HC

Chapter 13 Hydrocarbons

NCERT-Picks
ElectrolysiSR-R+2CO, +H, +2KOH
Themajor
of aliphatic hydrocarbons is petroleum and 2RCOOK+2HOH
source

as paraffi. because of their low reactivity

are
also known Mechanism RCO,K : R CO,+K**
towards c h e m i c a l s .

At Anode: R>R- R
>R+CO,; R+
R CO, RCO,+e; RCO,
Alkanes At Cathode:
2H,0+2e20H+2H+2K H(g)+2KOH
method.
by kolbe's electrolytic
Preparation M e t h a n e cannot be prepared
number
of alcohols, aldehyde, ketones and carboxylic method contain twice the
By reduction Alkanes formed by this
sodium salt of
/ potassium
acids hydrocarbons
are formed.
of carbon atoms present in the
R-OH R-H carboxylic acid.

R-CHO
Red P
R-CH
HI, 150°C RCH,CH, Physical properties
R-COCH exist in two isomeric forms.
R-COOH
R-CH, The compound C,H1o i.e.butane can
Alkanes with even number of carbon atoms have higher
From grignard reagent: than alkanes with odd number of carbon
(1) HOH melting points
atoms due to symmetry.
R-MgX
) CHOH R- H
Except for the very small alkanes, the boiling point
rises 20
(I) C,H,NA,| for each carbon that is added to the chain.
to 30 degrees
Branched chain alkanes have lower boiling point. As
By wurtz reaction
in dry ether
Alkyl halides on treatment with sodium metalalkanes. molecular size increases, boiling point increases.
solution give higher This
free from moisture) Isomerisation:
reaction is known as
for the
Wurtz reaction and is used
CH
preparation of.higher alkanes containing even number of
carbon atoms. CH(CH)CH CH-CH-CH,
2R-X + 2Na R-R + 2NaX
ether n-Butane iso-Butane

R-X+R-X Na R - R, R-R', R'- R' Chemical properties

ether (dry)
At room temperature methane and chlorine reacts in
Mechanism: (a) lonic mechanism: 2Na 2Na° + 2e°;
R-X +2e > R°+ x° presence of light.
(1,2) CH, +CI, ,
reaction is given as- CH,CI+HCI
CH,Cl+Cl, CH,CI, + HCI
R-R; Na+X NaX
CHCL +C, h, CHCI, +HCI
(1P or 2)
0) Free radical mechanism : CHCIL +CLCCL +HC
Fluorination is too violent to be controlled. Iodination is
e;R- X+ R° +X; R° +R°-R-R very slow and reversible. it can be carried out in presence
Kolbe'
Anaq eou
s electrolysis: of oxidising agent like HNO
s solution of sodium or potassium salt of a carboxylic The rate of reactions of alkanes with
acid halogens decreases as
Clectrolysis gives number of F> Cl,Br,> 1, Electro
arbon atoms at the anode.
alkane containing even
negativity of halogens
decreases
as F> C, Br,> I,.
 Reaction with halogen: Iemia Hydrocarbons 291
290 undergoes allylic bromination when it is t
temp R-CH-CH, ith N-bromo succinimide (NBS) in CCI, in presence of
ropene
Substitution reactions:
Complete Combustion of alkanes
1,soln. ionic addition)
R - C H - C } = C H C C 1 s 0 n R
eroxides or light.
Amm. Cu,Cl,
o , CO,-(n)H,O high temp alkene is found
alk to be more
f polar than the
C gas phase CH CH=CH ,cis-
orm
m The groups are in
opposite directions in the redippt. RC CCu+HCI
Ontroled Oxidation: 2CH, +0,
2CH,OH
methanoi
i ranfarm, the dipole monents oI Donds cancel each other RCH=CH
(free radical substinution
rans-1t
(9: )
making
rans-IOm
almost olar,
non-po
Amm. AgNO,RC= CAg HNO +
or chlorine add 3 to cycloalkenes
Oxidation ofcycl leads to the ring openings and white ppt.
CH+0, HCHO +H,O Halogens
like
bromine
alkene t
d i h a l i d e s . A d d i t i o n

of halogen t
alkene is an dicarboxylic acids
or keto acids.
2CH,CH, +30, O, N2CH,COOH+2H,0 vicinal This reanse an e gives
ethanoic acid addition
reaction.
eaction is used
(CH),CH M(CH,),COH (For
alkanes having
30 ofelectrophilic
for
unsaturation.
lodine does not show addition re
as a Aromatic Compounds
atoms
normal condition.
CCI unda Alkynes
Huckel rule of
alkanes into smaler CH=CH,+ Br, çH-CH, me is acidic in nature in comparison to ethene and aromaticity: is applied to al the ring
yrolysis-Decomposition of higher
absence of air is caiiu
udgments on strong heating in the free radical reacion hybridised orbitals of carbon atoms in ethyne systems whether have benzene ring or not and possess the
PyTOysis or cracking. Pyrolysis is a Mechanismn
highest electro negativity hence can atract shared e following characteristies ;
bond to a greater extent.
C 973CH+CH,, +OtherProudcts
Heptance Pentence Step 1:
air of C-H Planarity: Complete delocalisation of t - electrons in the
Preparations of alkynes
Conformational isomers m Bydrolysis: From calcium carbide (Industrial Method)
ring
The potential energy difference among these conformations Halonium ion Presence of (4n+2) n -
electrons in the ring. (n=0, 1, 2,..)
of ethane is about 3 k cal/mol called torsional strain (or
step 2 CaC.+H0uroy H-C=C-H+Ca(OH)
Acetylene Benzene is isolated from coal tar by fractional
energy barrier). Due to small diífference in enengy, the two Calcium carbide
confomations are readily inter-convertible with ethane. Mg,.C, +4H,O CH,-C= CH +2Mg(OH), distillation
Staggered form of ethane is the most stable and eclipsed vicinal dihalides Under U-V light three chlorine molecules add to benzene to
From
form is the least stable. In staggered form, the electron )
(X attacks from the back side) Ex: Br-H,C-CH, -BrAlcoholic KOH produce benzene Hexachloride C.HCI, which is also called
clouds of C-H bonds are as far as
closer to each other in eclipsed form.
possible and it comes KBr,-H,0
gammaxane.
Addition of hydrogen halides HC= CH-Br CH CH+NaBr+ NH
=
Alkenes Addition of HX (HCI, HBr, HI) to unsymmetrical alkene pla: Acetylene can be prepared by the controlled high temperature Cl CI
according to Markovnikov rule. partial oxidation of methane.
+3C1 500 K (BHC)
Preparation CH-CH-H, CH-CH-CH Chemical properties CE CI
1. less stable
By partial hydrogenation of alkyne CH,-CH=CH,+HBr Alkynes are less reactive than alkenes towards electrophilic
Carbocation
(Minor Product) addition reaction because the electrons in
R alkynes are more Direct the
tightly held in alkynes than alkenes. incoming group to ortho and para positions of
R-CEC-R+HPncdC Reaction with sodium in benzene ring, for example
H bCH-H-CH,B CH,-CH-CH liquid ammonia: Terminal CH,, -OCH,,-NH,, -NHR
(CiS alkene) alkynes react with sodium in liquid ammonia or sodamide
More stable
Carbocation toform sodium alkynide
-
NHCOCH, etc is also known as ortho and para directing
H (Major Product) group is called activating group.
R-CEC-R+ H N c=C Peroxide effect is observed in addition of HBr but not n
Addition reactions:
addition /Ni Halogens are O and P directing groups but are moderately
(Trans alkene)
of HCI. H-Cl is stronger than H-Br bond and5 RCH,CH deactivating due to their strong - I effect.
not cleaved by the free radical. 200°C
2. By Debydrohalogenation of alkyl halides
Propene reacts with HBr in H,IPd Baso,RCH= CH, Meta directing groups also called deactivating
T presence of peroxide to g groups, direct
Bromopropane. In presence of peroxide, pro
-
heat the incoming group
reacts with HBr
to meta position of benzene ring for
by free radical mechanism accoruug
H antimarkovnikov rule. RCH=CH- Cl example:-NO,,-CN,-CHO, COR, -COOH, -COOR,
RCCL\CHC,
Ozonolysis: This reaction is used -S0,H, ete
=Cl, Br, ) detect the osition
Chemical Properties
unsaturation i.e. double and
triple bond.
to
HCRcCl=CH HCIRCClCH, Toluene has the highest electron density in the benzene
ring
Alkenes react with cold Hydroxylation:
Test & hence can be most
readily sulphonated due to +I effect
concentrated for
sulphuric acid to form
compounds of the general formula ROSO,H unsaturation, called Baeyer test ana ai KMa KMnO,+ dil. H,SO,RCOOH HCOOH
hydrogen sulphates. known as alkyl (MnO,+OH) is
alkaline KMnO, called baeyer's reagent in uink Col
in. +
of-CH,group.
fades. oxidises alkene to glycol a
RCH
MnO RCH-0
RCH
Mn HOCH~o
RCH 0 HO RCH-OH
RCH-OMnO,H RCH-OH
 when methane reacts witn conc.
methane
Hydrocarbons 293
W/hat
happens HNO, at .31.
hglh temperature?
Ethylene is
is converted to ethane in the presence Ni a
converted
Is formed 0 C In this reaction the hybridisation of carbonotchanges
methane
Nitro Is lormed
Trom:
Methanof
1) sp to sp? 2) sp to sp
2) are formed
and H,0 3) sp to sp
3) CO, formed 4) sp to sp
MCQS CO and H0
are
4 dihedral angie between the hydrogen atoms of 2 methyl
The
L. Which conformer of butane molecule
1) Ellipsed 2) Skew
has lowest energy
of ethaneis 3) Staggered
in staggered
conformation
groups 4) Anti staggered
60 34. The molecule
0
which is free from angular strain is:
4) 240° 1) Cyclopropane
1200 2) Cyclobutane
contormation
of ethan is 3) Cyclopentane 4) Cyclohexane
The most stable 35.
) Eclipsed 2) Skew Which cycloalkane has the lowest heat of combustion per
4) All are equally stable CH,8 TOup
NCERT Topic-wise McQs 3) Staggered
1) Cyclopropane
of the following alkanes cannot be produced 2) Cyclobutane
Which
Kolbe electrolysis of sodium or potassium salts of 3) Cyclopentane 4) Cyclohexane
carboxylic acids? 36. In the
9. Among the following, select the alkane that following reaction, the major product is
that is expectedt
Alkanes NCERT Pg 374-384] have lowest boiling point? 1) Methane
).
Butane

