Part I: Organic Chemistry

Choose the most correct answer:

1) Methyl acetylene is also known as :

a) Butyne b) propyne c) ethyne d) pentyne
2) The loss of _____and _______ atoms from the double-bonded carbon atoms leads
to alkyne formation.
a) Oxygen, halogen b) oxygen, hydrogen c) hydrogen, d) carbon, halogen
halogen
3) What is the reagent used and appropriate temperature required to prepare
ethene from ethyl alcohol?
a) Diluted H2SO4, 1600C b) Concentrated H2SO4, 1700C
c) Diluted HCl, 1700C d) Concentrated HCl, 1600C
4) _________ on heating with alcoholic potash loses one molecule of hydrogen
halide to give alkene.
a) Halogen b) Haloalkanes c) Haloalkynes d) None of the
above
5) The IUPAC name of the compound H2C=CH−CH(CH3)2:
a) 2-Vinylpropene b) 1,1-dimethyl-2-peopene
c) 3-Methyl-1-butene d) 1-Isopropyl ethylene
6) Ethylbenzene reacts with Cl2 in sunlight to give:
a) 1-Chloro-1-phenylethane b) 1-Chloro-2-phenylethane
c) 4-Chloroethylbenzene d) 3-Chloroethylbenzene
7) Benzene Can be :
a) Discharge the color of KMNO4 b) Discharge the color of bromine water
c) Polymerize d) Undergo substitution reactions
8) Which of the following reactions will yield 2, 2 -dibromopropane ?

9) Give the structure of reactants :

a) A: Benzaldehyde, B: Acetylene b) A: Benzyl alcohol, B: Ethanol
c) A: Benzoic acid, B: acetylene d) A: Phenol, B: Acetylene
10) Which one of the following IUPAC name is not correctly matched?

11) When n-butane is treated with chlorine, how many monochloro products are formed?
a) 1 b) 2 c) 3 d) 4
12) Which is an important raw material in the chemical industry to produce
polyethyelene?
a) Acetylene b) Ethyne c) Both a and b d) None of the
above
13) What is the product of the following reaction:-
CaC2 + CH3CH2Cl (excess)→
a) 1-butyne b) 3-hexyne c) Ca(C2H5)2 d) Cl-C≡C-Cl
14)…….. can be prepared by Huns-Diecker reaction using silver salt of carboxylic acid.
a) Alcohol b) Alkyl halide
c) Alkane d) Acid
15) The reaction of ethyl iodide with sodium ethoxide is ….
a) Williamson’s reaction b) Sandmayer reaction
c) Grignard reaction d) Wurtz reaction
16) DDT is …..
a) Dibromodiphenyltribromoethane b) Dichlorodiphenyltrichlorobutane
c) None of them d) Dichlorodiphenyltrichloroethane
17) Formic acid can be prepared from oxidation of ….. using …...
a) Methanol / KMnO4 b) Ethanol / KMnO4
c) Ethanol /KOH d) Methanol / KOH
18) Reaction of diethylether with hydrogen iodide at low temperature gives
a) CH3CH2OH + CH3CH2I b) 2 CH3CH2OH + H2O
c) 2 CH3CH2I + H2O d) No reaction.
19) The steps of the transformation of phenol into acetophenone are…………..
a) [Zn dust/ heat] then [CH3COCl/AlCl3 ].
b) [Zn dust/ heat] then [ CH3Cl/AlCl3 ].
c) [SO3 / H2SO4 ] then [CH3COCl/AlCl3 ]
d) [Br2/ AlBr3 ] then [ CH3COCl/AlCl3 ]

20) ………………….is the reaction between benzamide with bromine Br2 in presence of
potassium hydroxide KOH.
a) Hofmann reaction b) Sandmayer reaction
c) Friedel-Craft’s alkylation d) Ozonolysis

21) The product of the following reaction is

a) CH3CH2COOH b) CH3COOH
c) CH3COOEt d) CH3CHO

22) …………….. is produced from the reaction of ethyl acetate with CH3MgI.
a) Acetaldehyde b) Acetone
c) Benzaldehyde d) HCHO

23) Paraffin wax is:-

a) Saturated hydrocarbons b) Unsaturated hydrocarbons
c) Alcohol d) Ester

24) Two isomeric forms of a saturated hydrocarbon

 a) have the same structure. b) have different compositions of elements.
c) have the same molecular formula. d) react vigorously with one another.

