ATOMIC STRUCTURE

01) 4)

Statement I: Assertion(A):

The position of an electron can be determined exactly Absorption spectrum consists of some bright lines
with the help of an electron microscope. sperated by dark spaces..

Statement II: Reason(R):

The product of uncertainty in the measurement of its Emission spectrum consists of bright lines
momentum and the uncertainty in the measurement of
1) both (A) and (R) are correct but (R) is not the correct
the position cannot be less than a finite limit.
explanation of (A)
1) Statement 1 is true, statement 2 is true,statement
2)(A) is correct but (R) is not correct
2 is correct explanation for statement 1
3)(A) is not correct but (R) is correct
2) Statement 1 is true statement is true ,statement 2 is
NOT a correct explanation for statement 1 4)Both (A) and (R) are correct and (R) is the correct
explanation of (A)
3)Statement 1 is true,statement 2 is false
4)Statement 1 is false statement 2 is false
5)
Assertion(A):
2)
The kinetic energy of photoelectron ejected increases with
Statement I :
the frequency of incident light
3dz2 orbital is spherically symmetrical.
Reason(R):
Statement II :
Increase in intensity of incident light increases the
orbital is the only -orbital which is spherical in shape. photoelectric current.
1) both (A) and (R) are correct but (R) is not the correct
explanation of (A)
1) Statement 1 is true, statement 2 is true,statement
2 is correct explanation for statement 1 2)(A) is correct but (R) is not correct

2) Statement 1 is true statement is true ,statement 2 is 3)(A) is not correct but (R) is correct
NOT a correct explanation for statement 1
4)Both (A) and (R) are correct and (R) is the correct
3)Statement 1 is true,statement 2 is false explanation of (A)

4)Statement 1 is false statement 2 is false 04) match the following prefixes with there multiple

3) 6) which of the following statement is incorrect

regarding photoelectric effect ?
Which one of the following is not the characteristic of
Planck's quantum theory of radiation? (i) The number of electrons ejected is proportional to the
intensity of light.
(1) The energy is not absorbed or emitted in whole
number or multiple of quantum (ii) There is some time lag between the striking of light
beam on the metal surface and the ejection of electrons.
(2) Radiation is associated with energy
(iii) The kinetic energy of ejected electrons depends upon
(3) Radiation energy is not emitted or absorbed the brightness of light.
continuously but in the form of small packets called
quantum. (iv) The kinetic energy of the ejected electron is
proportional to the frequency of the incident radiation
(4) This magnitude of energy associated with a quantum is
proportional to the frequency.
 2) Statement 1 is true statement is true ,statement 2 is
NOT a correct explanation for statement 1
1) 1 & 2 2)2 & 3
3)Statement 1 is true,statement 2 is false
3) 2 only 3) 2 & 4
4)Statement 1 is false statement 2 is false
7)
Assertion(A):
10) Statement I : The amount of light emitted
For Balmer series of hydrogen spectrum, the value n, =
(intensity of radiation) from a black body and its
2 and n, = 3, 4, 5.
spectral distribution depends only on its temperature
Reason(R):
Statement II – When a ray of white light is passed
The value of n for a linein Balmer series of hydrogen through a prism, the wave with shorter wavelength
spectrum having the highest wavelength is 4 and bends more than the one with a longer wavelength.

1) both (A) and (R) are correct but (R) is not the correct 1) Statement 1 is true, statement 2 is true,statement
explanation of (A) 2 is correct explanation for statement 1

2)(A) is correct but (R) is not correct 2) Statement 1 is true statement is true ,statement 2 is
NOT a correct explanation for statement 1
3)(A) is not correct but (R) is correct
3)Statement 1 is true,statement 2 is false
4)Both (A) and (R) are correct and (R) is the correct
explanation of (A) 4)Statement 1 is false statement 2 is false

11) match the following .

