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2 - Mole Concept-Level

The document contains 14 chemistry problems and their solutions. It provides examples of stoichiometry calculations involving gases, atoms, molecules, and compounds. It demonstrates how to calculate amounts, masses, volumes, and numbers of particles using molar masses, gas laws, and mole ratios.

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0% found this document useful (0 votes)
87 views18 pages

2 - Mole Concept-Level

The document contains 14 chemistry problems and their solutions. It provides examples of stoichiometry calculations involving gases, atoms, molecules, and compounds. It demonstrates how to calculate amounts, masses, volumes, and numbers of particles using molar masses, gas laws, and mole ratios.

Uploaded by

PALAK GEHLAWAT
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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ACME Study Point

Chemistry Problems
SOLVED EXAMPLE
Ex.1 8 litre of H2 and 6 litre of Cl2 are allowed to 108
=
react to maximum possible extent. Find out the 6.023 10 23
final volume of reaction mixture. Suppose P and = 17.93 × 10–23 gm.
T remains constant throughout the course of
reaction - Ex.5 In 5g atom of Ag (at. wt. = 108), calculate the
(A) 7 litre (B) 14 litre no. of atoms of Ag -
(C) 2 litre (D) None of these. (A) 1 N (B) 3N (C) 5 N (D) 7 N
Sol. (B) Sol. (C)
H2 + Cl2  2 HCl  1 gm atom of Ag has atoms = N
Volume before reaction 8 lit 6 lit 0  5 gm atom of Ag has atoms = 5N.
Volume after reaction 2 0 12
Ex.6 Calculate the mass in gm of 2N molecules of
 Volume after reaction
CO2 -
= Volume of H2 left + Volume of HCl formed
(A) 22 gm (B) 44 gm
= 2 + 12 = 14 lit
(C) 88 gm (D) None of these.
Ex.2 Naturally occurring chlorine is 75 % Cl35 and Sol. (C)
25 % Cl37. Calculate the average atomic mass of  N molecules of CO2 has molecular mass = 44.
chlorine-  2N molecules of CO2 has molecular mass
(A) 35.5 amu (B) 36.5 amu
= 44 × 2 = 88 gm.
(C) 71 amu (D) 72 amu
Sol. (A) Ex.7 How many carbon atoms are present in 0.35
Average atomic mass mol of C6H12O6 -
= % of I isotope its atomic mass  %of II isotope  Its atomic mass
100 (A) 6.023 × 1023 carbon atoms
(75  35)  (25  37) (B) 1.26 × 1023 carbon atoms
=
100 (C) 1.26 × 1024 carbon atoms
= 35.5 amu. (D) 6.023 × 1024 carbon atoms
Sol. (C)
Ex.3 Calculate the mass in gm of 2g atom of Mg-
 1 mol of C6H12O6 has = 6 N atoms of C
(A) 12 gm (B) 24 gm
(C) 6 gm (D) None of these.  0.35 mol of C6H12O6 has
Sol. (D) = 6 × 0.35 N atoms of C
 1 gm atom of Mg has mass = 24 gm = 2.1 N atoms
 2 gm atom of Mg has mass = 2.1 × 6.023 × 1023 = 1.26 × 1024 carbon atoms
= 24 x 2 = 48 gm.
Ex.8 How many molecules are in 5.23 gm of glucose
Ex.4 calculate the weight of one atom of Ag – (C6H12O6) -
(At. wt. of Ag = 108) (A) 1.65 × 1022 (B) 1.75 × 1022
(A) 17.93 × 10–23gm (B) 16.93 × 10–23 gm (C) 1.75 × 1021 (D) None of these
(C) 17.93 × 1023 gm (D) 36 × 10–23 gm Sol. (B)
Sol. (A)  180 gm glucose has = N molecules
 N atoms of Ag weigh 108 gm
5.23  6.023 10 23
108  5.23 gm glucose has =
 1 atom of Ag weigh = 180
N
= 1.75 × 1022 molecules
ACME Study Point
Chemistry Problems

Ex.9 What is the weight of 3.01 × 1023 molecules of Sol. (C)


ammonia -
 weight of 1 atom of element
(A) 17 gm (B) 8.5 gm
= 6.644 × 10–23 gm
(C) 34 gm (D) None of these
 weight of 'N' atoms of element
Sol. (B)
= 6.644 × 10–23 × 6.023 × 1023 = 40 gm
6.023 × 1023 molecules of NH3 has weight
 40 gm of element has 1 gm atom.
= 17 gm
40 103
 3.01 × 1023 molecules of NH3 has weight  40 × 103 gm of element has
40
17  3.011023 = 103 gm atom.
=
6.0231023
= 8.50 gm Ex.13 Calculate the number of Cl– and Ca+2 ions in
222 g anhydrous CaCl2 -
Ex.10 How many molecules are present in one ml of (A) 2N ions of Ca+2 4 N ions of Cl–
water vapours at STP -
(B) 2N ions of Cl– & 4N ions of Ca+2
(A) 1.69 × 1019 (B) 2.69 × 10–19 (C) 1N ions of Ca+2 & 1N ions of Cl–
(C) 1.69 × 10–19 (D) 2.69 × 1019 (D) None of these.
Sol. (D) Sol. (A)
22.4 litre water vapour at STP has  mol. wt. of CaCl2 = 111 g
= 6.023 × 1023 molecules 111 g CaCl2 has = N ions of Ca+2
1 × 10–3 litre water vapours at STP has
N 222
6.023  10 23  222g of CaCl2 has
= × 10–3 = 2.69 × 10+19 111
22.4 = 2N ions of Ca+2
Also  111 g CaCl2 has = 2N ions of Cl–
Ex.11 How many years it would take to spend
Avogadro's number of rupees at the rate of 1 2 N  222
 222 g CaCl2 has = ions of Cl–
million rupees in one second - 111
(A) 19.098 × 1019 years = 4N ions of Cl– .
(B) 19.098 years
(C) 19.098 × 109 years Ex.14 The density of O2 at NTP is 1.429g / litre.
(D) None of these Calculate the standard molar volume of gas-
Sol. (C) (A) 22.4 lit. (B) 11.2 lit
 106 rupees are spent in 1sec. (C) 33.6 lit (D) 5.6 lit.
Sol. (A)
 6.023 × 1023 rupees are spent in
1.429 gm of O2 gas occupies volume
1 6.023 10 23
= sec = 1 litre.
106
32
1 6.023 10 23 32 gm of O2 gas occupies =
= years 1.429
106  60  60  24  365
= 22.4 litre/mol.
= 19.098 × 109 year
Ex.15 Which of the following will weigh maximum
Ex.12 An atom of an element weighs 6.644 × 10–23 g. amount-
Calculate g atoms of element in 40 kg- (A) 40 g iron
(A) 10 gm atom (B) 100 gm atom (B) 1.2 g atom of N
(C) 1000 gm atom (D) 104 gm atom (C) 1 × 1023 atoms of carbon
ACME Study Point
Chemistry Problems
(D) 1.12 litre of O2 at STP (A) M2PO4 (B) MPO4
Sol. (A) (A) Mass of iron = 40 g (C) M3PO4 (D) M(PO4)2
(B) Mass of 1.2 g atom of Sol. (B) MCl3 indicates that metal is trivalent.
N = 14 × 1.2 = 16.8 gm
(D) Mass of 1 × 1023 atoms of C Ex.19 A silver coin weighing 11.34 g was dissolved in
12 110 23 nitric acid. When sodium chloride was added to
= = 1.99 gm.
6.02310 23 the solution all the silver (present as AgNO3)

