M A T C h e m i s t r

y
OCTOBER
2020

BY P’GOFT IGNITE BY ONDEMAND

นองๆ สามารถดูคลิปไดที่นี่

PA R T 1 PA R T 2
 Chapter 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 Total Introduction
Stoichiometry 1 2 1 2 1 2 3 2 1 2 1 1 2 2 2 3 28
Fundamental 2 1 1 1 1 3 2 2 1 1 1 16
Chemistry
7 questions 1 min per question
Boost Up BMAT Chemistry 2020

Periodic Table 1 2 1 1 3 1 1 2 1 1 1 1 16
Organic Chemistry 1 2 1 1 2 1 2 1 11
Atomic Structure 1 2 1 1 1 1 1 1 1 10
Rate of Reaction 1 1 1 1 1 2 1 1 1 10
Chemical Bonding 1 1 1 1 1 1 1 1 8
Electrochemistry 1 1 2 1 1 6
Thermochemistry 1 1 1 3
Chemical 1 1 1 3
Equilibrium
Acids and Bases 1 1 1 3
BMAT Chemistry Question Trend (2003-2019)

Solution 1 1 2
Experiment 1 1 2
Total 6 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 118
 4

Matching chapters with BMAT test specification

Chapter Specification related to Chapter

Fundamental Chemistry C3, C17
Atomic Structure C1
Periodic Table C2, C7, C14
Chemical Bonding C6
Stoichiometry C4
Solution C4.9
Rates of Reaction C10, C15
Thermochemistry C11
Chemical Equilibrium C3.5
Acids and Bases C9
Electrochemistry C5, C12
Organic Chemistry C13
Experiment C8, C16
 5

Fundamental Chemistry (C3, C17)

Bond Types

Metal + Metal = Metallic Bond

Metal (or NH 4 ) + Non-metal = Ionic Bond
+

Non-metal + Non-metal = Covalent Bond

Chemical Formula
ionic only one formula covalent more than one formula
K
+
S
2-
K2S C+O CO N+O NO
CO2 NO2
Na PO Na3PO4
+ 3-
4
CO 2-
3
NO -
3

transition more than one formula

Fe Cl- FeCl2
2+

Fe3+ Cl- FeCl3

Pure Ionic VS Ionic with Covalent

pure ionic metal + non-metal    KCl, Na2O
ionic with covalent has NH +4 , OH- or oxo anion CaCO3, NH4Cl, Na2SO4

Chemical Equation (ionic + ionic)

1) Write reactants
2) Write products by switching ion
3) Balance equation by adding numbers to
atom in reactant  =  atom in product
*Tip for balancing equation
Balance the elements at last
C3H6 + O2 CO2 + H2O
balance this one at last

C3H6 + 29 O2 3CO2 + 3H2O

if the question said “lowest whole-number”, you need to adjust number to be integer.

2C3H6 + 9O2 6CO2 + 6H2O

 6

Basic Chemical Equation (that you should know)

• Metal + Acid Hydrogen
E.g. Zn + H2SO4 ZnSO4 + H2

• IA + H2O Hydrogen
E.g. 2Na + 2H2O 2NaOH + H2

• IIA + H2O Heat Hydrogen

E.g. Mg + 2H2O Mg(OH)2 + H2

• Neutralization [Acid + Base Salt + Water]

E.g. H2SO4 + 2NaOH Na2SO4 + 2H2O

• Reaction with carbonate

E.g. H 2 CO 3 H 2 O + CO 2
2H+ + MgCO3 Mg2+ + CO2 + H2O
2H+ + Mg(HCO3)2 Mg2+ + 2CO2 + 2H2O
NaHCO 3 + HCl NaCl + H 2 O + CO 2
CaCO 3 + H 2 SO 4 CaSO 4 + H 2 O + CO 2
CaCO 3 Heat CaO + CO 2
 7

Atomic Structure (C1)

Nuclear Symbol
Mass number p+ + n Isotope p+ same element
A !
Z
X can find e- Isotone n
Atomic number p+ Isobar mass number
Isoelectronic electron not the same element
different charge

