e

Physical Chemistry : Thermodynamics &

Thermochemistry
1. Which of the following relation is correct for the combustion of Toluene.
(A) DH = DE (B) DH > DE (C) DH < DE (D) none of these
2. If HCOOH+NaOH ® HCOONa+H2O DH= -13.1 kcal then enthalpy of dissociation of HCOOH is
(A) 600 cal (B) 60 cal (C) – 600 cal (D) cannot be calculated
dH
3. For which of the following cases dS=
T
(A) a process for which DCp = 0 but DCv ¹ 0
(B) an isothermal process in which reversible phase transition takes place
(C) an isobaric process
(D) an adiabatic process.
4. The latent heat of vaporisation of a liquid at 500 K and 1 atm pressure is 10 kcal /mol . What will be change in internal
energy of 3 mole of liquid at same tempereture?
(A) 13 Kcal (B) –13 Kcal (C) 27 Kcal (D) –27 Kcal
5. When a diatomic gas undergoes an adiabatic process it’s temperature and volume are related by the eqvation TVn = constant.
What will be the value of n.
(A) 1 (B) 0.6 (C) 0.4 (D) 0.2
6. For which of the following conditions a reaction is nonspontaneous at any temperature ?
(A) DH > 0 < DS (B) DH > 0 > DS (C) DH < 0 < DS (D) DH = 0 = DS
7. During combustion of CH4 in a bomb calorimeter and finally cooling the mixture to 27°C.
(A) DU = - ve , P D V = '- ve' (B) D U = - ve, D (PV) = '- ve'

