Section A

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• Write the answer of the following questions. [Each carries 4 Marks] [120]
1. For the reaction :
C3H8(g) + 5O2(g) ® 3CO2(g) + 4H2O(l) DH – DU = ..........
(A) RT (B) –3RT (C) 3RT (D) –RT
2. If K < 1, DG° = ..........
(A) +ve (B) –ve (C) Zero (D) 1
3. Hess’s law of integrate enthalpy is related to ...........

YA
(A) change in enthalpy of reaction. (B) rate of reaction.
(C) equilibriums constant. (D) effect of pressure an the volume of gas.
4. NH3 + 3Cl2 ƒ NCl3 + 3HCl ; –DH1

LA
N2 + 3H2 ƒ 2NH3 ; –DH2
H2 + Cl2 ƒ 2HCl ; DH3
Calculate the enthalpy of formation of NCl3

(A) DH f = –DH1 +
DH 2 3
2
– DH 3
2
YA (B) DH f = DH1 +
DH 2 3
2
– DH 3
2
– DH 2 3
ID
(C) DH f = – DH1 + – DH 3 (D) none of above
2 2
5. Given that bond energies of H – H and Cl –Cl are 430 kJ/mol–1 and 240 kJ/mol–1 respectively and DHf
TV

for HCl is –90 kJ/mol–1, bond enthalpy of HCl is

(A) 380 kJ/mol (B) 425 kJ/mol (C) 245 kJ/mol (D) 290 kJ/mol
6. Which of the following are not state functions ?
YO

(i) q + w (ii) q
(iii) w (iv) H – TS
(A) (i) and (iv) (B) (ii), (iii) and (iv) (C) (i), (ii) and (iii) (D) (ii) and (iii)
J
AN

7. For the gas phase reaction,

PCl5(g) ƒ PCl3(g) + Cl2(g)
Which of the following conditions are correct ?
(A) DH = 0 and DS < 0 (B) DH > 0 and DS > 0 (C) DH < 0 and DS < 0 (D) DH > 0 and DS < 0
GY

8. Bond dissociation enthalpy of H2, Cl2 and HCl are 434, 242 and 431 kJ mol–1 respectively. Enthalpy
of formation of HCl is
(A) 93 kJ mol–1 (B) –245 kJ mol–1 (C) –93 kJ mol–1 (D) 245 kJ mol–1
9. The values of DH and DS for the reaction, C(graphite) + CO2(g) ¾® 2CO(g) are 170 kJ and 170 JK–1,
respectively. This reaction will be spontaneous at
(A) 910 K (B) 1110 K (C) 510 K (D) 710 K
1
10. Standard entropies of X2, Y2 and XY3 are 60, 40 and 50 JK–1mol–1 respectively. For the reaction
2
3
X2 + Y ƒ XY3 , DH = –30 kJ
2 2
to be at equilibrium, the temperature should be :
(A) 750 K (B) 1000 K (C) 1250 K (D) 500 K
11. For vaporization of water at 1 atmospheric pressure, the values of DH and DS are 40.63 kJ/mol–1 and 108.8
JK–1/mol–1, respectively. The temperature when Gibbs energy change (DG) for this transformation will be
zero, is :
 For vaporization of water at 1 atmospheric pressure, the values of DH and DS are 40.63 kJ/mol–1 and 108.8
JK–1/mol–1, respectively. The temperature when Gibbs energy change (DG) for this transformation will be
zero, is :
(A) 293.4 K (B) 273.4 K (C) 393.4 K (D) 373.4 K
12. The following two reactions are known :
Fe2O3(s) + 3CO(g) ¾® 2Fe(s) + 3CO2(g); DH = –26.8 kJ
FeO(s) + CO(g) ¾® Fe(s) + CO2(g) ; DH = –16.5 kJ
The value DH for the following reaction
Fe2O3(s) + CO(g) ¾® 2FeO(s) + CO2(g) is
(A) + 6.2 kJ (B) + 10.3 kJ (C) – 43.3 kJ (D) – 10.3 kJ
13. If the enthalpy change for the transition of liquid water to steam is 30 kJ/mol–1 at 27°C, the entropy
change for the process would be :
(A) 10 J mol–1 K–1 (B) 1.0 J mol–1 K–1 (C) 0.1 J mol–1 K–1 (D) 100 J mol–1 K–1
14. For complete combustion of ethanol, C2H5OH(l) + 3O2(g) ® 2CO2(g) + 3H2O(l), the amount of heat