25) Which of the following hydrocarbons does not have isomers?

a) C7H16 b) C4H8
c) C6H14 d) C3H8

Choose the most correct answer:

1. …….. can be prepared by Huns-Diecker reaction using silver salt of carboxylic acid.
e) Acid f) Alkane g) Alkyl halide h) Alcohol

2. The reduction of benzaldehyde using LiAlH4 produces………..

a) Benzoic acid b) Benzyl alcohol c) Benzal chloride d)
Benzene

3. ………is the reaction between benzamide with bromine Br2 in presence of potassium
hydroxide KOH.
a) Sandmyer reaction b) Cannizzaro reaction
c) Wurtz reaction d) Hofmann reaction

4. In the ozonolysis reaction, acetylene forms

e) Formaldehyde f) Glycol
g) Glyoxal, formic acid h) None of the above

5. Aniline is a derivative of benzene which contains

a) Imino group b) Amide group
c) Nitro group d) Amino group
6. When n-butane is treated with chlorine, how many monochloro products are formed?
e) 1 f) 2 g) 3 h) 4
7. Replacement of hydrogen of benzene by alkyl group in the presence of alkyl halide &
AlCl3 is known as
e) Dows process f) Friedel & Craft acylation
g) Friedel & Craft alkylation h) Clemmenson reduction

8. How many isomeric alkanes of the molecular formula C5H12 are there?
a) 1 b) 2 c) 3 d) 4

9. Two isomeric forms of a saturated hydrocarbon

a) have the same molecular b) have different compositions of elements.
formula
c) have the same structure. d) react vigorously with one another.
Part I: Organic Chemistry
Choose the most correct answer:

26) The hydrolysis of Mg2C3 produces:

i) Butyne j) propyne k) ethyne l) pentyne
27)Find the alkane (C5H12), which will give only one type of monohalogenated
compound
e) 2,2-dimethylpropane f) cyclopentane
g) 2-methylbutane h) n-pentane

28) Halogenation of aniline with bromine water gives

a) 2-Bromo aniline b) 3-bromoaniline
c) 2,4,6-Tribromoaniline d) None of all.
29)The Wolf- Kischner reduction of acetone gives
e) Propane f) Propanal g) Propenal h) Propionic acid
30) The IUPAC name of (CH3)3C-OH is
e) 2-methyl-3-propanol f) 2-methyl-2-propanol
g) 3-methyl-3-propanol h) 3-meyhyl-2-propanol
31)Picric acid can be prepared through
e) Nitration of Toluene. f) Nitration of Phenol.
g) Nitration of Benzene h) None of all.
32) Select the incorrect statement regarding alkanes
i) It is otherwise known as Paraffin j) It is an acyclic saturated hydrocarbon
k) In alkanes, C-C bonds are single l) Alkanes have the general formula CnH2n
33) Which of the following statements is FALSE regarding the reaction between Cl2and
C2H6?
a) It is a substitution reaction.
b) The reaction will give a single product of C2H5Cl.
c) The reaction can be initiated with either sunlight or heat.
 d) The first step in the mechanism is the cleavage of the Cl-Cl bond to give
chlorine atoms.

34) 1-butyne and 2-butyne can be identified by using which of the following reagents?
i) O2 j) HCl
k) NaNH2 l) Br2
35) Which compound form benzoic acid on oxidation with acidified KMnO4 or
K2Cr2O7
m) Toluene n) Ethyl benzene
o) n-propyl benzene p) All
36) The bond angle between H-C-C bonds in ethane is
i) 120° j) 180° k) 109° l) 109.5°
37) Chlorination of toluene in the presence of sunlight produces
e) Benzyl chloride f) o-chlorotoluene
g) p–chlorotoluene h) Benzoic acid

38) Which of the following is used for welding?

e) CH4 f) C2H2 g) C2H6 h) C2H4
39) What is required other than anhydrous AICI3 when toluene is prepared by Friedal
Craft reaction.
a) C6H6 b) C6H6 + CH3CI

c) C6H5C2H5 d) C6H5CI & CH3Cl

40) Isopropyl bromide on Wurtz reaction gives

e) Hexane f) Propane
g) Neohexane h) 2, 3-Dimethylbutane
41) Pure methane can be prepared by
e) Soda lime decarboxylation f) Wurtz reaction
g) Kolbes electrolytic method h) Reduction with H2
42) All of the following give Aldol condensation except
e) Formaldehyde f) Acetophenone
g) Acetaldehyde h) Acetone
43) Halogenation of acetophenone gives
i) O- chloroacetophenone j) m- chloroacetophenone
k) p- chloroacetophenone l) No reaction.
44) Which among the following is not exist?
a) Methene b) Ethene
c) Propene d) Butene

