Page 1/9

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 29.06.2021 Version number 4 Revision: 29.06.2021

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
· 1.1 Product identifier
· Trade name: GLUMA Bond universal
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture Dental bonding material
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Kulzer GmbH
Leipziger Straße 2, 63450 Hanau (Germany) Tel.: +49 (0)800 4372522
· Informing department: E-Mail: msds@kulzer-dental.com
· 1.4 Emergency telephone number: Emergency CONTACT (24-Hour-Number): +49 (0)6132-84463

* SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
Flam. Liq. 2 H225 Highly flammable liquid and vapour.
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2 H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H336 May cause drowsiness or dizziness.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms

GHS02 GHS07

· Signal word Danger

· Hazard-determining components of labelling:
7,7,9(or 7,9,9) -tr imethyl-4,13-diox o-3,14-diox a- 5,12- diazahex adecane- 1,16- diyl
bismethacrylate
acetone
4-methacryloxyethyltrimellitic acid anhydride
· Hazard statements
H225 Highly flammable liquid and vapour.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H336 May cause drowsiness or dizziness.
H412 Harmful to aquatic life with long lasting effects.
· Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P261 Avoid breathing mist/vapours/spray.
P273 Avoid release to the environment.
(Contd. on page 2)
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 Page 2/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 29.06.2021 Version number 4 Revision: 29.06.2021

Trade name: GLUMA Bond universal

(Contd. of page 1)
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water [or shower].
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
· Additional information:
Contains isocyanates. May produce an allergic reaction.
· 2.3 Other hazards -
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients

· 3.2 Chemical characterisation: Mixtures
· Description: -
· Dangerous components:
CAS: 67-64-1 acetone 25-50%
EINECS: 200-662-2 Flam. Liq. 2, H225
Reg.nr.: 01-2119471330-49-xxxx Eye Irrit. 2, H319; STOT SE 3, H336

CAS: 72869-86-4 7,7,9(or 7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12- ≥10-<25%

EINECS: 276-957-5 diazahexadecane-1,16-diyl bismethacrylate
Reg.nr.: 01-2120751202-68-xxxx Aquatic Chronic 2, H411
Skin Sens. 1B, H317
CAS: 70293-55-9 4-methacryloxyethyltrimellitic acid anhydride 10-25%
Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1,
H317
· Additional information For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· After inhalation
Supply fresh air and call for doctor for safety reasons.
In case of unconsciousness bring patient into stable side position for transport.
· After skin contact If skin irritation continues, consult a doctor.
· After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor.
· After swallowing
In case of persistent symptoms consult doctor.
Rinse out mouth and then drink plenty of water.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 29.06.2021 Version number 4 Revision: 29.06.2021

Trade name: GLUMA Bond universal

(Contd. of page 2)
· For safety reasons unsuitable extinguishing agents Water with a full water jet.
· 5.2 Special hazards arising from the substance or mixture
Can form explosive gas-air mixtures.
Formation of toxic gases is possible during heating or in case of fire.
· 5.3 Advice for firefighters
· Protective equipment: No special measures required.
· Additional information -

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions: Prevent material from reaching sewage system, holes and cellars.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (diatomite, universal binders, for small amounts tissues).
Ensure adequate ventilation.
Send for recovery or disposal in suitable containers.
· 6.4 Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
-

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling Keep containers tightly sealed.
· Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage
· Requirements to be met by storerooms and containers: Store in cool location.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Keep receptacle tightly sealed.
Protect from the effects of light.
Store in cool, dry conditions in well sealed containers.
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· 8.1 Control parameters
· Additional information about design of technical systems: No further data; see item 7.
· Components with critical values that require monitoring at the workplace:
67-64-1 acetone
WEL Short-term value: 3620 mg/m³, 1500 ppm
Long-term value: 1210 mg/m³, 500 ppm
· DNELs
67-64-1 acetone
Oral ge.pop., l.te, syst. 62 mg/Kg (nd)
(Contd. on page 4)
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 Page 4/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 29.06.2021 Version number 4 Revision: 29.06.2021