2) Ethane
4) Hexane
CH
1. ) Hexane 2) 2-methylpentane
Which of the
following compounds will react with Na to 3) 3-methylpentane 4) 2,2-dimethyl propane 21. The ILU.P.A.C. name of neopentane is:
form 4,5 diethyloctane? 10. The compound with highest boiling point is:
) 2-Methyl butane 2) 2,2-Dimethyl propane
1) CH, CH, CH, CH, Br 3) 2-Methyl propane 4) 2,2-Dimethyl butane
1) n-hexane 2) n-pentane
CHBr CH,
12, Methyl bromide is.converted into ethane by heating it in
CH 3) n-butane 4) 2,2-dimethylpropane ether medium with:
Br
2) CHCH,CH,-H-CH-CH.Br 11. An alkyl halide by formation of its Grignard 1) Al 2) Mg
3) CHCHCH,CH-ÇH-CH, reagent a 4) Cu
heating with water gives propane. What is the originalalki 3) Na CH, CH
halide? 24. Pyrolysis of methane and ethane respectively are: Br
Br
1) Methyl iodide 2) Ethyl iodide 1) Exothermic & Endothermic
4) CH,CH,CH-CH-CH-CH
3) Ethyl bromide 4) Propyl bromide Endothermic & Exothermic -Br
37. Cycloalkanes are isomeric with:
Br 12. For preparing an alkane a saturated solution of sodium 3) Both are endothermic
2. Which of the 1) Alkane 2) Alkenes
following is the most stable free radical? potassium salt of carboxylic acid is subjected to:
a 4) Both are exothermic
3) Alkynes 4) Arenes
) CH,CH, 2) CH, CHCH, 1) Hydrolysis 2) Oxidation 25. Wrong statement regarding alkanes:
3) Hydration 4) Electrolysis 1) All alkanes burn in air to give C0, and H,O Alkenes INCERT Pg 384-392]
3) CH, CHC,H, 4 CH,CH, CH, 13. Of the five isomeric hexanes, the isomer which can ghe 2) At room temperature, some alkanes are gases, some are
3. Hydrocarbon which is liquid at room temperature is: two monochlorinated compounds is: liquids and some are solids 38. Which of the following reactions does not show the correct
1) Pentane 2) Butane 3) What ever the molecular products of the reaction?
1) n-hexane 2) 2,3-dimethyl butane weight of alkane, its density
3) Propane Ethane 3) 2,2-dimethylbutane is less than water 1) CH, -CH = CH, PeroxideC H , -CH, -CH, -Br
4) 2-methyl pentane
4. The major constituent of natural gas is: 14. Which of the
4) Most of the alkanes are soluble in water.
following reactions is not correct T
26. The
2) CH-CH= C H , n CH, - CH, -CH, - Cl
1) Methane 2) Propane reaction
3) Butane 4) Hexane
preparation of alkanes? represents Br
5. Which of the following products is formed when n-heptane
) (CH,), CHCIIA(CH,), CH, CH,+CH HBr
is passed over (Al,O,+Cr,0) catalyst at 773 K?
1)Subsititution
3) Cracking
2) Synthesis 3) CH-CH=CH, CH-CH-CH,
1) Benzene 2) Toluene
2) (CH,), cCiLA (CH,), CH .
4) Polymerization
Bromination of alkane HCI
is initiated by a process or:
4) CH-CH=CH, CHCH-CH
3) Polyheptane 4) cycloheptane 3) (CH,), CHCIN ) Pyrolysis
6. Which compound cannot be formed from Wurtzreaction?
(CH,),CH, 3) Homolysis
2) Substitution
39. Which of the following compounds will show cis-trans
4) Peroxidation
1) Propane 2) Butane 4)(CH,), CCINa(CH,), CH .Fi isomerism?
4) Methane
15. Pick out the alkane which differs from the othermemberu products
) Acid of complete oxidation of hydrocarbon is:
3) Ethane
2) Dihydric alcohol 1) (CH), C CH-CH, 2) HC CCI,
the group: 3) Aldehyde
7. Sodium salt ofX is heated with soda lime and gives ethane, 4) HCIC CH
1) 19, 4) H,O +CO0, 3) CHHC=CCI CH,
Xis 2,2-Dimethyl propane 2) Pentane Isomerisation alkane in be brought by usin
3) 3-Methyl butane can 40. The ease of dehydrohalogenation for different halogens is
1) Ethanoic acid 2) Methanoic acid 4) 2,2-Dimethylbu ALO, Fe,O
3) Propanoic acid 4) Either (1) or (3) 16. Which of following isomeric heptanes
the an ) Anh.AICI,/HCI 4) Conc.H,Sso,
in the order:
called marsh gas? different
monochlorinated products upu
ee ad iree The num > Chloride
1) lodide > Bromide
8. Which of the following is chlorination? Overlaer of sigma bonds formed in ethanè'by the
2) Bromide> lodide
> Chloride
1) CH 2) CH,
1) 3-methyl hexane
verlapping
)7 of sp-sp? orbitais Bromide > lodide
4) CH, 2) 2-2, dimethyl pentu 3) Chloride>
3) CH, 3) 2-methyl hexane 3)1 2) 5 > Chloride > Bromide
4) 2, 3-dinmethyl penta 4) 4 4) lodide
 objective NGERT Punoh
294
Ozonolysis of 2,3- dimethyl but - 1 - ene tolloweu 52. The is heated withwhen
compound
dibromide
forned
granulatcd zinc ion.
s Pundh-dhemis
coholic solution
alcoholie.
of ethy d. Whlhe main

ours are
passed over alumina
product oblained is: heated at Hydrocarbons 295
reduction with zinc and 2) Ethyne 2) C,
1) Methanal and hexanoic acid
water gives: 1) Ethene
3) Ethane
4) bromocthene
150'C,
4) CH,OC,H, Alkynes NCERT Pg 392-396]
3)
2) Methanoic acid and butanone
Methanal and
3-nmethylbutane 2- one
53. Which
of the folowing compounds conpounds will
show
Cof
,f CH, CH,- CH CH,+ HCI
fthe following will
=

