Salt Analysis In-Depth Revision
Salt Analysis In-Depth Revision
Qualitative Analysis
Analysi
Salt
si ⑳
cations Anous
[Bavic Radicals) lacidic Radicals!
they
acid
react with
(they show
reactwith Bar
to show characteristic to
uopety property)
characteristic
Acidic Radicals: -
ng+2]
au-# cut, cat, Pft, Bit3, disHU
+ HeS
⑬ Ast35, syt2/4,syt3/+5
no
① conate):
↳ lity;all nomal carbonates
exceptions
with
insoluble.
oing,
Bicarbonates Ca, Sr, in
only
* Ba exist
solution.
aqueous
sall + dikson Brick
effervesence
colourless,odourlers
of
a
gaswhenit
↓
ge
Nazcoz +
disson - Nazson +
co24+hs
CO2 calony-cacosI
+
+
to
white
cridic limewater
gas
(Bau)
↓
Co2
CaCH203) 2
E miskynettes,appeas
BaCO3I H20
--
CO2 Balonz
+
+
saray later
white
thermally
unstable
AgacostI ia
Ma,Cop
AgN83 - a
+
chilli
E
Lunar caustic white
Isoluble in
pete.
NO3 & NH3
,
occur heat
of Agro.
Thisexw will when we
the mixture.
At co24
AgaCOs Ag,o+
↓
04
2Ag Black
-
1105in normal cationates!-
for
Test
presence of a mixture
Adding of
calls
of
* an excess to
white
solution pass
filtering rapidly
on the rcos into
filtrate. On
adding its it, a
to white
pit
cloudiness is obtained ifMC0sis
or
prevent
HC05"+cat2 +
Ny ->
CaCO3 +
sulphite (sog):-
*
i
olubility whites alkali metal & H
only of
the
The metal
ephites are incluble
either or
sparingly
soluble soluble extent)
upto some
alkali metals
isos
of
* as soluble in water
② the
firephites of alkaline metals
earth are known
solutions.
only
in
age
having
small like
is burning
produced
which turns lime
water
milly. ↓
MazSOs + dilH2SO4 MacSO4 + S024 +H
-
SO2 +CaCOng-> casost
milky
N
Soz
↓
theo
(a(HS0312
water soluble.
+4 +4
CO2 SO2
↓
10/ oxidation ↓ (0) -oxidation
+ 6
X noraw.
Y
4 6 3
set ?His
02+
+ + +
t -> SO3 I
SO2
(i) (SOG)
[SO3 (oxidising agent). green.
orange Isince CO2 is in
CO2 +
(Ol ↓Ne
I white Bat SO24 H2O.
+
BaSO4
+
insoluble in ne
BasgtBuztH- BasonttB+
-
whiteppt
oxidizing
a mild
agent
Basoz +
Hog
->
BaSOn+H2O
2HNOS
↓
gas (paramagnetic)
neutral
say: -
AgNog
+
lAgsoble change
- 2:
↓
excess AgNos
503
a
(Agsos]
2
AgesObt
crystalline ppz.
-
Boil
↓
Limolable in die Hu)
son2+SO24
Ag1
2 +
Black
grey
to
+hY SO4
+2Agt+
H2O
AgeSoy
--
N92503 PVUz
+
whiteppt
↓ <dinalves in diLHNO3)
P6SO3 1 2 NaU
for
+
ppt
white
POSO4d
white.
SO +
En -
+
HIS4 but
+
+10
Rotten
egg
subide:-)
utility:The aid, normal &
polynelphides of
alkali
s
of hydrolysisof
alkaline
became
normal
mlphides other
the metals
of
The
* most
of
include thou earth metals
of
an a alkaline
sparingly
are soluble.
(H2S)
dilkeson-A colourless
having
salt+
gas
smell like
egg.
rotten
suffocating produced
a odour
-
Na2S+H2SO4 MALSO4 + H2 S4
- d(CH3cory ->
cast +
CH3CH.
yellow
-
7
+ +2
Cvelfhel
Pink colorless colloidal
-
-
(yellow or white)
orange green
32:+
Ag* -
Agast
Black
C cold, but
I
imoluble in
soluble in hot did HNO3
as Naz
+
(FeCCN15NO] ->
Man (FeCCN),NOS]
Sodium
nitrofuside violet
Blutet.
