Caustic Potash SDS
Caustic Potash SDS
Caustic Potash
Revision 3, Date 31 Jul 18
1. IDENTIFICATION
2. HAZARD IDENTIFICATION
Hazard Classification Hazardous according to the criteria of the Globally Harmonised System of Classification and Labelling of
Chemicals (GHS)
Pictograms
Precautionary Statements Prevention P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P260 Do not breathe dusts or mists.
Response P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing.
Rinse skin with water/shower.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
Storage P405 Store locked up.
P406 Store in corrosive resistant container with a resistant inner liner.
Disposal P501 Dispose of contents/container in accordance with local / regional / national /
international regulations.
Dangerous Goods Classification Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods
by Road & Rail (ADG Code)
HSNO Classifications Health 6.1C Substances that are acutely toxic- Toxic
Hazards
8.1A Substances that are corrosive to metals
8.2B Substances that are corrosive to dermal tissue UN PGII
8.3A Substances that are corrosive to ocular tissue
Environmental 9.1D Substances that are slightly harmful to the aquatic environment or are otherwise
Hazards designed for biocidal action
9.3B Substances that are ecotoxic to terrestrial vertebrates
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients
Chemical Entity Formula CAS Number Proportion
Potassium hydroxide KOH 1310-58-3 <=100 %
General Measures If safe to do so, move undamaged containers from fire area. Cool containers with water spray until well after fire is
out. Avoid getting water inside containers.
Flammability Conditions Non-combustible; Material does not burn.
Extinguishing Media If material is involved in a fire, use dry chemical, Carbon dioxide (CO2), foam or water spray for extinction - Do not
use water jets.
Fire and Explosion Hazard Risk of violent reaction or explosion: Contact with metals may evolve flammable hydrogen gas. Contact with moisture
or water may generate sufficient heat to ignite combustible materials. Containers may explode when heated.
Hazardous Products of Fire or heat will produce irritating, toxic and/or corrosive gases, including Potassium oxides.
Combustion
Special Fire Fighting Contain runoff from fire control water or dilution water - Runoff may be toxic and/or corrosive and pollute waterways.
Instructions
Personal Protective Equipment Liquid-tight chemical protective clothing (splash suit) in combination with self-contained breathing apparatus (SCBA)
should be worn.
Flash Point No Data Available
Lower Explosion Limit No Data Available
Upper Explosion Limit No Data Available
Auto Ignition Temperature No Data Available
Hazchem Code 2W
General Response Procedure Ventilate enclosed spaces before entering. ELIMINATE all ignition sources (no smoking, flares, sparks or flames). Do
not touch or walk through spilled material. Avoid dust formation. Do not breathe dust; Prevent contact with eyes, skin
and clothing.
Clean Up Procedures Collect material (sweep or vacuum up) and place it into suitable containers for later disposal (see SECTION 13).
Containment Stop leak if safe to do so – Prevent entry into waterways, drains or confined areas. Prevent dust cloud. Cover with dry
earth, sand or other non-combustible material followed by a plastic sheet to minimise spreading or contact with rain.
Do NOT get water inside containers.
Decontamination Wash away remainder with plenty of water.
Environmental Precautionary Spillages and decontamination runoff should be prevented from entering drains and watercourses.
Measures
Evacuation Criteria Spill or leak area should be isolated immediately. Keep unauthorised personnel away. Keep upwind and to higher
ground. Large spill: Consider initial downwind evacuation of areas within at least 250 m; Immediately contact Police
or Fire Brigade.
Personal Precautionary Do not touch damaged containers or spilled material unless wearing appropriate protective clothing (see SECTION 8).
Measures Large spill: Wear self-contained breathing apparatus (SCBA) and chemical splash suit.
Handling Safety showers and eyewash facilities should be provided within the immediate work area for emergency use. Ensure
adequate ventilation (local exhaust or respiratory protection required). Handle in accordance with good industrial
hygiene and safety practice. Avoid dust formation. Do not breathe dust; Prevent contact with eyes, skin and clothing.