Kharasch effcct
operate? Acetylene when treated with dilute HCI at 60°C (333K) n
presence of HgCl,
) Methyl chlorideproduces-
it.
-
4) Butanoic acid and 2.3
dimethyl butanoie ac
ISOmerism
1) (CH,), C = CH-C,Hs 2) H,C CCI
19t CH- CH,-CH CH,
+ HBr =
2) Vinyl chloride
2. 2)LCH=CHCH,+ HBr 3) Acetaldehyde
Arrange the following alky
oT
halides in decreasing order 3) CH,HC
=CCI CH, 4) HCIC= CH, 3) CH =CH, + HI
4) Formaldehyde
h e rate CH,-CH,-CH 14,
of ß elimination reaction with alcoholic K of 2,3- dimethyl butt -
I
olcfin which on 02onolysis gives
CHCH,CCH NaN,/NH,), CHCH,Br Li, NH,0,
54. Ozonolysis
reduction with zinc and water gives: enc followod s The
and CH,CHO is: 1) CH,CHCH=CH-CH,
(i) CH,-C-CHBr and hexan-2-one
CH,CHO
2) But-2-ene 2) CHCH,CH=CH,
1) Methanal 1 ) B u t - 1 - e n e
ethanoic acid and butanone 4) Pen-2-tene
CH, 2)
3) Methanal and 3-methylbutane - 2- one
3) Pen-I-tene
3) CHCH
(i) CH, - CH, - Br idation product of iethyiene by air at
200-400°Cin
4) Propanoic
acid and 12,3 dimethyl
-
butanoic acid e o fsil catalyst CHCH,
Gii) CH, -CH, presence
CH,CH
C=CCHCH,
-CH -
Br among the following is ) Ethylene glycol 2) Ethylene oxide
55. Vinyl group )
1) )> (Gi) > (iii) 2) HC= C 4) Ethylene chlorohydrin
3) (ii)> (ii)
2) (iii) > i ) > (i) 1) (CH,), CH- 1,2-Ethanedoil
H
> (i) 3) H,C =CH- CH, 4) CH, =
CH What are X
and Y
in the rection,
-
4) ) > (ii) > (ii) 75. Which of the
43.
For the given reaction. how many products 56. The alkene that exhibits geometrical isomeris is CH +H,SO4 X-HOy following
1) CH, C = CH
alkynes is most acidic?
substituted)will be inc n products (mon
obtained 2) 2-methyl propene
2) CH,
4) CH =C=C CH,
including all isomers
obtained
1) propene 1) CH, CH,OH 2) C,H. C,H,SH
3) CH, - C H - C = CH CH
XXBrh
Products 3) 1,2-dichloroethene 4) 2-methyl-2-butene cHOSO,H, CH,OH 4) CH,. CH,OH 76. What happens when calcium carbide is treated with water?
6 57. IUPAC name of the following alkene is, Ethane is
1)
3) 4
3. In the following squence of reactions the compound A is,
2)
formed
Methane and ethane is. formed
(CH,)CH-CH=CH-CH-CH=CH-CH- alc KOHCO 20/0CH,CHO+
HCHO 3)
Ethyne is formed
44. Which of the following is the predominant product in the
C,H, ) Ethylene 2) Acetic acid 4)
Ethene and ethyne are formed
reaction of HOBr with
propene? 1) 2, 8 Dimethyldeca-3,6-diene 3) Propene 4) 1-Butene
7. Ozonolysis products of 2-pentyne after decomposition of
1) 2- bromo-1- propanol 2) 2) 4,8 Dimethyl deca- 3, 6-diene 69. JUPAC names of the products obtained by addition of
3) 2-bromo-2-propanol 3-bromo-1-propano
4) 1-bromo-2-propanol 3) 2,4 Dimethyl deca-3, 6-diene HBrto hex-l- ene in the absence of peroxide and in the
ozonide with water and subsequent oxidation are:
1) Ethanoic acid and propanoic acid
45. For synthesis of 1-butene, 4) 3,9 Dimethyldeca-4,7-diene presence of peroxide respectively are: 2) Ethanoic acid and propanone
CHMgl should be treated with: 58. IUPAC name ofthe following alkene is, 1) 2-Bromohexane, I-Bromohexane
1) Propene 2) 2- chloropropene 3) Ethanoic acid
2) 2-Bromohexane, 3-Bromohexane
3) Allylchloride 4) Formic acid and glyoxal
4) Ethyl chloride HCCH-HC=CH,-¢=CH-HC=CH, 3) 1-Bromohexane, 3-Bromohexane
78. Which of the following will give 2,2- dibromopropane on
46. An alkene on
vigorous oxidation with hot KMnO, gives CH 4) 1-bromo hexane, 4-bromo hexane
only acetic acid, the alkene is: reaction with HBr?
1) 5-Methylocta-1,3,5,7- tetraene 70. Z-isomer-2-butyne E-isomer 1) CH, CH = CH, 2) CH, C = CH
1) CH, CH, CH CH 2) CH, CH- CH CH
=
Tespectively are
2) 4-Methylocta-1,3,5,7- tetraene 3) CH, CH CHBr 4) CH= CH
3) (CH)C=CH, 4) CH, CH= CH, ) Na /NHdig) and Pd/ BaSO, + H
3) 4-Butenylocta-1,3- diene 79. In the reaction,
47. When an alkene on ozonloysis gives formaldehyde and 2) Ni/140°C and Pd/BaSO, +H,
4) Octa-1, 5- diene B lindarcatalyst-E5- RC = CR A A and B are
3) Ni/ 140°C and Na
acetaldehyde, the alkene is:
9. The number of sigma and pi bonds in the following
/NHti) geometrical isomers:
1) Ethene 2) Propene
structure are:
4) BaSO, +H, and Na /NH0 1) A is cis and B is trans 2) A is trans and B is cis
3) But-l-ene 1. The final product in the given reaction:
4) but-2-ene 3) A and B are cisS 4) A and B are trans
48. Ethylene can be separated from acetylene by passing the
(CH,),CH-CH=CH-CH-CH=CH-CH-CH
mixture through: CH, US0
KMnO,i
A 80. The reagent used to convert an alkyne to alkene is:
1) Zn/HCl 2Sn/HCl
1) Fuming H,SO, 2) Pyrogallol 1). o bonds-33, T bonds -2 3) Zn-Hg/HCI 4) Lindlar's catalyst
3 ) Ammonical Cu,C1, 4) Charcoal power 2) o bonds -22, n bonds-2 OH 81. What is the product formed when acetylene reacts with
CHO0
3) a bonds - 42, T bonds 2 hypochlorous acid?
49. Aqueous solution of sodium succinate on electrolysis CHO
4) a bonds -40, T bonds -3 OH ) CH, COCI 2) CI-CH, - CH, CHO
gives:
3) CLCHCHO 4) CICH, COOH
1) CH, -CH
2) CH, = CH, 60. Lindlar's
catalyst is used for controlled: COOH
82. Ethylidene dichloride is obtained by the reaction of excess
3) CH = CH co, 1) Oxidation 2) Hydrogenation coOH
of HCl with:
50. 1,3,5,7-Octatetraene contains X
o bonds and Y n bonds. 3) Halogenation 4) Dehydration hich of the following has the maximum neat
O 1) Ethylene 2) Acetylene
X " and *Y" are: 61. Ethylene readily undergoes the following YP ydrogenation? 3) Propene 4) Methane
1) 23, 4 2) 17,4 1) Elimination 2) Addition CECH
D,
3) 18,5 4) 33,2 3) Rearrangement 4) Substitution
2)
NaNH Apd-BaSO,>B
51. The alkene that
exhibits geometrical isomerism is: 62. On reductive
ozonolysis ethylene gives
Do
2) 2-methyl propene 1) Aldehyde End product B is
-
1) Propene 2) Ketone
3) 2-butene 4) 2-methyl-2-butene 3) Carboxylic acid 4) Ether
 Objecu Funch
296 on
ver powder
heating with silver
Punch-
gives:
Uhomisj hstituted acetylene udergoes addition Hydrocarbons 297
lodofom with
97.
1) CH,
C,H, el o r e s e n c e
of Lindlar's cataylst, the alkene formed
CD=CD, Ph
4) CH hydrogen in +0 xn/HO_Y
3) CH
2) C=.
H reagent
uscd 1or ting Acetylene tetrabro
converting, Cis and trans
D 98. The
A mixture of 1) X
into ethyne is:
2) Conc.
2Transproduct only - Triozonide, Y= Glyoxal
Ph 1) Alcoholic KOH
,SO, at 170P
2) X * Diozonide,Y = succinic acia
3) 4) Ph-CECD Cis product only
4) Zinc dust
D
3) Aq. Potash
Cispresence
Pce of Linddar's catalyst, addition does not take
of L i n d d a r ' s cat
3) X =monoozoníde ,Y = Benzoic acid
smell,
sweet vhere In 4) X Triozonide, Y Benzaldehyde
=
84. 1-
butyne Pure acetylene nas ereas 4)
=
on
1) Butane-1, 2-diol
hydration gives: 2) Butan - 1-ol