Trade name: GLUMA Bond universal

(Contd. of page 3)
Dermal worker industr., l.te., syst. 186 mg/Kg/d (nd)
ge.pop., l.te, syst. 62 mg/Kg/d (nd)
Inhalative worker industr., l.te., syst. 1210 mg/m3 (nd)
worker industr., l.te., local 2420 mg/m3 (nd)
ge.pop., l.te, syst. 200 mg/m3 (nd)
72869-86-4 7,7,9(or 7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diazahexadecane-1,16-diyl
bismethacrylate
Oral ge.pop., l.te, syst. 0.3 mg/Kg (nd)
Dermal worker industr., l.te., syst. 1.3 mg/Kg/d (nd)
ge.pop., l.te, syst. 0.7 mg/Kg/d (nd)
Inhalative worker industr., l.te., syst. 3.3 mg/m3 (nd)
ge.pop., l.te, syst. 0.6 mg/m3 (nd)
· PNECs
67-64-1 acetone
freshwater 10.6 mg/l (nd)
marine water 1.06 mg/l (rabbit)
STP 19.5 mg/l (nd)
sedim., dw, fre.wat. 30.4 mg/Kg (nd)
sedim., dw, mar.wat. 3.04 mg/Kg (nd)
soil,dw 0.112 mg/Kg (nd)
72869-86-4 7,7,9(or 7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diazahexadecane-1,16-diyl
bismethacrylate
freshwater 0.01 mg/l (nd)
marine water 0.001 mg/l (nd)
STP 3.61 mg/l (nd)
sedim., dw, fre.wat. 4.56 mg/Kg (nd)
sedim., dw, mar.wat. 0.46 mg/Kg (nd)
soil,dw 0.91 mg/Kg (nd)
· Additional information: The lists that were valid during the compilation were used as basis.
· 8.2 Exposure controls
· Personal protective equipment
· General protective and hygienic measures
Avoid contact with the eyes.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
· Breathing equipment: Use breathing protection against the effects of fumes/dust/aerosol.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and
the degradation
If skin contact cannot be avoided, protective gloves are recommended to avoid possible
sensitization.
Check protective gloves prior to each use for their proper condition.
recommended
(Contd. on page 5)
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 Page 5/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 29.06.2021 Version number 4 Revision: 29.06.2021

Trade name: GLUMA Bond universal

(Contd. of page 4)
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on
further marks of quality and varies from manufacturer to manufacturer. As the product is a
preparation of several substances, the resistance of the glove material can not be
calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective
gloves and has to be observed.
· For the permanent contact of a maximum of 15 minutes gloves made of the following
materials are suitable:
Butyl rubber, BR
Nitrile rubber, NBR
· Eye protection: Tightly sealed safety glasses.
· Body protection: Light weight protective clothing

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
· Form: Liquid
· Colour: Clear
· Smell: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
· Melting point/freezing point: Not determined
· Initial boiling point and boiling range: Not determined
· Flash point: -19 °C
· Inflammability (solid, gaseous) Not applicable.
· Decomposition temperature: Not determined.
· Self-inflammability: Product is not selfigniting.
· Explosive properties: Product is not explosive. However, formation of
explosive air/vapour mixtures is possible.
· Critical values for explosion:
· Lower: Not determined.
· Upper: Not determined.
· Steam pressure: Not determined.
· Density at 20 °C 0.99 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
· Water: Partly miscible
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:
· dynamic: Not determined.
(Contd. on page 6)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 29.06.2021 Version number 4 Revision: 29.06.2021

Trade name: GLUMA Bond universal

(Contd. of page 5)
· kinematic: Not determined.
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Conditions to be avoided: Protect from heat and direct sunlight.
· 10.3 Possibility of hazardous reactions No dangerous reactions known
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: None
· Additional information: -