8) match the following prefixes with there multiple

Column I Column - II

A p
Column I Column - II Lymen series Visible region
A p
A p
Orientation of the
Principal V q
A p orbital quantum Humphery series Ultraviolet region
B q
Energy and size
V q C r
azimutal of orbital Pashchan series Infrared region
B q quantum number C r

C r of lectron
Spin D sFar infrared
magnetic Balmer series
C r quantum number D s region

D sShape of the
Spin quantum
D s orbital number

(1) A-(R); B-(S);C-(P); D-(R)

(1) A-(Q); B-(S);C-(P); D-(R) (2) A-(S); B-(R);C-(Q); D-(P)

(2) A-(S); B-(Q);C-(P); D-(R) (3) A-(Q); B-(S);C-(R); D-(P)

(3) A-(Q); B-(P);C-(S); D-(R) (4) A-(R); B-(S);C-(Q); D-(P)

(4) A-(Q); B-(S);C-(R); D-(P) 12)

Which of the following statements are not correct
about electromagnetic radiation ?
09) Statement I Chemical properties of atoms are
controlled by the number of electrons in the valance i) Electromagnetic waves require medium to travel.
shell.
ii) Different electromagnetic radiations travel at same
Statement II – The number of proton is equal to speed in vaccum.
number of electron in an electrically neutral atom.
1) Statement 1 is true, statement 2 is true,statement
2 is correct explanation for statement 1
iii) The oscillating electric and magnetic fields produced
by oscillating charged particles Vare perpendicular to each Column I Column - II
other, but to the direction of propagation.
A p
Lymen series Visible region
iv) The oscillating electric field and magnetic field are A p
perpendicular to each other, and also to the direction of
propagation. V q
Humphery series Infrared region
B q
13)
C rUltraviolet
Statement I : Pashchan series
C r regeion
According to Bohr's model of an atom, qualitatively
D sFar infrared
the magnitude of velocity of electron increases with Balmer series
decrease in positive charges on the nucleus as there is
D s region
no strong hold on the electron by the nucleus.
Statement II :
According to Bohr's model of an atom, qualitatively
the magnitude of velocity of electron increases with 16) match the orbitals the number of nodes quantum
decreases in principal quantum number number present in them.

1) Statement 1 is true, statement 2 is true,statement

2 is correct explanation for statement 1 Column I Column - II
2) Statement 1 is true statement is true ,statement 2 is
Number of
NOT a correct explanation for statement 1 A p
2p orbital spherical
A p
3)Statement 1 is true,statement 2 is false nodes=0

4)Statement 1 is false statement 2 is false. V q

Number of nodal
3d orbital
B q plane = 0

14) Identify the correct statement. Orbital angular

C r
2s orbital momentum
1) Quantum number (n, l, m, s) are obtained arbitrarily
C r number = 0
2) All the quantum numbers (n, l, m, s) for any Azimuthal
s
pair of electrons in an atom can be identical under special D quantum number
4f orbital s
circumstance D =0

3) All the quantum numbers (n, l, m, s) may not be D

required to describe an electron of an atom completely
4) All the quantum numbers (n, l, m, s) are required to
(1)A-(P); B-(Q);C-(R); D-(R)
describe an electron of an atom completely
(2) A-(Q); B-(S);C-(P,T); D-(R)
(3) A-(R,T); B-(P);C-(Q.S); D-(Q)
(4) A-(P); B-(P);C-(R,S); D-(S)
15) match the series of hydrogen spectrum with their
charactereristics 17)
Statement I :
Hydrogen has one electron in its orbit but it produces
several spectral lines .
(1)A-(P); B-(S,T);C-(Q); D-(R)
Statement II ;
(2) A-(Q); B-(S);C-(P,T); D-(R)
There are many excited energy levels available.
(3) A-(R,T); B-(P);C-(Q.S); D-(Q)
(4) A-(P); B-(Q);C-(R); D-(S)
1) Statement 1 is true, statement 2 is true,statement a) An electron in an orbital of high angular
2 is correct explanation for statement 1
momentum stays away from the nucleus than an electron
2) Statement 1 is true statement is true ,statement 2 is in the orbital of lower angular momentum
NOT a correct explanation for statement 1
b) For a given value of the principal quantum number, the
3)Statement 1 is true,statement 2 is false size of the orbital is inversely proportional to the
azimuthal quantum number
4)Statement 1 is false statement 2 is false
c) According to wave mechanics, the ground
state angular momentum is equal to h/2π
18)
Assertion(A): d) The plot of ψ vs r for various azimuthal quantum
numbers, shows peak shifting towards higher r value.
The position of an electron can be determined exactly
with the help of an electron microscope. 21) Which of the following statements is false?