99.
garlic odour
due to presence of
2) PH,
impure plaalysisZ0n
gives a dial while 'y' reacts with Baeyer's
121. The
following reaction is known as:
3) Butan-2-ol 4) Butan- 2-one ) NH zive a diol. 1Then "x and y ' respectively are CH, +CH,CI C,H,CH, + HCI
4) HCI *on
65. 3) SbH reaget
& C, 2) C, H, H, ) Wurtz - Fittig's reaction
Which of the following organic compounds has su & H
hybridisation its combustion
100. Which of the following possess acidic gen? )CH, & 4) C H, & C, H, 2) Friedal Craft's reaction
1) Ethane
as
product (CO) -
2) CH, 3) C H,
G,H
2) Ethyne C 4) CH
3) Rosenmund reaction
3) Ethene 4) Ethanol 4) Sandmeyer reaction
with KMnO, but does not 101. The reagent used
tor
oDtalning trans alkene
Aromatic H y d r o c a r b o n INCERT Pg 396-403) 122. Mark the incorrect statement
n or the following reacts
react with tollen's substituted acetylene With hydrogen is: irom tne
reagent? 2) LiAIH, of the
1) Benzene has a planar structure
1) C.H. 1) Na in liq.NH, correct
product following reaction:
3) CH CH 3) Zn+ HC 4) H, in presence of Ni 4.
Jdentity 2) Benzene is an unsaturated hydrocarbon and shows
4) C.H. addition reactions like alkenes
87. 102. Gem dihalides on treatment with alcoholic kOH
Which of the following
1) Al, C
gives propyne
2) Mg C
on hydrolysis
1) Alkyne 2) Alkene aaA 3) In benzene, carbon uses two p- orbitals for hybridisation
4) Aromatic hydrocarbons contain high percentage of
3) B, C 4) Ca C 3) Alkane 4) Cyclo alkanes
carbon hence burn with sooty flame
wnch ofofthe
O solution following compounds reacts with an aqueous 103. X+2Zn H-C=C-H, here "X' is
123. Benzene easily shows:
(Ag(NH,),)OH? 1) 1,1-D1bromoethane
2) 1,2-Dibromoethane 1) Ring fission reactions since it is unstable
1) Ethane Ethene
3) Dibromoethane 2) Addition reactions since it is unsaturated
3) 1- butyne 4) 2- butyne
4) None of these 3) Electrophilic substitution reaction due to stable ring and
. 4) 1, 1,2, 2-Tetrabromoethane
ow many structures are possible for C, H, with one triple 104. 2-Butyne when treated with lithium in presence ofliqi high Te density
bond? 4) Nucleophilic substitution reactions due to stable ring
15, The treatment of benzene with iso - butene in the presence
1) 4 2) 3 ammonia gives:
and minimum electron density.
3) 2 1) Cis-2-butene 2) Trans-2-butene ofsulphuric acid gives:
4) 124.
90. The most acidic hydrogen atoms are present in:
3) n-Butane 4) 1-Butyne 1) iso butyl
-
benzene 2) Tert - butyl benzene The most common reactions shown by benzene are
electrophilic substiution reactions, which of the following
105. Which one of the following possess the minimum boiling 3) n- butyl benzene 4) No reaction
1) Ethane 2) Ethenee undergoes electrophilic substitution reactions most readily?
3) Ethyne point? 16. Which one is the most reactive towards electrophilic 2) Benzoic acid
4) Benzene 1) Benzene
1) 1-Pentyne 2) 1-Butyne
91. reagent? 3) Nitrobenzene 4) Toluene
Excess of CH,COOH is reacted with CH=CH in presence 3) n-Butane 4) Isobutane
of Hg", the product is -
106. X+2KOHA>H-C=C-H here X is,
CH 125. Identify the product obtained in thefollowing reaction
1) CHCH(OOCCH) ,OCH, OH H,C OH
2) CH-CH(OOCCH) 1) 1,1-Dibromoethane
3) (CH,COO)CH,-CH,(OOCCH) 2) 1,2-Dibromoethane C B r e (X)
Both (1) and
4) None of these (2)
4) 1,1,2,2-Tetrabromoethane CH,
92. The number of possible alkynes with molecular formula Br H,C OH
107. precipitate with ammonicalsi CH,OH NHCOCH,
CH, is: Acetylene gives white
1) -CH,
2) 4 nitrate but ethylene cannot giv because:
1)
4) 6 1) Acetylene possess sp* carbon
3)5
93. Alkynes exhibit:
2) Acetylene posses acidic hydrogen .,
Acompound that undergoes bromination easily CH OH
3) Acetylene possess low electronegative carbon
1) Chain isomerismn
3) Functional isomerism
94. The IUPAC name of the

2) Position isomerism
4) All of these
compound having the formula

4) Acetylene posess-C=C-triple bond

108. Which
of these will not react with acetylene
1) Toluene
3) Phenol 4) Benzene
hich of the following will not be soluble in soaium

2) Benzoic acid 2)
- H,C OH

CH,
1) NaOH 2) Na
CH C - C H = CH,
hydrogen carbonate?
1) Butene-2-yne
3) 3-butane-1-ene
2) But-2-yne-3-ene
4) But-1-ene-3-yne
3) Ammonical AgNO,
109. Action of zinc
4) HCI
on tetrabromoethane
gives:
2,4,6 trinitrophenol
)0-nitrophenol
2) Benzoic acia
4) Benzene sulphonic acid
»O-CH-Ko Br
) CH-0DH 2) CH= CH
95. Acetylene can be obtained by the electrolysis of the 3) CH,-CH, 4) CH, = CH, Nitration and chlorination of CH OH
following compound: 10. What is the COphilic and electrophilic substitution respectively
benzene are:
Potassium fumerate 2) Potassium succinate product when acetylene reacis T
1) 1) CH,COCI CH- CN 3 rophilic and nucleophilic substitution respectively
3) Potassium acetate 4) Potassium formate 2) CH, =
3) CiCHCHO 4) CICH,COOH etrophilic substitution in both the reactions Br
rhe oas obtained when ethylene
is:
CniOC caes
wu ll. The
final product formed when ethyne and
aceue
T0,Nucleophilic substitution in both the reactions
alcoholic potash and sodamide
react, is; Similar to alkenes benzene also undergoes 126. Ozonolysis of
benzene yields:
) CH
2) C,H Vinyl acetate 2) Ethyl acetate 02onol nes and alkynes 1) Glyoxal 2) Glycerine
4) CH,Ci 3) Acetylene acetic acid acetate and . "
ne
sequence of the given reaction identity 4) Glycerol
3) C.H 4) Ethylidenc 3) Glycol
 298
Objective NCERT Punch-h
127.-Formation
the On of which
the
of
of the following compound contirms 136. Cyclobutadiene is said to be:
unsaturation
1) Cyclohexane character of benzene?
1) Aromatic 2) Aliphatic
3) Triozonide 2) Gammexane
3) Antiaromatic
4) Heterocyclic
128. Which 4) All the above 137. In the reaction,
ot
the following
electrophilic
1) C.HNO,
substitution? compounds reacts slower CIeCI4
- Cl+HCI

3) CHCH 2) CHOH the attaching species is:

29. 4) CH,NH
Aromatic conmpounds 1) Cl 2) CI
1) give smoky flame 3) C 4) FeCI
Hydrogen
2) Carbon percentage is more becau
138. Which one among the following
percentage
3) Delocalisation is more
compound with O, follo gives ak
owed by reduction
4) Saturation water? wit 1
wih
130. Bond length of 1) CH 2) CH
1) 1.34 A° C-C in benzene: 3) CH, 4) Both (2)
2) 1.39 A° 139. With which one of the following reage &(3)
3) 1.54A°
131. The 4) 1.20 A° undergo substitution reaction? benz
increase in stability and 1) Fuming sulphuric acid
compounds is due to: decrease in energy of
aromau 2) Nitration mixture
1) Localization
of
Delocalisation ofpi-electrons
3) Chlorine in presence of sunlight
2)
3) sigma-electrons
Localisation of sigma-electrons
4) Acyl halide in presence of AICI,

