CHEMISTRY (SCIENCE PAPER - 2) ‘Maximum Marks: 80 Time allowed: Two hours Answers 10 this Paper must be written on the paper provided separately. You will not be allowed to write during first 15 minutes. This time is to be spent in reading the question paper. The time given at the head of this Paper is the time allowed for writing the answers Section A is compulsory. Attempt any four questions from Section B. The intended marks for questions or parts of questions are given in brackets [ J SECTION A (40 Marks) (Attempt all questions from this Section.) Question 1 Choose the correct answers to the questions from the given options. Oey (Do not copy the questions, write the correct answers only.) (i) Anelement in period 3, whose electron affinity is zero: (2) Neon (b) Sulphur (c) Sodium (d) Argon i) An element with the /argest atomic radius among the following is: (a) Carbon (b) Nitrogen (©) Lithium (a) Beryllium cee “This paper consists of 11 printed pages and 1 blank page. ‘Turn Over 723 522 © Copyright reserved.Gi) Gs) o oi) (ii) ‘The compound that is not an ore of aluminium (a) Cryolite (b) Corundum (©) Fluorspar (ad) Bauxite ‘The vapour density of CHsOH is _ -(At. Wt C712, HT, OF 16) (a) 32 &) 18 (©) 16 (d) 34 Which of the following reactions takes place at the anode during the electroplating ofan article with silver? @) Ag-le > Ag” (b) Ag+le > Agh (© Ag-le > Ag (d)_ None of the above ‘The metallic hydroxide which forms a deep inky blue solution with excess ammonium hydroxide solution is: @ Fe(OH) () CuO: (©) Ca(OH (d) Fe(OH)s ‘An example of a cyclic organic compound is: (a) Propene (>) Pentene (©) Butene (a) Benzene "723 522(ii) In the laboratory preparation, HCI gas is dried by passing through: (a) dilute nitrie acid (b) concentrated sulphuric acid (©) dilute sulphuric acid (@) acidified water (x) The nitrate which on thermal decomposition leaves behind a residue which is yellow when hot and white when cold: (@) Lead nitrate (®) Ammonium nitrate (©) Copper nitrate @) Zine nitrate (s) The salt formed when concentrated sulphuric acid reacts with KNOs above 200°C: @ K2S0s (®) K2S03 (© KHsO. @ KHso; (xi) The property exhil ited by concentrated sulphuric acid when it is used to prepare hydrogen chloride gas from potassium chloride: (@)_Dehydrating property (©) Drying property © Oxidizing property @)_Non-vok acid property (xii) ‘The hydrocarbon formed when sodium propanoate and soda lime are heated together: (@ Methane (b) Ethane (©) Ethene (a) Propane 723 522 p Turn Overrn ——— (xl!) The acid which does not form acid salt by a Basie 7 (a) (by ©) (d) H2CO3 HsPOs H2SO¢ CH3COOH dical: (xiv) The general formula of hydrocarbons with single covalent bonds is: (a) (b) (c) (4) CoH2n+2 CoH2n CoH2n-2 CrHan-6 (xv) The indicator which changes to pink colour in an alkaline solution is: @ (b) () (4) Blue Litmus Methyl Orange Red Litmus Phenolphthalein Question 2 (i) Match the Column A with Column B: 6 Column A Column B (a) Sodium Chloride 1, has two shared pair of electrons (b) Methane 2. has high melting and boiling points (c) Hydrogen chloride gas 3. a greenhouse gas (4) Oxidation reaction 4, has low melting and boiling points (©) Water 5. Zn 26° > Zn 6. S4+2e > sr rm am 4i, 1 ee Gi) The follow 4 ian ¢ following sketch illustrates the process of conversion of Alumina to Aluminium: (5) Study the diagr: Y the diagram and answer the following: ELECTROLYTE MIXTURE @ (&) Name the powdered substance ‘X” sprinkled on the surface of the electrolyte mixture. (©) What is the name of the process? (@)_ Write the reactions taking place at the electrodes ‘Y” (anode) and *Z? (cathode) respectively. (iii) Fill in the blanks with the choices given in the brackets: [5] (2) Metals are good - [oxidizing agents / reducing agents] (>) Non-polar covalent compounds are [good / bad] conductors of heat and electricity. (©) Higher the pH value of a solution, the more [acidic / atkatine] it is. @ , [Silver chloride / Lead chloride] is a white precipitate that is soluble in excess of Ammonium hydroxide solution, (©) Conversion of ethene to ethane is an example of . [aydration / hydrogenation 723 S22 3 Turn Overoa : (GY) State the terms / process for the following: by ; (@) The energy released when an atom in the gaseous state accepts an electron fo form an anion. (b) Tendency of an element to form chains of identical atoms, (©) The name of the process by which Ammonia is manufactured on a large scale, (a) A type of salt formed by partial replacement of hydroxyl radicals with an acid radical. (©) The ratio of the mass of a certain volume of gas to the same volume of hydrogen measured under the same conditions of temperature and pressure. (%) —@)_ Give the structural formula of the following organic compounds: i} 1, + 2-chlorobutane 2. Methanal 3. But-2-yne (6) Give the IUPAC name of the following organic compounds: 1 HO 2. H H OHH n—¢—ton node td —H i 7 awd SECTION B (40 Marks) (Attempt any four questions from this Section.) Question 3 (i) Identify the eation in cach of the following cases: el es a white precipitate which does not dissolve in excess of ammonium hydroxide (2) Ammonium hydroxide solution when added to Solution B giv solution. (b) Sodium