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Coordination Compounds

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110 views17 pages

Coordination Compounds

Theyrhfnffjf jfbdbd ffvc jdgddjd hdhddbd hdb dhbd dudvd. Ddudbdndvd ddudjfhd f hddidd iddidbdhd bdudhiddbs uddjdjdhdbd bdjdidhd ddhddjd. Dhhdjidjdhdbf. Jdjdvdjdj

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Addition Compound 2- When wo or most Sales cus minedl together and stomas for sometime, vapoud sation Some Cuptals oe formed vu cabled adldlittion vomporn| | @-ORDIMATION Com; Dov6Le SALT 9 K50, + MSG, tLe eg> KON FRC) 904A, (544),. 200,0 (Potashatum) Ke Ceeen?d Thay base cuit > Muy hire ifs ions. Same ions wi He lomp. 05 thee towti- = Lueuk ion ome _umpomiant Cum tovrdinalion sphoe Greco] psi TT tigre el lonisation . He tovedinatio* saieatin cram, EEE) e (combrod rneka! asc) Contras _metak oom 5 en de block metal ack ws cma dwe to tnx small ‘eize, high muclear charge and awcivenility of vacint d- gdoitals. queue atom howing tendlen| — oy to donate C” pars te fis can and form coordinate loond gama ogee po Senticlly ae Wr propyely of Lyard) tok gk WY He donor giv omy Egan - gee 7 aniily =! lomplene having q. ReCeecene > comple saa cabinie , Aniodie = Non- lorie Gy a) Coop, Gretom FC Fete I~ 8: Sdentify vomplen 1. NOx Che CGtyls J? Sipe cotter ‘ontplaw anion lomplew Tomolep ie lomprons kowumy move Hham one ype yy ligand» tg Cen am one type of uigand yan cn" +cyave Po; » phosphate — yo + mij bose to + convo Myt w,-N4, hyd azine (on tes basa q donereitey) 1. Monodentate - Ligamols hawing one en I donor site eg Nin, 7M 2. bidentate tgamrds bonus 2 clowtov Si tes 3. Tuidintate - legomay hating $ donor site Sys 4 Polyclentate SON eo haung “ore two demo cites © scanned wthonenScaner ating ligands > Th ke SthucHbu = axound metal ettom, ty O% (oxalate) G04” & Blenidentate ligand — Ligands vespauls a} stow dinticrg. © Celta) + diqnmiv 7 tno tetra curate CHT N Cat-wo? i iN Un, toe? dente om eo enw 5b Some _tommon ligands 2- 1, en - ettuplene diamine i dentitity 7 2 chasige — 0 (neutral 2, (di-e) ~ dittuylen bad amas Hin. dently +3 CH, Te Lo 3 hasye 20 on, at NA, x | Ny Uy OH, 3, (Euien) tHlethytone tebracmmie gn He Bh, dimticity = 4 f L auge = 2 > M 4° Sreubred) 1 ot a f Nike ay - 4, — 8, 1 cobuplen dieomioe Feber deta 4. eda” t ,a4 Chase = 4 seal =, eer na = “ty, - oe 5 eka? > Ctuplene damming bi -eetal} aentioty = 45 change = 3 4, Nh U1, -Weo® — ne WUVVVVVVEEEEEELUUUUUULELELLCUU CCU O CTU uuu eve e eee 6. Suyare » og chen ticihy Chang e's 2 20 Ns ae ty Pysicine ontitity Charge 7 netbral t fO) hig 8. guy Coy cinate) ith, dowti city > 2 havege *N\ 6-98 & u ° 9, acac Cacetyeaceronate) i ainsicity = 2 charge =~! Acetyl acerake ae -~0-%, tHe Ox Coxalate) C,04* i andy 2 1 py Chase = -% ae ° 13. Bipy CBrpyal dgl) = \ denticity = 2 { ye cnebige = © (nuutrod) \ mM v mm Ambidentate ligand dig amas fauing more tran One dlover Site out Can donate Kon ens done sive at a Hau, - CN. New a a ar C ~~ WN clones 10" Z ees Jee wegen) etwen) MECN amo Bocyous Mv oun (© scanned wthonen Sane OX d ation re. and ~toorainali- ! 