4) OH
Delocalisation of pi-electrons
132. Which of the
1) Benzene
following cannot form ozonide? 140. O +Zn-X Here the product X is used as a
2) Ethene
3) Ethyne 1) Insecticide
4) Ethane
133. Chemical 2) For welding purpose
name of the insecticide gammaxene is
1) DDT 3) For dry cleaning
2) Benzene hexachloride
3) Chloral 4) Hexachlor ethane 4) Artificial ripening of fruits
134. Preparation of benzene 141. The conversion
from phenol is:
1) Reduction 2) Oxidation CH,CH,CH CHCHCH,
3) Addition 4) Dehydrogenation
135. Benzene is resonance hybrid of mainly two Kekule
structures. Hence, can be effected using:
1) Half the molecules correspond to one structur and halff 1) Br,/CC 2) Br,/H0
to the second structure 3) Br,/ Fe 4) Br,/ benzoyl perou
2) At low temperature benzene can be separated into two 14. 1he order of reactivity towards S. reactions of-
structures

3) Two structures make equal contribution to resonance

-CH, (). ¢ -

CH, -

CH, (1I), ¢ -CHl

-C(CH,), IV)
hybrid Where -cH,
4) An indívidual benzene molecule changes back and
1) I>II> III> IV 2) IV> II>I>I
forth between two structures
3) II>I > III >IV 4) III > II> 1>V
 nyarocaioorS
Rank Booster MCQs

0K', major product A:

CH

Br
CH
CH=C
3)
Br
4) None of these
6. The final
4) -0- major product of the following reaction is:

Na
CH-CHCEC-H(2) CHCHBr
(1) NaNH,
(2) CH,CH,Br
B(A)dry ether (B). Product Bis: 1)
CH,- CH
2) CH-CH-CEC-H
-

C= C-CH, - CH,

CHCH,
3) CHCH-CH-CH
2)
NH,
4) HC CH, -C =C- NH,
7. Which of
the following reactions result in the formation of
3 4)

cumene
yCOH 2 KOH A
o0H
electrolysis B+C.
AICl,
ProductsB& C are:
) Position isomers 2) Enantiomer
Geometric isomers 4) None of these 2) + C-AIC,
How may distinct monochlorinated
products, including
Sire0-1S0mers, can result when the alkane below is heated 3)
nte presence of
CI,?
4) All of these

2 CH-C
5 2)4 Anhyd X, the product X° is:
4)8 CH- AICI,
ich of the following /are the major of the
Tolowing reaction'! product,
CH,
HBr

CH,

Br
 300
Objective NCERT Punch-
3) 12. Which of the following molecule :
is not aromatie
-CH=CH-Ë-OH 2
4) C.H-ë-CH-CH-Ë-

9. C1
4
CI + Anhyd. The final
product 'Y' is: AICI,
13. Ethylene is treated with Br,, in the
the
1) C.H,-C.H, -CI
The products formed are:
CH-CH,
presence of (.
2) C,H- -CH, 1) 2) CH,-CH
Br Br
OCH, OCH,
3)
CH CH 4) Both (1)
3)
=0
Br OC,H, &(3)
4) 14. But-2-ene is treated with HO
ACl. The
=0
1)(+) sec butyl chloride2) product forr
sec butv fomel
3) t) sec butyl chloride 4) None of thesechloride
Cl 15. Maleic acid reacts with
10.
Br,/CC. The product f
Which of the CI 1) Meso-2, 3-dibromosuccinic acid forme
following
reaction shown below? species
is 2) (+)-2, 3-dibromosuccinie acid
an
intermediate in ne
3) (+)-2, 3-dibromosuccinic acid
4) -2,3-dibromosuccinic acid
Br
16. Which of the following reactivity orders is/are cr
HO 1) CH-CH CH,> CH= CH, (towards electre
= Corre
*"OH 2)
addition reaction)
CH,CH, =

1) CH-CH=CH, (towards ca
2) hydrogenation).
3) CH-CH, > H-C=C-H (towards electrophilic ad
4) All of these are correct
17. Which the
H following methods yield str
hydrocarbon?
BH,
3) (A)R-CH=CH; CH.COOH
Br (B) R-CH=CH, CHN
N
A
C) Na/ ether
A
COOH
11. 1)O
2) Zn/H,0
A-LiAlHL, B c
J NaOH +CaO
The correct code is -
1) A
2) A, B
3) A, B, C 4) A, B, C, D
identify the product C- 18. Which of the reactwe

Wurtz reaction?
following compounds is most
OH OH
Br
1)CH-CH-CH, 2)

OH
CH

4)
-OH
3 4) CH--Br

CH,
 301
Hydrocarbons
he
m g j op
r roduct
nct of the following reaction is :
Cl Br D
Na/Ether alc.
KOH 2)

3) 4)

Excess gives
saind is a possible product from addition of Br.
Ph-CH-O-CH Clyhv
Whicth
n l-butene?

Br

Br
2) Br
) Br

4) Br
Br Br
CHO
n thereaction
Br CHOH
obtained is
Themajorproduct
OC.H,
Ph
2)
3) Ph-cKO-cCC
4)
VY 4) None of these
following triene gives following products
on
27. Which of the
Which ofthe following is true? Ozonolysis?
)Acetylene is more reactive than ethylene to an

electrophilic attack H
ethylene towards Products=
2) Acetylene is less reactive than H H H H H
electrophiliç attack
Acetylene may show more reactivity or less reactivity
towards electrophilic reagent.
reactivities 2)
4 Acetylene and ethylene show identical
towards an electrophilic attack
Acompound "X' on ozonolysis followed by reduction gives
'X' 1s
Y
analdehyde, C.H,O and 2-Butanone. Compound ) 4
) 3-methyl pent-2-ene 2) 3-methyl pent-3-ene
93-methyl hex-3-ene +CH,-= CH,- HPO X
4) 3-ethyl pent-3-ene
28.
CH=CH CH,
KMnO B The compound °X' is :

CH
Umpound Aand B respectively are - CH-CH-CH, CH-CH-CH,
C-bromostyrene, benzoic acid
Pbromostyrene, benzaldehyde 2)
-bromostyrene, benzaldehyde
styrenedibromide,
Br
benzoic acia CH,
CH--CH,
gether D,O Na/ether(X) 4) None of these
3)
C
Compound (X) is:
 302
29.
Objective NCERT Punch
Which of the
following
ng procedure would be best for 36. The ratio of products, 1-chloronreOpane to 2-dlka
achieving proceau? respectively formed in the chlorinati
the
following reaction
hydrogens are abstracted
inaion ot Propane
at equal rates is
Br CH-C=(-CH, 1) 50:50 2) 25:75
)
BrO 3) 75:25 4) 12.5:87.5
)KOH and heat 37. The hydrocarbon that cannot be Dren.
(i) CH-C= C-Br
KMnO,
H,O and heat (ii) CH,- C=C Na' (ii) Wurtz reactions: ed effeci
Excess o
3)) NBS in 1) Y
4)() Mg in CCl, and heat (ii) CH,-C Na
ether (ii) CH,-
H,PO C =
CNa' (ii) excess of
o 2)
30.
E, reaclion
+
In the Hoflimann product) (Satyzeff
above product)
1) X= reaction, Satyzeff product will obtained when-
3) X =
Br 2) X= CI
31.
cis-2-Butene on
treatment with
4) All of these
1) +-2,3-dibromobutane bromine gives:
2) -2,3-dibromobutane 38. Amount of oxygen consumed for
3) t-2,3-dibromobutane 29 g butane?
complete com
4) meso-2, 3-dibromobutane 1) 104 g
2) 52 g
3) 29 g
32. 4) 208 g
_Chlorine
Cl+H,Owater Major 39. In the following reaction, A and B
product is respectively are.
1)
AHBE CH,Br A
<OH 2) 1) CH, and alcoholic KOH/A
2) CHCI and aqueous KOH/A
3) CHOH and aq KOH/A
4) CH, and Br,
3) -