(C) D U = - ve, P D V = 0 (D) Both (B) and (C) are correct

8. When liquid HCl and water are mixed then
DHmix DVmix DSmix DGmix
(A) 0 0 0 0
(B) + + + +
(C) – – + –
(D) – – – +

9. The bond enthalpies of H 2 , X 2 and HX are in the ratio of 2:1:2 of Enthalpy of formation of HX is –50KJ\mole, The bond
enthalpy of X2 is
(A) 100 KJmol–1 (B) 200 KJmol–1 (C) 300 KJmol–1 (D). 400 KJmol–1
10. The difference between the heat change at constant pressure and that at constant volume for the combustion of 46 g of
ethanol at 27o C is
(A) – 4.59 kJ (B) + 4.59 kJ (C) + 2.49 kJ (D) – 2.49 kJ
11. For a reaction at 25ºC, enthalpy change DH and entropy change DS are –11.7 x 103 and 105 Joule per mole K–1, respectively,
the which of the following statements is true?
(A) Spontaneous reaction (B) Nonspontaneous reaction
(C) Can be 1 as well as 2 (D) At equilibrium
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12. Enthalpy of carbon, hydrogen and ethyl alcohol on combusion at 25ºC are –94.0, –68.4 and –327.0 kcal per mole, then the
formation enthalpy of ethyl alcohol will be
(A) –66.2 kcal/mol (B) 58.2 kcal (C) 60.2 kcal/mol (D) 60.4 kcal/mole
13. The work of expansion for a system is 500 cal. The heat given to the system is 80 cal. The change in internal energy in the
process will be -
(A) 80 cal. (B) 500 cal. (C) –420 cal. (D) 420 cal.
14. From the following thermochemical equations, find out the heat of ionisation Z for a weak acid HA–
HA ® A– + H+, DH = Z
H++ OH– ® H2O, DH = X
HA + OH– ® A– + H2O, DH = Y
(A) X + Y (B) –(X + Y) (C) X – Y (D) (Y – X)
15. What is true for the reaction : PCl5(g) ® PCl3(g) + Cl2(g)
(A) DH = DE (B) DH > DE (C) DH < DE (D) None of these
16. The gaseous endothermic reaction P + Q ® 2R + 3S at 27ºC takes place spontaneously, because -
(A) DH < 0; DS < 0 (B) DH > 0; DS > 0 (C) DH < 0; DS > 0 (D) DH > 0; DS < 0
17. N2(g) + 2O2 ® 2NO2(g) + X kJ
2NO(g) + O2(g) ® 2NO2(g) + Y kJ
What is the heat of formation (DHf ) of NO –
1 1
(A) (2X – 2Y) (B) X – Y (C) (Y – X) (D) (X – Y)
2 2
18. For the vaporisation of water : H2O (l) H2O(g) [1 atm. pressure]
Given : DS = 120 JK–1 and DH = + 45.0 kJ.
Evaluate the temperature at which liquid water and water vapours are in equilibrium at 1 atm. pressure –
(A) 273 K (B) 370 K (C) 373 K (D) 375 K
19. The heat capacity of a bomb calorimeter is 500 J/ºC. In an experiment, in the combusition of 0.1 gm. methane, the
temperature rise was by 2.0ºC. What is the value of DE per mole?
(A) 1 kJ (B) +160 kJ (C) –160 kJ (D) –1 kJ
20. For a certain reaction the change in enthalpy and change in entropy are 40.63 kJ mol–1 and 100 JK–1. What is the value
of DG at 27ºC and indicate whether the reaction is possible or not?
(A) +10630 J mol–1; possible (B) +10630 J mol–1 not possible
(C) – 7990 J mol–1; possible (D) +7990 J mol–1; possible
21. The bond dissociation energies of methane and ethane are 360 kcal mol–1 and 620 kcal mol–1 respectively. The C–C bond
energy in kcal mol–1 is –
(A) 130 (B) 260 (C) 180 (D) 80
22. For the reaction H2(g) + Cl2(g) ® 2HCl(g) DH 298K = –44.12 kcal
At 298 K, the enthalpy of formation of HCl is -
(A) –44.12 (B) –22.06 (C) 44.12 (D) 22.06
23. Consider the following data H2O(s) ® H2O(l), DH = 6.05 kJ
H2O(l) ® H2O(g), DH = 43.7 kJ
At 273 K, the sublimation energy of H2O(s) ® H2O(g) is –
(A) 43. 7 kJ (B) 6.05 kJ (C) 49.75 kJ (D) 37.3 kJ
24. The heat of formation of ICl DH(ICl) = 4.2 kcal mol–1, DH(Cl) = 29.0 kcal mol–1, DH(I) = 25.5 kcal mol–1. What will be
the bond energy of ICl?
(A) 58.7 kcal (B) 50.3 kcal (C) 29.7 kcal (D) 33.2 kcal

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25. For a spontaneous process the values of free energy and entropy change are respectively –
(A) Postiove and negative (B) Negative and positive
(C) Positive and positive (D) Negative and neative
26. Which one of the following has the maximum entropy of vaporization ?
(A) Water (l) (B) toluene (l) (C) diethyl ether (l) (D) acetone (l)
27. Consider the reaction N2 + 3H2 2NH3 carried out a constant temperature and pressure. If DH and DU are the
enthalpy and internal energy changes for the reaction, which of the following expression is true:
(A) DH = 0 (B) DH = DU (C) DH < DU (D) DH > DU
28. The free energy change (DGº) is negative when :
(A) the surroundings do no electrical work on the system
(B) the surroundings do electrical work on the system
(C) the system does electrical work on the surroundings
(D) the system does no electrical work on the surroundings.
29. Bond energy of N–H, H–H and N º N bonds are Q1, Q2 and Q3; DH of N2 + 3H2 ® 2NH3 is :
(A) Q3 + 3Q 2 - 2Q1 (B) 2Q1 - Q3 - 2Q 2 (C) Q3 + 3Q 2 - 6Q1 (D) none of these
30. The absolute enthalpy of neutralization of the reaction :
MgO(s) + 2HCl(aq) ® MgCl 2 (aq) + H 2O( l) will be :
(A) –57.33 kJ/mol (B) > –57.33 kJ/mol (C) < – 57.33 kJ/mol (D) 57.33 kJ/mol
31. Which of the following equations represent standard heat of formation of C 2H4 :
(A) 2C (diamond) + 2H2 (g) ® C2H4(g) (B) 2C (graphite) + 2H2 (g) ® C2H4(g)
(C) 2C (diamond) + 4H (g) ® C2H4(g) (D) 2C (graphite) + 4H (g) ® C2H4(g)
32. In the reaction : CO(g) + ½O2(g) ® CO2 (g), the change in DS° is (given Sº for CO, O2 and CO2 are 197.6, 205.3 and
213.6 JK–1 mol–1 respectively) :
(A) –78.6 JK–1 mol–1 (B) –50 JK–1 mol–1 (C) –86.5 JK–1 mol–1 (D) –30 JK–1 mol–1
33. The heat liberated on complete combustion of 7.8 g benzene is 327 kJ. This heat was measured at constant volume and
at 27ºC. Calculate the heat of combustion of benzene at constant pressure (R = 8.3 J mol–1 K–1)
(A) –3274 kJ mol–1 (B) –1637 kJ mol–1 (C) –3270 kJ mol–1 (D) –3637 kJ mol–1
34. DGº for the reaction, x + y z is –4.606 kcal. The value of equilibrium constant of the reaction at 227ºC is :
(A) 0.01 (B) 100 (C) 2 (D) 10
35. The standard heat of combustion of Al is –837.8 kJ mol at 25ºC. If Al reacts with O2 at 25ºC, which of the following
–1

