Chem Notes v2
Chem Notes v2
Acids vs bases:
Strong acids/bases: These ionize completely meaning there is nothing of the original
acid/base left.
weak acids/bases: These react reversibly so they don’t ionize completely. This means they
have a mix of the original acid/base and the ions.
Acids: hydrochloric acid, vinegar, battery acid, acid rain , lemon juice
Bases: sodium hydroxide, bleach, ammonia
Neutral : water, salty solution, sugary solution
Acids are sour, their PH is lesser then 7 (<7), turn litmus red.
Bases are bitter-their PH is greater than 7 (>7), turn litmus blue.
PH indicator is a chemical that turns different colors into different mediums.
Blue litmus turns red in acidic medium and red litmus turns blue in bases medium
Litmus solution/paper is commonly used as indicator of PH.
PH paper is a strip of paper which is coated with PH Indicator that change color in response
to the acidity or alkalinity of a solution.
Strong acid/base: Ions fully dissociate. pH either very low or very high
Weak acid/base: Ions partially dissociate, in a reversible reaction. pH on either side of 7, but
not too extreme.
Strong Weak
PH End of spectrum Towards middle of spectrum
Electrical conductivity high Low
Rate reaction high low
Simple definitions
Reactions Of Acids
Neutralization reactions
In neutralization reactions an acid and a base react together to form a salt and water. This
neutralization always occurs when the pH of the solution is 7.
The reaction is always exothermic and thus the enthalpy change (ΔH) is negative.
Paper chromatography:
Used to separate dyes in a mixture.
Definition: Chromatography is a separation technique used to separate the components of a
mixture based on their physical and chemical properties. There are several types of
chromatography, but the basic steps are similar.
Materials:
Method:
Chemicals switch between both phases-more soluble = more time in mobile phase, less
soluble = more time in stationary phase.
To measure how far each substance moves (identify): find Rf value: distance travelled by
substance/distance travelled by solvent.
Filtration:
PH Scale:
PH vs strength vs solution
People often get confused about whether pH, is to do with an acids strength or it’s
concentration and the answer is it’s both. This is because they the hydrogen ion concentration
depends on both the overall concentration and the strength of the acid/base. However strong
acids ionize more than weak acids and so they will have more hydrogen ions.
Strong acid: 0-3
Weak acid: 4-6
Neutral: 7
Weak base: 8-10
Strong base: 11-14
Acid deposition
Why is rain acidic: Acid rain contains dissolved CO2 which lowers its pH to around 5.6. CO2
(g) + H2O (l) ⇌ H2CO3 (aq) Forms hydrogen carbonate. This process above is NATURAL,
this is NOT considered "acid rain". Acid rain comes from oxides of 2 main elements: Sulfur
and Nitrogen.
Sulfuric/sulfurous acid
When fossil fuels like coal or oil are burned, sulfur can change into gases. These gases mix
with water in the air and turn into acids, like sulfuric acid or sulfurous acid. These acids are
formed when sulfur from decayed dinosaurs and plants, which is found in substances like
amino acids such as cysteine, is burned.
1. S (s) + 3O2 (g) → 2SO3 (g)
2. SO3 (g) + H2O (l) → H2SO4 (aq)
3. H2SO4 (aq) → H+ (aq) + HSO4-(aq)
4. S (s) + O2 (g) → SO2 (g)
5. SO2 (g) + H2O (l) → H2SO3 (aq)
6. H2SO3 (aq) ⇌ H+ (aq) + HSO2 - (aq)
Nitric/nitrous acid:
Nitrogen can be turned into gaseous oxides in the heat of combustion engines. Usually
nitrogen gas and oxygen gas will not react, but at high temperatures (ex. in an engine), they
have enough energy to overcome the Activation Energy. This then reacts with water to form
nitric acid (strong) and nitrous acid (weak).
Formation:
N2 (g) + 2O2 (g) → 2NO2 (g)
2NO2 (g) + H2O (l) → HNO3 (aq) + HNO2 (aq)
HNO3 (aq) → H+ (aq) + NO3- (aq)
Zinc is quite a reactive metal so is oxidised easily when it reacts with an acid:
Zn + 2HCl ---> ZnCl2 + H2 (+2)
Copper is very unreactive so rarely undergoes oxidation:
Cu + 2HCl ---> No reaction
Different metals have different levels of reactivity as shown in the "Reactivity Series".
Redox reactions:
A redox (short for reduction-oxidation) reaction is a type of chemical reaction where there is
a transfer of electrons between reactants. In these reactions, one substance loses electrons
(oxidation) while another gains electrons (reduction).
Eg. Iron and oxygen:
4Fe + 3O2 → 2Fe2O3
Relation between hydrogen and chlorine:
H2 + Cl2 → 2HCL
Zinc and HCL:
Zn + 2HCL → ZnCl2 + H2
A reversible reaction is a chemical process in which reactants can transform into products,
and products can, in turn, convert back into reactants. The reaction can proceed in both
directions, and the system reaches a state of equilibrium when the rates of the forward and
reverse reactions are equal.
1. Dissociation of acetic acid:
CH3COOH ⇌ CH3COOH- + H+
2. Formation of Ammonia Chloride:
2H2 + O2 ⇌ 2H2O
Electrolysis:
Element: Substance that CANNOT be broken down into simpler substances. Only one type of
atom.
