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HIGHLY THEORETICAL ↳ S BLOCK

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A- CHEMISTRY 180
1-

PBLOCK JOSH
https://aph.bailin.io/nitesh
↳ dustbin
regular

→ TAG
D and F BLOCK

D- BLOCK Last e- in Cn Dd
-
orbital
↳ Penultimate shell
General Electronic ' '

(n 1)d 0ns
-

0-2
% -

Configuration
43 to 612
Transition elements 8-
incompletely filled d- orbital
either in as or in onidatoir state .

Mn [Arf 3d5 us
orbital
↳
incompletely filled
d-

'° •

Cu [An] 3d us

Cut [Aee]
'°
3d us

orbital
uwiomfbbly filled d-
2
Cut 3d 9
°
AH] us →
2nCAeif3d0us2DBh0CKznNotznt2@trf3.d
412

'°ys°
43 to a12
ihhntilioir
Cd
element Transition element

Hg 63 to all
D- BLOCK
Scf
'

4ᵗʰ Period 3d series → zn3°

39 48
ud Allies Y
5ᵗʰ Period →
Cd

daft
"
6ᵗʰ Period 5d series →
,
Hf Hg&°
"
series
" "2

7ᵗʰ Period Gd → Ae ,
Rf Cn

Lanthanides → 2--58 to 71 PG

2--90 to 103
Adinoids → PF
 ]
Lanthanides → series
f. block
Actinoid

]
Lanthanum 2--57
element d- block

Actinium 2--89
So Ti V Ge Mn Fe Co Ni Cee Zn
}
'
3d2 3d 3d5 3d5 3d° 3d73d8 3d
"
3d
'°
3d
Usf Ust 482 4s
'
qg2 482 482 482 Us
'
4s2

Y be Nb Mo Te Ru Rh Pd
Ud
" Ag
ydlo
Cd
yd
"

58° 58 ' 582

Ta the Rt Au
Hf 0s
Hg
La w In

5d9 5d'° 5d'°

gg.BE
' '

6s 68
Properties :-

an danot

↳
High
Tensile Cd
fan
'
→ Malleable ,
Ductile Hg kathie
Mn
↳ tusture
PHOTO
↳
High
Thermal and electrical
conductivity Telegram
channel
↳ Less volatile
# MP and BP 8-

Moreno .

of
valence e- Movies metallic
bonding
lwfouiedé )
GO
↓
Mollis MPIBP

:O
Man
unpaired
e-
g.
↳ 912
To MPIBP
µ, Highest Zn Min

BPIMP
w Cd
↳ MPIBP

suddenly falls Hg
 energy required
atomisalñen to break
#
Enthalpy of metal lattice § convert into

goseoeet.IM '

- i - i -

vanadium
i -
zd series

Ma
1 I ) ul
-0-0-0
-
→
0cg

i i Y
- - -
Its Atomic Size

3d series So > Ti > v > be > Mn > Fe=co=Ni n

→ -

-
\

off Screening Zeffs

--

effect Sirleaf
* 2 Factors
Atomic size effect
i
) Zeff 3dL Uda 5A
ii
) screening effect kaathanoed
contraction
size a

Igg
✗
Screening effect
 267 Electronic
Ionisation
Energy
.

A-
configuration
3d Sc < Ti > v < be < Mn < Fe > co > Nicker

series

orbital
IE
of
a Cd
Hg Highest
do
fully filled
S2

Iea Cu
IEA of be > Mn of
Gi rent tight how
"
cut
3d5 3d5 Us
3d
"
* Oxidation state

All d- block element show valuable

↳ OS
Manos = +8 Odoy
So zn
encept 0s Ru
3d series
Se Ti V be Mn Fe Co Mi Cee en

+2 +2 +2 +2 1- I
+ 3 +2 +2 +2 +2
+3 +3 +3 +3
1- 3 +3 +3 +2
+4 +4 +4 +
+4 + y +
y y
+5
+5 +5
+ 6 tb
+ 6
+7
* Halides and Orioles

Halide
=

Ti V be Mn Fe Cee Ni Cee Zn
Se

Tila VX2 Gexa MnX2 Feta 6×2 Nix , Cui

✗ 42

No TiX3 VX} Crxg MF} Fetz Cofz Cldzxz

Halide Tilly Vxy Cuxu MnF4
VF5GF5
Vas ✗
Aifb
+7

does not exist ( stirred hindrance )

MnFy
F
FsµyÉ F

F
+7

Moroz F- exists ✓

↳ multiple bond

E
Mn

0--110×0
 ciiaxa exist
enaft beak

medium and
cut
compound
unstable in
eq
.

undergoes
disproportionation
2 Cut cut ? caq ) + Cuts)
log )
- .