(D) Mass of 1.12 litre of O2 at STP was precipitated as silver chloride. The weight
of the precipitated silver chloride was 14.35 g.
321.2
= = 1.6 g Calculate the percentage of silver in the coin -
22.4
(A) 4.8 % (B) 95.2%
(C) 90 % (D) 80%
Ex.16 How many moles of potassium chlorate to be
Sol. (B)
heated to produce 11.2 litre oxygen -
Ag + 2HNO3  AgNO3 + NO2 + H2O
1 1
(A) mol (B) mol 108
2 3
AgNO3 + NaCl   AgCl + NaNO3
1 2
(C) mol (D) mol. 143.5
4 3
 143.5 gm of silver chloride would be
Sol. (B)
precipitated by 108 g of silver.
2 KClO32KCl + 3O2
or 14.35 g of silver chloride would be precipitated
Mole for reaction 2 2 3 10.8 g of silver.
 3 × 22.4 litre O2 is formed by 2 mol KClO3  11.34 g of silver coin contain 10.8 g of pure
2 11.2 silver.
 11.2 litre O2 is formed by
3  22.4 10.8
 100 g of silver coin contain × 100
1 11.34
= mol KClO3
3 = 95.2%.

Ex.17 Calculate the weight of lime (CaO) obtained by Ex.20 If the Faraday were to be 60230 coulombs
heating 200 kg of 95% pure lime stone instead of 96500 coulombs, what will be the
(CaCO3). charge on an electron ?
(A) 104.4 kg (B) 105.4 kg Sol. One mole electron carries 1 Faraday charge.
(C) 212.8 kg (D) 106.4 kg As 6.023 × 1023 electrons carry = 60230 C
Sol. (D) 60230
So 1 electron carries = C
 100 kg impure sample has pure 6.023  1023
CaCO3 = 95 kg = 1 × 10–19 C.

 200 kg impure sample has pure CaCO3


Ex.21 On heating 0.199 g of a metallic oxide in a
95 200 current of hydrogen 0.045 g of water is formed.
= = 190 kg.
100 Find the equivalent weight of the metal.
CaCO3  CaO + CO2 Sol. Weight of Metallic oxide = 0.199 g
100 kg CaCO3 gives CaO = 56 kg. As 16 g oxygen is present in = 18 g H2O
16 0.045
56 190 So O2 present in 0.045 g H2O =
 190 kg CaCO3 gives CaO = = 106.4 kg. 18
100
= 0.04 g
Weight of metal = 0.199 – 0.04 = 0.159
Ex.18 The chloride of a metal has the formula MCl3.
The formula of its phosphate will be-
ACME Study Point
Chemistry Problems
0.159  8
Equivalent weight of metal = = 31.8 Ex.25 2.68 × 10–3 moles of a solution containing an
0.04
ion An+ required 1.61 × 10–3 moles of MnO 4
Ex.22 10 ml of 0.02 M KMnO4 is required to oxidize for the oxidation of An+ to AO3 in an acidic
20 ml of oxalic acid of certain strength. 25 ml of
medium. What is the value of n?
the same oxalic acid is required to neutralize 20
Sol. As 1.61 × 10–3 M KMnO4
ml of NaOH of unknown strength. Find the
 2.68 × 10–3 M solution of An+
amount of NaOH in a litre of the solution.
(Molecular weight of NaOH = 40) : 2.68 103 M M
So M/5 KMnO4 = ×
Sol. In acidic medium 1.61103 5
1 M KMnO4 = 5 N KMnO4 = 0.33 M solution of An+
0.02 M KMnO4 = 0.1 N KMnO4 M
0.33 M = .
According to normality equation, 5n
N1V1 (KMnO4) = N2V2 (Oxalic acid) 1
5–n= =3
0.1 × 10 = N2 × 20 0.33
10 0.1 n=2
N2 = = 0.05 N
20
Again Ex.26 The label on a H2O2 bottle reads as 10 Vol. Find
N1V1 (Oxalic acid) = N2V2 (NaOH) the concentration of the H2O2%.
0.05 × 25 = N2 × 20 Sol. 2H2O2  2H2O + O2
0.05  25 10 vol. means 1 vol H2O2 = 10 ml O2
N2 = = 0.0625 N
20 22400
1 g H2O2 = = 329 ml
As S = N × E 68
So S = 0.0625 × 40 = 2.5 g L–1. 1 litre of 10 vol. means = 10000 ml of O 2
Weight of H2O2 to give 10000 ml
Ex.23 What volume of a solution of hydrochloric acid 1
= × 10000 = 30.4 g
containing 73 g of acid litre would suffice for 329
the exact neutralization of sodium hydroxide Conc. = 30.4 g/lit
obtained by allowing 0.46 g of metallic sodium 100
to act upon water ? Conc. % = 30.4 × = 3.04%
1000
Sol. Na + H2O  NaOH + ½ H2
NaOH + HCl  NaCl + H2O Ex.27 Calculate the volume of 20 g of hydrogen gas at
Thus, meq. of Na = Meq. of NaOH formed NTP.
= Meq. of HCl used 20
0.46 Sol. Moles of hydrogen gas = = 10.
× 1000 2
23 Volume of the gas at NTP = no. of moles × 22.4
73 = 10 × 22.4
= ×V
36.5 = 224 litres.
(eq. of HCl = N × V) = 10 ml
Ex.28 Calculate the number of atoms of each element
Ex.24 Find weight of iron which will be converted present in 122.5 g of KClO3.
into its oxide by the action of 18 g of steam on
122.5
it. Sol. No. of moles of KClO3 = = 1.
122.5
Sol. 3Fe + 4H2O  Fe3O4 + 4H2
(mol. wt. of KClO3 = 122.5)
3 × 56 4 × 18
From the formula KClO3, we know that 1 mole
As by 72 g steam the weight of Fe oxidized = 168 g
of KClO3 contains 1 mole of K atoms, 1 mole of
So by 18 g " " " "
Cl atoms and 3 moles of O atoms.
16818
= = 42 g
72
ACME Study Point
Chemistry Problems
 no. of atoms of K  1 6.022  10 23 