7on_No. 4 CMA Onication no Fhe chauge presunk on ome un tine wordnctian wrmpourd loovainarion re > Tre no. Wo-ordtinake bend forms fey ela Uigonts cite crn inter tomplen i called to -Dvtlincltion Now @ cma, (Ho. of ligamals ¥ dently GQ Cabeutobe ON § CN H following: ) kylFe Cow), D 2) Ccocnn), 4s Hw +6lo) +3(-D=9 on 2 Cricwy J kh +4lod=e on 4) [ee CsI n+ 5f0=0 cv = ext cnc 4x! =4 cus sxled on 5) na, Cee (ors ] B+ m4 3-2-0 are- ol =3) 6) Crete), wt 6 = nat3 *) Ceolen)s IOs Mm $3) 3 7% ON = 3X2 me %) Ceeetmiig, I** covaax! Lupne NOMENCLATURE 1) Cation Crive pas) 4 widitin First Followed ay 2) busing nan ae weben Fst Contral metad Owdation “% 3) of emp & tht onion. Ing sormpiere J0n, Ug ands wlprasch rally followed atom willl, thee th bracker. Lomplex cation comple anion v Fe +rren Fe 7 Femate Ph teak > cupecate examples -~ te Ky CeCe), J tsimpe cation, Conpyr ani Potassium henacy amopannee a 2. Ceolny), JU; hevaammins Cobalt (ii) chlo ries (oonpies cation, simple amiaKa | Hi ot — Sl tuiaminessd agua cooale (111) Chioside Xf 4) Kk, Centondy J (simp. cation, comp anton) MH Poranivum tebrahy dnene zincate C1) ml 3) Na,Cre C603) (simpie catien , vorapitex) anion Sodium tHlenalatepoucatke (11) He [Tor Potg dentate légand] 25 be | 3 bis oy pebrary ——_—— Ceo tna), wns), J +3 Complex cations) txtamine tual nitho -N- cobalt cw B) Cm (Cody Jorracan bony Moke LO) 3) Kp Cee Cov),J Csimele’ tation ;cornpler anion Potasdiues hexa ayonogovate (in) 8) Ceo (NNg)s HO Sets Crompies Cahlon, ee ae 14 oho) Cauetea t 9) Cpt NH, Br & HOT amine agua bscorntel, crlori ap Plast snltter 10) Ci (end, J*> (vomplex Cation ) eb bctetytens chidammi ar Mickel (1) 5 70? MW) Cm , Cond, TS0y (lomp. cation dampe bisetry lone diamine lobete (wd sulprate mH =4 Micntoucicte (© Same with ORE Se WUGUU UYU UU UU KEES LULELELULELLGELEL 2 WUVPbbb 12) Cou (10), (Nit) J clg tetrawmine digagua Coppi Cl) Chboside 13) C5CAu lenny] (Simple cation , complen) Gasiwm tetra cyomeaumate (iN) 4) Cea, Cnr dyJ** Crs ay I? Z é lonplex AHon complex auton tetraminine dictlomid Platinium (Wr) tebvacnastide Platinake C1) 15) Puwesian Blue wlow Fe,CFeCuv),I, Sinpiecanon complex Gaion Dron (Mm) hexacyanoyorcnate cy) MK! c Je) CEnCnay), Cb), TL, (romper cation Gig tat) tHiamina tel agua Chicone wn (in) Utovid) 1) Lag Gun), 3 Cg cow 3 Campo iain, cUinwraminesdlyer (0) oi yao sitverk beyeil) 13) CPE Cw )ol Ch)ewe,) J (vemplex anion) diam mine Ouoxonitre platinate OH) 19) ks Cen(Gud3) Potassium teioxalate Chuomate (VI) 28) Clade) Con), CL dichlome dt cutoma mitt yoloalt (I) 2) Ceotnny)s Coe,)J Ct Pentamming Casbonote oleae (i) Chien 22) Hg Crolsewly) mexusey veer thiowy ante lorvale (1v) 1, Waite thu formilod fry Obs Lllow. wor. &. womp. (0) Tetrcwmineaguadtlosudpwbart (1) Chlowite [ieocnitsy, Mock J ch, CL Poberrians ettra hy dronider Mature CL) kK C2n Con),J 2 (C) Didusrd dob (ermam -1,2-clemncinr) vobauis (111) " (co (e (erla) Bonding _1N COMPLEXES Toon N SS 2 ween o's ver cCeT €Ay Mor theowg | WARNER'S THEORY | 2 ee 1 Sa to- ouclinedton compoumas moka chow two type % Lnkager (valence) - primary amd seconchang. 