4) 40. Planar
-OH molecule among the
CI 1) CH=CH following is
2) CH,-CH
33. Which of the 3) CH =

following alkenes can be used to C-CH, 4) Cyclohexane

prepare 41. The
1-Bromo-1-methylcyclopentane by the addition of HBr? relative
chloroform is:
reactivity of the
following towaru
CH,
CH i) CH, CH
i) CH, CH
-COCH,
=

CH
Gii) CH=CH -0-CH,
-

CH,
(iv) CH= CH,
3) 4) All of these
1) i>i> ii> iv 2) il > ii > iv>i
3) i>ii>ii> iv
42. The 4) ii> i>ii>iv
34. The gases liberated at anode in the
electrolysis of sodium compound that would produce
acetate are ozonolysis is: Heptane-,6-dio
1) CO, & H 2) C.H, & CO,
3) H, &C.H, 4) H, &0,
2)
35. The following substance reacts with water to give ethane
1) CH, 2) C.HMgBr
3) C.H,OH 4) CH,OC.H,
 nd CH, on atment
comp
with dil 303
which on reductic n with H,SO, & Hydrocarbons
s 0 , g i vX
yon
eX

ith concIH,SO, give Z.

r e a c t h o nw i t h LiAIHJH,
On
O give Y,
49. A
nitne gives white precipitate with ammonical silver
is formed. Find the
2
ene, heating Z, 2,3 nitrate
1)
but ethylene cannot give because
Acetylene possess sp? carbon
but
Ainethyl

CH-C C-CH
structure of A. 2) Acetylene posses acidic hydrogen
S)
Acctylene possess low electronegative carbon
CH 4) Acetylene possess triple bond
50.
CH-CC-CH-CH monosodium salt of acetylene on treating with metnyi
CH
chloride forms
1) CH C.coOH 2) CH = C-CH,
C-C= CH
3) CHC= CCH 4) H - C= C-CH,-CH,
.
CH 1-pentyne and 2-pentyne can be distinguished by
these
of
1) Silver mirror test 2) lodoform test
None

3) Addition of
4)
52.
H 4) Baeyers test
NBS X (major Consider the following reaction
1 eq. product) ; X is: sequence
CH-C=C-CH, Pd-BaSOA5B
H
A& B, respectively, are
CH
(meso) CH, CH(Br) CHBr)CH,
CH,
CH CH,
Br 2) C ) CH, CH(Br) CH(Br)CH,
H

4)
Br
o 3)
CH
t ) CH, CHBr) CH(Br)CH,
H CH
&CH-C CH YNaBHZ is: 4) None of these
HSO,
53. In nitrating mixture
1) Acetone
HNO, acts as a
2) Propan-2-ol 1) Base Acid
) Propan-1-ol 4) Propanal 3) Reducing agent 4) Catalyst
54. Which of the
&Select the correct match following cannot form ozonide
1) Benzene 2) Ethene
Compound Ozonolysis products 3) Ethyne 4) Ethane
A. Acetylene 1. HCHO & CH 55. The order of activites of the various Ortho and
CH0 Para director
B. Ethylene 2. CH,CHO
-

C.Benzene 1) -0>-OH>-OCH,> -OCOCH,

3. One mole of (CHO),
D. 2-Butene 2) -OH-0>-0CoCH>-OCH,
4 3 moles of (CHO),
3) -OH-0r>-COCH, -OCOCH,
5. CHO
) A-3 B-2 C-5
4)-0>-OCH>-OCOCH, -OH
D-4 56. Which of the following is not meta directing group ?
2 A-4 B-2 C-1 1)-SOH 2)-NO,
D-3
3) A-3 B-5 3)-CN
4)-NH
C.4 D-2
A-5 B-1 C4 D-4 57. In the nitration mixture concentrated sulphuric acid is used

.osfiorm
form on with heating silver powder gives
1) As a sulphonating agent
2) As dehydrating agent
CH 2) CH 3) For the formation of nucleophile
CH 4) CH 4) As a solvent
&Coldandar HPt B
dil.Alk.KMnO,
) Bhylene glycol will oxidise acetylene to 58. A
alkane Alkene A may be
alkene
2) Ethylalcohol
)Oxalic acid 4) Acetic acid
(CH)C-Br ? C H C H B r
Cul
 ODJecuVe NGERT

NalNH PUnC
dh-
304
+ NaNH
1) 2,3-dimethyl but-2-ene 63.
C H - C E C - C H ,

2) 2,2,3-trimethyl butene product y is

3) 2,3,3-trimethyl butene 1) Racemic Mixture 2) Optically active
4) 2,3,4-trimethyl pentene
59.
3) Meso compound 4) Fom of prOdnctdive
Which of -OH
following carboxylie acid undergo fastest CH,-CH, -CH, -CH,
arboxylic
decarboxylation whon action with sodalime?
64.

CH,-CH,-CH, -CH,-CIac KoH

HSOJA
CHCOOH CH-COOH
Relation between
X & Y are-
1) Same product
2) Position isomers
3) Both can show Geometrical isomer
4) Chain isomer
NO
CHCOOHA CHCOOH
65. Find total possible isomers formed when..
en n-
catalytic reforming by reatment of ALO,. Ockanem
3)
600°C
1) 3 2) 4
Cr0as
3) 5 4) 6
OCH, CH 66. Match the following reaction with thei
OH involved meche
60.
Conc.HS0, Majo
A
(P) Cracking
(Q) Catalytic reforming
a Free radical
b. Free radical
suhgt
(R) Halogenation of C.
eliming
Free radical adlie,
alkane
(S) Wurtz Reaction d.

4) 1) P-b, Q- a, R - d, S - c
Dehydrogenation
2) P-b, Q -d, R - a, S - c
D 3) P-a, Q -b, R - c, S -b
61. R-Br
+Mg y etner, AD CH-CH-CH 4) P-d, Q-b, R - a, S - c
67. How much volume of air will be
Na B Bis needed for co
R-Br combustion of 5 lit of propane?
dry ether
1) 25 lit 2) 125 lit
1) CH-CH-CH-CH-CH-CH, 3) 100 lit 4) 135 lit
68. An organic
CH compound 2, 2 dibromo propane on tn
with Zn dust give X which on
treatment with HI gve
2) CH-CH-CH-CH-CHCH
1) HC-HC-¢-CH,
CH CH
CH CH
t3) CH-CH-CH-CH,
4) CH-CH-CH-CH-CH, 2) H,C-CH,CH-CH-CH-CH,
CH CH I
3) HC-CH-CH,
62. CH-C=CH+C,HMgBr- X+W (Y)
(A)
Which of following statements are correct regardingA
4) HC-HC-CH-H,C-CH
&Y
1) A&Y both have
same molecular mas CH
69. Which
2) A&Y both show
acidic behaviuor of the following
compounds
exhibitgeomd
will exnio
1Somerismn?
3) A &Y are same compound than A
1) 1-Phenyl-but-2-ene
2) 3-Phenyl-but-1-et
molecular mass
4) Y have lesser 3) 2-Phenyl-but-1-ene
- / 4

4) 1, 1-Diphenyl-prop
 ne
product
fromed when
acetylene reacts with 305
ochorous.
uhat
is cid? Hydrocarbons
2) CICH,CHO
CHCOCT 74. The
(]CHHO 4) CICH COOH 1UPAC name of- S
n
ot
the
fol.

compound has the lowest 1) 4,4-dimethyl-5,5-deithylpentane

tith
dipole 2) 5,5-diethyl-4,4-deithylpentane
CH
2) CHC= CCH, 3) 3-cthyl-4,4-diemethylheptane
H 4) 1,1-diethyl-2,2-dimethylpentane
y CH,CHC=CH 4)
CH,= CH -C= CH . Ofthe isomeric hexanes, the isomers that give the
Metlylbutare reacling with bromine in the and
maximum number of monochloro derivatives
minimuare
snalghtgrves main, mainly presence respectively
bromo-2-methylbutane

