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Thermodynamics Full Notes - Kiran Dev

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156 views125 pages

Thermodynamics Full Notes - Kiran Dev

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Neeraj
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- i... a “ea y stern - 7 Surroundings , Cesc Mi, om ileted Syphon o_o ; open systenn . anal System - v Diff. Proce ss - shady wendy Laws of Thermodynamics . i =e hg eee : Thermpdynémics —» Pech sith chely Feat smohor tranler: — decent Contidey Hime « Ment prolidn- | tyreasfer - »> Basic fe Syttens - A porta space which ot shady egcrern Fetal ‘i Onside systonn — Surroundings Syston + Suyvoundanps —» Univerte - ° Different types syctom- Systems “ cer _. 0 Closed system (wopen _sychems (wy dat No mam dtranstey. Mass dranshe ant Head tyansbey- ag Heat teoma{ev Work 4 mmper > ARE ere 4 Maveronté p> cope: o - ° ee Volume ap Bul Coafidey. ti 0 ates thermod “track i. ® Cnssical theymody feawuc, > a = —> hype fy a ee boundary (lente boand ) Peay bietteens tetany 2 System —_, minimum one bound, fesable . Bee ~ EE Clos eat any should be moving preperhés ohh > Trermedenante Properhes Chit, v er) — dhovredenshe ean co Extensive > ror a rth Depart endiet & on aoe F530 mass > Fag $ ig the eae eq: Vdume, fneray Fone = of: Pasta, , Mars lent if Viscosity @ Sichia ts net Possible / present > Thermodynamic Cite - +3 A system fs sad to be Under , ' Thermedynemie cycle ty ihe i P and juin) siete ave me: (> henge Thevmody navn le bec wevemedyaarnic Cau briunn, The body should Juve no mass tvansfey, heat trans and weak tvansfey: Thema dyprarate valibrtiine Theveral Catlin — Me daanteal Cqpblome No heat trans ber a Me he work trunsloy in Aone on the syckeos oy 5 hea ‘t — Heoct Hransb ered fom sytem, 27 ‘ Meat tvansfevved Aine systen —> ve ) > closed system > > Area undew PM ocean aan tee (Enerq 4 ‘iinhachby ) f wnekdone : v— ct Head transfer bier 5 Apert - a 2ao4\21 , 7 > Thermal vnnl_ quan When a beches in he Bis cotectt a pv= nRT by R=T > urwvemal sou Comt 5 2314 FInd, R—> tharredoashe ye enat cE bl massc Cre rane iP > Coustont Volum Volume tern sxchew io rh Dr aD he Re b> Tov clednd Rekclonu thermometer «| ay > Hos te menire Laaportint , ea sas gis thaw assy f ealekapie 2 po tbar Ibar Senet Pease TS nee at Tewporulne j 20bar, o> % , aor ge use velahan ho 20 baw prerere Vbay =, trot Lec a6 bev me aQox too} 304) 21 > Gus Thermomete mab uy > oy Lorstan} volume type pvameT Comat premuere hype arc AV: hue =(V)4 O Ran ib od A (ae chenates a" TO ae wite porte e inorenies toe incyease AN pressure @ But Rignt hab ty lel shod amaunted Wur ‘the help 4 {toxivle hibe = Clechical Rerwlente thermameler . Ve jn = height A ssie | teem p = Resslme ak Oe 4 = bempernhwe 