Reason(R): 1) Splitting of spectral lines in electrical field is called

Stark effect.
The product of uncertainty in the measurement of its
momentum and the uncertainty in the measurement 2) Frequency of emitted radiation from a black body goes
oftheposition \ cannot be less than-a finite limit . from a lower wavelength to higher wavelength as the
temperature increass
3) Photon has momentum as well as wavelength
4) Rydberg constant has unit of energy
1) both (A) and (R) are correct but (R) is not the correct
explanation of (A) 22)

2)(A) is correct but (R) is not correct Assertion(A):

3)(A) is not correct but (R) is correct The number of speherical nodes in 3p orbitals is one

4)Both (A) and (R) are correct and (R) is the correct Reason(R):
explanation of (A) Number of spherical nodes =1, for orbital = 1 .
19) 1) both (A) and (R) are correct but (R) is not the correct
Assertion(A): explanation of (A)

Black body is an ideal body that emits and absorbs 2)(A) is correct but (R) is not correct
radiations of all frequencies. 3)(A) is not correct but (R) is correct
Reason(R): 4)Both (A) and (R) are correct and (R) is the correct
The frequency of radiation emitted by a body goes explanation of (A)
from a lower frequency to higher frequency with an 23)
increase in temperature.
Assertion(A):
1) both (A) and (R) are correct but (R) is not the correct
explanation of (A) The absorption spectrum consists of some bright lines
separated by dark spaces
2)(A) is correct but (R) is not correct
Reason(R):
3)(A) is not correct but (R) is correct
Emission spectrum consists of dark lines
4)Both (A) and (R) are correct and (R) is the correct
explanation of (A) 1) both (A) and (R) are correct but (R) is not the correct
explanation of (A)
2)(A) is correct but (R) is not correct
20) Which of the following combination of statements
is true regarding the interpretation of the atomic 3)(A) is not correct but (R) is correct
orbitals?
4)Both (A) and (R) are correct and (R) is the correct
explanation of (A)
24) 1) both (A) and (R) are correct but (R) is not the correct
explanation of (A)
Assertion(A):
2)(A) is correct but (R) is not correct
The energy of an electron is largely determined by its
principal quantum number 3)(A) is not correct but (R) is correct
Reason(R): 4)Both (A) and (R) are correct and (R) is the correct
explanation of (A)
Principal quantum number is a mesure of the most
possible distance of finding the electron around 27)
nucleus
Assertion(A):
1) both (A) and (R) are correct but (R) is not the correct
Heisenberg uncertainity principle is not applicable for
explanation of (A)
a moving tennis ball
2)(A) is correct but (R) is not correct
Reason(R):
3)(A) is not correct but (R) is correct
Tennis ball in motion does not exibite wave nature
4)Both (A) and (R) are correct and (R) is the correct
1) both (A) and (R) are correct but (R) is not the correct
explanation of (A)
explanation of (A)
2)(A) is correct but (R) is not correct
25) match the following
3)(A) is not correct but (R) is correct
Column I Column - II 4)Both (A) and (R) are correct and (R) is the correct
explanation of (A)
A P 4s
N= 2 , l = 1
A 1
V Q 28)
N =4 , l =0 2p
B 2 Assertion(A):
C R When we give electron beam of 10.60 eV energy on
N=5 , l = 0 3d
C 3 hydrogen sample it will excite to first exicited state
D S Reason(R):
N=3,l=2 5t
D 4
The difference between n2 and n1 is 10.2005 eV only
1) both (A) and (R) are correct but (R) is not the correct
explanation of (A)
(1) A-(4); B-(2);C-(1); D-(3)
2)(A) is correct but (R) is not correct
(1) A-(2); B-(3);C-(4); D-(1)
3)(A) is not correct but (R) is correct
(1) A-(2); B-(1);C-(4); D-(3)
4)Both (A) and (R) are correct and (R) is the correct
(1) A-(3); B-(2);C-(1); D-(4) explanation of (A)

29)

26) Assertion(A):

Assertion(A): Bohrs model I not applicable for He atom

Probability of finding an electron is directly Reason(R):

proportional to wave function
Bohrs theory does not consider inter electronic
Reason(R): repultion