* th
[0] kas
+ + 6ft -6Et2
"
-
- +
-
/
methylene
Blue
for soluble
sulphicles.
2 H2S
④ :
before taking actate ion in
aqueous
solution, it must be made me that solutiondoes
by
then ions be removed addition
of AgNos.
can
salt+dilkeson colourles
vapours
-
containing
acidic MU.
constant
of
solutions MH40H drop by with drop
etrinsing till
ppt
the
formed does not dissolve
Nitrite:(NO)
*
NO2
salt+dilfeson--Reddish
brown is
produced which
-
when gas
pared ↳son solution
through
a blown
formed
is
complex known as
(Brown tent).
Ring
2NaNOy + H2SO4 ->
NazSOn +&HNO2
HN0y ->
HNOz NO
+
(disproportinate)
NO +02 -> NOz
Reddish Brown
>paramagnetics
ReSO4t NO -e FeSOn NOw (fe(H2O)5NO] sOn
Brown
ling
I=
* Bu & coloured
other or
anions cations
- + NO2+CHINH- I +
NO4+43288-
Blue colour H20
+
stalach
with
Muon +n
- ⑦
+ ->
int2 NO3 He
NOg
+
+
Pink colourless
like)
+
Nor Hy Zi N24+ 2128 (diazotization)
HNOg* NM1-4-NHz
wea
↓
N24 2024 +H2O
+
-4 N24 SCN*-1H20
HNOg NM2 NY >
- +
-
-A+ 35 -
FelSCl
Blooded
-I
chloride it:
① -
mee
metal chlorides
ility:
All are soluble
water
ex a
thou ofAge,a t pacewhereare
salt+conc.Meson-- HU+HSon
↓
colourless with
smell which
gas pungent
in his giveswhite
&
James
intense
fumes ag.NH3
with
is evolved
MuC+2H2O+ G4
↳P MnOz +MU-> 2
quewish
yellow
NHGON+ MU-NHC THO
white
fumes
AgNOz
+HU
-AgUt HNOz
+
white
insoluble in water but
soluble in ag N13-
Tollent Reagent
(Ag(NGsIz]
>
AgU+
on
2NHOH =
↓
n
Agrite
POUk + MNOS
P6(NOzIg
+
+
HU -
18
POC (soluble in hot)
↳
cwamye
chloric feet.
when solid chloride is heated
with
cone. MISOn in
presence of K2Cr,O7 deep sed
vapours
of chomyl
chloride evolved.
(orangered)
Malt conc.Heson-> HU+NASO4
K2C207 2H2304-
+
KHSO4 003 +
+ Heb
COst2NY-CrO24+H2O
⑧
chromylchloid
X
a
c-a- orangered).
CrOU2 +2NOH -
NazCrOn +2NaU+H2O
yellow solution
↓
P6 [[4, (08) 2
166041 +
2CH3CCoNa
yellow ppt
Note:
-
is
given by
- * teet
of My, Ag,
This not chlorides
thistent
In such cases
may
be
performed
the
residue
by takingcastorate evaporation
obtained
extract
after
sodium
of
chomyl
② The chloride be
always
is
text to
test tube
the
obverations
there
vapours of
viz, led works,
yellow solution
of MazCWG yellow ppt. of 169204
&
is obtained
Bromides (B)!-
is
tubility:-solubility
same as chloides
NaBU+
conCH2SOn -> MaHSO4 +HB
L Seddick Brown
I
vapours
2 NaBr+MnOc+3H2SO4
->
2NaNSOn+ MuSO4
Br2Y H20
+
+
+AgNOs AgBrt
->
NaBU
Pale yellow
Linsoluble in water)
NH40H
(spacingly
↓
soluble) (Ag(Nks12]
+
kB + C2 -> 2KU+BU2
oxi d i z i n g
it
stronges
Brzt CHU-s Brown
layer.
ide!-
litiy. same chlorides.
as
violet
vapours
MnOc+3H2SO4-2NaNSOn+ MuSO4
2NaI+
Ic4 H20
+
+
NaI
AgNOs AgEL+MaNOg
+
->
stronges oxidizing
agent
violet
Ig t CHU3 I
lager
-POIS
(C1016+=
yellowppt
soluble in hot water
formiyields
ng a colourless solution
& a
golden yellow colours -
on
cooling
Est starch- Blue or Black
-stach-Blue/Black.
