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217 views156 pagesCRE-1 Written Notes
free
Uploaded by
arumugam gopalCopyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
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/ 156
ralte
Chemnbeal kbnetie:
4 Chemical kéinwhia hs a stiuly /
at which chemical axns pcewn and xh |
poramelins — uth as T,P and ten toe) Compeidian 0
gxn wales - '
Oaptrdiing on de no
a @ ontdateam Wittogen onde to Na Es
Bly oe, 4 ee
‘ No + 16, NO,
Gi) Fenmalin of tou spon eigen, 908
and altehols tn “prescon ¢ SHys0, 4 a Ly Ph
AxN- s
CgusOH + CH;C0OH poe CHg (ooC2Hs TF! 1
‘ s i
wianct — auhi atid ebhgl aulele '-
yratls yah
AXN: : ;
It ds one which Jnvohas . prusty | cataiyti: paauline :
/ Fhty. ans 000 which sires ee ea
| | cat
ayt ty enhans the yale af 4 naclan |
| {apa of a readin .
y; c Se ree +L 9) CFS,
/
Cg thy wee Cg Hb
ee Heat — ebhane
| ageralian 9 1 é
| #819 Wy; enh ean a
| Won - Catalybi Atacln :
: ;
| yee bith clara not trvolve
|e
| NM +10, 3d,
i
}
, | Enolothinmnic rxD!
: | An entothuunit AX As Mh ont; dh
Pen Sas "Sa
Js rege
cgHs0H - 422 > eying ¢Hgo-heat
thy | abirhat elhylint
Usa tn UO
| Buothenmic axn !
Jn cnothen't
“i A quolved {
xh ds Lhe tre » th
fy cmon rneat. Ruwrwible Anns ae Liste dn Whilth
tht power and rua peatliine Lavke ace
| Himudb ancewtly .
eC ¢. He oy 440
HE OH <7. CH COOH LS Cy loot, Hg 42
Uhinel << quibie auid ~ Cl acstal
e\-8
larewwible — yeatlime : \ 2
Thee Axns which proud oly Ln | destclim
q: -
Gus. + Ho; 4", Hew, +0
; Bonzne ikohoies
M3 + SNe > AHS
Fe,Mo
Fe - catalyst
My- molybdenum -
catalyst:
hh a subrtona which alls He pak ¥
Ais xn. Cebbares)
promoter ;
rey ann usta Lv enrance the acl yf
Catalyt
Inhibiprs :
> Ty ae ve catalyst.
> Tay aie wed dy clone tke
Oe fats 4 AMD. S059 a :
Nat dha == ang y
ee, Oe eh fas 9 WNT “tyatt Ayn me utd “he
a.
[Variable aching rath of DE —
41 LHI LST
1+hy [HBT t
\ . bingy . Greg
mh Ye
ahs Gh
eS Coruspundince ~ bw Hg0g 2 Hao +t 4m Pinon
Lobeewlanity
rroleuandly dfiid te ae ae
aoms oh tbat podlicpaliag vo hu nate —
dep 4 Ge tuachan -
Lio adler Axnt
Aana dt said Cage zero oder, if eo
vt. “ds Indipendin G te lo of The suackank
Bis) phlochurical Aun boi Hy Bele
Ha +g Fis gnc , os
2) 04 conpestin of Md. on bn led eu
Mo —> a the,
3) a 4 Why in prtsinue 4 mo of Hungslta
‘uz 22, rg t3Ny,
Yo 4) Wodlalionn of ‘heddme we HP ions
ae chs CoH + Ly ys Telex, 4H
at ash ard Axa) tk
mee stra etl eit oe 2
@ aM y maid &
3 o.emposiion 4 me da agus jolulian
MOD Was 4 aw 3h
FON aay ry el, v
SP Hadi sh eae “ @elal sa meee
CH3COOCH, H,0 + CH3e00H + CH 3) Invergeen 4 cae age
fea acids .
aes 0, tHgo Hut"
% pHa
2 Pn aioe’
| A) cecmpostin 4 emai le 29
Niyvo, —> Ng ‘+a .