45) ………………… undergoes Haloform reaction.

i) Formaldehyde j) Ethyl amine
k) Ethanol l) None of the above
46) The product formed in the reaction of ethyne with dilute H2SO4 and Hg2+ is
e) Ethyl hydrogen sulphate f) Methoxymethane
g) Ethanol h) Ethanal

47) When ethyne is passed through a red hot tube, _______ is formed
i) Cyclohexane j) Benzene
k) Neoprene l) Ethane

48) Nitronium ion is:-

i) NO j) NO2
-

k) NO2+ l) NO3

49) Which one of the following methods will not give benzene
a) Heating sod. Salt of Benzoic acid with soda lime
b) Distilling phenol with Zn dust
c) Chlorobenzene with NaOH at 360?C & 150atm
d) Hydrolysis of benzene sulphonic acid with superheated steam

50) Osazone reagent is-

 e) NH3 f) NH4Cl
g) NH2NH2 h) PhNHNH2

Part I: Organic Chemistry

A) Choose the most correct answer and put it in the answer sheet bellow :

51) Halogenation of aniline with bromine water gives

e) 2-Bromo aniline f) 3-bromoaniline
g) 2,4,6-Tribromoaniline h) None of all.
52)The Wolf- Kischner reduction of acetone gives
i) Propane j) Propanal k) Propenal l) Propionic acid
53)What is the reagent used and appropriate temperature required to prepare
ethene from ethyl alcohol?
i) Diluted H2SO4, 1600C j) Concentrated H2SO4, 1700C
k) Diluted HCl, 1700C l) Concentrated HCl, 1600C
54) _________ on heating with alcoholic potash loses one molecule of hydrogen
halide to give alkene.
m) Halogen n) Haloalkanes o) Haloalkynes p) None of the
above
55) The IUPAC name of the compound H2C=CH−CH(CH3)2:
m) 2-Vinylpropene n) 1,1-dimethyl-2-peopene
o) 3-Methyl-1-butene p) 1-Isopropyl ethylene
56) Picric acid can be prepared through
m) Nitration of Toluene. n) Nitration of Phenol.
o) Nitration of Benzene p) None of all.
57) Benzene Can be :
q) Discharge the color of KMNO4 r) Discharge the color of bromine water
s) Polymerize t) Undergo substitution reactions
58)which compound form benzoic acid on oxidation with acidified KMnO4 or K2Cr2O7
q) Toluene r) Ethyl benzene
s) n-propyl benzene t) All
59) Give the structure of reactants :

u) A: Benzaldehyde, B: Acetylene v) A: Benzyl alcohol, B: Ethanol

w) A: Benzoic acid, B: acetylene x) A: Phenol, B: Acetylene
60) Which one of the following IUPAC name is not correctly matched?

61) The reaction of ethyl iodide with sodium ethoxide is ….

m) Williamson’s reaction n) Sandmayer reaction
o) Grignard reaction p) Wurtz reaction
62) DDT is …..
i) Dibromodiphenyltribromoethane j) Dichlorodiphenyltrichlorobutane
k) None of them l) Dichlorodiphenyltrichloroethane
63)………………….is the reaction between benzamide with bromine Br2 in presence of
potassium hydroxide KOH.
q) Hofmann reaction r) Sandmayer reaction
s) Friedel-Craft’s alkylation t) Ozonolysis
64) The product of the following reaction is

m) CH3CH2COOH n) CH3COOH
o) CH3COOEt p) CH3CHO
65)Two isomeric forms of a saturated hydrocarbon
e) have the same structure. f) have different compositions of elements.
g) have the same molecular formula. h) react vigorously with one another.
66) Which of the following hydrocarbons does not have isomers?
i) C7H16 j) C4H8
k) C6H14 l) C3H8

Answer Sheet for Organic Chemistry

1 A B C D 9 A B C D
2 A B C D 10 A B C D
3 A B C D 11 A B C D
4 A B C D 12 A B C D
5 A B C D 13 A B C D
6 A B C D 14 A B C D
7 A B C D 15 A B C D
8 A B C D 16 A B C D

B) Complete the following equations: