ELECTRo CHEMIsTRY NUNE RICA CS

ExAMPLE PROBLEMS:
Pprob:3! Kepresent tte cetl is wtil tte
fotloung ueacbon ctekes place

(o-0o0IM) M +2A96
Co.l20m)

Calcuate ut E,, 3.I7V

Ecel
Soln

eel Ntatiog
AsAg
(0-130M) Co. oootm)
o.130
Eceu Ecey 2 ooo)
= 3.)7V .024 SS dog
h)2
= 3. -0.029 5y o o13
lo-8
= 34-o.02958 log (o3 xIo)

= 3 t- 025sS X 7./I 39)

..Ere! 3 H- .2) = 2. 96 V
Example protlems :
prob:32 Conotant
Caleutate tte apuilil riun,
Sact'y: 2+

Sotution.

o.e6V K2 =S.6
Consi de

= o X

1S
= lo x 398
 volt =
1Toule 1
coulomb 4
coujom b 1
No
=-212.21
F=S6C Shce
kTm1 T-2|2.
27
Tmo1 2)227 - =
x) $6SDO E-2x
Z+
cell
Sofn
CuG) +
the trenersy Cisbs
dar sten Caleulate iscell Dani
petentio!
tr elechode Standa 7he
'33 prc
proleng. Exampe
 chamcteristis
2: Mantiss

loq 2=0.301o
Smatisa
char decima
SeientHe notatio characterisie value
=5.678xIO 3
5678.o
= 5.678 xlo
561.6
56.78

5.6 7 Xo
=

to poue
Important fomulass

|og (a/ =Jos a -Jo_ 6

=o.TS42 t 3 dos lo 1536

7542

O.72 t 2()

2.154 2
 74) 39
(-3 -.3oo
(o.bo2| .(o699o
-z)-
-4
)
3 o004) (o-dos
. (0-os) los
Co.o2)2 log
|0 ? =
00
2458 075Y2
) .os
to
os6
78 value
9 dos Fund S-3)
not
= 67s. lo_
|.752
 = - | 3olo +3.379
3 3979
oo2) 2 oqtA 2o969

ANTILO,
velue
to fin autitos forr potitive

Ex

Fiud te autlos vale y . 256

/8.03

fr:2 5.9257
Fund the
o.93
5t!=6

S6 2 4
S.624 x to
 8

A.do 35.73/5 =

254! 36

53826
Ans 5.3ga xlo 53 9

loo7

Ex:5

o.9s3)
S994
2
8976 8976
s: 8.914
 ELECTRO CHENPRoRLEMS
BoOk
Wte the

(o.ooo)
mglMg2t = 2-37
Ectfeu = o34

Ecee E -E, loSS9 2e

= 0-24 -(-23 7) M tcuM +Cu

Eceu = 2:7 V

0.00o/
= log (o.oo1)- loy .oooI)
-tos o xio?
.000o+-3) 0.0000 +c4)
Jos a = los,a
3 -c4
= -3t¢ = 1

E ce
 wite Nermt epueaton tEME
29 Pk.
EFe2Fe = -ot

Fe t24t Fe+ H
red

los (I
=0- o44)

= log ( xio)-lej )
= 0+3)- o

= o.44 - 0.o3 (-3)

Ecel
Prob3 wie tte nenst esuati § ey 9 tte cel

at 29 k

co.osom)"
H Coozen)/"E SHE

21

Ecey Etet o.os9o

h
Red
.n=2_

o.o50
Ere E-E
=D-Co.
2

=04-o.o 29 SS los
O.DoD

50C

o.0004 Aio4
=/25
=04-0.0 25 sS os 2S

=D4 -O.o25 2096

(-0.0b196
0o78o4
 12
Wsit the Nernst eguatiy enf ke cell

298*

(S (ooloM (0.030M)

O.o9)dog

:h2

=-l.D8 O.02 $SS los

(o.ooo) (o. oso)

Ox16)9xhe)

Jog las)= le5 a ttag

+ -a dog to) 4.o©O0

= -4

= o952 +-4¢ dos lo)

o9592
o9s92 +40)
-3 04S8
3oE S
 13

=-l.oR -o o2455 (t. o4s)

o20&

E ce = - l 298

reaeton betweay
Predict it tte
Onf SE.P rales,
te torburing fasi lfe not

3+
(a)

34 +o.S4V
Fe cag) and Br 4)

2+

|ecteu
know Hal,
we ie, Spontan eous
AGE-nEE

poitie

24 24
Fe Fe
oxi,
(ay)
 14

E cel=o23 V

feast bte

) Fe and B

t
e >Fe
Ox

)o77

e = -o32
- ve ale

t fesible.

o. So-34

+e alue
 5
3+
) Ases and fe
3+ + 24
Ag + Fe + Fe
ra_y

tie atun; dh =tue (not feasibe

2+
ane
(5)
3+
+ fe
+ Fe

o32 V o=-ve (feaoible)

 Calcwlate ta ctanela cee potental q Galane
heatôy take place.
totlouing
t
2ce + 3co,
(a)
2 + 3cdas

+ Ag co
Calcate tke eguil'bun, Constant

2Co + 3c2+ 2 cr
3+

7in be
Givey: = -07e

Sotn:

-o4o to7y

cey

-196 P6o mot

= -|96. G6o KI ot
 A,G = -2-303 RT dog ke
- 146 gto

-196 &to
2-3o3 x .3/ x 23

Jos ke = 34. so4

k = Antlog (34 sol

k 3.174 xo

prcb :0) 24

Fea + AsaA
Given.

Soty:

,G= -nFE
= - | x 96SDO

= -295S C m o t - 2 4 s t m 1

=-2 895 kgmo

A,o= -2.302 RT log k
S -2-3o3 x &.914 x 2$ xl9 e
- 233
- 2g
= 0.5o 74
-2-303 x 8.34 x218
= A.log(o.so74) = 2217