5) Hydlotifes 4 oeazo olenstasintt spi
tHe
rn, swvel #10 cco! aoa".
tent eed ae)”
| Ach i dubumind by thoofe sagseiane — Hrs
5, be
8 pion 9H20 s Sd iydng Ao
and ;
Aydwgen dons : aga rr
aNoy 3 awo 405 Bias (
5 Wy ww “Sateen. ee “duclnpovs
*j rer TN 5
a ae
vo 8) In gas ped slg! Baga teemyor
walo- yp and BH Hts aig
EwoBA —3 aNd + €
Fy) Fes ar- —» Feds
at
2) arett + Sitt ay geet + Sn
3D) awo + tly Noel
4) ano + Bay ~3aN0BA
5) @wot Hy J WO, +H 0,
Regscotalin of sen” yale § nals _constank
aaider > thy flowing AXN,
Bran Seat
From He lech
Ag St Ao = LAr =e,
The lpi videnl ate sat yy,
Ce i L% Ay :
feeai “Lea F
ee By
su Lface] a
‘k, et pe [eet 3 sh wa ]
ole uber: 4
moktue R in él eh fos ee:
My if Rd Biyhty aitce x the maar Life tim
JR will be vag small god tone de Vity smelt
hh mearue- 80, it i Convidloud ag reachie
Tnlimdiak ¢ by math, i
They we sady :
Ctantain unpaiud 0) a: Pa Me
1) tens aad _Palar—aadbstane ytd
Toy aa Clechu' cally or ae
“? Banya > att —
J. AtB —>,.67
me tn == (Iniléal pot )*
piepepie, Oa tet nln = pat + Int pae
hectic :
Int pi == produd .
pon choi AXNBS
peactaris —> Intinnedliale * ee
Intermedia > product
Fag tiet traces x
toad, zl appnonimation Gr) $54) A =?
lif bin Cu ho Amal,
‘ei Rabe g goretes g Inlanmedetle Ao
Since Intormaedialis ae prt Lae Aine
The ote charge ‘gpl afl 0 ‘voy sn
can nue bo graalir . puncte, with: neggible one,
| Wile ght ak Anka fo be to. This 4 called a
“| steady stats “appovimatian. “ °\ ——* Ferporaline __oleptndortg
suite in en i a:
“ product af Jeon dpe §
dywndent Tem”! test 4
yore
z
“ye Cr) Ay eed.
x Tol such ruacllint, 7 pode P05
toe note torwlant — hae bean por and
alesrcled by Adheniug tow.
Consider Op bimekcules - tallitin “b> dike
the, Sinppalia
Fon beth
Mt giver by. aponkancedsly ale produch.
: The
ene §=blw cone
at alt tints, and Yat’ tole of decmpantion
achivaled tomplx . same yor all reaction and
a givth 7’
4 (7)
who, ?
&- bodtzman Cantark
4 - Plank’ ‘anslant .
For a hyouible AXM, ‘
& ,
Eu AB y DHA
chests AE 4
8 pet yA
os
i ae)
- a ta .
and , k
bee gM
hake
Me yale 4. et & give ¥
b ~ chit to
Wane * Gr x. 4 pl)
= fet) F at)
Thetefote :
he oe eo AY bance )
WAR,
s
Crate q duuanpuien hee oe
‘
alee xt Maa
y activated Be inlam pean fe
et Re
x Bae A
m 3
x
> : ree
4G = AH*- 745 “e *
*
Ne »
AG = «7 W()s
} 4 oS
e > fe |
oeae te wales
bewmth,\_®
Hy date <<, dpi wr t
Gianilin nue Stary ae give by - at.
‘ ¥ % ; ¥
cu 4
a 3) 4
: ~ anh ‘ ln ee
I.| On mt the, lone 4 ee
san lpr, fied “the lin sii.
soludion: ak wa
Rate 4 dhe AX,
= bey".
lomides, oh
-14,. 28 GI). ey ee
en — dloutling the tone, Aas Heubles,
36%) = abt)” -~O
Om >
CU), ROR
SCM) KA Ca
aes
Taking Ln on beoh® wd
\ * ;
Ma = Gah Bh
ning = dn3 ;
= % vigdis-t 3
; : ee A.