releases 250 kcal of heat :

(A) the reaction of 0.312 mol of Al (B) the formation of 0.624 mol of Al2O3
(C) the reaction of 0.712 mol of Al (D) the formation of 0.615 mol of Al2O3
36. If at 298 K the bond energies of C–H, C–C, C=C and H–H bonds are respetively 414; 347, 615 and 435 kJ mol–1, the
value of enthalpy change for the reaction H2C = CH2(g) + H2(g) ® H3C – CH3(g) at 298 K will be :
(A) +250 kJ (B) –250 kJ (C) +125 kJ (D) –125 kJ
37. In an irreversible process taking place at constant T and P and in which only pressure-volume work in being done, the
change in Gibbs free energy (dG) and change in entropy (dS), satisfy the criteria :
(A) (dE)V, E<0, (dG)T, P<0 (B) (dE)V, E>0, (dG)T, P<0 (C) (dS)V, E=0, (dG)T, P=0 (D) (dE)V, E = 0, (dG)T, P > 0
38. The internal energy change when a system goes from state A to B is 40 kJ/mol. If the system goes from A to B by a
reversible path and returns to state A by an irreversible path what would be the net change in internal energy :
(A) 40 kJ (B) > 40 kJ (C) < 40 kJ (D) zero

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 Inorganic Chemistry : Chemical Bonding

1. What is the Magnetic movement of K 3 [ FeF6 ] ?

(A) 3.87 BM (B) 4.89 BM (C) 5.91 BM (D) 6.92 BM
2. Which of the following combination leads to the formation of antibonding molecular orbital.

(A) + & + (B) & (C) & (D) &

3. Which of the molecule is not 5p2 hybridized ?

(A) BF3 (B) CO32– (C) N - atom in C5H5N (D) H3o+
4. Among the following spectes
CO2, CH3COO–, Co, CO3–2, HCHO which has the weakest C ––––––––– O bond ?
(A) CO (B) CO2 (C) CO32– (D) CH3COO–
(e) HCHO
5. Which of the following statement about Fajan’s rule is incorrect ?
(A) It deals with polarization
(B) Larger the size of cat ion learger it polarizes the anion
(C) smaller the size of cat ion larger it polarizes the anion.
(D) larger the size of anion larger it gets polarized by cat ion
6. Which of the following is correct order of bond dissociation energy ?
(A) F2 > Cl2 > Br2 > I2 (B) Cl 2 > F2 > Br2 > I2 (C) F2 > I 2 > Cl2 > Br2 (D) Cl 2 > Br2 > F2 > I 2
7. The ÐHSH bond angle in H2S is 920. It infers to
(A) S is sp3 hybridised
(B) Lonepair- lonepair repulsion is greater than bond+pair- bond pair repulsion.
(C) The bonds are more or less purely p-type
(D) The bondpair - bondpair repulsion is high enough due to larger size of sulphur.
8. Which of the following is incorrect for C2 molecule?
(A) Its bond order is 2 (B) Both bonds are p bonds.
(C) one bond is s and other bond is p (D) It is diamagnetic
9. Which of the following compound having maximum covalent character ?
(A) LiCl (B) NaCl (C) KCl (D) CsCl

