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1700588571-Unit 3 Test - Mr. Samai

This document contains a chemistry test on chemical equilibrium with multiple choice and short answer questions. It tests knowledge of concepts like equilibrium constants, Le Chatelier's principle, and factors that affect equilibrium. Example questions include calculating pH, determining concentrations at equilibrium, and explaining how temperature, pressure, and concentration affect equilibrium.

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505 views5 pages

1700588571-Unit 3 Test - Mr. Samai

This document contains a chemistry test on chemical equilibrium with multiple choice and short answer questions. It tests knowledge of concepts like equilibrium constants, Le Chatelier's principle, and factors that affect equilibrium. Example questions include calculating pH, determining concentrations at equilibrium, and explaining how temperature, pressure, and concentration affect equilibrium.

Uploaded by

rovshanmirzakhanli
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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SCH4U – Ontario Virtual School [UNIT 3 TEST: EQUILIBRIUM] Mr. M.

Samai

K/U Comm T/I App


/15 /9 /10 /8
Knowledge / Understanding

1. When solid magnesium phosphate is in equilibrium with its ions, the ratio of magnesium ions to phosphate ions is:

a. 3:2 b. 2:3 c. 1 :2 d. 2:1

2. Which of the following can act as a Bronsted-Lowry acid or base in water?


a. CO32-(aq) c. HCO3 –(aq)
b. OH-(aq) d. N2(aq)

3. In a saturated solution of ammonium carbonate, the concentration of ammonium ions is 13.1 mol/L. What is the
𝐾sp of ammonium carbonate?
a. 1.12 × 103 b. 343 c. 4.50× 103 d. 2.25×103

4. The 𝐾a of 𝐻3𝑃𝑂4 is 7.1 × 10-3. What is the 𝐾b of its conjugate base 𝐻2𝑃𝑂4 - ?
a. 7.1 × 1011 c. 1.4 × 10-12
b. 1.4 ×1012 d. 7.1 × 10-11

5. In the following reaction, what are the two Bronsted-Lowry acids?


𝑁𝐻3 (aq) + 𝐻𝐶𝑙(aq) ↔ 𝑁𝐻4+ (aq) + Cl- (aq)

a. HCl and NH4+ b. HCl and Cl- c. NH3 and NH4+ d. NH3 and HCl

6. For the equilibrium system below, which of the following would increase the concentration of 𝐻2𝑂(g)?
𝐶(s) + 𝐻2𝑂(g) + 131𝑘𝐽 ↔ 𝐶𝑂(g) + 𝐻2(g)
a. Increased temperature c. Decreased container volume
b. Decreased [CO] d. Decreased pressure

7. For the equilibrium system below, which of the following would decrease the concentration of 𝑃𝐶𝑙3(g)?
𝑃𝐶𝑙3(g) + 𝐶𝑙2(g) ↔ 𝑃𝐶𝑙5(g) + 45𝑘𝐽
a. Increased [𝑃𝐶𝑙5] c. Increased temperature
b. Increased [𝐶𝑙2] d. Decreased pressure

8. The 𝐾sp expression for copper (II) sulfate is:


a. [𝐶𝑢𝑆𝑂4] b. [𝐶𝑢2+]2[𝑆𝑂42-]2 c. [𝐶𝑢2+]2[𝑆𝑂42-] d. [𝐶𝑢2+] [𝑆𝑂42-]
SCH4U – Ontario Virtual School [UNIT 3 TEST: EQUILIBRIUM] Mr. M. Samai

9. Consider the following equilibrium:


2𝐻𝐼(g) + 26kJ ↔ 𝐻2(g) + 𝐼2(g)
If some hydrogen gas were injected into the system at constant temperature and pressure, which of the
following would mostly likely occur?
a. Both a and c c. Increased [𝐻2] e. Increased [𝐻𝐼]
b. Decreased [𝐻𝐼] d. Both a and d f. Increased [𝐼2]

10. Which of the following is true about a chemical system in equilibrium?


a. The forward and reverse reaction rates become equal
b. All chemical reactions have stopped
c. The concentration of reactants is equal to the concentration of products
d. The system will remain at equilibrium regardless of any external factors

11. What is the correct equilibrium constant equation for the following equilibrium?

[CaO][CO2] [CaO][CO]2
a. 𝐾 = c. 𝐾 =
[CaCO3] [CaCO3]
b. 𝐾 = [𝐶𝑂2] d. 𝐾 = [CaO][𝐶𝑂2]

12. Which of the following statements is verifiably true about this equilibrium?
𝑃𝐶𝑙5(g) ↔ 𝑃𝐶𝑙3(g) + 𝐶𝑙2(g) K = 275
a. 𝑃𝐶𝑙3 will be in higher concentration than 𝑃𝐶𝑙5 at equilibrium.
b. The reactants are favored in this reaction.
c. If a fixed container is filled with 𝑃𝐶𝑙5 gas, the pressure of the container will decrease over time.
d. 𝑃𝐶𝑙5 will be in higher concentration than any other components.

13. The pH of a 0.1M solution of H2SO4(aq) at 25°C is .

14. The pH of a 0.23M solution of Ca (OH)2 at 25°C is .

15. Write an equilibrium equation for the formation of a precipitate when iron (II) nitrate solution is combined with
ammonium carbonate solution:
SCH4U – Ontario Virtual School [UNIT 3 TEST: EQUILIBRIUM] Mr. M. Samai

Thinking/Inquiry
16. Calculate the pH of a solution of Propanoic acid of concentration 0.2M/L, given that the pKa of propanoic acid is
4.82. (4)

17. Ethanol and ethanoic acid were mixed and allowed to reach equilibrium at a temperature T. The mixture
which initially contained 1 mole of ethanol and 2 moles of ethanoic acid in 1 L now contains 0.35mol dm -3 at
equilibrium.

a. Calculate the concentrations of the other species in the equilibrium mixture (3 marks).

b. Determine Kc and state its units (3 marks).


SCH4U – Ontario Virtual School [UNIT 3 TEST: EQUILIBRIUM] Mr. M. Samai

Communication

(18). There are various factors that affect an equilibrium. Give 3 of these factors and explain using examples and
equations how an equilibrium is affected by these factors. Please remember that this is a communication question so that
you are communicating your understanding of the factors that affect and equilibrium. (9 marks).

1.

2.

3.
SCH4U – Ontario Virtual School [UNIT 3 TEST: EQUILIBRIUM] Mr. M. Samai

Application
18. The Haber-Bosch process, devised in the early 20th century, revolutionized global industry. It provides a way of
“fixing” atmospheric nitrogen into ammonia, allowing for the production of fertilizers and the many nitrogen-
based chemicals we use today. The reaction is carried out in numerous industrial facilities all over the world:
𝑁4(g) + 3𝐻2(g) → 2𝑁𝐻3(g) ∆𝐻 < 0

a. Write a 𝐾eq equation for the reaction. (2)

b. Under what conditions would this reaction ideally take place? Explain fully three different
factors or considerations that would help increase the production of ammonia except for a
catalyst. (6)

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