Wear protective gloves/protective clothing/eye protection/face protection (see SECTION 8). To avoid violent reaction,
ALWAYS add material to water and NEVER water to material. Absorb spillage to prevent material damage.
Storage Store in a cool, dry and well-ventilated place, in an area having corrosion-resistant concrete floor. Keep container
tightly closed - Check regularly for spills. Avoid exposure to moisture/humidity. Avoid exposure to air. Keep away
from food, feedstuffs and incompatible materials (see SECTION 10). Store locked up.
Container Keep only in the original container or corrosive resistant container/container with a resistant inner liner.
General Information The substance is a strong base, it reacts violently with acid and is corrosive in moist air to metals such as zinc,
aluminium, tin and lead, evolving flammable hydrogen gas. Reacts with ammonium salts to produce ammonia and
causing fire hazard. Attacks some forms of plastics, rubber or coatings. Rapidly absorbs carbon dioxide and water
from air. Contact with moisture or water will generate heat.
Chemical Stability This material is stable under recommended storage at normal temperature and pressure.
Conditions to Avoid Avoid dust formation. Avoid exposure to moisture/humidity. Avoid exposure to air. Avoid contact with organic
materials.
Materials to Avoid Incompatible/reactive with strong acids, water, metals (when wet), ammonium salts, halogenated hydrocarbons,
maleic anhydride.
Hazardous Decomposition Fire or heat will produce irritating, toxic and/or corrosive gases, including Potassium oxides.
Products
Hazardous Polymerisation Will not occur.
General Information - Acute toxicity: Harmful if swallowed; Corrosive to the gastrointestinal tract, causing abdominal pain, burning
sensation, perforation of upper and lower gastrointestinal tissues, shock or collapse.
- Skin corrosion/irritation: Causes severe skin burns; Corrosive to skin, causing redness, pain, blisters, liquefaction of
skin and damage to underlying tissues, deep and painful wounds.
- Eye damage/irritation: Causes serious eye damage; Corrosive to eyes, causing redness, pain, blurred vision, severe
deep burns; Can result in permanent injury, blindness.
- Respiratory/skin sensitisation: Not considered to be a skin sensitiser.
- Germ cell mutagenicity: Chronic, systemic health effects are not expected.
- Carcinogenicity: Chronic, systemic health effects are not expected.
- Reproductive toxicity: Chronic, systemic health effects are not expected.
- STOT (single exposure): Corrosive to the respiratory tract, causing burning sensation, cough, sore throat, laboured
breathing, shortness of breath, possible pulmonary edema. Symptoms may be delayed.
- STOT (repeated exposure): Chronic, systemic health effects are not expected. Prolonged or repeat skin exposures
can result in dermatitis.
- Aspiration toxicity: No information available.
Acute
Ingestion Acute toxicity (Oral):
- LD50, Rats: 273 - 1,230 mg/kg bw.
Carcinogen Category None
General Information Dispose of contents/container via a licensed disposal company and in accordance with local/regional/national
regulations.
- Waste treatment method(s): Dissolve or mix the material with a combustible solvent and burn in a chemical
incinerator equipped with an afterburner and scrubber.
Special Precautions for Land Fill Contaminated packaging: Dispose of as unused product.
