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Chemsheets AS 1215 QC Equilibria D ANS

The document provides calculations to determine the moles at equilibrium for several chemical reactions. It also includes questions about how yield and equilibrium constant would change with increases in pressure or temperature based on thermodynamic properties of the reactions.

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93 views1 page

Chemsheets AS 1215 QC Equilibria D ANS

The document provides calculations to determine the moles at equilibrium for several chemical reactions. It also includes questions about how yield and equilibrium constant would change with increases in pressure or temperature based on thermodynamic properties of the reactions.

Uploaded by

Marina
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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EQUILIBRIA (D)

1 Calculate the moles at equilibrium in each of the following.

N2 + 3H2 ⇌ 2NH3 2SO2 + O2 ⇌ 2 SO3


a initial moles 1.0 2.0 0 c initial moles 5.0 2.0 0
change in moles –0.3 –0.9 +0.6 change in moles –1.2 –0.6 +1.2
equilibrium moles 0.7 1.1 0.6 equilibrium moles 3.8 1.4 1.2

b H 2 + I2 ⇌ 2HI d PCl5 ⇌ PCl3 + Cl2


initial mole 3.0 4.0 0 initial mole 2.0 0 1.0
change in moles –1.4 –1.4 +2.8 change in moles –0.4 +0.4 +0.4
equilibrium moles 1.6 2.6 2.8 equilibrium moles 1.6 0.4 1.4

2 A and B react to form C and D in an equilibrium in a closed system. At temperature T, the equilibrium
constant Kc has a value of 4.72. The forward reaction is exothermic.
–1
A(g) + B(g) ⇌ C(g) + D(g) ΔH = –57 kJ mol

a What would happen to the yield of C and Kc if the pressure was increased. Explain your answer.

equilibrium position does not move as there are same number of gas particles on each side
no effect on yield of C
no change in Kc

b What would happen to the yield of C and Kc if the temperature was increased. Explain your answer.

equilibrium position moves left in endothermic direction to oppose increase in temperature


decreases yield of C
Kc decreases

c 2.0 moles of A and 2.0 moles of B were placed in a flask at temperature T. Calculate the number of
moles of C in the equilibrium mixture.

A(g) + B(g) ⇌ C(g) + D(g)


moles at start 2.0 2.0 0 0
change in moles –x –x x x
moles at equilibrium 2–x 2–x x x

𝒙 𝟐
𝑪 [𝑫] 𝑽
𝑲𝒄 = =
𝟐!𝒙 𝟐
= 𝟒. 𝟕𝟐
𝑨 [𝑩]
𝑽

square rooting both sides and cancelling V:


𝒙
= 𝟐. 𝟏𝟕
𝟐!𝒙
𝒙 = 𝟐. 𝟏𝟕(𝟐 − 𝒙)
𝒙 = 𝟒. 𝟑𝟒 – 𝟐. 𝟏𝟕𝒙)
𝟑. 𝟏𝟕𝒙 = 𝟒. 𝟑𝟒 𝒙 = 𝟏. 𝟑𝟕

© www.CHEMSHEETS.co.uk 19-Apr-2017 Chemsheets AS 1215

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