)
2-bromo 2-tncthylbutane 3-methylpentane and 2, 3-dimethylbutane
2)
omo-3-methylbutane 2,3-dimethylbutane and n-hexane
3) 2,
hromo-3-methylbutane 2-demethylbutane and 2-methylpentane
4) 2-methylpentane and
bromid reacts with 2, 2-dimethylbutne
ny/magnes
a mixture ofbenzene and Mg (OMe)Br
methanol to give 76. An organic compound with molecular formula
)&mIxture of toluene and Mg(OH)Br
CH, upon
0Zonolysis gave only acetone as the product. The compound
s nixture of phenol and Mg(Me)Br is
s mixture of anisole and Mg(OH)Br 1) 2,3-dimethyl-1
butene 2) 3-hexene
3) 2-hexene 4) 2,3-dimethyl-2-butene
*****

Match the Columns

MCQs
Match the reagent from Column I
which on reaction with 3. Match the
CH-CH= CH, gives some product given in Column II following reactants in Column I with the
s per the codes given below: corresponding reaction products in Column II.
Column I Column II
Column I
Column II
a Benzene+Clh AICl (1) Benzoic acid
a0Zn+H0 () Acetic acid and CO,
6) Benzene+CH,CIACh (ii) Methyl phenyl
O) KMnO /H ) Propan-1-ol ketone
Benzene+CH,COCIAIC (ii) Toluene
0)KMnO/0H (ii) Propan-2-ol
C) HOH (iv)| Acetaldehyde and a) Toluene KMnO,/NaOH iv) Chlorobenzene
formaldehyde (v) Benzene
e BH NaOH and H,O, (v)Propane-1,2-diol hexachloride
(a-t) (b)-(iv) (c)-(V) (d)-(i) (-Gi) 1) (a)-(ii) (b-i) (c-ii). (d)-iv)
2) (a)-i) (b-i) (c)-(iv) (d)-(ii)
(a-6iv) b)-6) (c)-(v) (d)-(ii) (-Gi) 3) (a)-Cii) (b)-(iv) (©)-() (d)-(ii)
aHii) (b-(Gi) (iv) (d)-) (e-) 4) (a)-(iv) (b-(ii) (c-(i) (d)-(i)
(-v) (b)-(iv) (¢)-) (d)-(ii) (e)-(i) 4. Match the reactions given in Column I with the réaction
types in Column II.
the
POnts
hydrocarbons in Column I with the boiling
given in Column II. Column II Column II
-
Column I
(a) CH=CH, +H,O () Hydrogenation
Column I
a) n-Pentane CH,CH,OH
i ) 282.5 K
D) iso-Pentane (b) CH, CH+H, (i) Halogenation
(ii) 309 K
c)neo-Pentane (ii) 301 K CH-CH
(c) CH-CH,+ ClL (ii) Polymerisation
-i) (b)-(ii) (c)-G) Cl-CH-CH-CI
(b)-i) c)-Gii) (a3 3 CH=CH - Cutube
Heat CH, (iv) Hydration
9la-Gii) (6-6) (c-Gi)
(a-tii) (b)-Gi) c)-(1i)
(v) Condensation
 306 Objective NCERT Punch
1) | Gii) -Ch
-u
2)
(a)-(iv) (b)-6) (c)-(ii) (d)-(ii)
(c) Ethyne
Dehydration,
iv) Electrophilic ofsubstitu
3)
(a)-(i) (6)-(ii) (c)-(iv) (d)-(ii)
(d) Butane ethana
(a)-(ii) (b)-iv) (d)-(ii) 1) (a)-(ii) (b)-(iv) (c)-(i)
5. 4) (a)-(iv) (b)-(iil) ()-(i) (d-6i)
Match the (c)-i) (d)-(i) 2) (a)-(iv) (b)-(iii) (c)-(ii)
following
Column (d)-()
Benzene I 3) (a)-i) (b)-(iv) (c)-(i)
(a) Column
(6) Ethene (1) Wurtz reaction 4) (a)-(ii) (b)-(iii) (c)-Gi)
(i) Evolves H, when heated with (a)-iv)
Na metal

Correct & Incorrect MCQs

1.
Which of the
)
Alkanes following statements is 2) Cis form of alkene is found to be leo
of atoms. in wurtz reaction incorrect odd
carbonformed trans form. Jess pokar t
contain nu nber
)Sodium salt of 3) The cis - isomers have higher dipole

propane. butanoic acid can be used to preparc corresponding trans- isomers. dipole moments th
Methane
method. cannot be
prepared by 4) In the case of solids, it is observed that t
4) Both kolbe's electrolytic has higher melting point than the cis the tr
.
(2) and (3). form
which of the
following
7. Select the correct statement:
alkanes? statement is not correct about 1) Partially deactivated palladised charcoal
1) The first is 1

2) Alkanes
four alkanes are Ziegler catalyst. KnOH
3) possess weak vangases.
der Waals 2) Alkynes on reduction with
sodium in liquid
Alkanes are almost non-polar forces. form cis alkenes. amt
4) There is molecules.
with
a
steady decreas in boiling point
3) Vicinal dihalides on treatment with
increase in molecular mass. of alkanes
molecule of ZnX, to form an alkene.zinc metall
3. Which of the
following known as dehalogenation. This reastio
A. statement (s) are correct?
n-pentane has
higher boiling 4) Both (1) and (2).
of reaction of alkanespoint
B. The rate than
neopentane.
with halogens is
>Br,>I2
C. Rate of
F,> Cl, 8. Which amongst the
following is incorrect statement?
1) Hydrogen halides (HCl,
2>1°. replacement of hydrogens of alkanes is :3°> to form
HBr,HI) add up to ale
alkyl halides. The order of reactivity
D. Boiling oi
point increases ith increase in hydrogen halides is HI > HBr> HCI.
1) A, B and C 2) A and D
branching. 2) According to Markovnikov's
3) A, C and D 4) B, C and D the rule,
negative par the
4.
addendum gets attached to that carbon
Select the incorrect statement/s: possesses lesser number of
atom ws
A. Alkanes contain carbon-carbon
sigma (o) bonds. 3) Peroxide effect is also hydrogen atoms.
B. Magnitude of torsional strain depends upon the angle of observed in addition of HCL
4) Peroxide effect is not
rotation about C-C bond.
H-I bond is weaker
observed in addition of
Hi
C. Staggered form of ethane has the maximum than H-Br bond.
torsional 9. Select the
strain and the eclipsed form has the least torsional incorrect statement/s about
strain. A. First three alkynes
members of
They are weakly polar inalkynes
D. are gases.
Staggered conformation of ethane is less stable than the B.
eclipsed conformation. C. They are nature.
1) A and B 2) B, C and D heavier than water and miscible withwatdt
soluble in
3) Cand D 4) B and C
D. Their
organic solvents.
5. Which of the following statements is incorrect about melting
with increase inpoint, boiling point ana do
nsityI n c r

alkenes? molar mass.

) A,B and C
1) Carbon-carbon double bond in alkenes consists of one 2) A and D
strong sigma (o) bond and one weak pi (7) bond. 3) A, C and D
4) Only C
2) Alkees are not attacked by electrophilic reagents. 10. Which
amongst the following is incorrect sta
3) The presence of weaker t-bond makes alkenes:unstable 1)-OH group activates the for theata
molecules in comparison to alkanes. an
electrophile at o and p-
benzene
ene ring
rinE
4) Strength of the double bond is greater than that of a
carbon-carbon single bond in ethane.
2) positions.
Halogens are moderately deactivating eror
Toupinthe
of aryl halides.
the following statement ? is incorrect
6. Which amongst 3) Chlorobenzene
of cis-
1Somers are higher than is more reactive than o
enzene

1) The boiling points the trans-isomers. the

those of the corresponding electrophilic substitution reaction.
4)NO, is a meta directing group.
 Statement Based MCQs Hydrocarbons 307

consist of two
se estions
qnd Statement-Il. While
statements
ents each,
Statement-i and 5.
pUestonsyoUare to choose answering
any one
Statemen
But-1-ene But-2-ene shows geometrical isomerism but
esponses
of the does not show.
ent-I and Statement-I are Tatement-II: Geometrical isomerism arises due to
n
Statement-Il are correct
Bolh
nent-I and
restricted rotation of the double bond.
6.

etement-I is
correct &
Statement-Il isincorrect.
e m e n e
Statement-I: lodination of alkanes is very fast.
Statement-l iincorrect. Otatement-II : lodination of alkanes is carried out in tne
incorrecs