6I+ cr,O7+THzSOn-- 3I2+2ut+ 7SO4+TH2O
orange green
3I +
N0 4n* + --
738 + 2N04 +H2O
linear neutral oxide
31 +
2lut2 > 2 m=1+ Is8
Brownppt
↳. +
gcla
->
ngIct+au
scarlet led
I
↓
(excen)
-In]
NO -Nitrate! All mital nitrates as water eluble
N1, diamagnetic
formation of
=
N -
N204.
0 colourless.
ur 4HNy -Cu(NOzic
+
+ [NO2 +2H
turning
Brown
Ring Test:
NaNOztH2SO4 -> MaNSOn + HMO3
6 FeSO4t 2HNOz +3H2SO4 ->
3Fez(sOnly 7HD
NO
↓
Browning
27:
/On
NacO4+conc.HSOn-NazSOn +HeOh
Bally+ Nagson-Basont+2MaU
white
Linsoluble in warm HUR dil HN03]
but soluble
moderately boiling
in
conchu]
sOR" +4N
3Ngt 2420
-Hgson2NgO
+
yellow ppz
Basic mercuric
sulphate
prevent, they
is also then also
y Ag&PC may
*
getppt AgU by
addition
of
as & POUs Balle
be used
To avoid it, BalNobly
may
in
placeof Balle
-hate.
*
NazPOnt 3HNOg NaNOz +
H3PO4.
H3POh+ 12
(N)gMoO4 + 2INNO3
(excess)
↓ -
Ammonium phosphomoly
date
Fide:-
NaF + H2SO4 ->
NacSO4 +HeFz
sto I - o -
NayS203
ability: cable
of thiosulphates
most the are water
Sonof PS,
sparingly
soluble
Ag&
Ba are in
water.
* 5,02 2
+ - St +
S024 +H2O
colloidal
sulphur
↳yellow thebid)
titrations white
odimetric
Is t
500
2: - 25+ suOy2
starch colourles
Blue
sgO2*
AgQ -
Agr(Sa83) t
+
white
H20
↓
210 son2
Ages
+
Black
5902
2
463283
+
pf
+ - +
420
HiO
↓ 2:1
P6S + 2HO+ son
Black
SyO+KCN- scO+sO-
Fells
↓
fe.(SCN13
(Blood red colour)
25gOg2+ret
3
-
(Fe(s203)2]*
dark violet colour
disappears
on
colour
standing.
+ret3 saOG2
[Fe(SOs) -> Fet2 +
-
Basic Radicals
o
solution
original
mother solution
-
or
salt+H20
-
soluble insclable---soluble
↳ Ensoluble
Idiesel
-I
soluble inscluble
Icome Mi
↓ ↓
soluble insoluble
Lagua
sagion
soluble.
Basic Radicals
e
ar-I-Ag*, J
2
p6+2,
+
① dil HCS
igz
Pot Hgat.Bits,catecatyne
② Ii-
-
⑰
-
MHC- NHyOH.
of
⑥ Nat,
kt,ingt2 J- no
group Reagent.
⑰
⑦ J
Gr-zeo NHh
group reagent
- no
This
table is
formed basis
the
solubility
*
of
on the
poduct p
group
will be
colubilitygreater
creater
the the no
↳5 min)
Take a
print out and sevice.
Idaily):
-
white
↓
- Resident
1
GU I
unknown
compound in
*
petrate pendam
Gr-
indilHU etrate POUz
M2sgas ~
Agu,allz
W
↓ ↓ has
Residue filtrate Brloff
au as GUIB I add NHUANAH
As,S3 yellow
ackys- Sus Blown
BigS3
-
I
yellow
- gelatinous
white
GUIV
culphide. x, dirty
green NHOH
~
(NulaSs 2.
