SAFETY DATA SHEET FOR CHEMICAL PRODUCTS

（SDS）

Report No. NB2022054062 Date: June 23, 2022 Page: 1/9

Applicant Name : SHENZHEN ESUN INDUSTRIAL CO., LTD.

Applicant Address : WUHAN UNIVERSITY BUILDING A401, NO.6 YUEXING 2 ROAD,

NANSHAN DISTRICT, SHENZHEN, CHINA 518057

Product Name : Water Washable Resin

Received Date : May 30, 2022

Compilation Period : May 30, 2022 to June 23, 2022

Regulatory Requirements : As requested by the applicant, the Safety Data Sheet is prepared
according to Globally Harmonized System of Classification and
Labelling of Chemicals (GHS) Rev_9（2021）.

This report cannot be reproduced partly, without prior written permission of Laboratory.Any unauthorized
alteration,forgery or falsification of the content of this document is unlawful. Unless otherwise stated the results
shown in this test report refer only to the sample（s） tested.

No.1, 8/F, Shengfeng Road, Venture Industrial Park, Xinhe Community,Wanjiang District, Dongguan City, China

Tel：400-877-6107 Website：www.nbtscn.com

Fax：0769-22777508 E-mail：newbest@nbtscn.com
 SAFETY DATA SHEET FOR CHEMICAL PRODUCTS
（SDS）

Report No. NB2022054062 Date: June 23, 2022 Page: 2/9

SECTION 1. Identification of the substance/preparation and company

1.1 Product Identification : Water Washable Resin

1.2 Model No. : /

1.3 Recommended Use : 3D Printing

1.4 Manufacturer Name : SHENZHEN ESUN INDUSTRIAL CO., LTD.

1.5 Manufacturer Address : WUHAN UNIVERSITY BUILDING A401, NO.6 YUEXING 2

ROAD, NANSHAN DISTRICT, SHENZHEN, CHINA 518057
1.6 Manufacturer Tel : 86-755-26031979

1.7 Manufacturer Fax : /

1.8 Manufacturer Email : BRIGHT@BRIGHTCN.NET

1.9 Emergency Phone : /

SECTION 2. Hazards identifications

2.1 Hazard Class:

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) (part

2~4), classification of risk categories.

Acute toxicity, oral, categories 4

Skin corrosion/irritation, categories 2

Sensitisation, skin, categories 1
Serious eye damage/eye irritation, categories 2

2.2 Pictograms:

2.3 Signal word:

Warning

2.4 Hazard description:

H302 Harmful if swallowed

This report cannot be reproduced partly, without prior written permission of Laboratory.Any unauthorized
alteration,forgery or falsification of the content of this document is unlawful. Unless otherwise stated the results
shown in this test report refer only to the sample（s） tested.

No.1, 8/F, Shengfeng Road, Venture Industrial Park, Xinhe Community,Wanjiang District, Dongguan City, China

Tel：400-877-6107 Website：www.nbtscn.com

Fax：0769-22777508 E-mail：newbest@nbtscn.com
 SAFETY DATA SHEET FOR CHEMICAL PRODUCTS
（SDS）

Report No. NB2022054062 Date: June 23, 2022 Page: 3/9

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation

2.5 Precautionary description:

P264 Wash hand and face thoroughly after handling

P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

2.6 Other hazard

PBT and vPⅤB： None

SECTION 3. Composition / information on ingredients

Ingredient(s) of the product: Mixture
Substance name Conc. (%) CAS. No
Urethane acrylate 39 68987-79-1
Epoxy acrylate 9 71281-65-7
Acryloylmorpholine 15 5117-12-4
Ethoxylated trimethylolpropane triacrylate 31 28961-43-5
Trimethylbenzoyldiphenylphosphine oxide 4 75980-60-8
UV Color pigment 1 1333-86-4/482-89-3
BYK 1794 1 128-37-0

SECTION 4. First aid measures

General advice: Immediate medical attention is required. Show this safety data sheet (SDS) to the
doctor in attendance.

4.1 Following inhalation:

Move victim into fresh air. If breathing is difficult, give oxygen. Do not use mouth to mouth resuscitation
if victim ingested or inhaled the substance. If not breathing, give artificial respiration and consult a
physician immediately

This report cannot be reproduced partly, without prior written permission of Laboratory.Any unauthorized
alteration,forgery or falsification of the content of this document is unlawful. Unless otherwise stated the results
shown in this test report refer only to the sample（s） tested.

No.1, 8/F, Shengfeng Road, Venture Industrial Park, Xinhe Community,Wanjiang District, Dongguan City, China

Tel：400-877-6107 Website：www.nbtscn.com

Fax：0769-22777508 E-mail：newbest@nbtscn.com
 SAFETY DATA SHEET FOR CHEMICAL PRODUCTS
（SDS）

Report No. NB2022054062 Date: June 23, 2022 Page: 4/9

4.2 Following skin contact:

Take off contaminated clothing and shoes immediately. Wash off with plenty of water for at least 15
minutes and consult a physician if feeling uncomfortable.