2. The puirnaiuy valences ome normally | jonictole amd atu Samsfied by negative ions Me Secon valences cue Mon jontabe. moe au sansficd by Muntrod mores or neganve lors. Tie sewondaity vatem “45 Cynat to Me toordination “no. Amel a Fixed fra metal y vuoups bolind by the te lel eae et ane chaxactéwitic epatral aan gemerd corresponding to dippount Coordination numb oe > ta womplen, central metal fons haw so types of valency Paks velen Secondary valeny — Oxidation Number | > ceorcnahon Wo, — lonisalle > Non lent able > Sokitied ay -ve Ugn-| > Satisfied by ~ve. ~amal ae HVE, as Well ay miubel a repuaented by Anitel | lgams nS Represonibed by selia hor Haponsible PY | anes. ponetry . S reiponsibre Fr oey Aatomaple ) Cott, .64,0 Ceo hp)Ja, * 34g No, Ceounox J? + sager 2) Cott ,. 5,0 Coe yor, t Sut, +249 — a y © scanned wtnonen Sane KS. ns mae 1 dome Lone ami at a bom 9 amd) 3 ae valency and pect represouta EAN we Atomic numbex) beh dotted and sotid Lines, metal borin lonplen sn ord, to 7 %- Colt, 6NHy acquies Sums te § C* as we Ciscid, 1G atomic no. 4 newt noble gas to (NK ee a . ra ° [EAN = Z-0S +2XCNel A t= tain Trani a ea “ eye OS Gq kyLFeteny) 5 \ CAN = 26-2 42X6 ms I le = 26-2412 2 3e follows EAN Coch, .4ni a atomic no. J cia.A Ceo cwugh tte] Oxidablen Satels 9 CMA my Cra >Coordincsian no. 4 6000 es ; ae @ Cn Codd Nay | x NAS 3D ganz 23-0 4264) Oo oO 2er8 = 36 ws EAN Axawbkak o- . 4 2. Cre cad Faited to tuplain colour, magnetic tigomd ‘amd lectsolytic Netti OF Complexes 5 lexer which protuces Tons ts Ut Soubien ack as Ultclyolyter anc conduck electric ty Conductana & mo. g Tons Conplence, nauuing ive ions GUdside He Coordination Sphinn veack ait, AgNO; te form silva Sate Complex "Ao, 64g Coty SNM dels. Yay Coll. 304, cays FE -24 200 = 3a-2+8 om (rot follows GAN) 3 Cpe CNM, I fan = 7g-24+8 = 34 (het fpllonean) 4. Ks Fe Cw > Ean= 264-3 + 216) = 35 (not fotows AW) Gpplicalions EAN. 4) Mo. % CO baxbonyt Carbone cont be Ni (to), follows EAM EAN = Z- 0S +2xK0M 40 = 26-94 2K Siu cz 2. Celtel) follows EAN D fans zros + 2KCN 3( 26-0 + 2Ky {* quoups) da Mid & predicted . (© seamed th oF Se 2. Ondidisi ut ud Reoluting | i igegee SY - a = = = 4. Canoe) 2 = 25-0 +12 von k = 3 igang ugands act as good RA as it welt C done 7N 7070 be stobte at 36 atm. ne- to reoltule. strength 4 gands © (ner guien in vet) Bo tutu %. Cvcor) To < ar onsite quelopped and for bylbid a) tei Thuse huptapih orbit de 05 <3 0-873 a oalapping fore Coorclinaly bend 4 ha p. occu ST no, hybulddianen gor | Witeut " 2 for -—< “4 y Tebrabedral = “— _ — Sqyote i = ‘aman | i Agana igen onn a weak Wong = Ce eho "peat no paiwig nogaon 2 pets | & Sarit tapes) @ Soe te Follow. gues bascd on ver oP — lLompleres involwes Sy Caan? ma Bet i inner osbi tals +y10)= = he affiliate x THOS Te tm onbivas tamper (A* ni i 2, ° (4 *%5p3, dep) na strong Ugansh S&P, exes LuVvotnt a ate = 7 i a 1, sia OO buke d- orbital idan a OT) Pour “Erbitold vowielll " Parag} ty ce - & > spam aie aig — relrabudee v4 feline) CI Col! Sue oO Bd % tte