hydroxide solution when added {0 Solution C gi A white precipitate which is insoluble in excess of sodium hydroxide solution, 6 "723 522Gi) Fill in the blanks by choosing the correet answer from the brackets: 2) (@) During electrolysis, the compound ‘5 molten state liberates teddish brown fumes at the anode. [NaCl / PbBr:] (©) The ion which could be discharged most readily during electrolysis is - (Fe? /Cu*) (iii) Arrange the following as per the instruction given in the brackets: B) (@ ALK, Mg, Ca (decreasing order of its reactivity) (0) N, Be, 0, C (increasing order of non-metallic character) © P.Si,F, Be (decreasing order of valence electrons) (iv) Complete and balance the following equations: BI (a) NHACl + Ca(OH): > (b) CuSO, + NH;OH > (©) Cu + Conc. HNO; > Question 4 (i) State a relevant reason for the following: @] (@) Hydrogen chloride gas cannot be dried over quick lime. (b) Ammonia gas is not collected over water. i) Identify the alloy in each case from the given composition: (21 (@) aluminium, magnesium, manganese, copper (b) iron, nickel, chromium, carbon Gil) Solve the following numerical problem. B) Ethane burns in oxygen according to the chemical equation: 2C2H¢ +702 > 4COr+ 640 1f 80 mal of ethane is burnt in 300 ml of oxygen, find the composition of the resultant gaseous mixture when measured at room temperature, 723 S22 7 Turn Overaration of Ammonia (3) i ini the laboratory PreP* (iy) The following questions are pertaining to gas from Magnesium nitride: (a) Write a balanced chemical equation for its preparation: () Why is this method seldom used? (©) How do you identify the gas formed? Question 5 Ry (Write one use of the follo (@) Bronze (b) Fuse metal Gi) Draw the eleetron dot structure for the following: Q (2) Ammonium ion (b) A molecule of nitrogen [At Nor N=7,H= 1] Gi) Give a balanced chemical equation for the following conversions with conditions BI (2) Ethene from ethanol (6) Ethyne from calcium carbide (©) Monochloromethane from methane (Gv) Study the following observations and name the anions Present in cach of the reactions. [3] (2) When a crystalline solid P* is warmed with concentrated HaSOs and copper turnings a reddish brown gas is released, (®) When few drops of dilute sulphuric acid is added to Salt ‘R? and heated, a colourless yas is released which turns moist lead acetate Paper silvery black. (©) When few drops of barium nitrate solution is added to the salt solution *Q’, a white precipitate is formed which is insoluble in HCI, 723 522 a ss = ee rr ee ~Question 6 De a ¢/ State: (2) (a) Electronegativity (b) Gay: a 's Law of ¢ combining volumes (ii) The Empirical formula a * of an organic compound is CHCl. 2 its relative molecular mass j mass is . ae ‘ass is 168, what is its molecular formula? it. WiC = [At Wt C= 12, H= 1, Cl=35.5) (ii) Choose the substances given i S inces given in the box below to answer the following questions: GI Iron i 5 Magnesium sulphite Zine ‘Sodium sulphide Lead i ‘ Ferric chloride Copper Ferrous sulphate (a) The metal that will not produce hydrogen gas when reacted with dilute acids. (6) The compound that will produce sulphur dioxide gas when reacted with dilute HCl. (c) The solution of this compound produces dirty green precipitate with NaOH. (iv) State one relevant observation for each of the following: BI (a) Tothe copper nitrate solution, initially few drops of sodium hydroxide solution is added and then added in excess. (6) Burning of ammonia in excess of oxygen (©) Dry ammonia gas is passed over heated PbO. Question 7 (i) Name the following? e] (a) Organic compounds with same molecular formula but diferent structural formula. (b) Group of organic compounds: where the su sive members follow a regular structural pattern, suecessive © mpounds differ by a *CH2? group, Turn Over ‘123 822(ii) (a) ) Gi) @ (b) dv) @ (b) © Question 8 @ @) (b) Gi) @) (b) (iii) 723 522, Give reason for the following: lon ion potential decreases down a group. onic compounds do not conduct electricity in solid state. late: ‘The percentage of phosphorus in the fertilizer super phosphate Ca(H2POs)2 correct to 1 decimal point. [At. Wt. H=1, P=31, O=16, Ca=40] Write the empirical formula of CsHis. Answer the following questions with reference to electrorefining of copper: Arrange the following according to the instructions given in brackets: Differentiate between the following pairs based on the criteria given in the brackets: What is the anode made of? What do you observe at the cathode? Write the reaction taking place at the cathode. Hz, CsHo, CH, Cals (In the increasing order of the molecular weight) Cut", Na’, Zn®, Ag’ (The order of Preferential discharge at the cathode) e Cane sugar tind hydrated copper sulphate [using concentrated H2SO4) Sulphuric acid and hydrochloric acid [pe of salts formed] Convert the following reactions into a balanced chemical equation: @) (b) © ‘Ammonia to nitric oxide using oxygen and platinum catalyst. Sodium hydroxide to sodium sulphate using sulphuric acid. Ferrous sulphide to hydrogen sulphide using hydrochloric acid, 10 Ry B) By) Q) RI BI(3) ; Choose the answer from the list w « (©) A compound which is a non. electrolyte. TIs2