4 ae wheabsbone budge yap 2. J = Thermocouple - = WOU ancl ken Enoryy, pels 5 Heat 4 temp change « Werk tvuntfer - Work a sid to be done, by « Stowe Sle qed on thangs entered te the sy Can be rcduced to the aaising | : Werle done by the Sashes 4 ae oe mh | pu Medes ae | 4 Sa Norkdone = Forex dspace wont wae For sent A Ee 2 yaa ae tte = Fxal pr >P2 Os, vic Vo. Vite F= PA P- premure- inside the caplinder at that wheat a ona Uh Cross felon 4 pater - s.dwe Pa-dl On bes FE ne = feaal = fray a % ‘the Loren ender the curve We fs>4 : Constant -bemapantere poe ry va Cotten &p~) eo | Jont oe a ® Pybap proces We PM — Poo : N-1 6 Adinbeces, trocim W = Pim —P2V2 Ostnt Promre ee Poet a bi sPVe fo PL > Piva = P2No ari Te Ti ow i T= Tp = bul cect t Chaves Ma =V2 ~- Pav, = PaVo nv Te Go Moke: # pybope pocen 7 hn PY=c RR PU=CQ oy t= n -nt _-n+i a 2 [cv CVE oy Te Ae “as sepa n 7 a ( Pea ze — Avie i a =1 [ avy -hw) i-n a ys | ONE " cil ‘i 2 n— ny rena) eS “A Cav — Avs | a 2 (-1) oJ : oink funchen 8 Path, bunctisn Pronk fenchon & © Fanchina shack, ase only Leperdedk on thateriepaaty i io Thevrmedynavr ches eo” aa pee es act & pth 2 m7 8 Ey °5: fayen eee eV (haya J Tov opdin proces > pers hange tt 2070 ‘4 (Sats imbal g fa) paint ae Sa jd 1-B-2 = I-ce-2 A — ) \ ’ . Week done ding prrcent 1-2 Phew the prthy me arferer- / 4 k a a . cy Sau =W ? 1 1 wD — JA Jn ercact Afferenttal SS Heat Transfer (Q) > Hest tramalor ba eneing 1 4 eystorn by Virtue 4 ae fi form Bik Leper Ln > Hed tanfer 5 path funckten > Snook Sferontl Lo Saline ick: “3 ip Sapte ahessoe 6 Ho Derren ei a ete oe Beds tele % Zo Hullo a a Q. A pe: hades spevels “baty — ts Cf Wwele e k Pee. erence es anh e Beck pocee ‘- at 0, abe Bante Aewele ‘1 tated ak duaknh prone volt Cones tach to Me 4 al pale Fe pola vaabletd, Baad ty zestorr UL to Me Sucte! cad a Me sae % aaa ce? ~ 3 pea fi ees ae: : $e ab Nams s we = ody rs a yo > ae Behn: ary L ; aaa i a poi as Mpa = loiaas pa. N = 10600 Tas Ne Hanah = 66>: D= Dbm-> Yo Forde Gantmlead 4 fet |) aw =7 $4425 oitis ome Jo eel {rete > Mechendued pay th T= on > Sa 7 Taw f Therwnedymaiies Va enter te, FZ 4“: » . om e Coated FBP te~ Pelee ee sythone || a me io The nit deat Gwhent 4 a apclom MULT PV. 5 Crlengeel wat — - , ST oid > Toles. a Ag | at ‘ey } Te Me abe 1 = J ebadaape : wt FE i pia A pen © kothuema process Gr big dq=du +4u: ee precens dg=dautdwe. ee aa en lea as “= sy es ae | fat ay! vy~Aavi| as partle)| — f {, v a Autdw deg = dat fue peo me + Paver Prva as aydu a ~e)> ee moat), p= Cy C#-1) = Tiles Siren Enya, al dong sot at sp es 1 1 eae (s = Pk th onl a Pee eo nae : ct ae ty L |= tie on obs 2(e- 2) Rete soi P OM ee 2. uz ei [nw Fe phi Tete ' opel we Kage Boo perpechus made iene: ao rendre which 9 Bie by real hhuche, ae "0 sud von ching + \ =) Aplin Fk Jab 4 "ARetmaedl - tates” to pce proces Copen ays [2 ' mathe me (Grex) The she al’ which Ho 120) Lavintalinaie ree TYPE | bow ait ~~ * 5) ae : Pthe prpethes wll” hand Jaded” valor ab pactealas x © Ord val nck aller oth me: ty SS baw dh Marmodunanis 3 E oa on “Hoowak ie vat ar = - ell fw wth pro -po a i = fan ght) C4 (eo vale lela) qehudkcal ae opr g 3 2 a fie a 443 aaa ee 4 +4 = po ae Q= ™ 1000 | WG-2) 3 4 1800 ae BRIE +3909 4-8) 4 3 wl 1 t 1o©0 eer Tuchas— - 130: 63592" 7 wide He volt. ie, re Sea U+EPV F i 2 GDH) — Gaited) = 180" om «has =i, + Pv — peV2 = leo- (oa BSG 2K ca My Up. = 18063592 —P\vy “+ Poll i hve ri - aha 180 68592 — Coa xe / _ (ook ms) Wot = 20- 63592 + “Kilks hae FFs ay trina (hy EY HE i: Book pect Wi = or! 0 inn = Th, jy =2Anastyy te Maw You wl UJsec) = and Gal 005 by) ~The ante ema = ip nae aie a Maan poets ear, 4 Eanes Hh: Gren .. . : wis fos rat, m= Sky/s > Aq 1 = Vy = Some. , ohoak I hie 900 kiifiee Ln: pl ale ae C2= Vg =Ast} wo , p=. O85 hg = Hoo tly a PT = Ioe a Bass a sl die 3 a aa “ 2385 lyfe 7 me rsa . ae . the Ba Ss oe. | 5 ec e alter ae i es he | et ‘s il Ae SASH 3h Vet f Be Pa. 15. athe nly dea ’ Mary ie sae glen, Calg (| Brgy along = gg ef En = rer + Ue PW aad fray 4 She Rcd - dernd enugy CE FE 2 ut pp epee uate gz : Pay Pos Sanrgy {the baa + San End = + U9, Pe Vo. dite Wer + Wy Pik ! VP irae eam 1 (ut cy 32) + us Pitt de = wv ui Whe “ qj oe hock te ere red Gpek = tas) COP = ort « sth & J = QQ Or —— a $ PSran dlid law {th exon 2 Gero Jaco ms ia foal Ta ene 88 * py SEES 5 SR Stig 2 | C z = ts a= oe = an ‘ v r Qh rh sevoriible fai ie operae Seb. — . Baro rents - A wt TK Avaws 1200 KW Somme xt 4oocg in a ak Arawgs 3 for fours ab toe «th bh tha, of chine ; wher Fapeh a speck. hed fo a thom gent 2e¢ D Dolermune dhe oo Ww whith one Adives move ae on aa Baroy cieccom — cella . te = th Y= Daa oo ae At i Fle, By nl es A st FC ‘ Ee | at (a a= ete, OD. bah nt Ne ie P ; sevembl We vw 4 Hamed santa , & Tha, tel effO=T,, eo pnp & i oe 2 Tangy FEL = Da +5. am when “PLS 7S eee 2s che etlic| ellie oe fe 3% Aged Lgeeger: within « mp | The ambient, ain 4 a Boc - &4 dock Text fal hh. Jal al a Conlmoes wale 2 Belt oh Q Cntinéo bi Co oe : ‘ag a & SS Qge- 243 Gp = as 42 s & oe Cop = = 19°40 aca Co na wach. 4 atte oss ‘ae . CR corn = Hie oy 7 CT rest be ; the® “mnventon die 6 BSA had copie oe ie 4 “Ge bode ond ub O° Aenenae Stag a “Is - Have} 3 ” wed n ' poet = otsk Ta 4oe = 313K |- phil = ease = the ia, - ei ge Box 4-bal Q= te es Pees, fw = 2Sp0 — Ltd : Oe \@6o ky . Net head Avera fey \ “ed te racer = Rat Ro = £30. 