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Exercise C5 - Ans Scheme

The document contains 9 questions from past year exercises on acid-base titration calculations. Question 1 asks to classify species as acids or bases. Question 2 involves calculating the volume of NaOH needed to neutralize H2SO4. Question 3 involves calculating molarity and pH from a titration. Questions 4-6 involve calculating pH, pOH, and molarity from given information. Questions 7-9 involve additional titration calculations and determining molarity, pH, pOH, and volume needed.

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31 views4 pages

Exercise C5 - Ans Scheme

The document contains 9 questions from past year exercises on acid-base titration calculations. Question 1 asks to classify species as acids or bases. Question 2 involves calculating the volume of NaOH needed to neutralize H2SO4. Question 3 involves calculating molarity and pH from a titration. Questions 4-6 involve calculating pH, pOH, and molarity from given information. Questions 7-9 involve additional titration calculations and determining molarity, pH, pOH, and volume needed.

Uploaded by

knn233610437
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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EXERCISES CHAPTER 5 (PAST YEAR)

1. Classify each of the following species in aqueous solution as a Brønsted acid


or base:
i. HBr. Brønsted acid
ii.H3PO4. Brønsted acid
iii. Ca(OH)2 Brønsted base
(3 points)

2. How many mililiters(mL) of a 0.610 M NaOH solution are needed to


neutralize 20.0mL of a 0.245 M H2SO4?
H2SO4 + 2NaOH Na2SO4 + 2H2O
MA = 0.245 M MB = 0.610 M
VA = 20.0 mL Vb = ?

MAVA = 1
MBVB 2
(0.245)(20) = 1
(0.610) VB 2
VB = 16.066 mL
(4 points)

3. A 25.00 mL solution of sulfuric acid (H2SO4) is required to titrate with 42.25


mL of 0.015 M sodium hydroxide (NaOH).

i. What is the balanced equation for the reaction.

H2SO4 + 2NaOH Na2SO4 + 2H2O


(1 point)

ii. Calculate the molarity of H2SO4 used.

H2SO4 + 2NaOH Na2SO4 + 2H2O


MA = ? MB = 0.015 M
VA = 25.00 mL Vb = 42.25 mL

MAVA = 1
MBVB 2
(MA)(25) = 1
(0.015)(42.25) 2
VB = 0.013 M
(4 points)
iii. Determine the pH of NaOH before the neutralisation was performed.

pOH = - log [OH-]


= - log [0.015]
= 1.8

pH = 14 – 1.8
= 12.2
(3 points)

4. A sodium hydroxide (NaOH) solution has a concentration of 0.001 M, with 10.5%


dissociation. Determine the pH of this solution.

pOH = - log [OH-]


= - log [0.001]
= 13

pH = 14 – 3
= 11
(3 points)

5. Calculate the molar concentration of H+ if the solution has the pH value of 2.40.
pH = - log [H+]
2.40 = - log [H+]
[H+] = 3.98 x 10-3 M @ 0.004 M
(2 points)

6. In a titration experiment, 12.5 mL of 0.5 M H2SO4 neutralize 50.0 mL of NaOH.

i. Write a balanced equation for this reaction.


H2SO4 + 2NaOH Na2SO4 + 2H2O
ii. Determine the molarity of NaOH.
(4 points)
H2SO4 + 2NaOH Na2SO4 + 2H2O
MA = 0.5 M MB = ?
VA = 12.5 mL Vb = 50.0 mL

MAVA = 1
MBVB 2
(0.5)(12.5) = 1
(MB)(50.0) 2 MB = 0.25 M
7. Determine the pH and pOH value of the following solution:
i. 0.00125 M HCl.
pH = - log [H+]
= - log (0.00125)
= 2.9

pOH = 14 – 2.9
= 11.1
(2 points)

8. A 30.00 mL solution of nitric acid (HNO3) is required to titrate with 45.00 mL of


0.015 M sodium hydroxide (NaOH).

i. Calculate the molarity of HNO3 used.


HNO3 + NaOH NaNO3 + H2O

MA = ? MB = 0.015 M
VA = 30.0 mL Vb = 45.0 mL

MAVA = 1
MBVB 1
(MA)(30.0) = 1
(0.015)(45.0) 1
MB = 0.023 M
ii. Determine the pH of NaOH before the neutralisation was performed.

pOH = - log [OH-]


= - log [0.023]
= 1.6

pH = 14 – 1.6
= 12.4
(4 points)
9. A student prepared 500 cm3 of a standard KOH solution by dissolving 1.5 g of
the base in a distilled water. 25 cm3 of the KOH solution prepared above is
titrated with 0.1 M H2SO4.

i. What is the balanced equation of the reaction

H2SO4 + 2KOH K2SO4 + 2H2O

ii. Calculate the volume of acid required to neutralized KOH solution.


H2SO4 + 2KOH K2SO4 + 2H2O

MA = 0.1 MB = ? 0.054M
VA = ? Vb = 25 cm3

1.5
Moles KOH =
39+16+1

= 0.0268 mol

0.0268
M KOH =
0.5

= 0.054 M

MAVA = 1
MBVB 2
(0.1)( VA) = 1
(0.054)(25) 2
MB = 6.75 cm3
(5 points)

• Buat exercises dan past year.

* Buat exercises dan past year.

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