Chem PP3 QNS
Chem PP3 QNS
CANDIDATE’S SIGNATURE…………………………….
233/3
CHEMISTRY
PAPER 3
TIME: 2 HOURS
INSTRUCTIONS TO CANDIDATES:
(i) Write your name and index number in the spaces provided above.
(ii) Sign and write the date of examination in the spaces provided above.
(iii) Answer ALL the questions in the spaces provided.
(iv) Mathematical tables and silent electronic calculators may be used.
(v) All working must be clearly shown where necessary.
(vi) Candidates should check the question paper to ascertain that all the pages
are printed as indicated and that no questions are missing
FOR EXAMINER’S USE ONLY:
2 12
3 13
Total Score 40
QUESTION 1
You are provided with solution K and L
1
Solution K is 1M H2SO4
Solution L contains 8.7g of the hydroxide of metal M (with formulae MOH) in
600cm3 of the solution
You are required to carry out the experiment to determine;
i. Concentration of solution L
ii. R.A.M of metal M
Procedure
1. Measure 75cm3 of solution K and put into a clean 250cm3 volumetric flask and
add distilled water up to the mark
-label this solution W
2. Fill a clean burette with solution W
3. Pipette 25cm3 of solution L into a clean conical flask and add 2 drops of
phenolphthalein indicator
4. Titrate the solution W in the burette against solution L in the conical flask and
record the results in the table below
5. Repeat {3} and {4} above as you fill the table below.
TABLE 1
I II III
3
Final burette reading {cm }
Initial burette reading {cm3}
Volume of solution W used
{cm3}
(4
mks)
{a} Calculate the;
(i) Average volume of solution W used (1mk)
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………………………………………………
(iii) Number of moles of solution W that reacted with each 25cm3 portion
of solution L
[2mks]
2
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………………………………………………
{b}Calculate the;
{i} Number of moles of the metal hydroxide {MOH} in solution L that
reacted with each portion of solution W [2mks]
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………
QUESTION 2
3
Solution N is 2M HCl
Solution P is 0.16M sodium thiosulphate
You are required to carry out the experiment below to determine how
concentration affects the rate of reaction between HCl and sodium thiosulphate
solutions
PROCEDURE
TABLE 2
Expt
1 2 3 4 5
3
Volume of solution p(cm ) 25 20 15 10 5
Volume of water added to solution 0 5 10 15 20
p{cm3}
Volume of solution N 10 10 10 10 10
Time taken for the cross to become
invisible [in seconds]
1
S-1
t
(4mks)
1
(a) Plot a graph of t against volume of solution P on the grid provided (4mks)
4
{b} From the graph
(i) Determine the time taken for the cross to become invisible when
12.5cm3 of solution P is used (2mks)
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………
5
{ii} Explain the effect of concentration on the rate of reaction between HCl
and sodium thiosulphate solution (2mks)
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………………………………………………
………………………………………………………………………………………
QUESTION 3
You are provided with solids Q
You are required to carry out the tests below as you record your observations
and inferences
(i) SOLID Q
-Add about 5cm3 of distilled water to solid Q, shake the mixture thoroughly
for a while and then filter it
NOTE: Retain both the filtrate and the residue for the tests below
OBSERVATIONS INFERENCES
(1mk) (2mk)
6
ii) Scoop the 2nd portion on a metallic spatula and ignite on a non-luminous
flame
OBSERVATIONS INFERENCES
(1mk) (1mk)
OBSERVATIONS INFERENCES
(1mk) (1mk)
OBSERVATIONS INFERENCES
(1mk) (1mk)
7
B (i) Put the residue in a test tube and add about 2cm3 of HNO3
OBSERVATIONS INFERENCES
(1mk) (1mk)
OBSERVATIONS INFERENCES
(1mk) (1mk)