Hazchem 2W
Pack Group II
Special Provision No Data Available
Sea Transport
IMDG Code
Air Transport
IATA DGR
Dangerous Goods Classification Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods
by Road & Rail (ADG Code)
National/Regional Inventories
Related Product Codes CAPOTA0600, CAPOTA0700, CAPOTA0800, CAPOTA0900, CAPOTA0950, CAPOTA1000, CAPOTA1001,
CAPOTA1002, CAPOTA1003, CAPOTA1004, CAPOTA1005, CAPOTA1006, CAPOTA1007, CAPOTA1008,
CAPOTA1009, CAPOTA1010, CAPOTA1011, CAPOTA1012, CAPOTA1013, CAPOTA1014, CAPOTA1015,
CAPOTA1016, CAPOTA1017, CAPOTA1018, CAPOTA1019, CAPOTA1020, CAPOTA1050, CAPOTA1100,
CAPOTA1200, CAPOTA1201, CAPOTA1202, CAPOTA1203, CAPOTA1204, CAPOTA1205, CAPOTA1206,
CAPOTA1207, CAPOTA1208, CAPOTA1209, CAPOTA1210, CAPOTA1211, CAPOTA1212, CAPOTA1213,
CAPOTA1214, CAPOTA1215, CAPOTA1216, CAPOTA1217, CAPOTA1218, CAPOTA1219, CAPOTA1220,
CAPOTA1221, CAPOTA1222, CAPOTA1223, CAPOTA1224, CAPOTA1225, CAPOTA1226, CAPOTA1227,
CAPOTA1228, CAPOTA1229, CAPOTA1230, CAPOTA1231, CAPOTA1232, CAPOTA1233, CAPOTA1234,
CAPOTA1235, CAPOTA1236, CAPOTA1237, CAPOTA1238, CAPOTA1239, CAPOTA1240, CAPOTA1241,
CAPOTA1242, CAPOTA1243, CAPOTA1244, CAPOTA1245, CAPOTA1250, CAPOTA1270, CAPOTA1300,
CAPOTA1350, CAPOTA1351, CAPOTA1352, CAPOTA1353, CAPOTA1360, CAPOTA1400, CAPOTA1500,
CAPOTA1600, CAPOTA1700, CAPOTA1800, CAPOTA1813, CAPOTA1814, CAPOTA1815, CAPOTA1816,
CAPOTA1817, CAPOTA1818, CAPOTA1819, CAPOTA1824, CAPOTA1826, CAPOTA1827, CAPOTA1828,
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CAPOTA1836, CAPOTA1837, CAPOTA1838, CAPOTA1839, CAPOTA1840, CAPOTA1841, CAPOTA1842,
CAPOTA1843, CAPOTA1844, CAPOTA1845, CAPOTA1846, CAPOTA1847, CAPOTA1848, CAPOTA1849,
CAPOTA1850, CAPOTA1851, CAPOTA1852, CAPOTA1853, CAPOTA1854, CAPOTA1855, CAPOTA1856,
CAPOTA1857, CAPOTA1858, CAPOTA1859, CAPOTA1860, CAPOTA1861, CAPOTA1862, CAPOTA1863,
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CAPOTA2000, CAPOTA2100, CAPOTA2150, CAPOTA2155, CAPOTA2250, CAPOTA2255, CAPOTA2500,
CAPOTA3000, CAPOTA3001, CAPOTA3002, CAPOTA3003, CAPOTA3004, CAPOTA3005, CAPOTA3010,
CAPOTA3011, CAPOTA3020, CAPOTA3030, CAPOTA3031, CAPOTA3050, CAPOTA3060, CAPOTA3100,
CAPOTA3101, CAPOTA3102, CAPOTA3103, CAPOTA3104, CAPOTA3500, CAPOTA4000, CAPOTA4001,
CAPOTA4002, CAPOTA4003, CAPOTA4600, CAPOTA4700, CAPOTA5000, CAPOTA5100, CAPOTA6000,
CAPOTA7000, CAPOTA7500, CAPOTA8000, CAPOTA8050, CAPOTA9000, CAPOTA9050, CAPOTB4400,
CAPOTB4500, CAPOTB4501, CAPOTB4502
Revision 3
Revision Date 31 Jul 2018
Key/Legend < Less Than
> Greater Than
AICS Australian Inventory of Chemical Substances
atm Atmosphere
CAS Chemical Abstracts Service (Registry Number)
cm² Square Centimetres
CO2 Carbon Dioxide