Electron Configuration

Rules: Step up & down the ladder

1) Step up first. If you cannot
32 32
step up, should step down.
18 18
Can stay only 2) You cannot stand at each step
8 8 two times more than 2 times.
2 2
The number is maximum of electron ** Cannot use this method for
“Transitions”

• Position of each element in periodic table

2nd period
F = 2, 7
9
Group VIIA
3rd period
11
Na = 2, 8, 1 Group IA

• Electron structure of ion

9
F = 2, 7 9F- = 2, 8
11
Na = 2, 8, 1 11Na+ = 2, 8
 8

Periodic Table (C2, C7, C14)

Properties of Element
EN
IE, Non-metallic character

Atomic radius, Metallic character

Main-Group Elements Math-Group Elements

metals

earth metals

Noble
Alkali

gases
Halogens
Alkaline

1 18
IA VIIIA
1 2 13 14 15 16 17
IIA Transition Metals IIIA IVA VA VIA VIIA
2 3 4 5 6 7 8 9 10 11 12
3 IIIB IVB VB VIB VIIB VIIIB IB IIB
Period

4
5
6
7

Inner-Transition Metals
*Lanthanides
**Actinides

- The elements are arranged in order of increasing atomic number.

Reactivity of Element
• Metal increases down the group
• Non-metal decreases down the group

Extraction of Metals (in ore)

Ores are mostly oxide of the metal and extraction of metals is reduction process.

Metal oxide (in ore) reduction metal

Example: the extraction of lead from lead oxide
lead oxide + carbon lead + carbon monoxide
  PbO +    C  Pb + CO
 9

Chemical Bonding (C6)

Intermolecular Force VS Intramolecular Force

Intramolecular force (strong force)

Metallic bond
Ionic bond
Covalent bond

Intermolecular force (weak force)

London dispersion force
Van der Waals
Dipole-dipole force
Hydrogen bond (H-bond)

Types of Bonds and Properties

Metallic bond = Metal + Metal

Ionic bond = Metal, NH +4 + Non-metal
Covalent bond = Non-metal + Non-metal
Giant structure = C, SiO 2

Properties Metals or Alloys Ionic Covalent Covalent

Compounds Compounds Network
Mostly solid Solid, liquid, and
State Solid Solid
except : Hg gas
Melting High Usually low
points and Usually high but less than (depended on Super High
boiling points metal molecular mass)
Only when Most are
Electrical molten Poor insulators
conductivity Good or dissociate in except for acids except for
water graphite (C)
Solubility in Only polar
No Usually yes No
water molecules
 10

Stoichiometry (C4)
Relative Atomic Mass (Ar)

Average atomic mass = %1 × (atomic mass) 1 + % 2 × (atomic mass) 2 + ...

Mass Spectrum Graph

Mass spectrum of chlorine, Cl2
Isotopes Cl-35, & Cl-37 Molecules Cl2-70 Cl2-72 Cl2-74

relative
abundance

10 20 30 40 50 60 70 m/z

Mole Concept

mol = mass
MW = N = V24 RTP(L)

6.02 # 10 23

* Be Careful!!
If the molar volume of gas at room temperature and pressure is determined by
24 dm3 instead of 22.4 dm3.

Percent Composition
% = nMW # MW of element
of molecule 100
#

Empirical Formula & Molecular Formula

calculate fraction of mole by: mass mass % %

MW : MW or MW : MW
Molecular formula = (Empirical formula)n
E.g. C6H12O6  = (CH2O)6
 11

Relationship in Chemical Equation

2A + B " 3C
mol A molB mol C
= = 
2 1 3
mol is the time of reaction that occured
coeff.
However, time of reaction should be equal, no matter which compounds we calculate.
mol mol
` coeff. = coeff.

Limiting Reactant
E.g. 2A + B " 3C
5 mol 3 mol ??

1) Find limiting reactant 2) Find product use limiting If question asks about remaining of
reactant for calculation B, you need to calculate reacted B
mol A mol B
mol = mol mol = mol
2 1
2
A
3
C
2
A
1
B

Time of reaction occurs 5 = mol C 5 = mol B

2 3 2 1
5= 3=
2 2.5 1 3 7.5 = mol C mol = 2.5
B

The least one is limiting reactant. This one is reacted

` so, remaining
B = 3 - 2.5 = 0.5 mol
 12

Percent Yield
Given
Actual yield # 100
% yield = Theoritical yield
Calculated

Percent Purity
pure subtance # 100
% purity = impure substance

Stoichiometry of Gas
When temperature and pressure are constant,
V \ n
coefficient in equation

2A(g) + B(g) " 3C(g)

molA : molB : molC = 2 : 1 : 3 only molecules that
** VolumeA : VolumeB : VolumeC = 2 : 1 : 3 ** react in reaction
 13

Solution (C4.9)
Concentration
M = mol
V × 1000 MV
mol = 1000

Dilution

+ =

more sweet less sweet

(8 molecules of sugar) = (8 molecules of sugar)

molinitial = molfinal
M1 V1 MV
= 2 2
1000 1000
M1V1 = M2V2
* Be careful!! : V2 is volume of solution, not the added water

Acid-base Titration

Trick! If the question gives both acid and base in term of solution
From acid From base

Because, 1H+ + 1OH- " H2O

Then, mol H+ = mol OH-
a MaVa = b Mb Vb
1,000 1,000
a MaVa = b Mb Vb

a, b are the number of H+ or OH- in acid or base
 14

Rate of reaction (C10, C15)

Reaction Theory
normally use concentration
rate = substance change =
time change
T[ ]
Tt

Collision Theory
Reactions occur when
1) particle collide with each other
2) sufficient energy
3) correct orientation

Activation Collision Proportion of Total molecule

energy (Ea) frequency molecule with E ≥ Ea with E ≥ Ea
Concentration - Greater - Greater
Surface area - Greater - Greater
Temperature - Greater Greater Greater
Catalyst Reduced - - Greater

Phase Change

TH+ (Endothermic)
Sublimation
Melting Vaporization
Solid Liquid Gas
Freezing Condensation
Deposition
TH- (Exothermic)

A change in phase relates to the bonding and structure (intramolecular force or intermolecular force)
 15

Thermochemistry (C11)
Sign of Heat
Endothermic TH + break bond
Exothermic TH - form bond

Heat in Reversible Reaction

exothermic
In equilibrium    A + B endothermic C + D + TH

Heat of Reaction Calculation

Heat of reaction can be determined from bond energies.
TH rxn = R ]TH's bond brokeng - R ]TH's bond formedg
Energy required Energy released

Positive Negative

Energy Diagram
• Forward reaction
A + B  "   C Exothermic ( TH-) A + B  "   C Endothermic ( TH+)

Activation energy
Ea Activation energy Ea C
Energy
Energy

A+B A+B
TH TH
C
Reaction coordinate Reaction coordinate

With Catalyst reduce Ea but energy of reactant and product are the sam
TH not change
Energy

E' a   1 Ea
A+B Ea E' a

C
Reaction coordinate
 16

Chemical Equilibrium (C3.5)

Definition
- Dynamic equilibrium (The reactions still proceed but the concentrations remain constant)
- Equilibrium 1) Reversible
2) Rate of forward reaction = Rate of reverse reaction

Graph
Concentration VS Time Rate VS Time
[] Constant Rate
Must be equal

Time Time
Concentration is not necessarily equal Rate of forward reaction = Rate of reverse reaction

Le Chaterlier’s Principle
Concentration Opposite site of change
-
Pressure & Volume P - or V Fewer mole
-
P or V - More mole
Temperature T \ K1 (Exothermic reaction) Treat T H as
T \ K (Endothermic reaction) substance
 17

Acids and Bases (C9)

• Strong acids and bases
Strong acids :  HCl, HBr, HI, HNO3, H2SO4, HClO3, HClO4
Strong bases :  LiOH, NaOH, KOH, Ca(OH)2    IA, IIA + OH -
None of these is weak acid and base.