Ssh \ xe a x
“fps = Teed] om
andes ‘y Wwe Oy) 2 86
ee The Jrtaca dle” “88 Ns A heresies
Ved henclicolly aoa) pate: Pf fermions of
produict bas beens. eat way, he wel Orelalid
Jy fleet WOE
a
Westy ssh tie
en s
VFL NS what Axn» mtchaniom it saggae Oa
exguesyen 4 be y :
yin - IS % g Heatly’
role ond tat a e
: ae we aA
Adlukan : ‘ .
racdel_=) ! ee
aAAtB —>AQB
wA wm =H < BS Lae
s ae
te “hi fe & Me NE
4 G- ad) es bt.
Ung SSA, Tay Poe
B cag*~ by LAR] = hy LAX] [07 + bo ab] = 0-
by [at] + & [A*T pT: BLAS + LA
[As a Chg +&(8]) = 4 LAT*t 4; lAgé)
[ast] = A LAT'+ & PAg8)
Ay tks fs].
wou, the ahove it] ton be aubmilied b &.
1 @>. tn ee bs Det 18) = a Laz8]
2k
| ry 2 siacues) aj.~ to Lee]
hy + &3La7
if a4 tao small, “yet
ai AOA
7A se Lays vag? hey
UPAC aa inc es yt ee Ley
ea % LAA
Lema b & ee LAT C8) + byte POPERe hp Roce t bh
ey eee a wd
« wrt ‘
oa eS = Re \Bae ak + AO VIAY A
\may ah Pris ‘ Og faa). ]
> pee oa
| Fi ab Safer setalarivon oe ainag, ia
at have do s prapsst. fiat ae : model - 4: ae
&, ee % >
s @ +8 => AB
.- a ae
& 1
ABt tA => Ay Bu ; A
ay Wn
= eye 240 tan. be, will, 2 ons
nN & ate 74 > ag* 3 ryaie
af BF ee —@
nx VA Lead (Pas
.
naeeee bs, SMe ao
Sah ty ta Say
AB -, Ls +A ee
S Toe { 5 de Ya al wes ae
= Tags = key a] - 'y fae © oe
Ip. ta “above. —, oS sp ip a
“Yaa®] + ‘ae we tore fe | eae
dum of hie ¢ mreavunable ae yy
SSA > at =0 awe gh h aa \
Now,
aries ginen bys A
\ es ‘ Now, Aubsitdt, the Value of AG" ta ()—
Ge & RiLAIL8I + hy ABI] py — Ltd)
aban # ks LAD
Yon = 4x4 CArlatCa] + ky apres]. ~ by led
he thks LA]
If eat “boo tmall,
Tua = Ars CATCASEB]
Ry FRAT 8-314 T |
hi 8 LAD OR > dad
hae Rl ® bay 0108207 me
Pe 1.98 tad [rel k
&
' *
31 show thot, Lhe ; frbawing Scheme toes id;
\ a
No; * 55 po" +d
iter nom 40 * Fy, ano,
proposed y 6 a diel jth and Can Oxplad
aa a onder wee g oa
4| The Saabs 00 oeuig. (2 Me hemegeneous
decompesilitm g naetn. ve pound & te,
u ‘
C0 a Ny IR AE as Elia) _
Cast. he
Punic a mechaniom. td (136 981 Myth 5400 Ug1i8 16850
gurn? gabe? 3300
" °
ef: pee
3:boxid’_\ Ragbud® Fos 0n*
M yh) c ex Seordg
ma + ipxe 39" & = lox” (098)
é 2
“i ue 1, cal get es
* aK é. i Gin:
‘ id p ye now.