336 +1860 = 2455p “336k7 —- qs ding rain ( Teraporahere - Enboopy “ A s ( 7 \ : Af Lys Sr r Gtayy om a - 35h jan ved Weal We discal ale 2 bat v. : ) Revertible co —3) Both sgslen a Soran | the etgenal bE, wothout ae chants on Ahe’ | universe - Revewuble process An carkied, oak dapentt me wgltgie gredfent 0 that ek ey XK a an Reversible Pere ee ze oa Guses 4 Serrevernbit ty © est transfer hoof Ket: @ “thermal equilebaren does v5 oy Distme 2 dala, (aew) eee arta abe => Draw en uctheym AL >) pr ot = Aeca z al Fw Aven ~viside cyele > Weel Weel ercdunna dur coy A brteseceh wi a a ie Ah Wietcts. f tod Lew Het Reverable elles luis newor oY 4 Geng = pepoty ¢ a . AQ, ices Sag = fra oe | > Foc sey adiskedte pres hs =oCF 4g = Agpev . ¢. As 20” “ce Lentil - | donde ean” oaga under 127 opal to awa onder a = cl seein Ta + CoM) Br pm ; f ea a i rere Che a rr, zi Fick» same C aie ane’ ny “path Conssl i Aev-adsebcl, , or or. ae adishdic., tech Fhe Meak Toner human Stone - A seth cleed courre dived. sok a hap by. mazes |b ro h Tep # beowe of cade ahscp a albeccd by sever Jon theme ° Thy a Tel 43 4 «~ i ee a a. ga rrees on ic = is + nS cenenbion sh | yee 1 ds = 4a. op ke An iss lied system * dowsnct see ade | 4 = da=o als 20 ye Fora ze yer pres , As Added = 0” 3 = constant pd br om taseveralee pros a: >6 a Thes enloopy an. water system cane derstare “ak ail ‘ ae e cle Ean pra Consider onvene 25 an vole dsyat cS [ig I! e a - = P ™ es |* meee cde Gh. ‘s fie 4% |: ac ee j 5 7 i : 2 ea Nec by lt fod Bell goo ly al ©. woek thlaineble ee too oe Vine at ne , i a Po nosh (2) alnts ly x th (22) = IG1sqxo- 1312) = 1°306F Hi/k. = O56, +45, =-l- ee 1-3064 AS = oiethoks |p Oreyae (ee ] 27h 37, Q i> 303k >Ta = MCAT, = 1x 157-( 323-29) tel wBkaT Sree gS ky @ = R@- & =@ 419-4 207-85. - Qy = 210-85 kf = &(1-h) Ti Ta = 2to "Sf (373-349 378X329 Sunivene Pi = o-s Mpa = 0-5 R10" pa - WY =-60-2m4 V2 = posm?-: i We e IAAT) S 7 pv = wash - Fa reversible Adusbohe. y > ds=o° ag=o | » Bo = Yet a8 » Ais o=-W+d4U . * {jis CaAUe ( We PV) —P2¥2 n-| pv! 7 = coast ; F (2 she pve’ 2 ey PV pz Rife +200 Ga) -_ a X lo = 1a ky ——- H= U+ pv =dU + apy 44 = 111400 + DeExtO x 0°2 AW-= 241400 J pale at 243 kL bronghl ude & with “A Meal rciervor ak 313 e- elie, adied gazk , fod otiayal durge 4 water, Lhe ven ¥ & 213K e Uniivege , Cs valor a deded ae x aia Aarved ak 920k, hal dl be onbapy @ Work ll be marimum the Leoel- pesedle Lemp erchere. Pe epue 1a 4 s 3 $ pli we ea TH Aw R es ial el i : nRT T oer = ae = P3ag ne wader PMs ™ = M Msi y ) PV= met! = WMeT Pv - ie | a s Wak 4 MS oe ¢ G Qa = = Bde be Pi ds = Cy dn zs +R tne Ass mis, + ™m255 ; x Meal 4s Arsumnpliod Foon . © bs parbile Mave “ad Velie. © bus polka ace eqnally aed and denst y ine ‘ eaulan fores § (dtachsn x a OD tne peskie Ue aneve Keane 4 agnement tadlen's Law Jd melien « ® One pectele me. Panes clans Colleibas wile Ler - - oy prety fee a Cashak | premure pouw => ue 7 |we [w= pO) , dat dw ee “v1 rs F ake 4, hate ' eS. ; quabens Jd states are ed to. behave fh xeal gases - W Vanderiwaal 's fucken UI > Bethlet equal ten + Gy Redifch's equation ™ Vatal Pepention equclion, i, er ire us gqualina j Pre Ale uk aa op red on Vanclr, Hh (wy Basle § fahen a (P+ #2) (v=RT (Ww Redalch's cou cao a Faw 2) 7 RK. Rew Virial 06m Onree Chawnetlig Onnes Piet ved . Shek ties Seu in a Zi alkd w Gonprens ble de ha (2) ae Ahead A OAS, fs elgg ideal Ge Jew te account fet i, zeal ae : ° ac Subst ib Ac Ay ferent ¥ Reduted Preperty ; b—> OL The Speajre va Co al wee a Nom 4] : ae rh a ® vse Vader oes ae & delemune remorse excited by Con @® Cro perve Ahe saulb ba dread Gn & Med ges bee valic 4, a = 365-£kN oy ol)” a We valu fb = 08428 * Pry = Povo n-! pM = met Vi= wb = xe 2FI4 x 350 hi ex ios Mate 12 Si 3 Pav, EMT, b Mass Peachen (reg; Be 1. os “ert wy Ag ge SE ey g LS JP if ay eke Bacher (xi) L = ony { Ahk Ssbetrnto 2x st-\ mSles ss a a cer : i 4 - mmr t MM, + MMs al gi kl | Se, @i-%)=" cy eben N Quin a=" cuba = BR Se Ms M1 4+ M> + Ng Mst he My Ny Fw5 $03 Ne = @ Stuy + (Ks + 2 Tig Be oe PE Sree +29 GS >) ee = 5-41.29 + 22-9¢ +0 5h t SWS) 25°68 — Poy - K = S23 wo We Mynd 2 SS TaBe = 227k Mm = 6 ole ole. Be 314 Sy p fy = net, W= o-sx 883i ¥(8 323) 1S Ke" Y= 0-995 wi? sie N= yt Mot Nz Pie 4 Ne eo rer - by E Pa 4 PV2 4 pe = a a | oa e ee Lyn vs ri / 5 a he Halal vA ate kot nal fo Be Sum ae it yaa t bf SF vehore Sp. Se, 1 Sp = | s 7 p Aisi V2 : 4», Gibbe—DaLlon Dalbon's Luo end Cibbi thuseme | and goctend to Cover the obfee propels ‘ talled Cibhs—pabbas how .. ” clades NRE” vasnlan yee deal gases tse seeped equal + | et Irtunel, enegd , erbubfir e td Gp : A Wain qual te ahet ae oi Geis ga h- Ts cqectie 4 = dh — Tas — sa —@ - @& hautpy Ah= du + Pav tap ° ae =du+ dw dig = du+ pay ah = da+Vdz {ond dg =Tas Biend*= Tas + Vd p —@ Ag = TAs +Vdp_ tas — sd [45 = vdp ~ att © : dt —€ . 4 Gy" Ge t ee tpv dn = da +p dv — VAP Ag —dataw 4Ae = dat ply — Tae 7 dz = Md + dg —@) 5 - Copper orO Neg by Tn beh aes ' Tde = was) 47 b 1(25) i ey ao o AT + "Ge [t= = .. +/ (Sp) a _ (or li Ae 5 1 Gy a py To wh ode TA = 1s) aT + TBs) dy ¢ dee a fC4 0) : da-(ée) dy + ber de= (4) dr + Bx) dv Ben (34), =. da = cyat 4 (Bt) dv Oe Gade s= flr o4- Oar Ge dy = Tas - pav = 7%) 5 \ AT +T Be dy a a 7) att dv ( 1), 9 er | eis E/fe3) a a=) +5). = Cy dr (€) ) dv [a= Such Bs) oe 7 5 Sm hs vars $i, avo gen +f [es wird = ” an ne — ye “a se ¢(mP &- (bi) 47 + GS h 2u +P Vv dh= dat pel % 1p AQ = dad Age duty tds = du + pv dh, - 148+ vay dhe Tf - Gl Gata We Bae fet val f 4 ghee sete | By), } WF af co a) .... 4 - i“ bo A i c ayy [evate. in & soak AST “b ad. ol gee G- Cy 4 S=f( rw) dos a (®) a ee Gi dy i : pare fa eh yaa ti = bos lpn Vi = 1bmfe — Mek 135 bye zef Q=~ Ny ~ hy + ae * set 4 @ bs Gtiga CtPi vy + ee +92) +@ = ‘i 2am [evo ews 4 2

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