no. of atoms of Cl  1 6.022  10 23 

no. of atoms of O  3  6.022  10 23 

Ex.29 If the components of air are N2, 78%; O2, 21%


Ar, 0.9% and CO2, 0.1% by volume what would Ex.30 The vapour density (hydrogen = 1) of a mixture
be the molecular weight of air ? consisting of NO2 and N2O4 is 38.3 at 26.7ºC.
Sol. The volume ratio of the gases will be the same Calculate the number of moles of NO2 in 100 g
as their mole ratio (Avogadro's principle) of the mixture.
 mol. wt. of air (wt. in g per mole) Sol. Wt. of NO2 = x g.
78  28  21 32  0.9  40  0.1 44 wt. in g
=  obs. mol. wt. (wt./mole) =
78  21  0.9  0.1 total moles
= 28.964 
100 
(N2 = 28, O2 = 32, Ar = 40 and CO2 = 44)   2  38.3.
 x 100  x 
   
 46 92  
 (0.437 mole)
ACME Study Point
Chemistry Problems

LEVEL # 1
Questions Determination of Number of Different
based on Type of Particle
Q.8 Total number of atoms present in 64 gm of SO2
Q.1 Mass of 1 atom of Hydrogen is - is -
(A) 1.66 × 10–24 g (B) 10–22 g (A) 2 × 6.02 × 1023 (B) 6.02 × 1023
(C) 10–23 g (D) 10–25 g (C) 4 × 6.02 × 1023 (D) 3 × 6.02 × 1023

Q.2 Which of the following contains the largest Q.9 The number of oxygen atoms present in 14.6 g
number of atoms - of magnesium bicarbonate [Mg(HCO3)2] is
(A) 11g of CO2 (B) 4g of H2 (A) 6NA (B) 0.6NA
(C) 5g of NH3 (D) 8g of SO2 (C) NA (D) 0.5 NA

Q.3 How many atoms are contained in a mole of


Q.10 One mole of P4 molecules contains -
Ca(OH)2 :
(A) 1 molecule
(A) 30 × 6.02 × 1023 atoms/mol
(B) 4 molecules
(B) 6 × 6.02 × 1023 atoms/mol
(C) 1/4 × 6.022 × 1023 atoms
(C) 6.02 × 1023 atoms/mol
(D) 5 × 6.02 × 1023 atoms/mol (D) 24.088 × 1023 atoms

Q.4 What is correct for 10 g of CaCO3 - Q.11 The total number of protons, electrons and
neutrons in 12gm of 6C12 is -
(A) It contains 1g-atom of carbon
(B) It contains 0.3 g-atoms of oxygen (A) 1.084 × 1025 (B) 6.022 × 1023
(C) 6.022 × 1022 (D) 18
(C) It contains 12 g of calcium
(D) None of these Q.12 The number of sodium atoms in 2 moles of
sodium ferrocyanide Na4[Fe(CN)6], is-
Q.5 The total number of electrons present in 18 mL
water (density 1 g/mL) is - (A) 2
(A) 6.023 × 1023 (B) 6.023 × 1024 (B) 6.023 × 1023
(C) 6.023 × 1025 (D) 6.023 × 1021 (C) 8 × 6.02 × 1023
(D) 4 × 6.02 × 1023
Q.6 Number of oxygen atoms in 8 gms of ozone is -
6.02  10 23 Q.13 Out of 1.0 g dioxygen, 1.0 g (atomic) oxygen
23
(A) 6.02 × 10 (B)
2 and 1.0 g of ozone, the maximum number of

6.02 1023 6.02 1023 oxygen atoms are contained in -


(C) (D) (A) 1.0 g of atomic oxygen.
3 6
(B) 1.0 g of ozone.
Q.7 No. of oxalic acid molecules in 100 ml of 0.02
(C) 1.0 g of oxygen gas.
N oxalic acid is -
(D) All contain same number of atoms
(A) 6.023 × 1020 (B) 6.023 × 1021
(C) 6.023 × 1022 (D) 6.023 × 1023
ACME Study Point
Chemistry Problems
Q.14 Number of Ca+2 and Cl– ion in 111 g of Q.21 Equal masses of O2, H2 and CH4 are taken in a
anhydrous CaCl2 are - container. The respective mole ratio of these
(A) NA, 2NA (B) 2NA, NA gases in container is -
(C) NA, NA (D) None (A) 1 : 16 : 2 (B) 16 : 1 : 2
(C) 1 : 2 : 16 (D) 16 : 2 : 1
Questions Vapour Density, Number of Moles
based on and NTP & STP Q.22 Number of moles of water in 488 gm of
BaCl2.2H2O are - (Ba = 137)
Q.15 2 moles of H2 at NTP occupy a volume of
(A) 2 moles (B) 4 moles
(A) 11.2 litre (B) 44.8 litre
(C) 2 litre (D) 22.4 litre (C) 3 moles (D) 5 moles

Q.23 16 gm of SOx occupies 5.6 litre at STP.