> Ny 05 ING FG
4
VENTE oh eth
wot atts wo 40,
*
wor + nojt #4, tng Ok
The ale eqn tan il
Ny 05 ——> Woy + Wa," 5)
‘+t
Nog + age “8 5% ©
peas 8 . SOA
ol ea)
N03
Wo¥ +n, * 4» envoy
To ie Yuyte
Yigog =
Inthe alow wy, dt offal Lo
ae figs], 40,78, mk bo cmverted tale
“a ee mail sual -
|
\
=A, hao, J thy [m2] bt
Msi SSA‘ 5
HY SA, Tygt = 0. ‘
jotwgt eB, Erste]. ~4e Eng Iemehy - hones]
2 ALP... oe ky Pot] Bae)
a] de [oad 007 hy Luge] + by Eno] Lweg*] = b Loo
y
VV \
wth 6 fatZns heeds] S95
ky laa] +43 thglnoe] \
< {
PRES) See
ese 4 t
a ym To* .
S Iypt =O os 3 ss ky Loot] = - ky [NOI imi
To® =a
hy Cwo®d Dna] = bs LJ ee
ee
wh @ in ©.
fost] = By L295]
by [MO + Byte
fof]- &, Lmets]
ahs t RgLNa] ®
pubsiilile §— ean oO a ®
A, [uses F #y ad hae
Woe ~~ Bs 2 2s a le ad
\.
Tv, 05 = =k £N1057 t Ry LN] A006] a
L027
tH, 0 20 - b, L% 95]
No <= 2-414 04
~she above michaniira can be wiilitn Ob,
M0 ae oF
N30 EM FU,
Ne a wi 0* 2
Ngo" Se
> NgO* "Bes: Wit BoD so
hy
6) Ma tae TR? GO =: *
% fo “yor 2 ‘two + kj frie] tL)
rhe [J | La ae : 94 Meant
1 dafftealh b lain LO
muse be dohubde die fone gp g
mearrealle dqueniie 4 ”
ee > Tyo =0
To" = ky Duoy -RefmeT 5
& Lnop* by [meth ae
[ryor) = pina. 6
Aebrllel: Vasa gf bat} HO a
hg, rhe ft] ob Loo)
: 1 Quejloag”
Ineo oot
The phased echo fly ta We Fone Lo
prepare can nothin —mechandim-
Ome ~)
modtl- : We know hat,
Tyo = Th,
Dtcompattifiian cempstifiim Hf Wiliour onude gus rs
Mg = [ue] —o
(n0t] th ving cleffyoull tp meawne, mo st
piste be vonvetted to mecsenble 9 tunntlics. hy SéA
Acc Ss, Got] wa =0
%y,0% Sees Cayo] - Ry Coyog br40%J- a; [ae]
4 Laoy? = Ay LAG ST + ke [uo]
[707] (é Lao] + by) =k Eu”
LaoJ® = % fisoy £5 .
ke [m0] +%
t, by Logo
ey beet
2 & [ey Logo?
% it Bb
ys Ch = & Lmag ein ts Oe
by) edi £ Lig] (ae
yt + i & Intoynetaliin of pabin niall eee
y 0 ffacatial rthed Pas
of) Inlegral bod. : owe
D olfpountial mebhid :
° it (al)
Hapolhena 0 mechan an
jeteler, jm i vbtan Aol 4,
a} ~% =, -4G 2 key
# dot,
: Faom catia Ma tint pl
un tb a gh
: i ct
_ Draw a Areoth told ee «
ulirmine the tp en e
suitably selected conanbaion Via C TB)
plot (dia i) Ve the
Avatual p Ce a)
each eee value. *
fier pt La(-%) dy Yo ante aod
|G b x- ax, a ale anh, vated 93d
G = mx
oG £1
se walla Inlipral — Mathed : Saas
tn Ialigal milled, we gus a particular
fmf ral. Mgpatin and ft pnts Inga,
and mablunaliial manipiclaliony pridiite thal, ple a
Gnewlilin — funttim te Atne should yield Hiei
die. The dala are plaltdd mod if a acondlly
ood +t lin ds wbtaiud, Gin the ale gn a
dad alifoatrly ft te olde. of net, We =
Lo heck =the © Yawaw abe toniealpalun Fes
pot |
he lanuspentling equals °
74 ondu:
th a ot, Go ne
G ond: y\ = Sinz /
MS Goo De eR
Cho a Oe” t
Luo vider: Gee
Cho ~~ = kk . het
Gy (nal) B81 BH BOE ie
}
de 2% +0077. 01085. 01069, 010308, 01018. 01014 r
Se ARO : ‘4
Me We EE et aa aa Stl so
ut WARN oHY y
Mn (|) 38560 62465 50,93 349 Th.017 d408
HS, 3 :
S 1% 168 , M33 019) 0140
Batten fist ieee Ca Varia according
ft Aas 4 Arn (-%)
Foo 9 ruactak A (celal Mt BO)
ee
t Lo osdt, wh
w
Lote, k > hinele corst » cvrise Me tapenn
ee et
ny by
hye -da - hy
at
pif ;
i -%, of. 1
pJat : i
dG jee
ee a
fe .