O*
||
10. Formal charge on the oxygen (O) in the phosphate ion will be O - P - O -
-
|
O-

(A) 0 (B) +1 (C) –1 (D) +2

11. Which of the following is correct for basic strength ?
(A) NI3 > NBr3 > NCl3 > NF3 (B) NI3 < NBr3 < NCl3 < NF3
(C) NI3 < NF3 < NCl3 < NBr3 (D) NF3 < NCl3 < NBr3 < NF3
12. N-N bond is absent in
(A) N2O (B) N2O3 (C) N2O4 (D) N2O5
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13. According to VSEPR theory, “as the electronegativity of peripheral atom increases bond angle decreases”. Hence the
correct order of bond angle is observed in
(A) BF3 < BCl3 < BBr3 < BI3 (B) BF3 > BCl3 > BBr3 > BI3
(C) BF3 = BCl3 = BBr3 = BI3 (D) BI3 > BCl3 > BBr3 > BF3
14. How the hybridisation, bond angle, bond length and dipole moment changes when BF3 is converted to BF4- ?
Hybridisation Bond angle Bond Dipole
length mom.
(A) sp2 ¾¾
® sp3 increases decreases increases
(B) sp3 ¾¾
® sp3 unchanged increases decreases
(C) sp2 ¾¾
® sp3 decreases unchanged increases
(D) sp2 ¾¾ ® sp3 decreases increases unchanged
15. The decreasing order of Bond length of the following species
(A) O-22 > O2 > O2- > O+2 > O +22 (B) O-22 > O-2 > O2 > O+2 > O +22

(C) O+22 > O2+ > O2 > O 2- > O -22 (D) O-22 > O+22 > O 2 > O+2 > O 2-
16. Bond length of HCl is 1.275 Å (Charge = 4.8 × 10 –10 e.s.u.) if m = 1.02 D, then HCl is:
(A) 100% ionic (B) 83% covalent (C) 50% covalent (D) 40% ionic
17. The dipole moment of the ammonia molecule is 1.48D. The length of the dipole is :
(A) 3.08 × 10 –11 m (B) 5 × 102 m (C) 308 m (D) None
18. Two elements X and Y have following electronic configuration :
X 1s2 ; 2s2 , 2p6 ; 3s2 , 3p6 ; 4s2
Y 1s2 ; 2s2 2p6 ; 3s2 , 3p 5
The expected compound formed by combination of X and Y will be expressed as :
(A) XY2 (B) X5Y2 (C) X2 Y5 (D) XY5
19. In which of the following compounds carbon atom undergoes hybridization of more than one type
(i) CH3CH2 CH2CH3 (ii) CH3 —CH=CH–CH3 (iii) CH 2 =CH–CH2 –CH3 (iv) H–C ºC–H
(A) (iii) and (iv) (B) (i) and (iv) (C) (ii) and (iii) (D) Only (ii)
20. The geometry of AlF 6–3 is as follows :
(A) Tetrahedral (B) Hexagonal (C) Pyramidal (D) Ocatahedral
21. The type of hybridization of Xe in XeF 6 will be the same as that of the central atom in the following molecule:
(A) PCl5 (B) SF6 (C) IF7 (D) CCl4
22. Which bond angle, q would result in the maximum dipole moment for the triatomic molecule XY2 shown below:
Y

q
X Y
(A) q = 90º (B) q = 120º (C) q = 150º (D) q = 180º
23. The order of increasing polarity in HCl, CO 2 , H2O and HF molecules is :
(A) CO2 , HCl, H2O, HF (B) HF, H2 O, HCl, CO2
(C) CO 2, HCl, HF, H2 O (D) CO 2 , HF, H2O, HCl

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24. Which one of the following species is diamagnetic in nature ?