Q.16 4.48 litres of methane at N.T.P. correspond to-
Assuming ideal gas nature, the value of x is -
(A) 1.2 x 1022 molecules of methane
(A) 1 (B) 2
(B) 0.5 mole of methane
(C) 3.2 gm of methane (C) 3 (D) None of these

(D) 0.1 mole of methane Q.24 The density of air is 0.001293 gm/ml at S.T.P.
It’s vapour density is -
Q.17 The weight of a substance that displaces 22.4
(A) 143 (B) 14.3
litre air at NTP is -
(A) Mol. wt. (B) At. wt. (C) 1.43 (D) 0.143
(C) Eq. wt. (D) all
Questions Percentage and Weight Based
based on
Calculation
Q.18 Mol. wt. = vapour density × 2, is valid for -
Q.25 The percentage of nitrogen in urea is about-
(A) metals (B) non metals
(A) 38.4 (B) 46.6
(C) solids (D) gases
(C) 59.1 (D) 61.3

Q.19 5.6 litre of a gas at N.T.P. weighs equal to Q.26 The mass of carbon present in 0.5 mole of
8 gm. Vapour density of gas is - K4[Fe(CN)6] is -
(A) 32 (B) 16 (A) 1.8 gm (B) 18 gm
(C) 8 (D) 40 (C) 3.6 gm (D) 36 gm

Q.20 The maximum volume at N.T.P. is occupied by- Q.27 1.2 gm of Mg (At. mass 24) will produce MgO
equal to -
(A) 12.8 gm of SO2
(A) 0.05 mol (B) 40 gm
(B) 6.02 x 1022 molecules of CH4
(C) 40 mg (D) 4 gm
(C) 0.5 mol of NO2
Q.28 Insulin contains 3.4% sulphur by mass. What
(D) 1 gm-molecule of CO2 will be the minimum molecular weight of
insulin -
ACME Study Point
Chemistry Problems
(A) 94.117 (B) 1884 (A) M2O (B) MO
(C) 941 (D) 976 (C) M2O3 (D) M3O4

Q.29 The percent of N in 66% pure (NH4)2 SO4 Q.36 A compound contains 69.5% oxygen and 30.5%
sample is - nitrogen and its molecule weight is 92. The
(A) 32 (B) 28 molecular formula of the compound will be -
(C) 14 (D) None of these (A) N2O (B) NO2
(C) N2O4 (D) N2O5
Q.30 The chloride of a metal contains 71% chlorine
by weight and the vapour density of it is 50. The Q.37 The formula which represents the simple ratio
atomic weight of the metal will be - of atoms in a compound is called -
(A) 29 (B) 58 (C) 35.5 (D) 71 (A) molecular formula
(B) structural formula
Q.31 The haemoglobin of most mammals contains
(C) empirical formula
approximately 0.33% of iron by mass. The
molecular mass of haemoglobin is 67200. The (D) rational formula

number of iron atoms in each molecule of Q.38 On analysis, a certain compound was found to
haemoglobin is-
contain 254 gm of iodine (at. mass 127) and 80
(A) 3 (B) 4
gm oxygen (at. mass 16). What is the formula of
(C) 2 (D) 6
the compound -
Q.32 A compound was found to contain 5.37% (A) IO (B) I2O
nitrogen by mass. What is the minimum (C) I5O3 (D) I2O5
molecular weight of compound -
(A) 26.07 (B) 2.607 Q.39 14g of element X combine with 16g of oxygen.
(C) 260.7 (D) None On the basis of this information, which of the
following is a correct statement :
Questions Empirical Formula & Molecular
based on (A) The element X could have an atomic weight
Formula
of 7 and its oxide formula XO
Q.33 An element (A) (at wt = 75) and another (B) The element X could have an atomic weight
element (B) (at. wt. = 25) combine to form a of 14 and its oxide formula X2O
compound. The compound contains 75% (A) by
(C) The element X could have an atomic weight
weight. The formula of the compound will be -
of 7 and its oxide is X2O
(A) A2B (B) A3B
(D) The element X could have an atomic weight
(C) AB3 (D) AB
of 14 and its oxide is XO2
Q.34 The empirical formula of a compound is CH. Its
Questions
molecular weight is 78. The molecular formula based on Limiting Reagent & Stochiometry
of the compound will be -
Q.40 A mixture containing 100 gm H2 and 100 gm
(A) C2H2 (B) C3H3
O2 is ignited so that water is formed according
(C) C4H4 (D) C6H6
to the reaction, 2H2 + O2  2H2O; How much
Q.35 An oxide of a metal (M) contains 40% by mass water will be formed -
of oxygen. Metal (M) has atomic mass of 24. (A) 112.5 gm
The empirical formula of the oxide is- (B) 50 gm
ACME Study Point
Chemistry Problems
(C) 25 gm (B) Definite proportion
(D) 200 gm (C) Reciprocal proportion
(D) None of these
Q.41 0.5 mole of H2SO4 is mixed with 0.2 mole of
Q.47 One of the following combinations illustrates
Ca(OH)2. The maximum number of moles of the law of reciprocal proportions-
CaSO4 formed is - (A) N2O3, N2O4, N2O5
(A) 0.2 (B) 0.5 (B) NaCl, NaBr, NaI
(C) 0.4 (D) 1.5 (C) CS2, CO2, SO2
(D) PH3, P2O3, P2O5
Q.42 How many mol Fe2+ ions are formed, when
excess of iron is treated with 50mL of 4.0M
Q.48 The law of multiple proportions is illustrated
HCl under inert atmosphere ? Assume no
by-
change in volume -
(A) Carbon monoxide and carbon dioxide
(A) 0.4 (B) 0.1 (B) Potassium bromide and potassium chloride
(C) 0.2 (D) 0.8 (C) Water and heavy water
Q.43 12 litre of H2 and 11.2 litre of Cl2 are mixed and (D) Calcium hydroxide and barium hydroxide

exploded. The composition by volume of mixture Q.49 The law of conservation of mass holds good for
is- all of the following except -
(A) 24 litre of HCl (A) All chemical reactions
(B) 0.8 litre Cl2 and 20.8 lit HCl. (B) Nuclear reactions
(C) 0.8 litre H2 & 22.4 litre HCl (C) Endothermic reactions
(D) Exothermic reactions
(D) 22.4 litre HCl
Q.50 If the law of conservation of mass was to hold
Q.44 For the reaction : A + 2B  C
true, then 20.8 gm of BaCl2 on reaction with 9.8
5 mole of A and 8 mole of B will produce -
gm of H2SO4 will produce 7.3 gm of HCl and
(A) 5 mole of C (B) 4 mole of C
BaSO4 equal to -
(C) 8 mole of C (D) 13 mole of C
(A) 11.65 gm (B) 23.3 gm
Questions (C) 25.5 gm (D) 30.6 gm
based on Laws of Chemical Combination

Q.45 Hydrogen and oxygen combine to form


H2O2 and H2O containing 5.93% and 11.2%
Hydrogen respectively. The data illustrates-
(A) Law of conservation of mass
(B) Law of constant proportions
(C) Law of reciprocal proportions
(D) Law of multiple proportions