Statement-I
is
s correct. .
presence of an oxidizing
agent.
wment,
Acetylene reacts with sodamide to
Statement-I: Alkanes are used as fucls.
evolve Statement-Il : A larger amount of heat is evolved during
Acetylene is a weaker
g a t e m e n t - l lA
: cer
acid than ammonia. combustion of alkanes.
8.
Benzene readily undergoes Statement-I : In ggered form, the electron clouds of C
ptement-

usituthon r e a c t i o n .
electrophoresis H bonds are as far as possible and it comes closer to eacn
other in
Benzeneis an unsaturated eclipsed form.
gyfement-Ii: compound. Statement-II : Staggered form of ethane is the least stable
Nitration of
re
ement-1:

yields m-dinitrobenzene.
nitrobenzene using nitrating 9.
and
eclipsed form is the most stable.
mAxture
Statement-I : Tertiary carbon atom is attached to three
ment-1: Nitro group
at benzene ring lower carbon atoms.
density at the m-position. the
Statement-II: 2,2-Dimethylbutane does
ent-: Staggered form is less stable than the tertiary carbon atom. not have any

T.
eclipsed 10. Statement-I: The second substituent may enter the
oment-I: The conformation in which the bond
Sarement monosubstituted benzene ring at either ortho,
pairs meta position. para or at
wo central atoms are very far from one another is called
gered form.
Statement-II: The position of the incoming
on the nature of the group depends
ww..wwwinwowd
entering group.
Assertion & Reason MCQs

raions: These questions consist of two statements 2. Assertion: Toluene on Friedal Crafts methylation
printed as Assertion and Reason. While and p-xylene. gives o
E
pestions, you are required to choose any answering
one of the
ng four responses. Reason: CH,-group bonded to benzene ring increases
electron density at o-and
f both Assertion an« Reason are True and the p-position.
3. Assertion: Nitration of
Reason is a correct explanation of the Assertion. the
benzene with nitric acid
requires
use of concentrated sulphuric acid
lboth
B not
Assertion and Reason are True but Reason
a
correct explanation of the Reason: The mixture of concentrated
9f Assertion is Assertion. sulphuric. acid
concentrated nitric acid produces the electrophile,
and
True but the Reason is
False. NO;.
Asertion is False but Reason is True. 4. Assertion: Tropylium cation is aromatic in nature
ertion: The
compou cyclooctane has the following
Snucturalformula
Reason: The only property that determines the aromatic
behavior is it's planar structure.
5. Assertion: Addition of HBr to 2-butene gives two
isomeric
products
Reason: Addition of HBr to 2-butene follows
h Cand has ajugated 8t-electron system but it is Markovnikov's rule.
an aromatic comi
npound. 6. Assertion: Benzene on treatment with excess of chlorine in
on:
(An + the presence of light give BHC.
nhg is not 2) m elects
ectrons rule does not hold good and
planar. Reason: BHC is also known as gammexane or 666.
 Objective NCER
7.
Assertion: The ERT Punch-
nitrating
benzene contains
conc.
eagent for carrying out nitration 9. Assertion: Boiling point of
that of n-butyl alcohol. tert-butyl alcgha
teason:
the HNO, acts H,SO,1and conc. HNO,
presence of conc.as a baseand produces 2 NO", ions in Reason: Boiling point decreases with
th branefin
8.
Assertion: H,SO,
peroxide to Propene reacts with HBr in presence of
benzoy
10.Assertion: Both cyclopropane
and propene g
Reason: In 2-bromopropan. presc
give reactions readily.

presence of pero
propene follows peroxide, the addition ofHBr to Reason: Cyclopropane and
free radical propene
mechanism. other

NCERT Exemplar Mcas

1.
Arrange the
points: following in decreasir
asing order of their boiling 1) A and B as major and C as minor produ
A. n-butane
C. n-pentane B. 2-methylbutane 2) B as major, Aand IC:as mino
1) A>B>C>D D. 2, 2-dimethylpropane 3) B as minor, A and C as
major
products
3) D C>B>A 2) B C> D>A 4) A and B as minor and C as product
6. Which of the
major prodie.
acts
.
Arrange the halogens F 4) C>B>D>A following will not show
geometrial
cal sone
+
increasing CL, Br, L in order
reactivity with alkanes: of their H F
1) 1
<Br,<Cl <F, =
C1 2)
3) 2) Br<
F<Cl, Br, 1, < <
4) Br,
Cl, <F, <1, HC C
3. The
increasing order of reduction<1Cl, <F 3) CH CH
zinc and
dilute HCl is: of alkyl. halides H.C 4) CH
1) R- CI
with CH, CH
2) <R-1<R -Br
7: Arrange the following
decreasing reactivity withhydrogen halides in ordsr
R-CI<R-
3) R-I<R- Br Br <R-I
1) HCI> HBr> HI propene:
4) R-Br <R CI 2) HBr> HI >
<R-I< R -CI 3) HI> HBr> HCI
4) HCI> HI >
HCI
4. The
correct IUPAC name of the 8.
Arrange the
following carbanions
HB
following alkane is: deçreasing stability: in order

H,C-CH-CH-CH-CH-CH-CH-CH,
CH
A. HC-C=C
1) A>B>C
B. H-C=C
2) B>A>C
C.H-
CH, CH 3) C>B>A
1) 3,6-diethy1-2-methyloctane CH 9.
Arrange the following 4) C>A>B
2) 5-isopropyl-3-ethyloctane the rate of alkyl halides in decreasing
B-elimination reaction with alcoholic Kt e
3) 3-ethyl-5-isopropyloctane
A. CH-C-CHBr
4) 3-isopropyl-6-ethyloctane
5. The addition of HBr to
1-butene gives a mixture CH
A, B and C: of products B.
Br C.
CH-CH, -Br
GH, 1)
CH,-CH,
A >B>C CH,-Br
-

HC CH H CH 3) B>C>A 2) C>B>A
H Br 10. Which of the 4) A>C>B
(A) (B) combustion? following reactions of metna nethane is incon

CH-CH-CH-CH-Br 1) 2CH, +0,Cu/S23 K/10.

(C) 2) CH+ tm2CH,OH
The mixture consists of: 3) O,MoD>HCHO
CH,+0,
+
H,O
4) CH, +20,
C(s) +2H,O()
Co, (g) +2H,O(
 309
Hydrocarbons

Answer Key
12 3 4

2
18 19 2021 22
4
3 910
4
11 12 13 14 15 1617
23 24 4 4 2 2 4 1
2 2 5
35 36 37
3 3 3 26 2728 29 30 31 32 33 34
38 4 3
40 3 4
2 2 3 41 42 43 44
3 3 2 4 4
1 3 45 4647 48 4950 51
52 54 55 56 4 1
57 58
4 3 2 2 2 2 3
3 4 59 60
3 1 61 62 63
71 2 64 65 6667 68
69 72 73 2 2
KERT

4 75 2 2 4 2 3 3
1 4 3 2 76 77 78
3 4
79 80 81 82 83 84 85
86 87 88 89 3
MCYs
90 91 92 93 9495
2 2 4 3 2 4 2
3 2 3 2 3 96 97 98 99 100 101 102
4
103 104 105 106 107
108 109
4 3 2 4 2 3 1
4 2 4 3 2
110 111 112 113 114 115 116 117 119
2 2
120 121 122 123 124 125 4 3 3 1 2 2 3
126 3 3
2 2 3 127 128 129 130 131
4 3 '4 132 133 134 139
137 1
138139 140 141 142 2 2 4 4 2 1 3 3
2 4 3 3 1

123 456789 10 11
12
2 1 3 2
3
12 13 14 15
13 14 15
167
16 17
18 19 20 3 3 4 3 2
21 4
23 24
2 4 3
27 28 29 30 31 32 33 34
2 2 3 3 3
Booster 35 36 37 38 39 40 42 43 44 45
4 3 4 4 2
MCOs 2 3 2 1 46 48 49 50 51
1 2 2 2
52 53 3 2 2
54
2
58 59 60 61 62 63 6465 66
1 4 1 4 2 67 68
3 2 2 3 2 3 2 2 2 2
69 70
3 74 75 76 3
13 2 2 1
3 4
dtch he
ms MCQs
34 5
2 1 4 2

rect & 12 345 6 7 9 10

"Iect MCQs 1 4 3 2 2 3 3 4 3
tement
AMCQs
3
4 5 6 7 8 9 10
1 3 4
141313
sertion &
on MCQs
4 6 8 9 10
1 133 2 4 4 2
NCERT
plMCo
or 234 5 6 7 8 10
-MCQs 4 1 2 4 3
11 4 3 2