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values that are relevant for classification:
67-64-1 acetone
Oral LD50 5800 mg/kg (rat)
Dermal LD50 >15800 mg/kg (rabbit)
Inhalative LC50/4 h 76 mg/l (rat)
72869-86-4 7,7,9(or 7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diazahexadecane-1,16-diyl
bismethacrylate
Oral LD50 >5000 mg/kg (rat) (OECD 401)
Dermal LD50 >2000 mg/kg (rat) (OECD 402)
70293-55-9 4-methacryloxyethyltrimellitic acid anhydride
Oral LD50 >2000 mg/kg (mouse)
Dermal LD50 >2000 mg/kg (mouse)
· Primary irritant effect:
· Skin corrosion/irritation
Causes skin irritation.
· Serious eye damage/irritation
Causes serious eye irritation.
· Respiratory or skin sensitisation
May cause an allergic skin reaction.
· Additional toxicological information:
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure
May cause drowsiness or dizziness.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
GB
(Contd. on page 7)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 29.06.2021 Version number 4 Revision: 29.06.2021

Trade name: GLUMA Bond universal

(Contd. of page 6)

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity:
67-64-1 acetone
EC50/48h 8800 mg/l (daphnia)
LC50/96h 6210 mg/l (fish) (OECD 203)
72869-86-4 7,7,9(or 7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diazahexadecane-1,16-diyl
bismethacrylate
EC50/48h >1.2 mg/l (daphnia) (OECD 202)
LC50/96h 10.1 mg/l (fish) (OECD 203)
ErC50 / 72 h >0.68 mg/l (algae) (OECD 201)
NOEC / 72h 0.21 mg/l (algae) (OECD 201)
· 12.2 Persistence and degradability
67-64-1 acetone
Biodegradation 90.9 % /28d (nd) (OECD 301D)
72869-86-4 7,7,9(or 7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diazahexadecane-1,16-diyl
bismethacrylate
Biodegradation 22 % /28d (nd) (OECD 301B; ISO/ 9439/ EEC 92/69/V, C.4-C)
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Do not allow product to reach ground water, water bodies or sewage system.
Danger to drinking water if even small quantities leak into soil.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
Disposal must be made according to official regulations.
Must not be disposed of together with household garbage. Do not allow product to reach sewage
system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information

· 14.1 UN-Number
· ADR, IMDG, IATA UN1090
· 14.2 UN proper shipping name
· ADR 1090 ACETONE, mixture
· IMDG, IATA ACETONE, mixture
(Contd. on page 8)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 29.06.2021 Version number 4 Revision: 29.06.2021

Trade name: GLUMA Bond universal

(Contd. of page 7)
· 14.3 Transport hazard class(es)
· ADR

· Class 3 (F1) Flammable liquids.

· Label 3
· IMDG, IATA

· Class 3 Flammable liquids.

· Label 3
· 14.4 Packing group
· ADR, IMDG, IATA II
· 14.5 Environmental hazards:
· Marine pollutant: No
· 14.6 Special precautions for user Warning: Flammable liquids.
· Kemler Number: 33
· EMS Number: F-E,S-D
· 14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· Transport/Additional information: -
· ADR
· Limited quantities (LQ) 1L
· Transport category 2
· Tunnel restriction code D/E
· UN "Model Regulation": UN1090, ACETONE, mixture, 3, II

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
No further relevant information available.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

These data are based on our present knowledge. However, they shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H225 Highly flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
(Contd. on page 9)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 29.06.2021 Version number 4 Revision: 29.06.2021

Trade name: GLUMA Bond universal

(Contd. of page 8)
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
· Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement
Concerning the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids – Category 2
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Skin Sens. 1: Skin sensitisation – Category 1
Skin Sens. 1B: Skin sensitisation – Category 1B
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered.
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52.1.17