• Diluted and concentrated

Diluted :  a small amount of solute in a large amount of solvent
Concentrated :  a large amount of solute in a small amount of solvent

• Acids reaction with metal

Acid + Metal Carbonate "  Salt + Water + Carbon dioxide
E.g. HCl + CaCO3 " CaCl2 + H2O + CO2
Acid + Metal Hydroxide "  Salt + Water
E.g. HCl + NaOH "  NaCl + H2O
Acid + Metal Oxide "  Salt + Water
E.g. 2HCl + ZnO " ZnCl2 + H2O

• Neutralization
acid  +  base  " salt + water   ; TH -
Neutralization is an exothermic reaction.
Example: HCl  + NaOH " NaCl + H2O    ; TH -
 18

Electrochemistry (C5, C12)

Redox Reaction
Change oxidation number
Redox = Reduction + Oxidation
reduce oxi no. increase oxi no.
gain electron lose electron
oxidizing agent reducing agent
reduced agent oxidized agent

+7 +4 +6
E.g. MnO 4- + SO 2-3 " Mn 2+ + SO 2-4
Mn +7 Mn +2 oxidizing agent reduction
S +4 S +6 reducing agent oxidation

Auto-redox Reaction/Disproportionation
Oxidizing and reducing is the same element
Oxidized

2CuCl " CuCl2 + Cu

+1 +2 0

Reduced

Oxidizing Form VS Reducing Form

Metal Non-metal
M+ oxidizing X2 oxidizing
M reducing X- reducing

E0 : IA < IIA < IIIA < Zn2+ < Fe2+ < Pb2+ < H+ < Cu2+ < Ag+ : reaction occurs when E 0
oxidizing >E 0
reducing
 19

Displacement Reaction
• Metal
Metal displace when the solid metal has reactivity more than the metal ions.
Metal reactivity: IA > IIA > IIIA > Zn > Fe > Pb > H > Cu > Ag

K  Na  Ca   Mg   Al   Zn

Tips! Please  stop  calling  me  a  zebra.
It’s  totally  like  hating  cool  smart  guy.
Fe  Sn   Pb  H   Cu  Ag  Au
(Iron)   (Tin)   
(Lead)   (copper)   (silver) (gold)

• Non-metal
Halogen reactivity: F2 > Cl2 > Br2 > I2
Halogen displace when X2 has more reactivity than X-.

K Cl + F2 KF + Cl2      Reaction occurs.

K F + Cl2       Reaction does not occurs.

Cathode VS Anode Galvanic VS Electrolysis

Cathode Reduction Galvanic : chermical electrical
Anode Oxidation Electrolysis : eletrical chemical
 20

Electrolysis
1. Molten with inert electrode
e- e-
+ -

B- A+

Cathode : A + + e - " A
Anode : B - " B + e -

2. Solution with inert electrode

e- e-
+ -

H2O H2O
B-
A+

Cathode : A+ and H2O select the better one in gaining electrons

2H 2 O + 2e - " H 2 + 2OH -  : H 2 O gains e - H2O gains e- better
Compare with A + + e - " A         than Group IA, IIA, IIIA

Anode : B- and H2O select the better one in giving electrons

2H 2 O " O2 + 4H + + 4e -  : H 2 O gives e - Most of metals give e-
Compare with B - " B + e - better than H2O
 21

Electroplating (with active electrode)

Voltage
source
e -
e-

Ag+
Silver Spoon
(anode) Ag+ (cathode)
AgNO3(aq)

Anode : metal that will form plating

Ag (s) " Ag + (aq) + e -
Cathode : the part that needs to be plated spoon
Ag + (aq) + e - " Ag (s)
Solution : contain metal ion of anode
Power source : DC
 22

Organic Chemistry (C13)

Hydrocarbon
Type Suffix General Bonding Saturation
Alkane -ane CnH2n+2 All single Saturated
Alkene -ene CnH2n 1 double bond Unsaturated
Alkyne -yne CnH2n-2 1 triple bond Unsaturated

Polymerization
• Adding polymerization
H H H HH HH H H H
n C C C C C [ C C [n
C C C
H H H HH HH H H H
Ethylene Polyethylene
• Condensation polymerization
Polyamide O
HO2C NH2 heat NH2
CO2H + H2N -H2O HO2C N
adipic acid hexamethylene diamine H

repeat
O H O H
N N N N Nylon 6,6
O H O H
repeating unit

Reaction of Organic Compounds

Decolorization
• Alkane

+ Br2 No reaction
Br
light
+ Br2 + HBr

• Alkene
+ Br2 Br Br

• Alkyne Br Br Br
+ Br2 + Br2
Br
Br Br
 23

• Benzene

+ Br2 No reaction

FeBr3 Br
catalyst
+ Br2

Cracking
H H H H H H H H H H H H H H
heat H
H C C C C C C C C H catalyst
H C C C C C H + C C C H
H H H H H H H H H H H H H H H H
long-chain alkane shorter alkane alkane