Q.46 If water samples are taken from sea, rivers,


clouds, lake or snow, they will be found to
contain H2 and O2 in the fixed ratio of 1 : 8.
This indicates the law of -
(A) Multiple proportion
ACME Study Point
Chemistry Problems

LEVEL # 2
Q.1 Which one of the following properties of an (A) 22 gm (B) 45 gm (C) 66 gm (D) 88 gm
element is not variable ? Q.8 If LPG cylinder contains mixture of butane and
(A) Valency (B) Equivalent mass isobutane, then the amount of oxygen that
(C) Atomic mass (D) All the three would be required for combustion of 1kg of it
Q.2 An element A is tetravalent and another element will be-
B is divalent. The formula of the compound 2C4H10 + 13O2 8CO2 + 10H2O
formed from these elements will be - (A) 1.8 kg (B) 2.7 kg (C) 4.5 kg (D) 3.58 kg
(A) A2B (B) AB (C) AB2 (D) A2B3
Q.3 The vapour density of gas A is four times that Q.9 1 gm - atom of nitrogen represents -
of B. If molecular mass of B is M, then (A) 6.02 x 1023 N2 molecules
molecular mass of A is - (B) 22.4 lit. of N2 at N.T.P.
M (C) 11.2 lit. of N2 at N.T.P.
(A) M (B) 4M (C) (D) 2M
4
(D) 28 gm of nitrogen.
Q.4 Percentage of copper and oxygen in sample of
Q.10 The moles of O2 required for reacting with 6.8
CuO obtained by different methods were found
to be same. This proves the law of - gm of ammonia.
(A) Constant proportion (4NH3 + 5O2 4NO + 6H2O) is
(B) Multiple proportion (A) 5 (B) 2.5 (C) 1 (D) 0.5
(C) Reciprocal proportion Q.11 If isotopic distribution of C–12 and C–14 is
(D) None of these 98% and 2% respectively, then the number of
Q.5 6 gm of carbon combines with 32 gm of sulphur to
C–14 atoms in 12 gm of carbon is -
form CS2. 12 gm of C also combines with 32 gm of
(A) 1.032 × 1022 (B) 3.01 × 1022
oxygen to form carbondioxide. 10 gm of sulphur 23
(C) 5.88 × 10 (D) 6.02 × 1023
combines with 10 gm of oxygen to form sulphur 20
dioxide. Which law is illustrated by them - Q.12 If 3.01 x 10 molecules are removed from
(A) Law of multiple proportions 98 mg of H2SO4, then the number of moles of
(B) Law of constant composition H2SO4 left are -
(C) Law of Reciprocal proportions (A) 0.1 × 10–3 (B) 0.5 × 10–3
(D) Gay Lussac's law (C) 1.66 × 10 –3 (D) 9.95 × 10–2
Q.6 Two elements X (at mass 16) and Y (at mass
Q.13 Total number of atoms of all elements present
14) combine to form compounds A, B and C.
in 1 mole of ammonium dichromate
The ratio of different masses of Y which
[(NH4)2Cr2O7] is
combine with a fixed mass of X in A, B and C
is 1 : 3 : 5. If 32 parts by mass of X combines (A) 14 (B) 19
with 84 parts by mass of Y in B, then in C, 16 (C) 6 × 1023 (D) 114 × 1023
parts by mass of X will combine with- Q.14 X gm of Ag was dissolved in HNO3 and the
(A) 14 parts by mass of Y solution was treated with excess of NaCl. When
(B) 42 parts by mass of Y 2.87 gm of AgCl was precipitated. The value of
(C) 70 parts by mass of Y x is
(D) 84 parts by mass of Y Ag + 2HNO3 AgNO3 + NO2 + H2O
Q.7 If one mole of ethanol (C2H5OH) completely
AgNO3 + NaCl AgCl + NaNO3
burns to form carbon dioxide and water, the (A) 1.08 gm (B) 2.16 gm
weight of carbon dioxide formed is about –
(C) 2.70 gm (D) 1.62 gm
C2H5OH + 3O2 2CO2 + 3H2O
ACME Study Point
Chemistry Problems
Q.15 What mass of calcium chloride in grams would Q.25 8 gm of O2 has the same number of molecules as -
be enough to produce 14.35 gm of AgCl. (A) 7 gm of CO (B) 14 gm of CO
(At. mass Ca = 40, Ag = 108) –
(C) 14 gm of CO2 (D) 12 gm of CO2
CaCl2 + 2 AgNO3  Ca(NO3)2 + 2AgCl
(A) 5.55 gm (B) 8.295 gm Q.26 4.4 gm of CO2 and 2.24 litre of H2 at STP are
(C) 16.59 gm (D) 11.19 gm mixed in a container. The total number of
Q.16 Total no. of atoms in 44 gm of CO2 is - molecules present in the container will be -
(A) 6.02 × 1023 (B) 6.02 × 1024 (A) 6.022 × 1023 (B) 1.2044 × 1023
(C) 1.806 × 1024 (D) 18.06 × 1022 (C) 2 moles (D) 6.023 × 1024
Q.17 If the density of water is 1 gm/cm3, then the Q.27 Find the volume of CO2 obtained at S.T.P. on
volume occupied by one molecule of water is
approximately- heating 200 gm of 50% pure CaCO3 -
(A) 18 cm3 (B) 22400 cm3 (A) 11.2 litre (B) 22.4 litre
–23
(C) 6.02 × 10 cm 3 (D) 3.0 × 10–23 cm3
(C) 44.8 litre (D) None of these
Q.18 How many grams are contained in 1gm-atom of Na- Q.28 A gas has a vapour density 11.2. The volume
(A) 13 gm (B) 23 gm (C) 1 gm (D) 1/23 gm occupied by 1 g of the gas at NTP is :
Q.19 1.35 gm of pure Ca metal was converted into (A) 1 L (B) 11.2 L
1.88 gm of pure CaO. What is atomic weight of (C) 22.4 L (D) 4 L
Ca - Q.29 A sample of AlF3 contains 3.0 × 1024 F– ions.
(A) 40.75 (B) 50 (C) 60 (D) 70
The number of formula units in this sample are -
Q.20 The % loss in weight after heating a pure
sample of potassium chlorate (M. wt. 122.5) (A) 9.0 × 1024 (B) 3.0 × 1024
will be –
(C) 0.75 × 1024 (D) 1.0 × 1024