co © scanned wthonenSaner a. Fey Ode di) Creceny 7” fe = sdtus* Fe =ad® mith O OD 3d as up atte ee Jedidee 30k aei.6) & fe, > a2sp? Cinner Orbiectl lomplex — Octakrchat Chee > pao Momoyretre ii), Cwiady 3” Hr a-2 wee -24y neat? Ni + aol? Us* Ni sad? rele Bd Ps ow Uganal 3 a ad > pee a ae (Tepalaedwel) > Malate) (Ponamagnstic Te WO Clr chy I Wrqened ke te hs & weak Vgtue hance fo paliuiig ue BAN tw sd? F wll) me SY 7 7. (Tara badral — sp? Kay” | paseonaspetd © (wy Eni Cow Colello! “ep 2d ‘ NW on aa —dsp* — Squom plomor di tamagmttre (50 Wy or uy) Sd see eds e pe = bdd ys? y Pe =baé dsp> Liane wbieel Compe) A Wow plemen — Mamogune Wid Cee cu) 7* u-b=-3 Az67 m6 Fe = 3d! usr Ferl= 303 th wnak Ugewek Mo pauig Azo —> Spd (oukn orbital wupen = inl ° D > paaongoqatte © pus Isis =e. wily Emig a —nsptd* (ours opitel “ nety ite y3 Ge as Wit = gat Puny 8tcus RWS G = tie GA Wes ow Tue bes Gane Bae = = = = ieee. Cinats Obits eonyoux) BO (slong ae) Cee cen jyy* = == se 7b = actus! me PE = aa? parry occum = (ieee) ) fat & yO = oN NN =P — dep® Cond plauan) SF = damage feo = =e Exception Bi Cay?” goes = ‘ ented = Ca > 3d" 4s Dw aw? 5 os — sto tigand nA = pabing octus, of) i -_D> a Wlolv | Fa - a4 hy Ra Me ") Ld — 2 > Syyare plone ee Ponommayrtic Me Speen = SE 2. Salli) Com) J 2 w= th em re ah 4s’ DB oe ad? i NH, gy a Shon Ugandl = page -» GhhT-) GI Gh - BA}! fs I tp — dh*sp3 ., (inner orbital complex? pt deat — ped 3(342) 20s. iin) Cer (n0),97* Met? cre 3474s! | crit « 3AF yp — weak ligand 4 no pairing suk. Spratt (ube Orbital cong) uivy Ccotnng2,I** Com ad F4s* (o** + 3b? pairing octive NH, shong Ugenst em 9 4s ERED] op ‘oD — d*sp3 oh pt T5 (Patemapetic (v> mnoy Mn = 298 ust mitts 3a! — $p? or dés st fetraledral - SI. o Limitations_of V8T > Jalled '~ cuplain nuAs % amet . s a Bo Mot predicr Gyauti tative eikneanin q siti ¥ Compiler. ws Th involues mamy anumpbe- 2) pw not predit euat qeorety wr oovelimation Mot ¢2 — pode anol Spectral properse J onypler OU nok erap (alrrd © Scanned with OnE Scanoee CET (Crystal Field Theory) — propesed by Hans Bee amd Hasbrouck "Ven leek, > Ther a no sharing , trdnsforg e; no overttypping | orbitals vin bjw metal ant “ugamd. SF ually “gan ond mete ane womideud “2 point — daargen ome lta on bly them pwr ALN RUT C le OY, tganct * necttrat trum parbellg suely charged pare y Ugawol & auNaced dows mptol abense gq Ugamd, apt Che dorbinds J metal ane degencrared (how Seome emdyy) lout at a Ugaonel Spproaches Con, spitting a ol Debited tarts ple, Ais os cold Cer Shapes g -orbi ta duy dye den, In bfvo the axis olny dey = a om Fietd Splitting In Octabe- lex -orah Gn Oitanedroh vornpler, wt ty & Ugandl appear on Same canis as Fh gerd appreochan the Ont8 ihe tavegy g all dm crbieats inuucaser eppastlly Tae frruly spuitiy sakes pine, Nau col jomercte opi tals B02 CSE Bm On Lampe P > paying emery Dubos the Fourth etechron x ee > 9F bo - OLDE | at cn) bg eg [pes teeKl 9 Foeaa deus) [ots tome 9 Hea Arcus) | agi eg” |-oux ese aE iC aend a Uns) Sptea egy PS eaa: | dS (Hs) | igh eg 0-43 Ho€x2 3[0) At (Lsy Todxy #09 -24+2F aus) | tag