FeCON13 2
Reddish
& MH44
Brown
-
↳ -
Under
~
wel chices
e n
ar-I A
do not dinove Gu IB
I
-
in YAS.
(Residue)
COS -
Black filtrate
GUI
L
NIS
2ns- white
Myoh in presence
Mns -
Buff colous
Reside
& 8(NHulqCO3 &
de NIC
white - Bacos, srco, (a.COb ratgoI
Radicals
-
-Hg
et
POUs (White
Ag,
Y
Pla
filtrate Reside
Ages, galle
KI
P6IzN + 2K4
POUg
->
not in exces
yellow
↳ K2CWOU
P6C204 k
L
yellow
dil H2SO4
POSOnt
↳ UCCONHa)
(soluble in
white ppt.
[POUn]"ecluble
sit
L HeS P6S ↓
Blackppt
Reside
agNty distrate (AgcNts)2)9
-
genteene
grey
(AgINsld] 4
NMENO
Ag
Like Agezont
t Brick Red
Age
Bright yellow
↓
u
insoluble in ag. N1y.
Mg Hg(NHe)4
+
ragia
3 NC+IHNz-> NOU+2U+H20
conc u
Rearon for
oxidationing
agent
ng+ax-ryck
Rg(z)
c
+
-
+N4 the
kgU+
K1
IgEst
->
Red
↓kI
K2(gIn] coloulers.
+suc
snlz
HgeUn
->
↳getzt
↓
white
sulle
↓
suln
sngt
t
Black
Z
MgU
call+
lg black
deposited
on
copper.
H2S = 2N*+32:
->
GI
-
the
Before passing
-
acidic
of
* H2s, the cone
is too acidicemail
not be
precipitated. On
get pin
also
**
profes ion cone is to
from
0.25N
0-5N HU.
solution
original
mustbe
fee from any oxidung.
The
*
oxidized
agent. get
Otherwise with
has
recipitation
of fees sulphure. by heating
This is done mixture the
concrete
with
for sufficient during preparation
time the
solution.
of original
GV-I
Blackppt
I
-
))
↳S
BigS3
&
is
CdS
yellow
⑬1
As,Sz -
yellow
range
-
stuss-
Sus + Blown
ne
~ S
chices I YAS
rg
-
#
->
divor -
only inaguaga
cob
/ -
revidue
petrate
is
-
#A #B
aqualagia
ngs+CK) AgUts
->
ngUrgent such
II= Isuck
↓ such
rg
+
HgEd Black
↓R (excess)
=
=n]
12g
rate
Cu(NO3)2
Passt
Reside
I
Cd(NO3)2 con -
Th
PO(N03)2
Bi(NO3) 2
↳petrate
[mephate salts)
H (4200/aP6 IPOSIUSCON
poson
Black
KI K2204
L ↓
PJI2 P6C8O4
yellow yellow
Residue BilOn)sI
filtrate CuSO4
cason
-a
L
Big(S04l3 Mon
futrate
((NH3) n) son
(Cd(NH3In) son
↓
NazSnO2/NaOH
Bit Na, SnOz
+
+2NaY
Black
⑧
p Bills Ho-BiOU
+
(excess
I
white
pearl
(Cu(N)n] SOn
[A(NbIn) SO4
3 OH CuSOn
C&SOY
+CHICLONHG
cason+ calris-COCM+IN
1CN (excens
↓
[CuCCN14]
L I
13 moestable.
/CACCWIn]
ews) cuz(te(ws]
cuson] Chocolate Blown
↓
colour.
