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Multiple Choice Questions: Worksheet Thermodynamics

This document contains a worksheet on thermodynamics for class 11 with multiple choice questions and short answer questions. Some of the multiple choice questions ask about criteria for spontaneity of processes in terms of changes in enthalpy, entropy and Gibbs free energy. Other questions ask about changes in internal energy, enthalpy and entropy for different chemical reactions and phase changes. The short answer questions ask about signs of various thermodynamic quantities for different reactions, calculation of enthalpy and entropy values, and determination of temperature and conditions for spontaneity.

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231 views3 pages

Multiple Choice Questions: Worksheet Thermodynamics

This document contains a worksheet on thermodynamics for class 11 with multiple choice questions and short answer questions. Some of the multiple choice questions ask about criteria for spontaneity of processes in terms of changes in enthalpy, entropy and Gibbs free energy. Other questions ask about changes in internal energy, enthalpy and entropy for different chemical reactions and phase changes. The short answer questions ask about signs of various thermodynamic quantities for different reactions, calculation of enthalpy and entropy values, and determination of temperature and conditions for spontaneity.

Uploaded by

Shashwat
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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DELHI PUBLIC SCHOOL BANGALORE NORTH(2022– 23)

Worksheet
Thermodynamics
CLASS : XI

Multiple choice questions


1. The process is spontaneous at given temperature if
a. ∆H is +ve and ∆S is –ve
b. ∆H is -ve and ∆S is +ve
c. ∆H is +ve and ∆S is +ve
d. ∆H is +ve and ∆S is zero

2. Considering entropy(S) as a thermodynamic parameter, the criteria for the spontaneity of


any process is:
a. ∆S system + ∆S surrounding>0
b. ∆S system + ∆S surrounding<0
c. ∆S system>0
d. ∆Ssurroundings>0

3. The change in entropy of an ideal gas during reversible isothermal expansion is:
a. Negative b. positive
c. Zero d. infinity

4. The internal energy change when a system goes from state A to B is 40kJ/mole. If the
system goes from A to B by a reversible path and returns to state A by an irreversible
path what would be the net change in internal energy?
a. >40 kJ/mole b. <40kJ/mole
c. zero d. 40kJ

5. For the reaction C(s) + O2 (g) CO2(g)


a. ∆H > ∆U b. ∆H < ∆U c. ∆H = ∆U

6. The value of ∆H and ∆S for the reaction:


C( graphite) + CO2 (g) 2CO (g) are 170kJ and 170JK-1 respectively. The
reaction will be spontaneous at
a. 910 K b. 1110k c. 510 K d. 710 K
7. When 1 mol of a gas is heated at constant volume, temperature is raised from 298K to
308K,heat supplied to the gas is= 500J.Which of the statement is correct?
a. q=W=500J, ∆U =0
b. q =∆U=500J, W=0
c. q=W=500J, ∆U=W=0
d. ∆U=0, q=W=-500J
8. An endothermic reaction is allowed to take place rapidly in air.The temperature of the
surrounding air will
a. Increase b. decrease
c. Remain unaffected d. May increase or decrease
9. For the reaction 2Cl(g) Cl2 (g),the sign of ∆H and ∆S respectively are:
a. +,- b. +,+
c. -,- d. -,+
10. A chemical reaction is spontaneous at 298 K but non spontaneous at 350 K. Which one of
the following is true for this reaction?
∆G ∆H ∆S
a. - - +
b. + + +
c. - + -
d. - - -

A statement of assertion is followed by a statement of reason. Mark the correct


choice from the options given below:
(a) Both assertion and reason are true and reason is the correct explanation of assertion.
(b) Both assertion and reason are true but reason is not the correct explanation of assertion.
(c) Assertion is true but reason is false.
(d) ) Assertion is false but reason is true
(e) Both assertion and reason are false.

11. Assertion: The heat absorbed during isothermal expansion of an ideal gas against
vacuum is zero
Reason: The volume occupied by the molecules of an ideal gas is zero.

12. Assertion:∆H and ∆U are same for the reaction N2(g) + O2(g) 2NO(g)
Reason: All reactants and products are gases.

13. Assertion: For every chemical reaction, at equilibrium ∆Go is zero


Reason: At constant temperature and pressure chemical reactions are spontaneous in the
direction of decreasing Gibbs energy

14. Assertion : As the solid changes to liquid and then to solid state and then to vapour
state , entropy increases
Reason: As the solid changes to liquid and then to solid state and then to vapour state,
disorderness increases

15. Assertion: Combustion of all organic compounds is an exothermic process


Reason: the enthalpies of all elements in their standard state are zero

Answer the following questions


16. A reversible reaction has ∆Go negative for forward reaction? What will be the sign of
∆Go for backward reaction?

17. When is the entropy of a perfect crystalline solid zero?

18. What is the the value of enthalpy change (∆H ) for the reaction:
CH4 (g) + 2O2(g) CO2(g) + 2H2O(l) .The value of change in internal energy for the
above reaction at 298K temperature is -885kJ mol-1.
19. Give reasons:
(i) Equilibrium constant (K) of a reaction is one or more if ∆rGo for it less than zero.
(ii) Dissolution of ammonium chloride in water is endothermic still it dissolves in water.
(iii) Bond energy of all the C-H bonds in CH4 are not equal.
(iv) Absolute value of internal energy cannot be determined.
(v) Many endothermic reactions which are nonspontaneous at room temperature become
spontaneous on raising the temperature.

20. What would be the work done on/by the system if the internal energy falls by 100 joules
even when 200J of heat is supplied to it?
21. Calculate the energy required to raise the temperature of 10.0g of iron from 25oC to
500oC if specific heat capacity of iron is 0.45J( oC)-1g-1.

22. Calculate the enthalpy of formation of methane, given that the enthalpies of combustion
of methane, graphite and hydrogen are 890.2kJ, 393.4 kJ and 285.7kJ mol-1 respectively.

23. Ethylene on combustion gives carbondioxide and water. Its enthalpy of combustion is
1410.0kJ/mol. If the enthalpy of formation of CO2 and H2O are 393.3kJ and 286.2kJ respectively,
calculate the enthalpy of formation of ethylene.

24. The thermite reaction used for welding of metals involves the reaction:
2Al (s) +Fe2O3 (s) ---→ Al2O3 (s) + 2Fe(s).
What is the ∆Ho at 25oC for this reaction? Given that the standard heats of formation of Al2O3
and Fe2O3 are -1675.7kJ and -828.4kJ mol-1 respectively.

25. Calculate the enthalpy change for the reaction: H2(g) + Cl2(g) ————-> 2HCl(g). Given
that bond energies of H-H, Cl- Cl and H-Cl bonds are 433, 244 and 431 kj mol-1 respectively.

For the reaction Ag2O (s) --→ 2Ag(s) +1/2 O2(g) ∆H is 30.56kJ mol-1 and ∆S is 66JK-1mol-1 at
one atmospheric pressure. Calculate the temperature above which the reaction is spontaneous.
which ∆G for it will be zero. What will be the direction of the reaction at this temperature and at
temperature above or below this temperature and why?

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