4.3 Following eye contact:

In case of contact may cause irritation, immediately flush eyes with plenty of water for at least 15
minutes. Call a physician immediately if eyes are hurt.

4.4 Following ingestion:

Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a physician or
Poison Control Center immediately.

SECTION 5. Firefighting measures

5.1 Hazardous Characteristics:

No hazardous characteristics.

5.2 Extinguishing Media:

Dry powder, Chemical foam, Carbon dioxide, water mist.

5.3 Firefighting procedures:

As in any fire, wear self-contained breathing apparatus (MSHA/NIOSH approved or equivalent) and full
protective gear.
Take all precautions to avoid mixing with combustibles.

5.4 Hazardous combustion products:

Carbon monoxide, organic volatiles

SECTION 6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures:

Wear appropriate protective measures (SEE SECTION 8).

6.2 Environmental precautions:

Do not empty into drains. If the product contaminates lakes, rivers or sewages, inform appropriate
authorities in accordance with local regulations.

This report cannot be reproduced partly, without prior written permission of Laboratory.Any unauthorized
alteration,forgery or falsification of the content of this document is unlawful. Unless otherwise stated the results
shown in this test report refer only to the sample（s） tested.

No.1, 8/F, Shengfeng Road, Venture Industrial Park, Xinhe Community,Wanjiang District, Dongguan City, China

Tel：400-877-6107 Website：www.nbtscn.com

Fax：0769-22777508 E-mail：newbest@nbtscn.com
 SAFETY DATA SHEET FOR CHEMICAL PRODUCTS
（SDS）

Report No. NB2022054062 Date: June 23, 2022 Page: 5/9

6.3 Cleaning method:

Remove by liquid absorbing material (e.g. kieselguhr) . Adhered or collected material should be
promptly disposed of. Disposal of discarded waste/pollutants refers to SECTION 13.

SECTION 7. Safe handling and storage

7.1 Handling Notes:

Keep indoor ventilation or local exhaust device.

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Use only outdoors or in a well-ventilated area.

7.2 Storage Notes:

Stored in cool and dry condition.

Do not store with incompatible material (see section 10.2)

SECTION 8. Exposure controls / personal protection

8.1 Occupational Exposure Limit:

No relevant data

8.2 Engineering Control:

Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local
exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of
particulates and solvent vapour below the OEL, suitable respiratory protection must be worn.
Ensure that eyewash stations and safety showers are proximal to the work-station location.

8.3 Personal Protection:

General requirement:

If exposure limits are exceeded or if irritation or other symptoms are

Respiratory: experienced, use a full-face respirator with multi-purpose combination
(US) or type AXBEK (EN 14387) respirator cartridges.

This report cannot be reproduced partly, without prior written permission of Laboratory.Any unauthorized
alteration,forgery or falsification of the content of this document is unlawful. Unless otherwise stated the results
shown in this test report refer only to the sample（s） tested.

No.1, 8/F, Shengfeng Road, Venture Industrial Park, Xinhe Community,Wanjiang District, Dongguan City, China

Tel：400-877-6107 Website：www.nbtscn.com

Fax：0769-22777508 E-mail：newbest@nbtscn.com
 SAFETY DATA SHEET FOR CHEMICAL PRODUCTS
（SDS）

Report No. NB2022054062 Date: June 23, 2022 Page: 6/9

Eyes： Wear protective goggle (Conform to EC EN 166 or US-NIOSH).

Wear protective gloves (such as butyl rubber), passing the tests

Hands：
according to EN 374(EU),US F739 or AS/NZS 2161.1 standard.

8.4 Sanitary Measure:

Forbid smoking, eating and drinking in working places. Washing hands after handling products.

SECTION 9. Physical and chemical properties

Light Gray/White/Clear/Yellow/Peach Puff/Black/

Appearance and Color Sky Blue/Transparent Green/Transparent Red/Gray/
Beige/Blue/Red liquid
Odour Slight,ester-like
PH value 5.7
Flammability Noncombustible
Density(g/cm³) 1.109 (25℃)
Relative steam density (air = 1) No Data
Vapor pressure(MPa) No Data
Octanol/water partition coefficient No Data
Viscosity 100-200mPa·s (25℃)
Flash point(℃,Closed cup) >380

Boiling point(℃) No Data

Melting point (℃) No Data

Evaporation rate (kg/s) No Data
UEL %(V/V) Not Applicable
LEL %(V/V) Not Applicable

Auto-ignition temperature(℃) No Data

Decomposition temperature(℃) No Data
Soluble in ethanol, ethyl acetate, benzene and other
Solubility
organic solvents, dispersible in water

This report cannot be reproduced partly, without prior written permission of Laboratory.Any unauthorized
alteration,forgery or falsification of the content of this document is unlawful. Unless otherwise stated the results
shown in this test report refer only to the sample（s） tested.

