:

https://youtu.be/EKZSwjVR594

Seatwork (1-6): refer to the textbook

Problems from Chapter 4 and 6: 4.55 (a) and (c), 4.61, 6.34 (a), 6.35 (a), 6.36 (a),
6.38, 6.40 (a) and 6.49

CHEM 7 Module 1: Review of General Chemistry 13/17

 University of San Agustin
General Luna St., Iloilo City 5000, Philippines
www.usa.edu.ph
COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

1.5 Acids, Bases & pH (refer to Chapter 8 of text book)

Arrhenius definition 1:
Acids- substances that when dissolved with water releases H+ ions in the form
of H3O+ ions

Bases – substances that when dissolved with water releases OH- ions

Limitations: This definition is only limited to water as a solvent and the production
of H3O+ and OH- ions

Brønsted-Lowry definition 2:
Acids - proton donors in a chemical reaction; can be positively charged, neutral,
or negatively charged; examples of each type are H3O+, H2CO3, and H2PO4-

Ex. Carbonic acid can give up

one proton to become
bicarbonate ion, and then the
second proton to become
carbonate ion. Carbonic acid is
a Brønsted-Lowry acid.

Bases – proton acceptors

Ex. H2O acts as a Brønsted-
Lowry base and HCl as a
Brønsted-Lowry acid

Limitations: This definition is only limited to inorganic reactions

Lewis definition 3:
Acids – electron pair acceptors
Bases – electron pair donors

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General Luna St., Iloilo City 5000, Philippines
www.usa.edu.ph
COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

The single product of a lewis

acid and lewis base is called
an adduct.

The Lewis definition is accepted for all acids and bases.

Amphiprotic substance – substances that can both donate and accept protons
Amphoteric substance – substances that can act both an acid and a base

Amphoteric

Amphiprotic

Figure 11. Concept diagram of Amphoteric and Amphiprotic

“Not all amphoteric are amphiprotic but all amphiprotic are amphoteric”

Because the concentrations of H+ and OH- ions in aqueous solutions are frequently
very small numbers and therefore inconvenient to work with, Soren Sorensen † in
1909 proposed a more practical measure called pH. The pH of a solution is defined as
the negative logarithm of the hydrogen ion concentration (in mol/L):

Figure 12. Formula and

guide for computing and
using pH to determine
acidity 3

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General Luna St., Iloilo City 5000, Philippines
www.usa.edu.ph
COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

Exercise:
Determine the pH and pOH of the following acids given their molar concentrations:
(a) 1.0 x 10-3 M HCl = -log (1.0 x 10-3) = 3.0
(b) 1.0 x 10-7 M HNO3 = -log (1.0 x 10-7) = 7.0
(c) 2.0 x 10-5 M NH4+ = -log (2.0 x 10-5) = 4.7

Conjugate pairs
A conjugate acid–base pair is a pair of molecules or ions that are related to one
another by the gain or loss of a proton.1

Figure 13. Concept of conjugate acid-base pairing

The conjugate base of an acid is the form of the acid where it lost one proton while
the conjugate acid of a base is the form of the base where it gained one proton, as
seen in figure 13. This relationship maybe used to determine the direction of the
acid-base equilibrium.

Strength of an Acid
The strength of an acid is characterized by how easily the acid releases its proton
(H+). The easier for the acid to donate its proton, the stronger the acid. The more
difficult for the acid to donate its protons, the weaker the acid. Since weak acids, do
not completely dissociate in water, this consequently creates an equilibrium constant
for the reaction, called the acid-dissociation constant or Ka. Strong acids completely
dissociates or ionizes in water and therefore will have a Ka that is too large to account
(>1). Ka’s also have a negative logarithm, expressed as pKa.

Table 2 shows the table of acids with their Ka and pKa.1

The stronger the

acid, the larger
the Ka, the
smaller the pKa

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 University of San Agustin
General Luna St., Iloilo City 5000, Philippines
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COLLEGE OF LIBERAL ARTS, SCIENCES, AND EDUCATION
DEPARTMENT OF CHEMISTRY AND PHYSICS

Seatwork (1-7): refer to the textbook

Problems from Chapter 8: 8.13 (a) (d) and (f), 8.14 (a) and (b), 8.17 (a) and (c), 8.20
(a) and (c), 8.22 (a) and (c),8.28 (a) and (d), and 8.37 (a) and (d)

Assessment Tasks:
1. Seatworks (1―1) to (1―7): Submit via Google Classroom under Assignment
dropbox labelled “Module 1 Seatwork (1―#)” with your LAST NAME as
filename.
2. Homework from 1.3 Chemical Bonding of this module: Submit via Google
Classroom under Assignment dropbox labelled “Module 1 Homework” with
your LAST NAME as filename.

References
1 Bettelheim, et. al. (2013). Introduction to General, Organic, and
Biochemistry, 10th edition. Brooks/Cole, Cengage Learning

2 Stoker, H. S. (2010). General, Organic, and Biochemistry, 5th edition.

Brooks/Cole, Cengage Learning

3 Silberberg, M. (2009). Chemistry: The Molecular Nature of Matter and

Change, 5th edition. McGraw-Hill Higher Education

4 Ketzbook. (2016). Retrieved from (YouTube):

https://www.youtube.com/channel/UCrA_TfLEOQnNtWwP3tbHcNw

5 Khan Academy. (2009). Retrieved from (YouTube):

https://www.youtube.com/user/khanacademy

Survey Form
Download the Survey Form template from our class at Google Classroom. Use the
template to evaluate this module’s session. Save the document as .doc file with a
filename Yourclasssection_Chem7 evaluation (ex. BSN1-A_Chem1 evaluation) and
submit at the google classroom assignment drop box labelled Module No. ## survey
form.

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