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Alcohol Phenol Ether Revision Notes

The document provides instructions for synthesizing various organic compounds using common organic reactions like Williamson ether synthesis, Grignard reactions, and acid-base reactions. Key steps include preparing phenol from cumene, generating alkyl halides and alkoxides for Williamson ether synthesis, preparing aldehydes and ketones from Grignard reagents, and generating esters from alcohols and acids. Common reagents include sodium, hydrochloric acid, magnesium, bromine, and sodium hydroxide.

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0% found this document useful (0 votes)
75 views3 pages

Alcohol Phenol Ether Revision Notes

The document provides instructions for synthesizing various organic compounds using common organic reactions like Williamson ether synthesis, Grignard reactions, and acid-base reactions. Key steps include preparing phenol from cumene, generating alkyl halides and alkoxides for Williamson ether synthesis, preparing aldehydes and ketones from Grignard reagents, and generating esters from alcohols and acids. Common reagents include sodium, hydrochloric acid, magnesium, bromine, and sodium hydroxide.

Uploaded by

Akku Akku
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Alcohol, pherol, her

aeachion
Reimes- Tieman
Kxplain in he prescra
taeaked wth chlosofo
when
phenol on
uoe ge
Na0H Rolloued by aciduicahi
salicqlaldehyde ONa
CHO
CHO
GrHclg+Qq Naol

ealaulaldede

Williamson 2tber Synthes


( Explaim alkoxi da
alkoxi de
Sodiumn
Sodium
wben Teact wtb
Alkyl balide
Eooonm ethes R-oR + Nax

R-X+R-ONa

dishinquish
distinguish
ard
2 and e
used to
GTive the est
a n b y d o u s Z n C l 2

alcohol and
Com Hcl
ucas esF ucas Tecaen

precip1kae
gent:-sudden

3 alcohol + kucas ales 5mi


precip1tatt
+ kucas
aeagent . precepiLata
tate
alcool
No precëpi
No
qeagent
dueorhol t tas

Gtive sBoucuze Cumere

Cumene
Prepaea phenol oorp OH
CH
CH -O-0-H
CH3
CHsCH Op H2O

Cumene
bydaopoortde

umene
using qriqnaad ecant
prcpare

altohol5 H oH Ha0

R-CH-OMgx
H-CHO + RMg X 7
Foomaldebyde Ginqnardnt
R-CHa-OH Jpco
alwho

alcohol
HoH
RHOtt
BCHOoMg x
R-CHD RMqx alohs
oomalodehyde (HCHo
All other aldebydes except
alcónol.
wth RMgX
qive
ushun aeat
alccbol oo
alccbol
phenol
phenol
moTe aidic
move Stabllised.
is Yesornane

iom is
W b i c h

phenoaide
phenot
soluble im ocitu
u oat 1
are
cobols bomdima
A lAl byda ogeo
i i i m o l e ula
Due to alohol
alcohól tBphenol
phensl
test to dishnquish
WTile a Na
Na,
(( ley vescone
wi
phenol qive
dlCohol doesmot etbeunat.
methonolP
mehod
to pepane
Gtive cu
is oomed 9
AspiainMedicime) acid w t acdhc
a cdC
How acid c o t
Saliculic
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By mediup.

ip acid
anhydaide cCoo
Coo H
ocOCH
FooH

o
oH
+CHa fo
Salicuc
Aspiri
acd
Copplete the ecachiom s
ind arsusers by osel
HsOA CH=CHa (Debydadtisn)
O CaH5OH
443K
ooH
Nach co
Ht
CS03 CHa-CHO
OH C2Hs OH
Ethanol etbanal
,4-ainitrop hen

Con HNOg O NOz icic ada)


OH
OH
Benzene
Zn dusE

OH
Y
B cOole
B
oH 4 , 6 -1baomophed

OH
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H
oH QH
dil HN03

CH2 Mg BT
A
HCHO d o yetbes

H20
C H c H - O H

dagethca

B+CHgMaY HaD cr
b e n z o q u i n o n e -

HsOu

h a t is rectified spisit 7

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