(A) H2 (B) H+2 (C) H-2 (D) He+2

25. The correct order in which the O – O bond length increases in the following is :
(A) O2 < O3 < H2O2 (B) H2O2 < O3 < O2 (C) O3 < O2 < H2O2 (D) O2 < H2O2 < O3
26. In which of the following there exists a pp -dp bonding ?
(A) Graphite (B) Diamond (C) Dimethyl amine (D) Trisilylamine
27. Number of sigma bonds in P4O10 is :
(A) 6 (B) 9 (C) 16 (D) 20
28. The value of electronegativity of atoms A and B are 1.20 and 4.0 respectively. The percentage of ionic character of
A – B bond is :
(A) 43% (B) 50% (C) 55.3% (D) 72.24%
29. CaO and NaCl have the same crystal structure and approximately the same ionic radii. If U is the lattice energy of NaCl,
the approximate lattice energy of CaO is :
(A) U (B) 2U (C) 4U (D) U/2
30. –
CH3 is an isostere of
(A) CH4 (B) NH 3 (C) BH3 (D) CH3 +
31. Indicate the order of stability among the following resonating structures for acetone.

CH3 CH3 CH3

+ - - +
C=O C O C O
CH3 CH3 CH3

I II III

(A) I > II > III (B) I < II < III (C) I > III > II (D) II > I > III
32. The nature of p-bond in perchlorate ion is
(A) O (dp) – Cl (pp) (B) O (pp) – Cl (dp) (C) O (dp) – Cl (dp) (D) O (dp) – Cl (dp)
33. Pt – Cl distance is 2.32 Å. Cl – Cl distance in I and II are :
NH3 NH 3

Cl Pt Cl Cl Pt NH3

NH3 Cl
(I) (II)
(A) 4.64 Å, 3.28 Å (B) 5.64 Å, 4.64 Å (C) 3.28 Å, 4.64 Å (D) None
34. –
In the anion HCOO the two carbon-oxygen bonds are found to be of equal length. What is the reason for it?
(A) Electronic orbitals of carbon atom are hybridised
(B) The C = O bond is weaker than the C – O bond
(C) The anion HCOO– has two reasonating structures
(D) The anion is obtained by removal of a proton from the acid molecule
35. In which of the following molecules/ions all the bonds are not equal ?
(A) SF4 (B) SiF4 (C) XeF4 (D) BF4

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36. The charge/ size ratio of a cation determines its polarizing power. Which one of the following sequences represents the
increasing order of the polarizing power of the cationic species : K+, Ca2+, Mg2+, Be2+?
(A) Be2+ < K+ < Ca2+ < Mg2+ (B) K+ < Ca2+ < Mg2+ < Be2+
(C) Ca2+ < Mg+ < Be2+ < K+ (D) Mg2+ < Be2+ < K+ < Ca2+
37. Which of the following are possible resonating structures of N2O ?

+ +
+
N N O N N O N N O and N N O

(1) (2) (3) (4)

(A) 1, 2 (B) 1, 3 (C) 1, 2 and 3 (D) All of these

38. The electronic configuration of 4 elements K, L, M and N are :
K = 1s2, 2s2 2p1 L = 1s2, 2s2 2p6 M = 1s2, 2s2 2p4 N = 1s2, 2s2 2p3
The element that would form a diatomic molecule with double bond is :
(A) K (B) L (C) M (D) N
39. If the ionic radii of K+ and F– are about 1.34 Å each, then the expected values of atomicradii of K and F should be
respectively :
(A) 1.34 and 1.34 Å (B) 2.31 and 0.64 Å (C) 0.64 and 2.31 Å (D) 2.31 and 1.34 Å
40. The correct order of bond angles is :
(A) PF3 < PCl3 < PBr3 < PI3 (B) PF3 < PBr3 < PCI3 < PI3
(C) PI3 < PBr3 < PCI3 < PF3 (D) PF3 > PCI3 < PBr3 < PI3
41. The hybridization of P in PO43– is same as in :

