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5 F 84 B 0 F 3005 A 620201012193931 Kinetics

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sanjay s
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31 views3 pages

5 F 84 B 0 F 3005 A 620201012193931 Kinetics

Uploaded by

sanjay s
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
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Kineiits 9 _vomplr 2actions.- The atu chematal indi dbusome righty compuicatid due to the occurence of Lempuix suactions whith sruoives moxe than ens sep, Impostront among Auth wracking ane the following = 1) && Opporing or Ruvesble Reactions a> Conecubve +e Gtons BD thorn seodiom @ Kusehea Of Spposi oy Revesyib Reoutioms:- The ener Of bud peachonr ae usr AGHA wn the Mmitiat stoge of poet shen the produc ate doo Low oa cencthtraHon +o set up the opposing neation at a netiadble nate, However, when the ite weotion abo tok ab O cemporsble yale, the becomes complicated and the rak eonstant ebtomed wy not quite welwable. Qdorsider the cre seattion tn urhech the poread OL well Os te suveaL suaskon aus hoth who k, and ky orm nat eomrant of the poruearc ond sroverse reactions, sunpectieliy dat @ be the inthot Lencentrahion of the reacrort A, ts omumed thar areola the concentation of B=-0) Then , ajer ume, t, the coneentration 65 *& ui be. (a-%) Sand that 6h the puoduc @ ull be 2. The yale of dorusand wadion wk equat to k, (as while that ©} the wea weveut meation ig k-i2. pa met sot of the 4ocmasion of B a queen o dx = kla-0- kyx —O ot I} Xe OB dhe concentrahion ef B ot equilib iohenvthe mit s0te 1 “ZeLO, then, k, La-xXe) — Ri%e = O Mca em or ky = kh, G-%)/%e — © Auoatitusing jor k-) *y equation (0) wh have de = b,(a-%) - k, (O=%e) at Ne awa k, (Xe) a — ak He @ Seperakng 4Re vacables, we have duet = GD pat 6 He-% Ke Tite grating, we get i Oe ett) a8 ure I & the contronr ef wtlegration or Xe in(%-O =kt+~ — @D oOo At 42-0, x=0.40 thar ae a faye, ee (at +20, x20, ro that) a for lL +n eq. @ —%e, Din (te) ] = hit ~ ke pn xe, a oO Oy. iRiter=ne Aen 75) ie - In eq-@) gee ki sn terms of eal menuurable quantsies fom eq. 42% 3) | we hove Cit R= kaos + 4/ Bo =o) he = Thus , pom Oo knouuedge et ky), and xe, the sate conuraut k, 4 the move 2actHor) can be cateutated. Now Auppose that init oli & small amount of B, 604 b motes, & putent ien, the not rote of fecmotion of B, ay b motes, tr patent then gure oY ax = k, (A-x) — ky lb = a ¢ (bad —O Sina at equilibuiuro ae =0 , henw _

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