ef [wwe re zea] de cus ee | dé Cus) tag? eg [exw hoges IURTH) ALFCLS)| eu. nee | a = eel Se A | af ces! bgh ef nouns co =[-24 +30] ans) ded ob 3 to4K3 ea | a tus] af of OTOH aig SEITE Yared a Us) | tag’ 9 FrORQETAM a dé | bag’ gt [-ouxe ro-exe as % 6,3 oie =| x | OENMOURS B= By 2 a 2_| bagieg? [cure sees ca _—a he a” by @ nouns $06x4 = [04 TT) a” XY 404K FA=L4 pat | oor ese | Loeystot Field splitting tn Tetrabedrl Conapsten. s 4, Tetroedial compte , lig anol 14 approaching tre CA from Yo He guy $0, me wmnetgy q these orbitas unk inoueses where lobe be bla Ae ames Who? Ne = mo. yf electrons tin € Orbital Me Ho. ge- dn te orbited he b pabeig wry Woe spin — Sony Uigamel —» prising Nigh spin > weak Hig arol =e - ely Lyyare Planar comple ane formes by rome! two ganas orn zany on Octabuctual “onnplta. | Now Onrrgey an orbitat: alory zon dials anol tnenyy 9 orautat along A amor, priacneasea, “, fl, Wy we, Squase J s dyn ~ Oclahasiral Uenplin Smo, eri order G eay https://t.me/Medicoinfinity +7 dun? der rdyerdcn f © scanned wthonen Sane hubs Vo fadors affediirg CASE 2 L Mature of cma A value P fom metab 3d —> yt us [ees @) oi Cr ody 7 Cre cen” Fet a $ Geometiy oF habe | bsp ptoh 2? ATA Dep 2130] fata Hae D = che a ' on = Octabudtal Th = Tebrabasleal 5. Cese x Bare stung ¢ ligand 4 hh, 2a A leaion. o ger tation 4 vompien can be enplatnede by f= of bids Hen for d-d transiian or’ a compler! tp enlastois unpaid © ey mut Ths unparid €- Mbrorbed Wits dae amen OH Fhawss vote volun Ht can tes > drwy aol Twamsltion @- seemmype Keon lower’ gt orbitad to Wgtsr © of orbital Gn ahswn 4g Uigamd » no splitting ¥ A- orbitad | becker place, he deel tyamare Oct, amd te Coloue ts Obsoued , mo Tha, > CT tor Us bate Miotet- usdy —B2— > wsay. 540 whicte Blue ters Stet tel tin ol- crbteat —> dor d-ol tamiten, be atleast cue €° Segegpli¢n = K,On0q KMney ) i co's s2 Mut? Sal” tags He + mekeul t Ugownst — ligtna +0 mead ange Comore | tangs won mene, ieee > Take place when mekod i tin Wigher Ob. he mesa howe orbieat ama lig ana havnt Sort ety 2° re- move from gana. do rested Faker get redeed ee nan merch get > Kemnay, ky or,02 09) Chapt) (orange) vo < EY [i + Dbrowest vole fig wml rove raph, m erbitel ana mural none pied d- orbital, a, ew , Gy, 20%, Buen, velemied if visible vagion ) (© seamed th oF Sane —> when one Ugonor sepltes one eiganct In case g ot amd al? ced bramsino do not occen but lonyplex May be Colowad tu te charge wenger » uctronic Coniston, CSP BESS & Crew) “4 A+oen nate Fe adbuss Fett saat CN Stvong Ugand, ‘ow SP, ee [10) tag “4 (oT) 3. Mage othe Natun un patickol oh if wo nb + Riamnagestre Conay PRUUEGLUGLUUU GLUE ENN Sd see e es yen Wolorr qf vompiex Conger cont tut > Paramagne| 'gQ “a A dhe tellewing m dec. order a { wWamelon gts tuferbed. A @ Ceo, T? () Cooto)I? Cuan, yt te Citron 2" “| ©) Croton]? (a) Ceo lo), te nagar bat n 43 Twice te (higem, co, ©) Cound Wiee” dank blue | 1 7% >Phzrem ON < (ay 7 (dy 22) 2@) 206) Di linitetions_ of _ CFT — Hwa — Uganda molecules aA Ve ee rot ‘appropriate because vn Oase netrad Uigands thks no amd MG, Fo