(A) I in ICl -4 (B) S in SO3 (C) N in NO3- (D) S in SO 24-

42. Which one is planar molecule :

(A) XeO4 (B) XeO3 F (C) XeO2F 2 (D) XeF4
43. The linear structure is possessed by :

(A) SnCl2 (B) NCO– (C) NO+2 (D) CS2

44. The correct order of dipole moment is :

(A) CH4 < NF3 < NH3 < H2O (B) NF3 < CH4 < NH3 < H2O
(C) NH3 < NF3 < CH4 < H2O (D) H2O < NH3 < NF3 < CH4
45. In which of the process, the bond order increases and magnetic behaviour changes ?

(A) N 2 ¾¾
® N +2 (B) C 2 ¾¾
® C 2+ (C) NO ¾¾
® NO+ (D) O 2 ¾¾
® O 2+

46. Which has zero dipole moment ?

(A) ClF (B) PCl3 (C) SiF4 (D) AgBr
47. Which of the following possess maximum hydration energy ?
(A) MgSO4 (B) RaSO4 (C) SrSO4 (D) BaSO4
48. The structure of ICl -2 is :
(A) trigonal (B) octahedral (C) square planar (D) distorted trigonal bipyramid

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49. Identify the least stable ion amongst the following
(A) Li– (B) Be– (C) B– (D) C–
50. In which of the following pp-dp bonding is observed :

(A) NO3- (B) SO32- (C) BO33- (D) CO32-

51. Which species has the maximum number of lone pair of electrons on the central atom ?
(A) ClO3– (B) XeF4 (C) SF4 (D) I3–

52. In NO3- ion, number of bond pairs and lone pairs electrons are respectively :

(A) 2, 2 (B) 3, 1 (C) 1, 3 (D) 4, 8

53. Four diatomic species are listed below in different sequences. Which of these presents the correct order of their increasing
bond order ?

(A) NO < C22- < O-2 < He +2 (B) C22- < He2+ < NO < O 2-

(C) He+2 < O -2 < NO < C22- (D) O-2 < NO < C22- < He 2+

54. What is the correct mode of hybridization of the central atom in the following compounds ?

NO+2 SF4 PF6-

(A) sp2 sp3 d2sp3
(B) sp3 sp3d2 sp3d2
(C) sp sp3d sp3d2
(D) sp sp2 sp3
55. In AB bond if per cent ionic character is plotted against electronegativity difference (XA – XB), the shape of the curve
would look like

The correct curve is :

(A) (A)
(B) (B)
(C) (C)
(D) (D)

56. The number of pp-dp ‘pi’ bonds present in XeO3 and XeO4 molecules, are respectively :
(A) 3, 4 (B) 4, 2 (C) 2, 3 (D) 3, 2
57. The type of bonds present in sulphuric anhydride is,
(A) 3s and three pp-dp (B) 3s, pne pp-pp and two pp-dp
(C) 2s and three pp-dp (D) 2s and two pp-dp
58. Which of the following species have undistorted octahedral sturctures

(I) SF6 (II) PF6- (III) SiF62- (IV) XeF6

Select the correct answer using the code given below :

(A) I, II and IV (B) I, II and III (C) I, II and IV (D) II, III and IV

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59. Which of the following statement is true ?
(A) Hybridization of the central atom in NH3 and CH4 is sp2
(B) BeCl2 has “V” shape while SO2 is linear
(C) SF6 is octahedral and F–S–F bondangle is 90°
(D) CO2 has dipole moment
60. Hydrogen bond is strongest in
(A) S – H – O (B) O–H–S (C)F–H–F (D) O–H–N
61. The acid having O – O bond is :
(A) H2S2O3 (B) H2S2O6 (C) H2S2O8 (D) H2S4O6
62. Arrange the following compounds in order of decreasing dipole moment.

