1.Which one of the following molecules will form a 10.

One of the four molecules that require the

linear polymeric structure due to hydrogen highest bond energy is
bonding? A) Nitrogen
(a) HCl B) Oxygen
(b) HF C) carbon monoxide
(c) H2O D) Hydrogen
(d) NH3 11.The energy of radiation emitted when an
2.Maximum bond angle is present in case of electron falls from n = 3 to n = 2 level in a hydrogen
(a) BBr3 atom will be: (RH = 2.18 x 10–18 J atom–1)
(b) BCl3 (a)0.3 x 10–18 J atom–1
(c) BF3 (b)3 x 10–18 J atom–1
(d) Same in all (c)0.03 x10–18 J atom–1
3.Which of the following pairs of molecules will (d)3 x 10–17 J atom–1
have permanent dipole moment for both 12.The first emission lines of the hydrogen atomic
members? spectrum in the Balmer series appear at:
(a) NO2 and CO2 (a)5R/36 cm–1
(b) NO2 and O3 (b)3R/4 cm–1
(c) SiF4 and CO2 (c)7R/144 cm–1
(d) SiF4 and NO2 (d)9R/400 cm–1
4.Which one of the following does not contain 13. What should be the maximum number of lines
coordinate bond? obtained in the spectrum, if the total number of
(a) BH−4 energy levels is five?
(b) NH−4 (a)10
(c) CO2−3 (b)6
(d) H3O+ (c)4
5.Amongst H2O, H2S, H2Se and H2Te the one with (d)2
the highest boiling point is 14. We can distinguish two electrons occupying the
(a) H2O because of hydrogen bonding same orbital by:
(b) H2Te because of higher molecular weight (a)Principal quantum number
(c) H2S because of hydrogen bonding (b)Azimuthal quantum number
(d) H2Se because of lower molecular weight. (c)Magnetic quantum number
6.Among KO2, AlO−2, BaO2 and NO+2 unpaired (d)Spin quantum number
electron is present in 15.Electronic configuration of the outer shell of the
(a) NO+2 and BaO2 element Gd with atomic number 64 is
(b) KO2 and AIO−2 (a) 4f4 5d5 6s1
(c) KG2 only (b) 4f3 5d5 6s2
(d) BaO2 only (c) 4f5 5d4 6s1
7.In which of the following pairs the two species (d) 4f7 5d1 6s2
have identical bond order?
(a) N−2, O2−2 16. Find the amount of dibasic acid with mol.
(b) N+2, O−2 weight 200 required to produce 100 ml of 0.1 N
(c) N−2, O+2 aqueous solution.
(d) O+2, N2−2 (a) 2 g
8.Which of the following is not paramagnetic? (b) 10 g
(a) N+2 (c) 20 g
(b) CO (d) 1 g
(c) O−2 17.What is the mole fraction of solute in 1 molal
(d) NO. aqueous solution?
9.Main axis of a diatomic molecule is Z. Atomic (a) 0.018
orbitals px and py overlap to form which of the (b) 0.009
following orbital? (c) 0.036
(a) π-molecular orbital (d) 0.027
(b) σ-molecular orbital
(c) δ-molecular orbital
(d) no bond will form
 18.Which of the following statement is correct? 26.Given : XNa2HAsO3 +YNaBrO3+ZHCl → NaBr +
a) The value of Avogadro’s number is H3AsO4 + NaCl
6.022×1022 atoms The values of X, Y and Z in the above redox reaction
b) One molecule of any substance contains are respectively :
Avogadro’s number of particles (1) 2, 1, 3
c) One mole is the amount of a substance that (2) 3, 1, 6
contains as many particles as there are atoms in (3) 2, 1, 2
exactly 12 g of the carbon atom (4) 3, 1, 4
d) 1 u is not equal to Ma/NA 27. In which of the following reaction H2O2 acts as a
19.Which one of the following pairs of gases reducing agent ?
contains the same number of molecules (1) H2O2 + 2H+ + 2e– → 2H2O
(a) 16 g of O2 and 14 g of N2 (2) H2O2 -2e– → O2+2H+
(b) 8 g of O2 and 22 g of CO2 (3) H2O2 + 2e– → 2OH–
(c) 28 g of N2 and 22 g of CO2 (4) H2O2 + 2OH– -2e– → O2 + 2H2O
(d) 32 g of O2 and 32 g of N2 (1) (1), (3)
20. The ratio of mass percent of C and H of an (2) (2), (4)
organic compound (CxHyOz) is 6 : 1. If one molecule (3) (1), (2)
of the above compound ( CxHyOZ ) contains half as (4) (3), (4)
much oxygen as required to burn one molecule of 28. How many electrons are involved in the