YA
produced as measured in bomb calorimeter is 1364.47 kJ mol–1 at 25ºC. Assuming ideality the
Enthalpy of combustion, DcH, for the reaction will be : (R = 8.314 kJ mol–1)

LA
(A) –1460.50 kJ mol–1 (B) –1350.50 kJ mol–1 (C) –1366.95 kJ mol–1 (D) –1361.95 kJ mol–1
15. The following reaction is performed at 298 K.
2NO(g) + O 2(g) ƒ 2NO 2(g)
YA
The standard free energy of formation of NO(g) is 86.6 kJ / mol at 298 K. What is the standard free
energy of formation of NO2(g) at 298 K ? (Kp = 1.6 ´ 1012)
ID
(A) R (298) ln (1.6 ´ 1012) – 86600 (B) 86600 + R (298) ln (1.6 ´ 1012)
ln (1.6 ´ 1012 )
(C) 86600 – (D) 0.5 [2 ´ 86600 – R (298) ln (1.6 ´ 1012)]
R (298)
TV

16. The standard Gibbs energy change at 300 K for the reaction 2A ƒ B + C is 2494.2 J. At a given time,
1 1
the composition of the reaction mixture is [A] = , [B] = 2 and [C] = . The reaction proceeds in
2 2
YO

the : [R = 8.314 J/K/mol, e = 2.718]

(A) forward direction because Q > Kc (B) reverse direction because Q > Kc
(C) forward direction because Q < Kc (D) reverse direction because Q < Kc
J

17. Which of the following statements is correct for a reversible process in a state of equilibrium ?
AN

(A) DG = –2.30 RT log K (B) DG = 2.30 RT log K

(C) DG° = –2.30 RT log K (D) DG° = 2.30 RT log K
GY

18. Which of the following species contains equal number of s and p bonds ?
(A) HCO3– (B) XeO4 (C) (CN)2 (D) CH2(CN)2

19. The heat of combustion of carbon to CO2 is –393.5 kJ/mol. The heat released upon formation of 35.2
g of CO2 from carbon and oxygen gas is :
(A) –630 kJ (B) –3.15 kJ (C) –315 kJ (D) +315 kJ
20. The correct thermodynamic conditions for the spontaneous reaction at all temperatures is :
(A) DH > O and DS < O (B) DH < O and DS > O
(C) DH < O and DS < O (D) DH < O and DS = O
21. For a sample of perfect gas when its pressure is changed isothermally from Pi to Pf the entropy change
is given by
æ Pf ö æP ö æ Pf ö æP ö
(A) DS = nRT ln ç ÷ (B) DS = RT ln ç i ÷ (C) DS = nR ln ç ÷ (D) DS = nR ln ç i ÷
è Pi ø è Pf ø è Pi ø è Pf ø
22. If the Eocell for a given reaction has a negative value, which of the following gives the correct
relationships for the values of DGo and Keq ?
(A) DGo < 0, Keq > 1 (B) DGo < 0, Keq < 1 (C) DGo > 0, Keq < 1 (D) DGo > 0, Keq > 1
 If the Eocell for a given reaction has a negative value, which of the following gives the correct
relationships for the values of DGo and Keq ?
(A) DGo < 0, Keq > 1 (B) DGo < 0, Keq < 1 (C) DGo > 0, Keq < 1 (D) DGo > 0, Keq > 1

23. If DH = 35.5 kJ/mol and DS = 83.6 J/mol K. At what temperature the reaction will be spontaneous ?
(A) T > 425 K (B) Each temperature (C) T > 298 K (D) T < 425 K
24. The bond dissociation energies of X2, Y2 and XY are in the ratio of 1 : 0.5 : 1. DH for the formation of
XY is –200 kJ mol–1. The bond dissociation energy of X2 will be
(A) 400 kJ mol–1 (B) 200 kJ mol–1 (C) 800 kJ mol–1 (D) 100 kJ mol–1
25. The combustion of benzene (l) gives CO2(g) and H2O(l). Given that heat of combustion of benzene at
constant volume is –3263.9kJ mol–1 at 25°C, heat of combustion (in kJ mol–1) of benzene at constant
pressure will be : (R = 8.314 J K–1 mol–1)
(A) 4152.6 (B) –452.46 (C) 3260 (D) –3267.6
26. At constant external pressure 4 Nm–2 ideal has undergo isothermal compression from 5 m3 to 1 m3.
The heat reused in this process is used to increase the temperature of 1 mole Al if heat capacity of Al is