No.1, 8/F, Shengfeng Road, Venture Industrial Park, Xinhe Community,Wanjiang District, Dongguan City, China

Tel：400-877-6107 Website：www.nbtscn.com

Fax：0769-22777508 E-mail：newbest@nbtscn.com
 SAFETY DATA SHEET FOR CHEMICAL PRODUCTS
（SDS）

Report No. NB2022054062 Date: June 23, 2022 Page: 7/9

SECTION 10. Stability and reactivity

10.1 Stability:

Stable under recommended storage and handling conditions (See section 7).

10.2 Material for avoiding:

Strong oxide, acid and alkali, Strong reducing agent.

10.3 Contact conditions for avoiding:

Sunlight, high temperature.

10.4 Hazardous decomposition products:

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11. Toxicological information

11.1 Acute toxicity:

Acryloylmorpholine (CAS: 5117-12-4) LD50=2370mg/kg, oral, rat

11.2 Skin corrosion/irritation:

Skin irritation

11.3 Serious eye damage/irritation:

Eye irritation

11.4 Respiratory or skin sensitisation:

Sensitisation, skin, categories 1

11.5 Germ cell mutagenicity:

Based on available data, the classification criteria are not met.

11.6 Carcinogenicity:

Based on available data, the classification criteria are not met.

11.7 Reproductive toxicity:

Specific target organ toxicity, single exposure; Respiratory tract irritation, categories 3

11.8 STOT-single exposure:

Specific target organ toxicity, single exposure; Respiratory tract irritation, categories 3

11.9 STOT-repeated exposure:

This report cannot be reproduced partly, without prior written permission of Laboratory.Any unauthorized
alteration,forgery or falsification of the content of this document is unlawful. Unless otherwise stated the results
shown in this test report refer only to the sample（s） tested.

No.1, 8/F, Shengfeng Road, Venture Industrial Park, Xinhe Community,Wanjiang District, Dongguan City, China

Tel：400-877-6107 Website：www.nbtscn.com

Fax：0769-22777508 E-mail：newbest@nbtscn.com
 SAFETY DATA SHEET FOR CHEMICAL PRODUCTS
（SDS）

Report No. NB2022054062 Date: June 23, 2022 Page: 8/9

Specific target organ toxicity, single exposure; Respiratory tract irritation, categories 3

11.10 Aspiration hazard.:

Based on available data, the classification criteria are not met.

SECTION 12. Ecological information

12.1 Toxicity:

No data available.

12.2 Persistence and degradability:

No data available.

12.3 Bioaccumulative potential:

No data available.

12.4 Mobility in soil

No data available.

12.5 Other Dangers:

PBT and vPVB evaluation results: Not applicable

SECTION 13. Disposal considerations

13.1 Handling method for waste:

Handling waste according to the local regulations. Contact specific waste disposal company or
companies recommended by local laws.

13.2 Handling method for uncleaned packaging

Processing as general waste processing after the empty container.

SECTION 14. Transport information

Land transport(ADG): Not regulated for transport of dangerous goods.
Air transport(ICAO-IATA/DGR): Not regulated for transport of dangerous goods.
Sea transport(IMDG-Code/GGVSee): Not regulated for transport of dangerous goods.
Transport in bulk according to Annex II of MARPOL and the IBC code. Transport within user's premises:
always transport in closed containers that are upright and secure. Ensure that persons transporting the

This report cannot be reproduced partly, without prior written permission of Laboratory.Any unauthorized
alteration,forgery or falsification of the content of this document is unlawful. Unless otherwise stated the results
shown in this test report refer only to the sample（s） tested.

No.1, 8/F, Shengfeng Road, Venture Industrial Park, Xinhe Community,Wanjiang District, Dongguan City, China

Tel：400-877-6107 Website：www.nbtscn.com

Fax：0769-22777508 E-mail：newbest@nbtscn.com
 SAFETY DATA SHEET FOR CHEMICAL PRODUCTS
（SDS）

Report No. NB2022054062 Date: June 23, 2022 Page: 9/9

product know what to do in the event of an accident or spillage.

Packaging Label None
UN NO None
Technical name None
Transport hazard class None
Subsidiary hazard class None
Packing group None
Special Provisions None

SECTION 15. Regulatory information

15.1 Safety, health and environmental regulations / laws for pure substances or mixtures

Catalogue of hazardous chemicals (2015 Edition)

Not included in the list.

15.2 Safety assessment of chemical substances

Not evaluated

SECTION 16. Other information

The above information is based on the data of which we are aware and is believed to be correct as of
the date hereof. Since this information may be applied under conditions beyond our control and with which
may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications
of the information, we do not assume any responsibility for the result of its use, this information is furnished
upon condition that the person receiving it shall make his own determination of the suitability of the material
for his particular purpose.

*************** END ***************

This report cannot be reproduced partly, without prior written permission of Laboratory.Any unauthorized
alteration,forgery or falsification of the content of this document is unlawful. Unless otherwise stated the results
shown in this test report refer only to the sample（s） tested.

No.1, 8/F, Shengfeng Road, Venture Industrial Park, Xinhe Community,Wanjiang District, Dongguan City, China

Tel：400-877-6107 Website：www.nbtscn.com

Fax：0769-22777508 E-mail：newbest@nbtscn.com