i oh, Advantages § disadvanlager ¥ /nlapaal I oH -
yee
Wig | ral
fay fe we if dala. are valine
than we Canhet we
J Aisfeuaal milked .
Receramendid : .
specie ae useful ah Inge donpltd
ANA Regnier rg anole
—& lange am dela
“his WEIR, Sail A a Inkegral muha ss — —
l \W () Find
Convidan 0 untrroletuler rene 4s,
YU = ph,
Te tal Lan dh f? by,
tae
Re annanging he above pr, wwe gel,
4G Ba.
G
ne
Ju: -f J dt
YN
- = ee
(LG i: 5
ye ee t OG “i bG,) »)
so
- i
Prastional converstan ttn):
kk aiid * justi ¥ “reacland
converted Aiko | ins
GG C=) > Case de,
™ = pee a s Cas Cag = Sx,
Gusn \
Ao, Qs. fa
aA Go- Cy ae
% 2
Pia wee eae i Yiald ¢ got . . ei
I. 2s lied fale + Aeactank
we — converted Nn dusixed praducl.
ay ;
aM = N O AAT). % oe i.
>a. sy ‘
1 % ; 1
Taam O, . 5
|p oh () slime) cht
ee es poco! danversion
oe
(a)
br (int
@nmenibl himsleaular gd od Ann:
Cmvider tha peg. precast ott
eS
\ The Aat “mn ay bi Pps SOK
ap. \ Meigs, maa hak x u
7) ee = 4 Oh —O
NK ae
DM = (a (12%), s!
& - g, (a),
ee
a Tharefors
quom O Ae : oh
ye pe ag Gay (14) % Oe
| (nls tat ae AG hah Have
vat at any dime are typed and 2 4y,
N X= (bo Xp —@
@>-%--da - 4 [er Gor Jl Co" %% |
dt ee
wh @ t te abe eqn,
-& [oo- Cra Me [ee a
© h Go [r-¥a J Chale -*4)
2 A i 3 h,? [em] Ex) -@
me =
whut, ~~ : We:
fs fae” = Intel fal Tae :
aos Cha r \
Ts jr ie ‘ade La ee
eR Bh Ohkh aie il
te ge byC ON
ay oe 2 GaX, ®G, Back aj) ire 4] Lo
Se
aan = Gd
- f-x,9 [m-xg}° Pat
5 er aleve, 240, ae ;
fe Baigs*) #--0
bg. poi i yo
gina) tatiem xo
cl pape both sick by C34) Gm- 34)
b= A(M-¥4) + b04- Ha) ET t—~—S
pus M2) Tat ee ‘ o
fe A(n-1) + B(0)
ts Acm-!) .
| ms xaos ;
2A(0) +6 UI- n)
be:
=m
wh 1 — Vale so © jg
EA x Ps V5
Ate 5 Nay dy ATA \tte
[xg ln- Xa] Gri. uy 7 em
* a) 2 7
Nee
- da Zz - diy ! i=
eee
b-xg7imxa]™ EMEA a ae ‘
a zs 0 “a =