2KClO3   2KCl + 3O2
Q.30 One mole of nitrogen gas is the volume of
(A) 12.25 (B) 24.50 (C) 39.17 (D) 49.00
Q.21 The minimum quantity in gram of H2S needed (A) 1 litre of nitrogen at S.T.P.
to precipitate 63.5 gm of Cu+2 will be nearly (B) 32 litre of nitrogen at S.T.P.
Cu + H2S CuS + 2H
+2 +
(C) 22.4 litre of nitrogen at S.T.P.
(A) 63.5 gm (B) 31.75 gm
(D) 11.2 litre of nitrogen at S.T.P.
(C) 34 gm (D) 20 gm
Q.22 Mass of H2O in 1000 kg CuSO4.5H2O is - Q.31 The mass of CaCO3 produced when carbon

(Cu = 63.5) dioxide is passed in excess through 500 ml of


(A) 360.5 kg (B) 36.05 kg 0.5 M Ca(OH)2 will be-
(C) 3605 kg (D) 3.605 kg (A) 10 gm (B) 20 gm
Q.23 Phosphine (PH3) decomposes to produce
(C) 50 gm (D) 25 gm.
vapours of phosphorus and H2 gas. What will be
the change in volume when 100 mL of Q.32 Atomic weight of Ne is 20.2 Ne is mixture of
phosphine is decomposed ? Ne20 and Ne22, relative abundance of heavier
4PH3(g) P4(g) + 6H2(g) isotope is :
(A) + 50 mL (B) 500 mL (A) 90 (B) 20
(C) 40 (D) 10
(C) + 75 mL (D) – 500 mL
Q.33 Which of the following contains maximum
Q.24 In the reaction 4A + 2B + 3C  A4B2C3 , what
number of molecules -
will be the number of moles of product formed, (A) 400 cc of O2 at S.T.P.
starting from one mole of A, 0.6 mole of B and
(B) 500 cc of NH3 at S.T.P.
0.72 mole of C ?
(C) 250 cc of SO2 at S.T.P.
(A) 0.25 (B) 0.3 (C) 0.24 (D) 2.32 (D) 150 cc of CO2 at S.T.P.
ACME Study Point
Chemistry Problems
Q.34 1.6 g of sulphur was burnt in the air to form (C) 48 (D) 6
SO2. The number of molecules of SO2 Q.36 Avogadro's number of Rupees can be spent in
introduced into the air will be - ..........years if 10 lac rupees per second are spent
(A) 6.02 × 1023 (B) 3.01 × 1023 (A) 1.91 × 1010 year (B) 2.91 × 1010 year
22
(C) 6.02 × 10 (D) 3.01 × 1022 (C) 3.91 × 1010 year (D) 4.91 × 1010 year
Q.35 1.5 gm of divalent metal displaced 4 gm of
copper (at. wt. = 64) from a solution of copper
sulphate. The atomic weight of the metal is-
(A) 12 (B) 24

LEVEL # 3
Q.1 4.0 g of caustic soda (mol mass 40) contains (A) 16 (B) 32 (C) 48 (D) 64
same number of sodium ions as are present in-
(A) 10.6 g of Na2CO3 (mol. mass 106) Q.6 2.76 gm of silver carbonate on being strongly
(B) 58.5 g of NaCl (Formula mass 58.5) heated yields a residue weighing -
(C) 100 ml of 0.5 M Na2SO4 (A) 2.16 gm (B) 2.48 gm
(Formula mass 142) (C) 2.32 gm (D) 2.64 gm
(D) 1mol of NaNO3 (mol. mass 85)

Q.2 0.01 mole of iodoform (CHI3) reacts with Ag to


Q.7 A hydrocarbon contains 80% of carbon, then
produce a gas whose volume at NTP is -
the hydrocarbon is -
(A) 224 ml (B) 112 ml
(A) CH4 (B) C2H4 (C) C2H6 (D) C2H2
(C) 336 ml (D) None of these

22
Q.3 If 1.6 gms of SO2 1.5 × 10 molecules of H2S
Q.8 A giant molecule contains 0.25% of a metal
are mixed and allowed to remain in contact in a whose atomic weight is 59. Its molecule
closed vessel until the reaction contains one atom of that metal. Its minimum
2H2S + SO2 
 3S + 2H2O, molecular weight is -
proceeds to completion. Which of the following (A) 5900 (B) 23600
statement is true ? 100 59
(C) 11800 (D)
(A) Only ‘S’ and ‘H2O’ remain in the reaction 0.4
vessel
(B) ‘H2S’ will remain in excess Q.9 CaCO3 is 90% pure. Volume of CO2 collected
(C) ‘SO2’ will remain in excess STP when 10 gms of CaCO3 is decomposed is -
(D) None of these (A) 2.016 litres (B) 1.008 litres
(C) 10.08 litres (D) 20.16 litres
Q.4 1.0 gm of a metal combines with 8.89 gms of
Bromine. Equivalent weight of metal is nearly : Q.10 The formula of a metal oxide is Z2O3. If
(at. wt. of Br = 80) 6 mg. of hydrogen is required for complete
(A) 8 (B) 9 (C) 10 (D) 7 reduction of 0.1596 gm metal oxide, then the
atomic weight of metal is -
Q.5 2.8 gm of iron displaces 3.2 gm of copper from (A) 227.9 (B) 159.6
a solution of copper sulphate solution. If the (C) 79.8 (D) 55.8
equivalent mass of iron is 28, then equivalent
mass of copper will be -
ACME Study Point
Chemistry Problems
Q.11 Percentage of Se in peroxidase anhydrous (A) SO2 is the limiting reagent
enzyme is 0.5% by weight (at. wt. = 78.4) then (B) O2 is the limiting reagent
min. mol. wt. of peroxidase anhydrous enzymes (C) both SO2 and O2 are limiting reagent
is -
4
(D) cannot be predicted
(A) 1.568 × 10
Q.17 Number of moles of SO3 formed in the reaction
3
(B) 1.568 × 10
will be -
(C) 15.68 (A) 10 (B) 4
4
(D) 2.136 × 10 (C) 8 (D) 14
Q.18 Number of moles of excess reactant remaining -
Q.12 The mass of carbon anode consumed (giving (A) 4 (B) 2
only carbondioxide) in the production of 270 (C) 6 (D) 8
Kg of aluminium metal from bauxite by the Hall Q.19 The calculation on the given reaction is based
process is - on -
(A) 180 Kg (B) 270 Kg (A) Boyle’s law
(C) 240 Kg (D) 90 Kg (B) Charle’s law
(C) Gay-Lussac’s law
Q.13 How many moles of lead (II) chloride will be (D) Avogadro’s hypothesis
formed from a reaction between 6.5 g of PbO Q.20 Total number of moles of gaseous component
and 3.2 g of HCl ? (Atomic wt. of Pb = 207) - will ...... after the reaction -
(A) increase
(A) 0.011 (B) 0.029
(B) decrease
(C) 0.044 (D) 0.333
(C) remain same
(D) may increase or decrease
Q.14 The emperical formula of an organic compound
is CH2. One mole of this compound has a mass True or False :
42 gm. Its molecular formula is - Q.21 Equal volumes of different gases under similar
(A) CH2 (B) C3H6 conditions of temperature and pressure contain
(C) C2H2 (D) C3H8 equal number of atoms.