YA
24 J mol–1 K–1 than the increase in temperature of Al is ...........
2 3
(A) 2 K (B) 1 K (C) K (D) K

LA
3 2
27. In which reaction antropy change is negative ?
(A) Disollution of I2 in water (B) Sublimation of dry ice

28.
(C) Synthesis of NH3 from N2 and H2 YA
For the reaction, 2Cl(g) ® Cl2(g), the correct option is
(D) Decomposition of CaSO4 in CaO and SO3
ID
(A) DrH < 0 and DrS > 0 (B) DrH < 0 and DrS < 0
(C) DrH > 0 and DrS > 0 (D) DrH > 0 and DrS < 0
TV

29. The correct option for free expansion of an ideal gas under adiabatic condition is :
(A) q < 0, DT = 0 and w = 0 (B) q > 0, DT > 0 and w > 0
(C) q = 0, DT = 0 and w = 0 (D) q = 0, DT < 0 and w > 0
YO

30. For irreversible expansion of an ideal gas under isothermal condition, the correct option is :
(A) DU = 0, DStotal ¹ 0 (B) DU ¹ 0, DStotal = 0 (C) DU = 0, DStotal = 0 (D) DU ¹ 0, DStotal ¹ 0
J
AN
GY
 Section [ A ] : 4 Marks Questions

No Ans Chap Sec Que Universal_QueId

1. B Chap 6 S6 6 QP22P11B1112_P1C6S6Q6
2. A Chap 6 S6 10 QP22P11B1112_P1C6S6Q10
3. A Chap 6 S6 14 QP22P11B1112_P1C6S6Q14
4. C Chap 6 S6 32 QP22P11B1112_P1C6S6Q32
5. B Chap 6 S8 1 QP22P11B1112_P1C6S8Q1
6. D Chap 6 S8 2 QP22P11B1112_P1C6S8Q2
7. B Chap 6 S8 3 QP22P11B1112_P1C6S8Q3
8. C Chap 6 S8 4 QP22P11B1112_P1C6S8Q4
9. B Chap 6 S8 5 QP22P11B1112_P1C6S8Q5
10. A Chap 6 S8 6 QP22P11B1112_P1C6S8Q6
11. D Chap 6 S8 7 QP22P11B1112_P1C6S8Q7
12. A Chap 6 S8 8 QP22P11B1112_P1C6S8Q8
13. D Chap 6 S8 9 QP22P11B1112_P1C6S8Q9
14. C Chap 6 S8 10 QP22P11B1112_P1C6S8Q10
15. D Chap 6 S8 11 QP22P11B1112_P1C6S8Q11
16. B Chap 6 S8 12 QP22P11B1112_P1C6S8Q12
17. C Chap 6 S8 13 QP22P11B1112_P1C6S8Q13
18. B Chap 6 S8 14 QP22P11B1112_P1C6S8Q14
19. D Chap 6 S8 15 QP22P11B1112_P1C6S8Q15
20. B Chap 6 S8 16 QP22P11B1112_P1C6S8Q16
21. D Chap 6 S8 17 QP22P11B1112_P1C6S8Q17
22. C Chap 6 S8 18 QP22P11B1112_P1C6S8Q18
23. A Chap 6 S8 19 QP22P11B1112_P1C6S8Q19
24. C Chap 6 S8 20 QP22P11B1112_P1C6S8Q20
25. D Chap 6 S8 21 QP22P11B1112_P1C6S8Q21
26. C Chap 6 S8 22 QP22P11B1112_P1C6S8Q22
27. C Chap 6 S8 23 QP22P11B1112_P1C6S8Q23
28. B Chap 6 S8 24 QP22P11B1112_P1C6S8Q24
29. C Chap 6 S8 25 QP22P11B1112_P1C6S8Q25
30. A Chap 6 S8 26 QP22P11B1112_P1C6S8Q26

Welcome To Future - Quantum Paper

 Section A
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• Write the answer of the following questions. [Each carries 4 Marks] [120]
1.

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