Big molecule Small molecules

*** can also produce H2

Oxidation / Reduction
• Oxidation increase O, reduce H

OH
O
OH H

• Reduction increase H, reduce O

OH
O
H OH

Esterification
R'COOH + ROH " R'COOR + H 2 O

Reaction of alcohol with Sodium

R–OH + Na " R–O-  Na+ + H2
 24

Experiment (C8, C16)

Gas testing
- H2 can be burnt and poping sound Testing with wooden splint
Delivery tube
Stand Burning of hydrogen
gas with a pop acured
Test tube Cundle
Dzute Hydrogen
sulphuric acid gas
bubbles Soap bubble filled
Zinc gramules with hydrogen

Soap solution

Popping sound
Photo : http://aimeesciencebruh.blogspot.com/2015/04/
tuesday-28-april-2015-today-we-did.html

- O2 helps for burning

Inverted
gas jar
Burning
candle Candle
stops Relights a Glowing
burning Splint

Photo : https://www.scribd.com/document/396809364/
Oxygen-Experiment Relight the flame

- CO2 reduce O2, extinguish the flame

Photo : https://qph.fs.quoracdn.net/main-qimg-1155 Extinguish the flame

cdb7712811817f194faf2661ee93-c

- Cl2 blue litmus paper turns red then bleaches

Litmus paper
Blue
Test solution Red
Bunsen burner White
 25

General Seperation Technique

• Paper chromatography
Piece of wood
Pin Solvent front
Paper Move fast Soluble in
solvent very well
Beaker Move slow A little bit soluble
Original spot of in solvent
sample mixture Original spot of
sample mixture
Solvent Solvent Sample
Start End mixture

• Distillation
Thermometer
Distillation flask
Clamp
Cooling water
Steam
Condenser
Salt water
Water out Condensed water
Bunsen burner
Water in
Clamp stand Receiving flask

Distilled water

• Crystallization
Fluted filter paper
Soluble
solid in Hot saturated solution
solution
Crystals of
soluble solid

Evaporation Filtrate Crystallisation

• Centrifugation

Before After
Supernatant
Pellet

Rapidly rotating rotor

 27

Full Test Set I

1. Which of the rows identify the incorrect products of electrolysis of the following electrolytes?

electrolyte being product at positive inert product at negative inert

electrolyzed electrode (anode) electrode (cathode)

(A) NaSO4 in water Oxygen Hydrogen

(B) AgNO3 in water Nitrogen gas Silver metal

(C) Molten NaCl Chlorine gas Sodium metal

(D) H2SO4 in water Oxygen gas Hydrogen gas

(E) CuSO4 in water Oxygen gas Copper metal

2. Which of the following atoms/ions contains(s) exactly 16 neutrons and 18 electrons?

1 32
16 S 2-
2 35
17 Cl -
3 40
18 Ar
4 28
14 Si
5 31
15 P 3-

(A) 3 only
(B) 1 and 2 only
(C) 1 and 5 only
(D) 2 and 4 only
(E) 2 and 5 only
(F) 4 and 5 only
(G) 2, 4, and 5 only
(H) 1, 2, 3, and 4 only
 28

3. A piece of zinc ribbon is dropped into a beaker of dilute aqueous sulfuric acid at room
temperature. After a while, the production of bubbles of the gas slows down.

Which of the following statements is/are true?

1 The activation energy for the reaction decreases.

2 The reaction rate will decrease when the temperature is increased.
3 The concentration of sulfuric acid decreases.
4 If the zinc metal exists as a powder, the reaction would be faster.

(A) None of them

(B) 1 only
(C) 4 only
(D) 3 and 4 only
(E) 1 and 4 only
(F) 2 and 3 only
(G) 2 and 4 only
(H) 1, 3, and 4

4. Disproportionation is the simultaneous oxidation and reduction of the same species in a reaction.

In which of the following chemical equations does disproportionation occur?