shoul be 4 stronger Ugewel as ot a -moce Polar, but at Meee — a dow not stake anything abouA 7 bondtigg om. Geomupter + & condos metah Brom as Vey changed paride ur to on Same cues 0 which Ke O. state gq metal ty 2040 Bonding IN METAL CARBON, Ce A Organam tellie “nyo lompocurels Wouting Cleon mere bonel catthon “ metalicid borat A: Idenrity the Orgamometaeei a7 D Ring x DCU), 2H 1 4) si Coty —— ) mien), 5) Kali — 6) 606%), X Boron 9 my 9) BO, AA Bove” 8) COMsAyPb — 9) Lich, i Ceasi eatin _T4pes ee meee, [Syomebeutcat aU organic womp Ablacad “arith Muley or Yes [Zens prametelcaly re ee 4 Jann = Teller Yfeue Te Oledses due Ww Uneg nel Aishi buHen of ena bag ancl ty Orbital Sock Bund SM bien Fs Weprmatid! 1p ie Wo seven i danqoue™ sq“ ei bwin 2 fia mae by orbitas (ode “ei egy Qe — md" am ai == 2 « a # ators) ais a ws) re Psy Pas datacteed! «tis ‘© samedithonen sare enn w> En(eh), J 3 Biese’s Gott 7 go Tl, we k (eba, (n° 44D of | nN or bonded 2 boned RN ZL Sou: sy, Sperone] ) Sigma bonded Ds] Bamagnt « Mantle ~ d mee Mm! 5 bonded Org anemttalll: FE and x Bonds » Examples of — Sigma bonds Orgautyn | cm te ta , a , cmn ligand nord’ Kg x Chuignasl Reagent) | gen donb ag Vee Chi: Se rates Sap eee a | The m-o & bonds a formed by he fk forme Free (eal leak poisoning Zeigler Masta. Cabalyst . LR, At. icky) Bo atky alumina’ im Titanium bebraclileride 3 4. Wilkingon » Catalyst Cop, spnod This tui phanyt pros; s. Reubi - Gilman's Reagent corny eure sypltenis 2) A= bended complexes *- 1 Pelsocens [he (4? (oss, J] &? fe ttps://t.me/Medicoinfinity 2. Dibenzen Clucomi win [te tat (Gh)] & iphire KRhooli wm cds elutkrons | Vlaneuion vF tone Pur B caton vile on be Mize hls Orblent ap He) etm. = tn at, & pe Smet % of a par 6 lt eth orbits ree vacant xt Orbital | Catiben tne donation Cleutrons Om 4 . aiibon dey mono nds, > Te metal Ug a syangic oe Hee ‘bond pelle mete. and bonding Onentes cauieh Slreng than co ome maa eo tan Arttbondi'f orb) tals, Borel Oreler a 0. BO x Bond strength %J— Bonet sgt om «KS B04 co Keve ost ie KL os. he — 9 no. molecular dieveases Aighes Ma dlonatton 4 Os 6-0 bond Sbengen i oto. jn? ) Cv] ° . () Cric@r,3* ©) Concur) (a) [ma (eos? © scanned wtnonenScanser D> camp > high the omen Ceacorney ! wine Ost, Bo fie g Beshery @ (rans Stability of Complen 4 Stability < Formation lonstaut or Stability constout ye ‘ Ter Stepwise Oval Stecbiti hy Salpollty constact lonateul mee ln) me Ne PTL yak qe ly Mote CML) Ke om 6 | GuFeed —m, —6 WLUW UE U EDD d seo a oS Matt k= Lines) cm J09 Muy te —S My Tm? —() cmy3Cu9 LEGG ay Ki 7K 7 Ky? Ky disouakKin tonsa / Basra, ree (Stability corgh 2. htability « te OS of CMA ed Sigeo# muttat jon % Strength 4) ligand 3 dutote Uganas forms more Stable lompuen, ] - Ceol) I? — Coolen),J”? MN, on Pay on iy en Sm BE LEI neo uigands J tnerepy ' Stabiity * 4 Maveeylle 2 JE gant 2 cycle Wom het ‘ak Ferma Stalste omplon. ortamce abd Licaliore. Coontination Compounds. wn and estimation gf metal fearive and j ka analy can be done Farrar colour! reattons uu 0 Mo. 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