Q.15 The mass of 70% pure H2SO4 required for Q.22 1 mole of C12H22O11 contains 22 hydrogen
neutralisation of 1 mol of NaOH - atoms.

(A) 49 gm (B) 98 gm
Q.23 Nitrogen forms five oxides. It proves the law of
(C) 70 gm (D) 34.3 gm multiple proportions.

Passage : Q.24 Empirical formula = (Molecular formula) × n


10 moles of SO2 and 4 moles of O2 are mixed
in a closed vessel of volume 2 litres. The Q.25 Mass of 3.01 × 1023 molecules of methane is
mixture is heated in presence of Pt catalyst. 8 gm.
Following reaction takes place :
2SO2(g) + O2(g)  2SO3(g) Q.26 Avogadro’s number varies with temperature and
pressure.
Assuming the reaction proceeds to completion.
Q.16 Select the correct statement - Q.27 18 gm of water vapour and 18 gm of ice will not
contain the same number of molecules.
ACME Study Point
Chemistry Problems
Q.33 Column matching :
Each of the questions given below consists of Column I Column II
Statement-I and Statement-II. Use the A. CaC2 P. 106 gm
following Key to choose the appropriate B. 2 g-equivalent of Q. 22.4 L at S.T.P.
answer. Na2CO3
(A) If both statement-1 and statement-2 are
C. 6.02 × 1023 Ne R. Molarity of solution
correct and statement-2 is not the correct
atoms
explanation of statement-1.
D. Number of S. 0.01 moles of solute
(B) If both statement-1 and statement-2 are
correct and statement-2 is the correct gm-molecules in one lit. of solution
explanation of statement-1. per litre of solution
(C) If statement-1 is correct and statement-2 is E. Centimolar T. N0 formula units
incorrect. solution Fe4[Fe(CN)6]3
(D) If statement-1 is incorrect and statement-2 is F. Mohr’s salt U. Calcium carbide
correct. G. Contain V. (NH4)2SO4.Fe(SO4).
18 gm-atom of N 6H2O
Q.34 Calculate the gm quantity of Na2CO3 which has
Q.28 Statement-1 : Molarity of pure water is same No. of atoms as the No. of protons
55.5 M. present in 10 gm CaCO3 -
Statement-2 : Molarity is temperature
(A) 20 gm (B) 88.33 gm
dependent parameter
(C) 44 gm (D) 60 gm

Q.29 Statement-1 : 1 g-atom of sulphur contains


Q.35 A sample of hard water is found to contain 40
Avogadro number of sulphur molecules.
mg of Ca+2 ion per litre. The amount of washing
Statement-2 : Atomicity of sulphur is eight.
soda (Na2CO3) required to soften five litres of
Q.30 Statement-1 : The number of O atoms in the sample would be -
1 gm. of O2, 1 gm O3 and 1 gm of atomic (A) 1.06 gm (B) 5.3 gm
oxygen is same. (C) 53 mg (D) 530 mg
Statement-2 : Each of the species represents
1/16 gm-atom of oxygen. Q.36 The mass of oxygen that would be required to
produce enough CO, which completely reduces
Q.31 Statement-1 : The ratio by volume of H2 : Cl2 : 1.6 kg Fe2O3 (at. mass Fe = 56) is -
HCl in a reaction H2(g) + Cl2(g)  2HCl(g) is 1 : (A) 240 gm (B) 480 gm
(C) 720 gm (D) 960 gm
1 : 2.
Statement-2 : Substances always react in such
Q.37 The amount of sulphur required to produce
a way that their volume ratio is in simple
100 moles of H2SO4 is -
integers.
(A) 3.2 × 103 gm (B) 32.65 gm
(C) 32 gm (D) 3.2 gm
Q.32 Statement-1 : 0.2 N H2SO4 solution has
molarity equal to 0.2 M. Q.38 The vapour density of a mixture containing NO2
Statement-2 : H2SO4 is a diabasic acid. and N2O4 is 38.3 at 27º C. The moles of NO2 in
100 mole mixture is -
ACME Study Point
Chemistry Problems
(A) 33.48 (B) 53.52 Q.40 The conversion of oxygen to ozone occurs to
(C) 28.3 (D) 76.6 the extent of 15% only. The mass of ozone that
can be prepared from 67.2 L of oxygen at S.T.P.
Q.39 Assuming that petrol is iso-octane (C8H18) and will be -
has density 0.8 gm/ml, 1.425 litre of petrol on (A) 14.4 gm (B) 96 gm
complete combustion will consume oxygen - (C) 640 gm (D) 64 gm
(A) 50 L (B) 125 L
(C) 125 mol (D) 50 mol

LEVEL # 4
(Question asked in previous AIEEE & IIT JEE)

(Avogadro constant, NA = 6.02 ×1023 mol–1)


SECTION : A

Q.1 The weight of 2.01 × 1023 molecules of CO is-


Q.5 How many moles of magnesium phosphate,
[AIEEE-2002]
Mg3(PO4)2 will contain 0.25 mole of oxygen
 (A) 9.3 gm (B) 7.2 gm
atoms ? [AIEEE 2006]
(C) 1.2 gm (D) 3 gm
(A) 3.125 × 10–2 (B) 1.25 × 10–2
(C) 2.5 × 10–2 (D) 0.02
Q.2 In an organic compound of molar mass 108 gm
mol–1 C, H and N atoms are present in 9 : 1 : 3.5
by weight. Molecular formula can be –
[AIEEE-2002] Q.6 In the reaction, [AIEEE 2007]
(A) C6H8N2 (B) C7H10N 2Al(s) +6HCl(aq)2Al3+(aq) + 6Cl¯(aq) + 3H2(g),
(C) C5H6N3 (D) C4H18N3
(A) 6L HCl(aq) is consumed for every 3L H2(g)
produced
Q.3 Number of atoms in 560 gm of Fe (atomic mass
56 g mol–1) is – [AIEEE-2003] (B) 33.6 L H2(g) is produced regardless of