In medium
aqueous ,

High Hydration dnugy

Cut
2
is _MOU stable than Cut

↳ HE
High
Oxide sets 0-2 £203
3d series
↳

Se Ti v be Mn Fe lo Ni Cee be

GO MO Feo Coo Mio Cuomo

Tio V0
Scaoz
"
203 9203 Mn203 Fe203 620g Ago
Tizoz
Tioz V2 y Croz MnOz Fezoy
↳ mined oxide
7205 Mnzoy
+2
+3
Feo .
Fez03
GO }
Mnz 7
#
Magnetic Property
Diamagnetic Paramagnetic Ferromagnetic
→

ounfvaiiede
→ attest
e-
one
unpaired
→
repelled by magnetic
→ Attraction
by magnetic
→

rhythm
attraction
field field
µ = 0 µ=Ñ+Ñ BM
↳
noofwfaiedé
 Find Mnt "
of
it
Eg
Ctr] 3d5 us
-

Mn

[An] 3d3 us
°
Mnt"

NÉE 3
impaired e-

µ =
Ñ+ BM
A- 3

=
Fs BM
 kÑi0u Purtle
F- colour
of compounds ligands
↳ colour change Transfer
unpaired e-

VIBay org

eg .

demission
→

→
1 I 1 1
transition
d- d

sets ◦
unpaired }
e-
tag
znt2 Colourless
 Catalytic Property
* % -

°o° variable
they
↳ show 0s .

Contact Process % -
V2 05
P Bloke
Haber's Process 8- Fe

Nil Rtlpd
Hydrogenation
: -

Fet
2
Fet 3
 choli
Interstate
compounds
# % - H, C N B
, , atoms aroids )
↳ interstate
0-0-0 occupy sites

&:f High MP
→

Very hard
→

① ÷:& →
chemically inert
→
Have metallic

conductivity
IF ALLOY FORMATION
↳ Mixture 2 or more metals
of
↳ size of
form alloy metals should be almost
To ,

Same .

BRASS : -
Cee + 2h

BRONZE :- Cee + Sn

Gun metal : -
Cut Ser + an

German Silver :- Get an + Ni

A- Electrode Potential Da= -
NFE

↳ reduction Potential E- + ve tennis Possible

☆fgwwwgTt¥lE=
_

eennnot Possible
/
ve
Mta M
-

↳ aeaannot
H2o
displace
NCERT
3d5Mn+2 znt-zd.IO stable EC Nitz
High HE
↓ ↓ niger -
ve
✗ ↓
electrode
High ve
-

Mm U Ni
Potential electrode Potential
 / M+2
+3
µ

Sets Sett Electrode Potential

Highly ve
-
-

'
AC] His 3d

stable unstable

zn+3 Electrode Potential

→ zn+2
"
Highly + ve

3d9 3d
unstable stable
Muta → Mnt3 Electrode Potential

305 3d4 be
-

stable unstable
IF Potassium Dichromate Kabra 07

PREPE RATION chromite one +

Washing soda
Feceeaoy Magog

1) FecrzOut NazC03
+ 02 →
NazCroy + Fez03 + CO2
sodium
chromate yellow
2) Naz Croy + [Ht] →
Navy 07
Sodium
Dichromate
3) Naira 7
+ KU →
K2Ay07 + Mall
Potassium
Dichromate Orange
Chromate Dichromate GeOy2¥+oyOÉ
Goya GyOy2- Yellow
-

OH
-

orange

( I
i "

%: ÷
-

÷
:)
kaiiiaoy .

strong oxidising agent

in acidic
medium
+6
H+ Get}
K2Oy0z + → +6 +3

Goof Gt3
-

Rabidly + → ,_

+402
-

I _
Is

Has → S

Sn+2 → Sn+4

Feta → Fe+3
%
, up
-

→ ¥02
 chloride Test
A-
Chromyl
metal chloride + cone .
Hasout 429202

↓
chloride
Croaaz chromyl
Red
vapour
 ( Kundu)
A- Potassium
Permanganate
Preparation Mnoa Pyrrhotite ore

Mroz + KOH + 02
→
K2Mn0yar⑥

6 +7
Manganate ton @nou2)
+4
÷ Machi
+

Naoya Mulla
Disfeeofoetn
-

+ + H2O

Permanganate
Purple
Commercial Prepare
Mn02 ÉÉg MnOy2-
+
onidesi with
Air or HNO
}
Manganate
MnOy2- _# Multi
Ouidalo
Permanganate
half
Mn+2 52082 Mnoci SOW
-

- +
+

Peimoganale
Manganate "
Permanganate
Mudug
Mnou

-1+6 9-7+7
Mn
Mn
110+0
-
o
-
"
"
110
o
0

"
3d° CHARGE
3d
TRANSFER
Paramagnetic Diamagnetic
.

GREEN PURPLE
 Kilroy in Acidic medium
N0TWA__ % -

Ninon Mutt we don't use Mclain

-

acidic medium
C2Ou2
-

→
CO2 Mnt
≥
Hut lhhlnoy →

Feta → Fet} 1- U2

2- →
22

S2
-

→ s

+50,2 %
-

2-
→
,
 medium
Ktllnoy in Neutral / very slight alkaline
+7

KMn0y → Mutt

↳ Out → CO2

S2
-

→ S

g- →
+25oz -
NO
TwA__ 8-
V20} Basic
down 0s Basic
v20 ,
Amphoteric
Intermediate OS
Amphoteric Basic
Geo
0s Acidic
Higher
+ 6 +6 chaos Amphoteric
Georg 1- H2O → H2Cr04 Acidic
Georg
1- 7 +7
Mna +
H2O Mna07 Acidic
7- →
HMn0y
 F BLOCK
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