In bhor orbit revolving electron makes same number 1) both (A) and (R) are correct but (R) is not the correct
of waves . explanation of (A)
2)(A) is correct but (R) is not correct
3)(A) is not correct but (R) is correct 33)
4)Both (A) and (R) are correct and (R) is the correct Assertion(A):
explanation of (A)
Number of radial and angular node for 3p- orbital are
30) 1, 1 respectively
Assertion(A): Reason(R):
An orbital cannot have more than two elctrons. No of radial and angular node depends only on
principal quantum no .
Reason(R):
1) both (A) and (R) are correct but (R) is not the correct
The two elctrons with opposite spin in an orbital create
explanation of (A)
opposite magnetic field.
2)(A) is correct but (R) is not correct
1) both (A) and (R) are correct but (R) is not the correct
explanation of (A) 3)(A) is not correct but (R) is correct
2)(A) is correct but (R) is not correct 4)Both (A) and (R) are correct and (R) is the correct
explanation of (A)
3)(A) is not correct but (R) is correct
34)
4)Both (A) and (R) are correct and (R) is the correct
explanation of (A) Assertion(A):
31) P orbital has dumbbell shape
Assertion(A): Reason(R):
The configuration of B atom cannot be 1s2 2s3 Electrons present in p- orbital can have one of three
values for ‘m’ i.e 0 , +1 , -1 .
Reason(R):
1) both (A) and (R) are correct but (R) is not the correct
Hunds rule demands that the configuaration should
explanation of (A)
display maximum multiplicity .
2)(A) is correct but (R) is not correct
1) both (A) and (R) are correct but (R) is not the correct
explanation of (A) 3)(A) is not correct but (R) is correct
2)(A) is correct but (R) is not correct 4)Both (A) and (R) are correct and (R) is the correct
explanation of (A)
3)(A) is not correct but (R) is correct
35)
4)Both (A) and (R) are correct and (R) is the correct
explanation of (A) Assertion(A):
32) No two electrons in an atom can have the same values
of four quantum numbers
Assertion(A):
Reason(R):
In hydrogen energy 4s is more than 3d
No two electrons in an atom can be simultaneously in
Reason(R):
the same shell , same subshell , same orbitals and have
An orbital with lower value of (n+l) has smaller energy same spin .
than the orbital with higher value of (n+l) .
1) both (A) and (R) are correct but (R) is not the correct
1) both (A) and (R) are correct but (R) is not the correct explanation of (A)
explanation of (A)
2)(A) is correct but (R) is not correct
2)(A) is correct but (R) is not correct
3)(A) is not correct but (R) is correct
3)(A) is not correct but (R) is correct
4)Both (A) and (R) are correct and (R) is the correct
4)Both (A) and (R) are correct and (R) is the correct explanation of (A)
explanation of (A)
36) 39)
Assertion(A): Assertion(A):
2p orbitals do not have spherical nodes Bohr model is not suitable in case of multielectron
species
Reason(R):
Reason(R):
The number of sphericals nodes in p-orbitals I given
by (n-2) . It does not tells about elctron – electron interaction .
1) both (A) and (R) are correct but (R) is not the correct
explanation of (A)
1) both (A) and (R) are correct but (R) is not the correct
2)(A) is correct but (R) is not correct explanation of (A)
3)(A) is not correct but (R) is correct 2)(A) is correct but (R) is not correct
4)Both (A) and (R) are correct and (R) is the correct 3)(A) is not correct but (R) is correct
explanation of (A)
4)Both (A) and (R) are correct and (R) is the correct
37) explanation of (A)
Assertion(A): 40)
There are two spherical nodes in 3s – orbital . Assertion(A):
Reason(R): Mass numbers of most of the elements are fractional
There Is no angular node in 3s – orbital. Reason(R):
1) both (A) and (R) are correct but (R) is not the correct Mass numbers are obtained by comparing with the
explanation of (A) mass number of carbon taken as 12 .
2)(A) is correct but (R) is not correct 1) both (A) and (R) are correct but (R) is not the correct
explanation of (A)
3)(A) is not correct but (R) is correct
2)(A) is correct but (R) is not correct
4)Both (A) and (R) are correct and (R) is the correct
explanation of (A) 3)(A) is not correct but (R) is correct
38) 4)Both (A) and (R) are correct and (R) is the correct
explanation of (A)
Assertion(A):
41)
For hydrogen 2s & 2p have same energy .
Assertion(A):
Reason(R):
Total energy of electrons in hydrogen atom is negative
For an atom , for same principal quantum number s ,