1 CH4 + 2O2 → CO2 + 2H2O

2 2KClO3 → 2KCl + 3O2
3 Cl2 + 2OH- → Cl- + ClO- + H2O
4 CuS + O2 → Cu + SO2
2-
5 3CrO 3-
4 + 8H → 2CrO 4 + Cr
+ 3+
+ 4H2O

(A) 2 only
(B) 2 and 4 only
(C) 3 and 5 only
(D) 1, 4, and 5 only
(E) 2, 3, and 5 only
 29

5. Propanoic acid is a monoprotic acid.

H H O
H C C C
H H OH

It can act as an acid when reacting with lithium metal. Which of the following chemical
equations is correct for the reaction between lithium metal and propanoic acid?

(A) 2C3H6O2 + Li2CO3 → 2Li(C3H5O2) + H2O + CO2

(B) C3H6O2 + Li2CO3 → Li2C3O2 + CO2 + 3H2O
(C) 2CH3CH2COOH + Li2CO3 → 2Li(C3H5O2) + H2O
(D) 2C2H5COOH + Li2CO3 → Li(C2H5COO) + H2O + CO2
(E) 2CH3COOH + Li2CO3 → 2Li(CH3COO) + H2O

6. Hydrated zinc(II) sulfate has the formula ZnSO4 ·7H2O.

400 cm3 of a solution contains 57.4 g of hydrated zinc(II) sulfate.

What is the concentration in mol/dm3, of this solution?

(Ar values: H = 1; O = 16; S = 32; Zn = 65)

(A) 0.050 mol/dm3

(B) 0.100 mol/dm3
(C) 0.200 mol/dm3
(D) 0.400 mol/dm3
(E) 0.500 mol/dm3
(F) 0.800 mol/dm3

7. What is the volume of the hydrogen gas formed (measured at room temperature and standard
pressure) when 0.78 g of pure potassium reacts completely with an excess of water and
produces potassium oxide and hydrogen gas as products?

(Ar values: H = 1; K = 39. Assume that the molar volume of gas at room temperature and
pressure is 24 dm3.)

(A) 0.24 dm3

(B) 0.36 dm3
(C) 0.48 dm3
(D) 0.96 dm3
(E) 1.20 dm3
 30

Full Test Set II

1. Which of the following statements for the atom, X, describe the most reactive metal?

(A) Electronic configuration is 2, 8, 1.

(B) It is an alkali earth metal.
(C) This atom does not react with water.
(D) The formula of its oxide is X2O3.
(E) The reactivity decreases with the increase of the atomic radius.

2. How many millilitres of 0.45 M hydrofluoric acid are needed to react with 15 mL of
0.225 M Ca(OH)2?

2HF (aq) + Ca(OH)2 (aq) → CaF2 (aq) + 2H2O (l)

(A) 4.00 mL
(B) 6.00 mL
(C) 9.00 mL
(D) 15.00 mL
(E) 20.00 mL

3. The reaction specified below is at its equilibrium point:

P(g) + 3Q(g) ? R(g) + 2S(g) ΔH is positive

Which conditions (A-E) would produce the highest amount of product S?

Temperature Pressure P Q Catalyst

(A) High High Add Remove Present

(B) Low Low Add Remove Absent

(C) High Low Remove Add Present

(D) High High Add Add Absent

(E) Low High Remove Remove Present

 31

-
4. From the reaction: I2(s) + 2S2O 32- (aq) → 2I (aq) + S4O 62- (aq)

-
1 I2(s) is reduced into I (aq).
2 I2(s) is a reducing agent.
-
3 S2O 32 (aq) is an oxidizing agent.
4 The oxidation number of sulfur does not change.
5 The oxidation number of oxygen changes.

Which of the above is correct?

(A) 1 only
(B) 2 and 3 only
(C) 1 and 5 only
(D) 1, 4 and 5
(E) 2, 3 and 5
(F) 3, 4 and 5

5. How many grams of Na2SO4 would be produced when 98 g of H2SO4 reacts with 40 g of
NaOH?

(A) 18 g
(B) 36 g
(C) 71 g
(D) 142 g
(E) 150 g
(F) 162 g
 32

6. Unknown element X+ has the electronic structure 2, 8, 8. Which of the following statements
about this element is/are correct?

