PES X Chemistry
PES X Chemistry
9LISH StHUUL
SECTION-A
A. Choose the correct option in each of the following [15]
1. () During the electrolysis of molten lead bromide,dark reddish-brownfumes of bromine evolved.
Which of the following could be the electrodes ?
P. Anode: Graphite Cathode : Platinum
Q. Anode: Platinum Cathode : Platinum
R. Anode : Graphite Cathode :Graphite
(a) Only P (b) Oniy Q (c) Only R (d) Onty Q and R
(ii) The molecular masses of Hydrogen (H2), Sulphur di-oxide (SO:) and chlorine (Clh) are 2, 64 and 71
respectively. Which of the following statements regarding 2g of hydrogen, 32g of sulphur di-oxide and
71g of chlorine is correct ?
P. 2g of hydrogen contains same number of molecules as 71g of chlorine
Q. 2g of hydrogen contains same number of molecules as 32g of sulphur di-oxide
(a) Only P (b)Only Q (c) Both P and Q (d) Neither P nor Q
(iüi) Asalt whose solution gives bluish precipitate when treated with NaOH and white ppt when
with barium chloride solution is -
tested
Glass retort
A+8
Cold water
Sink
(a) Write the balanced equation for the reaction in which copper is oxidised by concentrated nitric acid.
(b) Explain why only glass apparatus should be used for the preparation of nitric acid by heating conc.
sulphuric acid and potassium nitrate ?
(c) State the reason for the yellow colour that appears in concentrated nitric acid when it is left standing in an
ordinary glass bottle. Give balanced chemical equation for the same.
(i) Complete the following bychoosing correct answer from the bracket
(a) Alkynes undergo (addition / substitution) reaction.
(b) (Sodium hydroxide /Magnesium hydroxide) does not form a basic salt.
Pofsatfen.
(c) Process for formation of ions from the molecules is (dissociation / asseciaton).
(d) A (reddish brown / dirty green) coloured precipitate is formed when NaOH solution is added
to a solution of ferric chloride.
ColumnI Column II
electro refining
(d) Haemnatite 4. Atcathode
(e) Froth floatation method 5. Carbonate ore
3
(iv) Identify the following
(a) A solution which is used to reacts with bauxite as a first step in obtaining pure aluminium oxide in
the Bayer's process.
(b) A hydrocarbon which on catalytic hydrogenation gives a saturated
ydrocarbon.
(c) A pair of electrons which is not shared with any
other atom.
(d) A homogeneous mixture of two or more metals or a metal
and a non-metal in definite proportion.
(e) A type of salt formed by the partialreplacement of replaceable
hydrogen ions of an acid by a basic radical.
(v) (a) Draw structural diagram for the following
compounds
(1) 2-methylpropene (2) Butanoic acid (3) 2-bromo-2-methyl butanal
(b) Give the IUPAC name of the following compounds -
(1) (2)
CH3 CH, H H OH H
SECTION-B
(Attempt any four questions)
Question 3
(1) Identify the reactant and write the balanced chemical
equation for the following : [2)
Aluminium chloride reacts with Xto give aluminium hydroxide and ammonium chloride.
(ii) What property of Sulphuricacid is exhibited in each of the following cases :
[2]
(a) In the preparation of HNO3 gas when it reacts with Sodium nitrate.
(b) When conc. sulphuric acid reacts with sulphur to produce sulphur di-oxide gas.
(iii) (a) State whether the following statements are TRUE or FALSE. Justify your answer. [3)
(1) The reaction occurs in catalytic chamber during contact process is endothermic reaction.
(2)When sodium chloride is reacted with sulphuricacid below the temperature 200°c, sodium sulphate (Na,SO.)
and Hydrochloric acid (HCI) is formed.
(iv) The electron affinity of an element M is lower than that of element X. [3)
of X?
(a) How is the oxidising power of M likelyto compare with that
right of Xin the modern periodic table.
(b) State whether M is likely to be placed to the left or
compare with that of M? 4
(c) How is the electronegativity of Xlikely to
estion 4
()Agas cylinder filled with hydrogen holds 70 g of the gas. The same cylinder holds 560g of another
gas X. Considering the same conditions of temperature and pressure in the cylinder, calculate the relative
molecular mass of gas X. [21
(iii) Give balanced equation for each of the following : (3|
(a) Dehydrohalogenation of ethyl bromide by hot & conc. alcoholic KOH
(b) Action of warm water on Magnesium nitride
(a) Calculate the volume of oxygen reguired for thecomplete combustion of 200 litres of ethane according to
the following equation 2C,H6 + 70% 4C0: + 6H;0
(b) Acompound with empirical formula ABz, has the vapour density equal to its empirical formula weight.
Find its molecular formula.
Question5
(1) *Ammonia can act as a reducing agent" - Write a relevant balanced chemical equation for such a
reaction by stating the observation. [2]
(a) Aluminium and Magnesium (b) Iron, Chromium, Nickel and Carbon
(iii) Abhiadded dilute ammonia solution to a colourless sulphate solution of sulphate salt, which
results in formation of a white gelatinous ppt. This ppt. however dissolves on addition of excess of
ammonia solution. Answer the following : (3|
(i)Observe the diagram, given below used in the electrolysis of aqueous CuSO4 solutionusing
copper electrodes. Study the diagram and answer the following : [3]
Anode
CuSo,
soln
Cathode
(iv) X[2,6} and Y[2,8,8,1|are two elements. Using this information complete the following : [3]
(a) is the metallic element. (b) is a reducing agent.
(c) When element Xis a strongly heated in element Y, then compound is formed.
Question 7
(ii) A compoundX (having vinegar like smell) when treated with ethanol in presence of acid Z,
gives a compound Y which has a fruity smell. The reaction is given below. [3|
CzHsOH + X ’Y + H20
(a) Calculate the mass of KClO3required to produce6.72 litres of O2 at STP. (Given, K= 39,Cl = 35.5,O = 16)
(b)Calculate the number of moles of oxygen present in the above volume and also the number of molecules.
Question 8
(ii) Differentiate the following pairs based on the criteria given in the brackets - (2]
(iv) (a) Compound A is bubbled through bromine dissolved in carbon tetrachloride and the
CCl4
A + Br2 + CH2Br -CH2Br
(3)Name (not formula) the compound formed when steam reacts with Ain presence of acid.