Cl Cl Cl
Cl Cl Cl Cl CH3

(1) (2) (3) (4)

Cl Cl Cl

(A)1 > 3 > 2 = 4 (B) 3 > 1 > 2 = 4 (C) 1 > 2 > 3 > 4 (D) 4 > 3 > 2 > 1
63. Which among the following pairs represent isovalent resonating forms ?

O O O O
|| || || ||
1. Cl - C - OH R - C = OH 2. Cl - C - OH R -C-O

R R
+
3. C O C O 4.
R R

(A)1, 2, 4 (B) 2, 3, 4 (C) 3, 4 (D) 1, 3

64. Which of the following statements is not correct for s and p bonds which is formed between two carbon atoms ?
(A) free rotation of atoms about s bond is allowed but not in case of a p bond
(B) s bond determines the direction between carbon atoms but a p bond has no primary effect in this regard
(C) s bond is stronger than a p bond
(D) bond energies of s bond and p bond are of the order of 264 kJ/mol and 347 kJ/mol, respectively.
65. H2O is dipolar, whereas BeF2 is not. It is because
(A) the electronegativity of F is greater than that of O
(B) H2O involves hydrogen bonding whereas BeF2 is a discrete molecule
(C) H2O is linear and BeF2 is angular
(D)H2O is angular and BeF2 is linear
66. Identify the correct sequence of increasing number of p bonds in the structures of the following molecules
(1) H2S2O6 (2) H2SO3 (3) H2S2O5
(A) 1, 2, 3 (B)2, 3, 1 (C) 2, 1, 3 (D) 1, 3, 2

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67. Which of the following is correct ?
(A) The rate of ionic reactions are very slow
(B) The number of electrons present in the valence shellof S in SF6 is 12
(C) According to VSEPR theory SnCl2 is a linear molecule
(D) The correct order of stability to form ionic compounds among Na +, Mg2+ and Al3+ is Al3+ > Mg2+ > Na+
68. The nodal plane in the p bond of ethene is located in
(A) the molecular plane.
(B) a plane parallel to the molecular plane.
(C) a plane perpendicular to the molecular plane which bisects. The carbon-carbon s bond at right angle.
(D) a plane perpendicular to the molecular plane which contains the carbon-carbon bond.
69. Specify the coordination geometry and hybridization of N and B atoms in a 1 : 1 complex of BF 3 and NH3
(A) N : tetrahedral, sp; B: tetrahedral, sp3 (B) N : pyramidal, sp3; B: tetrahedral, sp3
(C) N : pyramidal, sp3; B: planar, sp2 (D) N : pyramidal, sp3; B : tetrahedral, sp3
70. Which one of the follwing compounds has the smallest bond angle in its molecule ?
(A) SO2 (B) OH 2 (C)SH2 (D) NH 3
71. The pair of species having identical shapes for molecules of both species is :
(A) CF4, SF4 (B)XeF2, CO2 (C) BF3, PCl3 (D) PF5, IF5
72 The correct order of bond angles (smallest first) in H2S, NH3, BF3 and SiH4 is
(A) H2S < SiH4 < NH3 < BF3 (B) NH3 < H2S < SiH4 < BF3
(C)H2S < NH3 < SiH4 < BF3 (D) H2S < NH3 < BF3 < SiH4
73. Which one of the following species is diamagnetic in nature ?
(A) H2 – (B)H2 (C) H2 + (D) He2 +
74. Which is the correct statement about s and p molecular orbitals ? Statements are :
(i) p bonding orbitals are ungerade (ii) p antibonding orbitals are ungerade
(iii) s antibonding orbitals are gerade
(A) (i) only (B) (ii) and (iii) only (C) (iii) only (D) (ii) only

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