1 This element is an alkaline earth metal, period 4 of the periodic Table.

2 An oxide compound of this element has the formula X2O.
3 The element X is a noble gas.
4 The atomic number of this element is 19.

(A) 1 only
(B) 3 only
(C) 1 and 2 only
(D) 2 and 4 only
(E) 1, 2 and 3 only
(F) 1, 2 and 4 only

7. Which of the following organic compounds will decolourise bromine water by reacting with it at
room temperature?

1 Benzene
2 Cellulose
3 Polyacetylene
4 Polyethylene

(A) 1 only
(B) 2 only
(C) 3 only
(D) 1 and 4 only
(E) 1 and 3 only
(F) 1, 3, and 4 only
 33

Full Test Set III

1. If the chemicals are mixed, Which of the following reactions cannot occur in a displacement
reaction?

1 2Br- (aq) + 2KI (aq) → 2KI (aq) + Br2 (aq)

2 F2 (aq) + 2KCl (aq) → 2KF (aq) + Cl2 (aq)
3 Pb(NO3)2 (aq) + Al (s) → Pb (s) + Al(NO3) (aq)
4 Al2(SO4)3 (aq) + 3Zn (s) → 3ZnSO4 (aq) + 2Al (s)
5 CuSO4 (aq) + Zn (s) → Cu (s) + ZnSO4 (aq)

(A) 1 and 3
(B) 2 and 4
(C) 1 and 4
(D) 3 and 5
(E) 1, 3, and 4
(F) 2, 3, and 5

2. Gases H2 and I2 react according to the following chemical reactions:

H2 (g) + I2 (g) → 2HI ΔH = -290 kJ/mol

Which of the following statements is correct ?

(A) When the temperature increases, the rate will decrease.

(B) If the reactants exist as a powder, the rate of reaction would be faster.
(C) This reaction is an endothermic reaction.
(D) The rate of reaction will increase if the container size increases.
(E) The activation energy will decrease when a catalyst is added.
 34

3. If 28 mL of nitrogen reacts with 15 mL of hydrogen, what is the total volume of gas present
after the reaction has occurred, assuming volumes are additive?

(A) 11 mL
(B) 17 mL
(C) 27 mL
(D) 33 mL
(E) 42 mL
(F) 66 mL

4. Balancing the redox reaction

aH2C2O4 + bMnO -4 + cH+ → dMn2+ + eH2O + 10CO2

Which one is correct?

(A) b + c + d = a + e
(B) e - a = b + d
(C) a + c – b = e + d
(D) c + b = e
(E) c + e = a + b - d

5. Scientists plan to produce ammonia by reacting nitrogen gas with hydrogen gas. They set
conditions of the experiment at 1800 °C and 1500 atm. Which of the following should they take
to obtain the maximum yield of ammonia ?

N2(g) + 3H2 (g) ? 2NH3 ΔH < 0

(A) Increase pressure and increase temperature.

(B) Increase pressure and decrease temperature.
(C) Decrease pressure and decrease temperature.
(D) Decrease pressure and increase temperature.
(E) Decrease temperature only.
 35

6. A compound of sulfur and oxygen has a relative molecular mass which is twice that of its
empirical formula mass 160 g of this compound contains 64 g of sulfur. What is the molecular
formula of the compound?

(Ar values : S = 32; O = 16)

(A) SO2
(B) SO3
(C) S2O4
(D) S2O6
(E) S3O6

7. Which of the statements is correct?

(A) Order of solubility: C3H8 > C3H7OH > C2H5COOH

(B) Order of polarity: CH3CH2CH2CH2COOH > CH3CH2CH2CH2OH > C4H10
OH O
(C) Order of boiling point: > >

(D) Order of bond energy: CH2=CH-CH3 > CH≡C-CH3 > CH3-CH2-CH3

(E) Order of the mole of Cl2 in an addition reaction:
CH3-CH2-CH2-CH3 > CH3-CH=CH-CH3 > CH3-C≡C-CH3
Answer key

Full Test Set I Full Test Set II Full Test Set III

1 B 1 A 1 C
2 C 2 D 2 E
3 D 3 D 3 D
4 C 4 A 4 D
5 A 5 C 5 B
6 E 6 D 6 D
7 A 7 C 7 B