p , d & f have same energy . Reason(R):
1) both (A) and (R) are correct but (R) is not the correct It I in bound state .
explanation of (A)
1) both (A) and (R) are correct but (R) is not the correct
2)(A) is correct but (R) is not correct explanation of (A)
3)(A) is not correct but (R) is correct 2)(A) is correct but (R) is not correct
4)Both (A) and (R) are correct and (R) is the correct 3)(A) is not correct but (R) is correct
explanation of (A)
4)Both (A) and (R) are correct and (R) is the correct
explanation of (A)
42) 45)
Assertion(A): Assertion(A):
Limiting line in the balmer series has wavelength o A special line will be seen for a 2px - 2py transiton .
364.7 cm
Reason(R):
Reason(R):
Only balmer lines are observed in the visible region
Limiting lineis obtained for a jump of elctron from
1) both (A) and (R) are correct but (R) is not the correct
n=∞ to n=2 for balmer series .
explanation of (A)
1) both (A) and (R) are correct but (R) is not the correct
2)(A) is correct but (R) is not correct
explanation of (A)
3)(A) is not correct but (R) is correct
2)(A) is correct but (R) is not correct
4)Both (A) and (R) are correct and (R) is the correct
3)(A) is not correct but (R) is correct
explanation of (A)
4)Both (A) and (R) are correct and (R) is the correct
explanation of (A)
46) Which of the following is the correct sequence in
43)
terms of increasing mass?
Assertion(A):
A) Proton, electron, alpha particle, hydrogen atom
In rutherfords gold foil experiment very few α –
B)Electron, proton, hydrogen atom, alpha particle
partical are deflected back
C)Hydrogen atom, proton, electron, alpha particle
Reason(R):
D)Alpha particle, proton, hydrogen atom, electron
Nucleus present inside the atom is heavy .
1) both (A) and (R) are correct but (R) is not the correct
explanation of (A) 47 )Which statement is not correct in case of isotopes
of chorine 17CL35 and 17CL37 ?
2)(A) is correct but (R) is not correct
1) Both have same atomic number
3)(A) is not correct but (R) is correct
2) Both have same number of electrons
4)Both (A) and (R) are correct and (R) is the correct
explanation of (A) 3) Both have same number of neutrons
44) 4) Both have same number of protons
Assertion(A):
In an atom , the velocity of elctron in the higher orbits 48)
keeps on decreasing .
Assertion(A):
Reason(R):
The position of an electron can be determined exactly
Velocity of electron is inversely proportional to radius with the help of an electron microscope.
of the orbit .
Reason(R):
1) both (A) and (R) are correct but (R) is not the correct
explanation of (A) The product of uncertainty in the measurement of its
momentum and the uncertainty in the measurement
2)(A) is correct but (R) is not correct
of the position cannot be less than a finite limit.
3)(A) is not correct but (R) is correct
1) both (A) and (R) are correct but (R) is not the correct
4)Both (A) and (R) are correct and (R) is the correct explanation of (A)
explanation of (A)
2)(A) is correct but (R) is not correct
3)(A) is not correct but (R) is correct
4)Both (A) and (R) are correct and (R) is the correct
explanation of (A)
49)
Assertion(A):
The position of an electron can be determined exactly ANSWER KEY 
with the help of an electron microscope
1) 4 2) 4 3) 4 4) 1 5) 2 6)2 7)3
Reason(R):
The product of uncertainty in the measurement of its 8) 1 9) 4 10) 1 11) 3 12) 3 13) 4 14)4
momentum and the uncertainty in the measurement
15) 3 16) 4 17) 1 18) 4 19) 2 20) 1 21) 2
of the position cannot be less than a finite limit.
22) 3 23) 4 24) 2 25) 3 26) 4 27) 3 28) 2
29)1 30)2 31)2 32)2 33)3 34)2 35)1
36)1 37)2 38)3 39)1 40)4 41)1 42)1
1) both (A) and (R) are correct but (R) is not the correct
explanation of (A) 43)2 44)3 45)4 46)2 47)3 48)4 49)4
2)(A) is correct but (R) is not correct 50)2
3)(A) is not correct but (R) is correct
4)Both (A) and (R) are correct and (R) is the correct
explanation of (A)

50)
Assertion(A):
Black body is an ideal body that emits and absorbs
radiations of all frequencies.
Reason(R):
The frequency of radiation emitted by a body goes
from a lower frequency to higher frequency with an
increase in temperature.
1) both (A) and (R) are correct but (R) is not the correct
explanation of (A)
2)(A) is correct but (R) is not correct
3)(A) is not correct but (R) is correct
4)Both (A) and (R) are correct and (R) is the correct
explanation of (A).