Compound: Can be chemically separated. Can’t separate physically. Substance that is made
from two or more DIFFERENT simpler substances and CAN be broken down into those
simpler substances. Not to be confused with a molecule which is formed when two or more
atoms are joined together chemically. Compounds have two or more DIFFERENT substances
joined together chemically.
Mixture: Two or more substances, can be separable physically. Mixtures are substances that
are a mixture of separate individual substances. They don’t always have the same
composition as they tend to retain some of the properties of their individual substances.
Homogenous: Substances are so evenly distributed that it is difficult to distinguish one
substance in the mixture from another. It usually appears to contain only one type of
substance. It is usually harder to separate its components. Examples are yogurt, vinegar,
lemonade, coffee, and honey.
Heterogeneous: Substances with parts of the mixture are noticeably different from one
another. It is usually much simpler to separate its components. Ex: Trail mix, Sand, Salad
Examples:
Atoms: Hydrogen (H), Lithium (Li), Beryllium (Be), Sodium (Na), Magnesium (Mg),
Potassium
(K), Calcium (Ca), Titanium (Ti), Carbon (C), Oxygen (O), Helium (H)
Elements: H 2 0, Boron, carbon, oxygen, iodine, argon, calcium, gold, silver, copper, zinc.
Compounds:
Pure substances: A pure substance is made of only one kind of matter and has definite
properties.
Some pure substances, called elements, cannot be broken down into other substances by
physical or chemical means.
A compound is a substance made of two or more elements that are chemically combined.
Atoms: Building Blocks of Matter
All matter with the same atoms
Water is not an element, It’s a mixture, In fact it’s a compound.
Compound: A compound is two or more elements linked togetherchemically in fixed
proportions.
Magnetisation:
iron fillings and sulfur-use magnet to attract iron fillings-sulfur not attracted.
Physical separation tehcniques:
1. By eye
a. to separate solid and liquid
b. to separate two or more liquids with different boiling points
c. to separate gases with different condensation temperatures
d. to separate pure liquids or solutions of compounds
Crude oil:
What is it?
1. IS A FOSSIL FUEL DERIVED FROM AN ANCIENT BIOMASS FOUND IN
ROCKS
2. IS A MIXTURE
3. CONTAINS A VERY LARGE NUMBER OF COMPOUNDS
4. CONTAINS MAINLY HYDROCARBONS
5. ALSO CONTAINS SULPHUR + SULPHUR COMPOUNDS
6. IS A DARK COLOURED VISCOUS LIQUID
Formation of crude oil:
FORMED FROM ORGANISMS WHICH LIVED MILLIONS OF YEARS AGO. THEIR
REMAINS WERE COVERED BY LAYERS OF SEDIMENTARY ROCK, HEAT AND
PRESSURE IN THE ABSENCE OF AIR CONVERTED THE REMAINS INTO FOSSIL
FUELS.
GAS AND OIL ARE TRAPPED UNDERGROUND - THEY CAN’T GET THROUGH THE
NON-POROUS LAYERS
10.
How do the fractions differ (IMPORTANT):
1. As we move up the distillation tower, MOLECULES HAVE FEWER CARBON
ATOMS
2. As we move up the distillation tower, MOLECULES ARE SMALLER
3. As we move up the distillation tower, MOLECULES HAVE LOWER BOILING
POINTS
4. As we move up the distillation tower, MOLECULES ARE MORE VOLATILE
(lower Boling points)
5. As we move up the distillation tower, MOLECULES ARE LESS VISCOUS
(VISCOUS = not very runny (a bit like syrup)
6. As we move up the distillation tower, MOLECULES IGNITE MORE EASILY
7. As we move up the distillation tower,MOLECULES REQUIRE LESS OXYGEN
TO BURN PROPERLY (The more carbon atoms there are the more oxygen you
need)
What happens to the fractions after the process:
FRACTIONS ARE STILL MIXTURES
DIFFERENT FRACTIONS ARE PUT TO DIFFERENT USES
FRACTIONS CAN BE DISTILLED FURTHER
SOME FRACTIONS ARE MORE VALUABLE THAN OTHERS
THE HEAVIER FRACTIONS ARE LESS VALUABLE
LARGER MOLECULES CAN BE BROKEN DOWN TO SMALLER ONES - THIS IS
KNOWN AS CRACKING
Cracking:
Reason:
LARGER HYDROCARBON MOLECULES ARE LESS USEFUL
THEY CAN BE BROKEN DOWN INTO SMALLER MOLECULES
SMALLER MOLECULES ARE MORE USEFUL
What happens in it:
LARGE HYDROCARBONS ARE VAPORISED (TURNED INTO GAS)
THE VAPOURS ARE PASSED OVER A HOT CATALYST
BONDS ARE BROKEN AND SMALLER MOLECULES ARE MADE
THERMAL DECOMPOSITION (BREAKING UP BY HEATING) TAKES PLACE
CATALYSTS HELP SPEED UP REACTIONS
What happens:
MANY DIFFERENT HYDROCARBONS ARE PRODUCED BECAUSE THE
MOLECULES CAN BREAK DOWN IN DIFFERENT WAYS.