(A) is twice that of 70 gm N temperature and pressure for every mole Al


(B) is half that of 20 gm H that reacts
(C) both are correct (C) 67.2 L H2(g) at STP is produced for every
(D) None is correct mole Al that reacts
(D) 11.2 L H2(g) at STP is produced for every
Q.4 6.02 × 1020 molecules of urea are present in
mole HCl(aq) consumed
100 ml of its solution. The concentration of urea
solution is - [AIEEE-2004] Q.7 A gaseous hydrocarbon gives upon combustion
(A) 0.001 M (B) 0.01 M 0.72 g. of water and 3.08 g. of CO2. The
empirical formula of the hydrocarbon is –
(C) 0.02 M (D) 0.1 M
[JEE Main 2013]
ACME Study Point
Chemistry Problems
(A) C6H5 (B) C7H8 6.023 1
(C) × 1054 (D) × 108
(C) C2H4 (D) C3H4 9.108 9.108  6.023

SECTION : B Q.6 In which of the following number of atoms are


maximum ? (IIT-2003)
Q.1 The weight of 1 × 1022 molecules of
(A) 24 gms C
CuSO4.5H2O is - [IIT-1991] (B) 27 gms of Al
(A) 41.59 g (B) 415.9 g (C) 56 gms of Fe
(C) 4.159 g (D) none of the three (D) 108 gms of Ag
Q.2 Rearrange the following (I to IV) in the order of
54 56
increasing masses and choose the correct Q.7 Give that the abundances of isotopes Fe, Fe
57
Answer from (A), (B), (C) and (D) and Fe are 5% 90% and 5% respectively, the
(At. mass : N = 14, O = 16, Cu = 63) atomic mass of Fe is - [IIT-2009]
(I) 1 molecule of O2 [IIT-1993] (A) 55.85 (B) 55.95
(II) 1 atom of nitrogen (C) 55.75 (D) 56.05
(III) 1 × 10–10 g molecular mass of oxygen Q.8 The simplest formula of a compound containing
(IV) 1 × 10–7 g atomic mass of copper 50% of element X (At. mass = 10) and 50% of
(A) II < I < III < IV (B) IV < III < II < I the element Y (At. mass = 20) is : [IIT-2011]
(C) II < III < I < IV (D) III < IV < I < II (A) XY (B) X2Y
(C) XY2 (D) X2Y3
Q.3 One mole of calcium phosphide on reaction
with excess of water gives [IIT-1999] Q.9 The volume (in mL) of 0.1 M AgNO3 required
(A) One mole of phosphine for complete precipitation of chloride ions
(B) Two moles of Phosphoric acid present in 30 mL of 0.01 M solution of
(C) Two moles of phosphine [Cr(H2O)5Cl]Cl2, as silver chloride is close
(D) One mole of phosphorus pentoxide to - [IIT-2011]

Q.4 At 100ºC and 1 atm, if the density of liquid


water is 1.0 g cm–3 and that of water vapour is
0.0006 g cm–3 , then the volume occupied by
water molecules in 1 litre of steam at that
temperature is [IIT-2000]
(A) 6 cm3 (B) 60 cm3
(C) 0.6 cm3 (D) 0.06 cm3

Q.5 How many moles of electron weigh one


kilogram ? [IIT- 2002]
1
(A) 6.023 × 1023 (B) × 1031
9.108
ACME Study Point
Chemistry Problems

ANSWER KEY
LEVEL # 1
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Ans. A B D B B B A D B D A C D A B C A D B D

Q.No. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40

Ans. A B B B B D A C C A B C D D B C C D C A

Q.No. 41 42 43 44 45 46 47 48 49 50

Ans. A B C B D B C A B B

LEVEL # 2
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Ans. C C B A C C D D C D A B D B A C D B A C

Q.No. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36

Ans. C A C C A B B A D C D D B D B A

LEVEL # 3
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Ans. C B C B B A C B A D A D B B C B C B C B
21. False 22. False 23. True 24. False 25. True 26. False 27. False
28. A 29. D 30. B 31. C 32. D
33. A U; B  P; C  Q; D  R; E  S; F  V; G  T
Q.No. 34 35 36 37 38 39 40

Ans. B D B A A C A

LEVEL # 4
SECTION : A
ACME Study Point
Chemistry Problems
Q.No. 1 2 3 4 5 6 7
Ans. A A C B A D B

SECTION : B
1.[C] 23
6.023 × 10 molecule = 249.5 = 9.108 × 10–31 × 6.023 × 1023 Kg
249.5 = 9.108 × 10–31 × 6.023 × 1023 Kg contains
1 × 1022 ––––––––––- × 1 × 1022 = 1 mole of electron
6.023 10 23
= 4.159 gm

1
1 kg contains =
2.[A] (I) Mass of one molecule of O2 = 32 amu 9.108  10 –8  6.023
= 32 × 1.66 × 10–24 gm 1
(II) Mass of one atom of Nitrogen = 28 amu = × 108 kg
9.108  6.023
= 28 × 1.66 × 10–24 gm
(III) 1 × 10–10 (gm molecular mass of oxygen)
= 1 × 10–10 × 32 gm mass
6.[B] No. of atom = × NA
At .mass
(iv) 1 × 10–7 (gm atomic mass of copper) 54  5  56  40  57  5
= 1 × 10–7 × 63.5 gm 7.[B] = 55.95
100
Correct order of increasing masses
= II < I < III < IV 8.[B]
X 50 2
3.[C] Ca3P2 + 6H2O  3Ca(OH)2 + 2PH3
10
4.[C] massH2O(  ) = massH2O( v ) X 50 1
(V  d ) H 2 O (  ) = (V  d) H 2 O ( V ) 20
V × 1 = 1000 × 0.0006 E.F.  X2Y
VH 2O(  ) = 0.6 cc 9 .[A] N1V1 = N2V2
0.1 V = 30 × 0.02
5.[D] Mass of an electron = 9.108 × 10–31 kg v = 6 ml
Mass of one mole of electron

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