Atomic Trends Assignment
Atomic Trends Assignment
Atomic Radius: the distance from the center of the nucleus to the outer most electrons in an
atom.
Ionic Radius: the distance from the center of the nucleus to the outer most electrons in an ion.
Effective Nuclear charge (Zeff): a measure of the pull of the protons in the nucleus on the valence
electrons in an atom/ion.
Zeff = atomic number – shielding electrons
Note: shielding electrons for our purposes are the inner electrons that block some
of the pull of the nucleus on the electrons that are farther out.
Example: Oxygen
b) Draw Bohr diagrams for hydrogen, lithium and sodium. Calculate the effective nuclear
charge for each atom and use this information to explain the atomic radius trend.
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a) the atomic radius increases.
b)
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2. a) As you go from lithium across a row what happens to the atomic radius?
Increases/decreases
b) Draw Bohr diagrams for lithium, beryllium and boron. Calculate the effective nuclear
charge for each of the three elements and use these values to explain the atomic radius
trend.
4. a) As you go from hydrogen down a column, what happens to the ionization energies?
Increases/decreases
b) Using your Bohr diagrams from question #1, explain this trend.
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a ) the ionization energies decrease.
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5. a) As you go from lithium across a row what happens to the ionization energies?
Increases/decreases
b) Using your Bohr diagrams from question #2, explain this trend.
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a) the ionization energies generally increase.
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b) Explain why this family wouldn’t have electronegativity values (Hint: draw the Bohr
diagram for Neon and calculate the Zeff to help you answer this.)
Noble gases, like Neon, don't usually have electronegativity values because they're very stable. If we look at
Neon's structure, it has 10 electrons and 10 protons. In Neon's Bohr diagram, there are 2 electrons in the first
shell and 8 electrons in the second shell, making it have a full outer shell. This full outer shell gives noble
gases like Neon stability, so they don't want to gain or lose electrons in reactions. When we calculate the
effective nuclear charge (Zeff) for Neon, it's relatively low because the outer electrons are well-shielded by
the filled inner shells. This means that the attraction for additional electrons is weak, leading to low
electronegativity______________________________________________________
values. So, noble gases don't usually have electronegativity values because they're already
happy with their______________________________________________________
full outer shells and don't need to grab or share electrons like other elements do.
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electronegativity.
9. a) Which property follows the same trend as ionization energy? ____________________
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b) Explain the above trend
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11. a) Compare the atomic radii for non-metals and the ionic radii for their negative ions. Are
the radii for the ions or atoms larger?
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The atomic radii for non-metals are generally larger than the ionic radii for their negative ions
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Non-metal atoms have small atomic radii due to their strong attraction for electrons.
However, when non-metal atoms gain electrons to form negative ions (anions), the additional electrons cause the electron cloud to expand, resulting in
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larger ionic radii for the anions compared to the atomic radii of the parent non-metal atoms.
.
13. Indicate which atom in each pair would have larger atomic radius.
a. Li or K e. Cl or Br
b. Ca or Ni f. Be or Ba
c. Ga or B g. Si or S
d. O or C h. Fe or Au
14. Indicate which ion in each pair would have smaller ionic radius.
a. K+ or O2- d. K+ or Cs+
b. Ba2+ or I- e. Fe2+ or Fe3+
c. Al3+ or P3- f. F- or S2-
15. Indicate which atom or ion in each pair would have larger ionization energy.
a. Na or O e. I or Ne
b. Be or Ba f. K or V
c. Ar or F g. Ca or Fr
d. Cu or Ra h. W or Se
16. Explain why there would be a large jump in ionization energy between the second and
third ionization energies for magnesium. (Draw a Bohr diagram to help you!)
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