Imp
As
-very ->
-
-
-
CaS
yellow
Ast3 AsTSEHAsOn
MyAsO4 + 12(N)>MoO4 +
GINNO3
2INH4NO3
↓ yellow I5N0
+
molybdate
Ammonium Arseno
salle+ligh-
sunt
myulla
↓suc
,
S6OU+anY
*S6Ug+H2O
-
rangtulraiy
⑭. Fet, cut, Alt3
I
Ahotelarouse Dirty gene
-
FeCONs + Reddich Brown
APE Allows -
gelatinous
white
NaOH
excess
S
fet, cut 3
filtrate
Resider
NadlO2
NadlOg NHDRie
+
NHGAO2 +Nal
H
↓
NH34 t Al(ON)3
gelatinous
white
>Residue FCON
3
+
"conle I
re(OH)3 ⑳
Brz-H20 ↳ NaCWOG
e
yellow relation
oxidizing agent
P6(N03)2
NazCrOn- P6C884 t
yellow
/Back Agnrz
Bacont t .
yellow ppt >Agatron
Brick Red
conc kn(Fe(cals]
FeCONs Ze Fells -
FenlieCNIs]s
solution
P Deep Blus
anhy-Fells - Black.
Fellz KSCN
+ ->
FeCSCNls
g Bloodled
MH4SCN
art
-
Intent cost with
-
↓
H2S inNHOH& NH44
zallz Mulz= -white
altrate I dil HIS
is -
Butt
E
Residue.
amphoteri
metalc eid M
et
~
excess -> inolta (Black)
Zucke
I -
MuC2
NaOH
↳ trate N92202
j --
↳zaUz+H2S
Us + k4(Fe(N)6) -> Inzlie(wis] d
In -
Bluick white
↳
k3(F((N16]
Ins(Fe(CN1s] 2
ppt
range
MnOg +P6O2 +conc.
4N0z->P6INOBy +HMnO4 tHO
Pink a
oxidizing purple
agent
inog+Nats +con.MNis-
Billogatninnou
pink or
purple
+
NANO3.
>
(U)
laga
↳
Nillz
green
His
coUr+NaNCOz ->
colOb+2MaU+CO24
CoCOpt NaNCOz -
Man[coLCOs),]
↓Brz
Max (CoCCOss]
applegran
NiCz + NaHCOz -> NiCO3 +2NaU + C024
↓
Brz + NaN103
NigOz + 2NaBr 2002
+
Black
contains at least
solution two
If of
* a one the
how
cot2with them
identify
the
frence of
to
there ions.
selection
s 1 Treat the Malecos in
with
frence of
-
--
change
on
heating
then Lot 2.
③ No
green
in cold but Black on
heating
then Nith.
④
Apple green
in cold but
Black on
heating
Both
prevent
then are
coUs
I H
Mills BVz + HO
colrt KCN -> colNiL kn/Co(CN)s]
Brownppt yellowish Brown
solution
↓
Bratto
k3(2o(2n)6] + kB2
yellow
Bright
solution
Nick KCN
+
NiCNIc1
green
fa
(NiCNIn]
↓
Burt Ho
Ni2O3 L +KCNO+IBU +40
Black
specific
tent
for with & cot2?-
k3(o(NO2Is]
*CoUL+ kN0y CCH
+ -
yellow
↓NAuscw/ethee
WHn)2 (Co(sawls]
Blue.
p.
Nice
+Mecor +
aNe
(DMG -n)
L
NICDMG) 2
Red pink
Rory
or
I
- 0
I
o
...
More
the
M c
=
-
MC
Nith
X k -
m
=
u
1 -
H-....
-
d
p squan/anas.
Gr-
-
Batt I
sut? Cat2
B, SCOb
white
↓
ancest
Acetates Bacront
yellow
rate (CTC081, Ca, [41,200/ySw
↓[NAue
Residue-Yunn
((2(a(son)
ErSO4
white
↓
(44)204
die tell CalyOnt
Car(feC(NoI
white
rekor1) white
⑰- -
with
Nat-
crimson]
red
yellow
fame calor
golden
Bettength they - do not
respond flame
to tel
NaL+KH2S604- NaHzS6OnL+ K4
white
124 Mas
+
NacHPOnt NHOH
ingelzt CNaC+ No
-
mg(MHa)POY
+
white
!*
Mg07 o
⑰
NM4
- NA4 +MaUtHO
NHuC + NaOH
pungent
odous
In dipped rod)
NHGU
white
fumes.
↳y
Reagent
NMU
Kellg=n]
kOn + +
-
↓
**2
rg- t
KI + K4
*↓
110
+
Brown
ppt
Iodide milon's Bar
of