compound CXHY completely to CO2 and H2O. The following redox reaction?
empirical formula of compound CxHyOz is : Cr2O72- + Fe2+ + C2O42- → Cr3+ + Fe3+ +
(1) C2H4O CO2 (Unbalanced)
(2) C3H4O2 (1) 3
(3) C2H4O3 (2) 4
(4) C3H6O3 (3) 5
(4) 6
21.The increasing order of the ionic radii of the 29. Which of the following is incorrect regarding
given isoelectronic species is? the first law of thermodynamics?
(1) K+, S2-, Ca2+, Cl– (a) It introduces the concept of internal energy
(2) Cl–, Ca2+, K+,S2- (b) It introduces the concept of entropy
(3) S2-, Cl–, Ca2+, K+ (c) It is not applicable to any cyclic process
(4) Ca2+, K+, Cl–, S2 (d) It is a restatement of the principle of
conservation of energy
22. Which of the following oxides is amphoteric in 30. Which of the following statements is correct for
character? (a) SnO2 (b) CO2 (c) SiO2 (d) CaO any thermodynamic system?
(a) The internal energy changes in all processes
23. In the long form of the periodic table, the (b) Internal energy and entropy are state functions
valence shell electronic configuration of 5s²5p4 (c) The change in entropy can never be zero
corresponds to the element present in: (d) The work done in an adiabatic process is always
(a) Group 16 and period 6 (b) Group 17 and period 6 zero
(c) Group 16 and period 5 (d) Group 17 and period 7 31. Which statement is incorrect?
(a) All reversible cycles have the same efficiency
24. Which of the following ion will form most water (b) The reversible cycle has more efficiency than an
soluble hydroxide? (a) K+ (b) Ni2+ (c) Zn2+ (d) Al3+ irreversible one
(c) Carnot cycle is a reversible one
25. Eka aluminium and Eka silicon are now known (d) Carnot cycle has the maximum efficiency in all
as: (a) Ga and Ge (b) Al and Si (c) Fe and S (d) H+ and cycles
Si 32. 100 g of water is heated from 30 °C to 50 °C.
Ignoring the slight expansion of the water, the
change in its internal energy is (specific heat of
water is 4184 J kg–1 K–1)
(a) 4.2 kJ 39. For the reaction, 2SO2(g) + O2(g) ⇌ 2SO3(g), ∆H = -
(b) 8.4 kJ 57.2 kJ mol–1 and Kc = 1.7 × 1016 Which of the
(c) 84 kJ following statements is incorrect?
(d) 2.1 kJ (a) The equilibrium will shift in the forward direction
33. One mole of a monoatomic gas is heated at a as the pressure increases.
constant pressure of 1 atmosphere from OK to (b) The addition of inert gas at constant volume will
100K. If the gas constant R=8.32 J/mol K, the not affect the equilibrium constant.
change in internal energy of the gas is (c) The equilibrium constant is large, suggestive of
approximately reaction going to completion and so no catalyst is
(a) 2.3 J required.
(b) 46 J (d) The equilibrium constant decreases as the
(c) 8.67 × 103J temperature increases.
(d) 1.25 x l03J 40. A vessel at 1000 K contains CO2 with a pressure
34. What will be the value of ΔH, if the forward and of 0.5 atm. Some of the CO2 is converted into CO on
reverse reactions have the same energy of the addition of graphite. If the total pressure at
activation? equilibrium is 0.8 atm, the value of K is
(a) ΔH = ΔG = ΔS = 0 (a) 1.8 atm
(b) ΔS = 0 (b) 3 atm
(c) ΔG = 0 (c) 0.3 atm
(d) ΔH = 0 (d) 0.18 atm
35. Find the pH of a solution when 0.01 M HCl and
0.1 M NaOH are mixed in equal volumes
(a) 12.65
(b) 1.04
(c) 7.0
(d) 2.0
36. The equilibrium constant is 278 for the reaction

at the same temperature, what will be the

equilibrium constant for the following reaction?

(a) 6 x 10-2
(b) 1.8 x 10-3
(c) 1.3 x 10-5
(d) 3.6 x 10-5
37. On increasing the concentration of reactants in
a reversible reaction, then equilibrium constant will
(a) depend on the concentration
(b) increase
(c) unchanged
(d) decrease
38. Find the conjugate acid of NH2–
(a) NH3
(b) NH4OH
(c) NH4+
(d) NH2–