(Physical Chemistry)

PRACTICE PROBLEMS
1. Chloride samples are prepared for analysis by using NaCl, KCl and NH4 Cl separately or as
mixture. What minimum volume of 5% by weight AgNO3 solution (sp.gr, 1.04 gml−1 ) must be
added to a sample of 0.3 g in order to ensure complete precipitation of chloride in every possible
case?

2. Find the sum of molarity of all the ions present in an aqueous solution of 5M NaNO3 and 3m
BeCl2. The specific gravity of the given solution is 1.665. Assume 100 % dissociation of each salt.
(Atomic mass of Be: 9, Cl: 35.5, Na: 23)

3. 500 gm of urea solution of mole fraction 0.2 is diluted to 1500 gm. Calculate the mole fraction of
solute in the diluted solution?

4. The incorrect statement(s) regarding 2M MgCl2 aqueous solution is/are (dsol = 1.09 gm/ml)
(A) Molality of Cl¯ is 4.44 m (B) Mole fraction of MgCl2 is exactly 0.035
(C) The conc. of MgCl2 is 19% w/v (D) The conc. of MgCl2 is 19 × 104 ppm

5. Select the correct statement(s):

(A) Ratio of gm/litre& % w/v of a solution is independent of solute substance.
(B) Ratio of % w/v and molarity of a solution depends on solute substance.
(C) Ratio of % w/v and molarity of a solution depends on solvent substance
(D) Ratio of % w/v & ppm for any solution is same

COMPREHENSION 6 TO 8

Water is added to 3.52 grams of UF6. The products are 3.08 grams of a solid [containing only U,
O & F] and 0.8 gram of a gas only. The gas [containing fluorine and hydrogen only], contains 95
% by mass fluorine.
[Assume that the empirical formula is same as molecular formula.]
6. The empirical formula of the gas is
(A) HF2 (B) H2F (C) HF (D) HF3

7. The empirical formula of the solid product is

(A) UF2O2 (B) UFO2 (C) UF2O (D) UFO

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 (Physical Chemistry)

8. The percentage of fluorine of the original compound which is converted into gaseous compound
is
(A) 66.66 % (B) 33.33 % (C) 50 % (D) 89.9 %

Paragraph for Q.9 to Q.11

Consider following vessel of given dimensions

Cube Sphere Cylinder

Cubical vessel is filled completely with 2M H2SO4 solution, whereas spherical & cylindrical
vessels are empty (Take p = 3) (Atomic mass of Br = 80)

9. If total content of cubical vessel is placed in cylindrical vessel and if it is further filled completely
with 1M BaCl2 solution. Molarity of SO2−
4 ions in aqueous solution

(A) 1M (B) 0M (C) 0.66M (D) 0.33M

10. Which acid will be left in cylindrical container and its molarity will be
2M 2M 4
(A) H2SO4, 2M (B) H2SO4, (C) HCl, (D) HCl,3 M
3 3

11. Now total content of cylindrical container is placed in spherical container and if it is further filled
completely with 32.4% w/v HBr solution. Molarity of H+ in final solution-
7 3 5
(A) 4 M (B) 2M (C) 2 M (D) 2 M

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 (Physical Chemistry)

ANSWER KEY
1. (𝟏𝟖. 𝟑𝟖𝐦𝐥) 2. (19) 3. (0.05) 4. (B,D) 5. (A,B)
6. (C) 7. (A) 8. (A) 9. (B) 10. (D)
11. (B)

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SOLUTION
2. Let volume of the solution = 1000 ml
Mass of the solution = 1000 × 1.665 = 1665 gm
No. of moles of NaNO3 = Molarity × Vol. (in )
=5×1=5
Let No. of moles of BeCl2 present in the solution = x
Moles of BeCl2
Molality of BeCl2 = Mass of NaNO3 × 1000
{Mass of solution –( + )}
Mass of BeCl2
x
3 = 1665−(5×85+80x) × 1000

x=3
 Molarity of BeCl2 = 3M
MAllions = MNa+ + MNO−3 + MBe+2 + MCl−
= 5 + 5 + 3 + (2 × 3) = 19 M

nurea 1
3. =4
nH2 O

Wurea 60
 = 72
WH2 O

 weight of solution= 132 gm

In 132 gm mole of urea = 1
1
 In 500 gm mole of urea = 132 × 500

Also, In 132 gm, mole of H2O = 4

4
In 500gm, mole of H2O = 132 × 500

Now, on dilution
500
xsolute = 500 4
132
1000 = 0.05
+( ×500+ )
132 132 18

4. 2 moles of solute in 1L of solution.

Mass of solution = 1090 g; mass of solvent = 900 g
2×2×1000 2
Molality of Cl– = = 4.44; Mole fraction MgCl2 = 52 = 0.038
900
190×100 190×106
%w/V = = 19% PPM of MgCl2 = = 17.43 × 104
1000 1090

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6. UF6 + H2O ⎯→ Ux Oy Fz + (H5 F95 ) or (HF)

5 19

(a) The empirical formula of gas is HF

 Correct option is (C)

7. UF6 + H2O ⎯→ Ux Oy Fz + (H5 F95 ) or (HF)

5 19

(b) Mass of H2O = 3.88 –3.52 = 0.36 gm

 moles of H2O = 0.2
 UF6 + 2H2O ⎯→ U1O2F2 + 4HF
 Empirical formula of solid is UF2O2
 Correct option is (A)

8. UF6 + H2O ⎯→ Ux Oy Fz + (H5 F95 ) or (HF)

5 19

(c) 1 mole UF6 gives 4 more HF

 % of fluorine converted in gaseous product
114−76
= 100– ( ) × 100 = 66.66 %
114

 Correct option is (C)

9. When H2SO4 solution is shifted to cylindrical vessel, then it occupy 100 cm3,
 BaCl2 solution occupy = 3000 – 1000 = 2000 cm3
Moles of BaCl2 = Molarity × Vol. (in )
= 1 × 2 × 103 × 10–3 = 2 mol.
H2SO4 + BaCl2 ⎯→ BaSO4 + 2HCl
2 mol. 2 mol. Ppt.
All SO2−
4 ions get precipitated

 SO2−
4 ions are not present in the solution. Hence molarity of SO4 = 0.
2−

10. H2SO4 is completely consumed,

 Acid left in cylinder = HCl
2
No. of moles of HCl produce = 2 × 1 = 4 mol.
4 4
Molarity of HCl = 3000 × 1000 = 3 M

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 (Physical Chemistry)

11. Cylinder content is transferred to spherical container. In cylinder 4 moles of HCl are present &
volume of solution is 3000 sphere is further filled with HBr.
 1000 ml of HBr solution is added to sphere
100 ml solution contains → 32.4 gm
1000 ml solution will contain → 324 gm
324
Moles of HBr = = 4 mol.
81

Total moles of H+ = (moles from HCl + Moles HBr

=4+4=8
No. of moles of H+
Molarity of H+ in final solution = Vol. of solution × 100
(in ml)
8
= 4000 × 1000 = 2M

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